Search Results (132)

As a critical trace gas and a sensitive indicator of climate change, water vapor (H₂O) plays a pivotal role in regulating the Earth’s radiative budget and middle-atmospheric chemical cycles. In this study, H₂O measurements from the Sounding of the Atmosphere using a Broadband Emission Radiometry (SABER) instrument on the Thermosphere Ionosphere Mesosphere Energetics and Dynamics (TIMED) satellite are analyzed to characterize the H₂O spatiotemporal distribution throughout the stratosphere–mesosphere–lower thermosphere (SMLT) region. Using eigen analysis, the bimonthly mean H₂O across different latitude bins between 2002 and 2025 is decomposed into four empirical orthogonal functions (EOFs). Results indicate that stratospheric water vapor remains relatively stable with weak latitudinal dependence, whereas H₂O in the mesosphere–lower thermosphere (MLT) at middle-to-high latitudes exhibits pronounced seasonal variations and distinct hemispheric antisymmetry. The first mode captures a global H₂O long-term increasing trend. Both EOF1 and EOF2 are associated with solar activity and the El Niño–Southern Oscillation (ENSO) to varying degrees, indicating that these dominant modes are driven by multiple concurrent forcing factors. EOF3 correlates with the Quasi-Biennial Oscillation (QBO), suggesting links to QBO-driven atmospheric dynamical processes, whereas EOF4 demonstrates no significant associations with natural activity indices, suggesting perturbations arising from alternative atmospheric mechanisms. By systematically applying EOF analysis to a 24-year dataset of H₂O observations in the SMLT region, this study characterizes the principal distribution patterns and evolutionary characteristics of SMLT H₂O. Through correlation analyses with natural forcing indices, the complex driving mechanisms governing its variability are elucidated. This work provides a comprehensive observational framework for SMLT water vapor variability, enhancing assessments of SMLT H₂O responses to long-term climate change and refining the understanding of the Earth–atmosphere system. Furthermore, these findings provide critical data support for the subsequent development and optimization of SMLT water vapor models. Full article

In this study, Ti-Co-Ce getter films were deposited via magnetron sputtering to investigate their activation mechanism—the thermal removal of surface passivation layers to restore gas sorption capability. The morphology before and after film activation was characterized using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The oxygen content on the film surface before and after activation was measured using an energy-dispersive X-ray spectrometer (EDS), and gas desorption during activation was monitored with a quadrupole mass spectrometer (QMS). The combined results confirmed the absence of O₂ desorption during activation, suggesting oxygen migration into the film bulk. Crucially, in situ X-ray photoelectron spectroscopy (XPS) combined with controlled Ar⁺ ion sputtering depth profiling (0–30 nm) was employed to directly probe the chemical-state evolution within the thin film before and after thermal activation at 400 °C, thereby providing direct evidence of the activation dynamics. The data reveal that within the 0–10 nm near-surface region, a strong oxygen chemical potential gradient drives rapid oxide reduction and inward migration of lattice oxygen. At depths of 20–30 nm, moderate reduction coupled with oxygen enrichment induces phase separation, while around 30 nm, a dynamic equilibrium between oxygen inflow and outflow is established. These findings provide a theoretical basis for optimizing activation processes and guiding the development of low-temperature getter materials. This work is particularly relevant for MEMS, vacuum electronics, and other applications with stringent thermal budgets, expanding the design possibilities for heat-sensitive device integration. Full article

Eutrophication is a pervasive issue in Mediterranean reservoirs, where external nutrient inputs and internal sediment releases interact to impair water quality and ecological stability. This study assessed the trophic condition of the artificial lake Cuga in Sardinia (Italy), mainly used for irrigation and providing potable water, by integrating watershed nutrient load estimates, inter-lake transfers, and internal phosphorus release. Field campaigns between July 2022 and May 2023 provided bi-monthly measurements of physical, chemical, and biological parameters, complemented by GIS-based land cover analysis and export coefficient modeling to quantify spatial nutrient sources. Additional phosphorus inputs from water transfers with a nearby reservoir were calculated, while internal sediment release was estimated using a calibrated mass balance model. Results revealed high nutrient concentrations, with mean total phosphorus of 128 mg P m⁻³, chlorophyll a averaging 9.9 mg m⁻³, and Secchi depth below 1 m, classifying the reservoir as eutrophic to hypertrophic under OECD and Carlson indices. Spatial loads were dominated by agricultural areas, while inter-lake transfers and internal sediment release contributed substantially to the overall phosphorus budget. The predictive Vollenweider model closely matched the observed conditions, confirming the robustness of the combined approach. Maintaining good ecological status in Mediterranean reservoirs is essential for safeguarding human well-being, as eutrophication degrades drinking-water quality, increases treatment costs, and can promote toxin-producing algal blooms with direct implications for public health. These findings highlight the need for integrated management strategies addressing both external and internal nutrient sources to mitigate eutrophication in Mediterranean reservoirs, which affects the ecosystem functioning and the related human needs and well-being. Full article

Recent measurements performed by the LUNA(Laboratory for Underground Nuclear Astrophysics) collaboration between 2019 and 2024 have provided the most precise direct determinations to date of several key reaction rates in the NeNa cycle, specifically the ²⁰Ne(p,γ)²¹Na and the ²²Ne(p,γ)²³Na reactions, as well as its bridge to the MgAl cycle, i.e., the ²³Na(p,γ)²⁴Mg reaction. Despite their improved accuracy, these updated rates are not yet consistently incorporated into widely used nuclear reaction network compilations. We explore the astrophysical impact of adopting the new LUNA rates by performing nucleosynthesis calculations, focusing on the case of ²⁶Al nucleosynthesis and considering four different stellar environments: low-mass AGB stars, massive stars, very massive stars and core-collapse supernovae. Our results show substantial sensitivity of ²⁶Al production to the revised rates. In the AGB model, the surface ²⁶Al abundance decreases by up to 30%, while in the massive star model, the ²⁶Al abundance in the C-burning shell increases by 51%. In contrast, the impact on both the ²⁶Al yields ejected by very massive stars and on the explosive nucleosynthesis in the supernova model is negligible. These findings have direct implications for galactic chemical evolution, the global budget of ²⁶Al, and theoretical predictions of the ⁶⁰Fe/²⁶Al ratio, which will be critically tested by forthcoming γ-ray observations from missions such as the Compton Spectrometer and Imager (COSI). Full article

Blasting operations associated with in-pit ramp construction in open-pit mines generate gaseous emissions originating from both explosive detonation and diesel-powered drilling and loading equipment. The research object of this study is the ramp construction process in an operating open-pit quarry, and the objective is to comparatively evaluate gaseous emissions across alternative blasting scenarios to support emission-aware operational decision-making. Five realistic blasting scenarios are assessed using a combined methodology that integrates laboratory fume index data for ANFO, emulsion explosives, and dynamite with diesel-emission estimates derived from non-road mobile machinery inventory factors. Laboratory detonation tests provide standardized upper-bound emission potentials for CO_x and NO_x, while drilling and loading emissions are quantified using a fuel-based inventory approach. The results show that the dominant contribution to total mass emissions arises from diesel combustion during drilling and loading, consistent with studies on real-world non-road mobile machinery inventory factors. Detonation fumes, although chemically concentrated and relevant for short-term exposure risk, represent a smaller share of the mass-based emission budget. Among the explosive types, bulk emulsions consistently exhibit lower toxic-gas emission indices than ANFO, attributable to their more uniform microstructure and a moderated reaction temperature. Dynamite demonstrates the lowest fume potential but is operationally less scalable for large open-pit patterns due to manual loading. Uncertainty analysis indicates that both laboratory-derived fume indices and diesel emission factors introduce systematic variability: laboratory tests tend to overestimate detonation fumes, while inventory-based diesel estimates may underestimate real-world NO_x and particulate emissions. Notwithstanding these limitations, the scenario-based framework developed here provides a robust basis for comparative evaluation of blasting strategies during ramp construction. The findings support increased use of emulsion explosives and emphasize the importance of moisture management, field-integrated gas monitoring, and improved characterization of diesel-equipment duty cycles. Full article

The behavior of the carbon cycle within the Land-Ocean Aquatic Continuum (LOAC) is shaped not only by aquatic processes but also by chemical interactions occurring at the atmosphere–water interface. In particular, the transport of acid rain precursors such as SO₂ and NO_x to surface waters via deposition can alter the water’s pH balance, thereby affecting Dissolved Inorganic Carbon (DIC) fractions and CO₂ emission potential. In this study, air quality measurements from three monitoring stations (Bosna, Karatay, and Meram) in Konya province of Türkiye, along with precipitation and temperature data from a representative meteorological station for the period 2021–2023, were analyzed using the Mann–Kendall Trend Test. Additionally, seasonal pH values of groundwater were examined, and their trends were compared with those of the other variables. The findings reveal striking differences on a station basis. At the Bosna station, while NO (Z = 10.80), NO₂ (Z = 9.47), and NO_x (Z = 10.04) showed strong increasing trends, O₃ decreased significantly (Z = −15.14). At the Karatay station, significant increasing trends were detected for CO (Z = 10.01), PM₁₀ (Z = 8.59), SO₂ (Z = 5.55), and NO_x (Z = 2.44), whereas O₃ exhibited a negative trend (Z = −6.54). At the Meram station, a significant decrease was observed in CO (Z = −11.63), while NO₂ showed an increasing trend (Z = 3.03). Analysis of meteorological series indicated no significant trend in precipitation (Z = −0.04), but a distinct increase in temperature (Z = 2.90, p < 0.01). These findings suggest that the increasing NO_x load in the Konya atmosphere accelerates O₃ consumption and, combined with rising temperatures, creates a potential for change in the carbon chemistry of aquatic systems. The results demonstrate that atmospheric pollutant trends constitute an indirect but significant pressure factor on the aquatic carbon cycle in semi-arid regions and highlight the necessity of integrating atmospheric processes into carbon budget analyses within the scope of LOAC. Full article

Given the deteriorating situation of ambient ozone (O₃) pollution in some areas of China, understanding the mechanisms driving O₃ formation is essential for formulating effective control measures. This study examines O₃ formation mechanisms and RO_x (OH, HO_2, and RO₂) radical cycling driven by photochemical processes in Bozhou, located at the junction of Jiangsu–Anhui–Shandong–Henan (JASH), a region heavily affected by O₃ pollution, by applying a zero-dimensional box model (Framework for 0-Dimensional Atmospheric Modeling, F0AM) coupled with the Master Chemical Mechanism (MCM v3.3.1) and Positive Matrix Factorization (PMF 5.0) to characterize O₃ pollution, identify volatile organic compound (VOC) sources, and quantify radical budgets during pollution episodes. The results show that O₃ episodes in Bozhou mainly occurred in June under conditions of high temperature and low wind speed. Oxygenated volatile organic compounds (OVOCs), alkanes, and halocarbons were the dominant VOCs groups. The CH₃O₂ + NO reaction accounted for 24.3% of O₃ production, while photolysis contributed 68.7% of its removal. Elevated VOCs concentrations in Bozhou were largely maintained by anthropogenic sources such as vehicle exhaust, solvent utilization, and gasoline evaporation, which collectively enhanced O₃ production. The findings indicate that O₃ formation in the region is primarily regulated by NO_x availability. Therefore, emission reductions targeting NO_x, along with selective control of OVOCs and alkenes, would be the most effective strategies for lowering O₃ levels. Model simulations further highlight Bozhou’s strong atmospheric oxidation capacity, with OVOC photolysis identified as the dominant contributor to RO_x generation, accounting for 33% of the total. Diurnal patterns were evident: NO_x-related reactions dominated radical sinks in the morning, while HO₂ + RO₂ reactions accounted for 28.5% in the afternoon. By clarifying the mechanisms of O₃ formation in Bozhou, this study provides a scientific basis for designing ozone control strategies across the JASH junction region. In addition, ethanol was not directly measured in this study; given its potential to generate acetaldehyde and affect local O₃ formation, its possible contribution introduces additional uncertainty that warrants further investigation. Full article

Molecularly imprinted polymers (MIPs) are promising sorbents for selectively capturing pharmaceutically active compounds (PhACs), but design remains slow because candidate screening is largely experimental or based on computationally expensive methods. We present MIP–PhAC, an open, curated resource of polymer–pharmaceutical interaction energies generated from molecular dynamics (MD) followed by MM/PBSA analysis, with a small DFT subset for cross-method comparison. This resource is comprised of two complementary datasets: MIP–PhAC-Calibrated, a benchmark set with manually verified pH-7 microstates that reports both monomeric (pre-polymerized) and polymeric (short-chain) MD/MMPBSA energies and includes a DFT subset; and MIP–PhAC-Screen, a broader, high-throughput collection produced under a uniform automated workflow (including automated protonation) for rapid within-polymer ranking and machine learning development. For each MIP—PhAC pair we provide ΔG* components (electrostatics, van der Waals, polar and non-polar solvation; −TΔS omitted), summary statistics from post-convergence frames, simulation inputs, and chemical metadata. To our knowledge, MIP–PhAC is the largest open, curated dataset of polymer–pharmaceutical interaction energies to date. It enables benchmarking of end-point methods, reproducible protocol evaluation, data-driven ranking of polymer–pharmaceutical combinations, and training/validation of machine learning (ML) models for MIP design on modest compute budgets. Full article

We have fabricated amorphous tin oxide (a-SnO_x) thin-film transistors (TFTs) with Al₂O₃ gate insulator from deep eutectic solvents (DESs). DESs were formed using the chloride derivates of each precursor (SnCl₂, or AlCl₃) mixed with urea. The DESs were then used as precursors for the semiconductor and dielectric. Our target was to form extremely thin semiconductor film, and a sufficient high capacitance insulator. We characterized the physical and chemical properties of the DES-derived thin films by X-ray diffraction (XRD), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). We could evaluate that the highest content of metal–oxygen bonds was from the DES condition SnCl₂–urea = 1:3. At a low 300 °C budget temperature, we could fabricate a 3.2 nm thick a-SnO_x layer and 30 nm thick Al₂O₃, from which the TFT demonstrated a mobility of 80 ± 17 cm²/Vs, threshold voltage of −0.29 ± 0.06 V, and subthreshold swing of 88 ± 11 mV/dec. The proposed process is adequate with the back-end of the line (BEOL) process, but it is also eco-friendly because of the use of DESs. Full article

The Hetao Irrigation District in Inner Mongolia is a major spring wheat production region in China. To synergize high wheat yield, water conservation, and carbon emission reduction in this region, a 2023 and 2024 field experiment was conducted. This study systematically analyzed the effects of organic fertilizer substitution for chemical nitrogen (T1:0%, T2:25%, T3:50%, T4:75%, T5:100%) on soil carbon emissions dynamics and carbon footprint of wheat fields, under two irrigation regimes: water-saving irrigation (twice at jointing and heading stages, 2W) and conventional irrigation (four times at tillering, jointing, heading, and grain-filling stages, 4W). The results showed that during the wheat-growing season, soil CO₂ emission rate exhibited a single-peak trend (peak at flowering stage), while cumulative soil CO₂ emission showed a “decrease-increase-decrease” pattern (peak at jointing to heading). At different growth stages, both CO₂ emission and its rate increased with higher organic fertilizer substitution ratios, and were higher under 4W than 2W. Irrigation and substitution treatments significantly affected the total carbon emissions, carbon sequestration, and carbon footprint: total emissions increased with substitution ratios, while sequestration and footprint first increased then decreased; all three indices were higher under 4W than 2W. Regression analysis revealed that maximum net carbon budget was achieved at 21.6–31.7% substitution (1402.3–1879.9 kg ha⁻¹) under 2W, and 31.0–33.8% substitution (2295.5–2822.0 kg ha⁻¹) under 4W. In conclusion, water-saving irrigation (900 m³ ha⁻¹ per application at jointing and heading stages) combined with an optimal organic-nitrogen ratio (1008.0 kg ha⁻¹ organic fertilizer, 193.1 kg ha⁻¹ chemical nitrogen) effectively coordinates water conservation and carbon emission reduction. This study provides a basis for synergizing these goals in Hetao’s wheat production. Full article

The accurate measurement of herbage mass is essential for feed budgeting and the management of sustainable and profitable grazing systems. There are many techniques available to estimate herbage mass in pastoral systems, and these vary in accuracy, cost, and time taken to implement. In situ and remote sensing techniques are both associated with moderate to high error, as herbage mass is affected by a number of dependent and independent factors, including sward composition, soil structure, chemical characteristics and moisture levels, climatic conditions, and grazing management, which must be considered in the development of an accurate local calibration model for precise estimation of herbage mass. This review provides an overview of commonly used herbage mass assessment techniques and describes their limitations, synergies, and trade-offs, and also covers the integration of new technologies which have the potential to monitor pastures at scale. This review highlights the need for further research and to integrate new technologies for accurate and precise measurement of herbage mass, noting the lack of calibration with in situ methods, the need for development of new protocols for assessment, variance in equipment and software compatibility, and the need to evaluate the effectiveness of methods/techniques on a variety of livestock operations for extended periods. Full article

This study experimentally investigates the dynamic behavior and energy conversion characteristics of a single contaminated bubble (d_eq = 2.49–3.54 mm, Re_b = 470–830) rising near a vertical wall (S* = 1.41–2.02) in a linear shear flow (the conditions of average flow rate 0.1 m/s and shear rate 0.5 s⁻¹) using a vertical water tunnel and varying sodium dodecyl sulfate (SDS) concentrations (0–50 ppm) and bubble sizes (via needle nozzles). High-speed imaging with orthogonal shadowgraphy captures bubble trajectories, rotation, deformation, and oscillation modes (2, 0) and (2, 2), revealing that an increasing SDS concentration suppresses deformation and the inclination amplitude while enhancing the oscillation frequency, particularly for smaller bubbles. Velocity analysis shows that vertical components remain steady, whereas wall-normal and spanwise fluctuations diminish with surfactant concentration, indicating stabilized trajectories. Additional mass force coefficients are larger for bigger bubbles and decrease with contamination level. Energy analysis demonstrates that surface energy dominates the total energy budget, with vertical kinetic energy comprising over 70% of the total kinetic energy under high SDS concentrations. The results highlight strong scale dependence and Marangoni effects in controlling near-wall bubble motion and energy transfer, providing insights for optimizing gas–liquid two-phase flow processes in chemical and environmental engineering applications. Full article

Chemical mixing of different types of magma, such as basaltic magma and silica-rich, hydrous magma, often triggers volcanic eruptions. However, the kinetics, mechanisms, and rates of sulfide dissolution reactions in hydrous melts are currently unknown, despite the fact that these reactions can influence the sulfur budget in the crust and mantle. I experimentally model dissolution of pyrrhotite minerals in hydrous rhyolite melt at conditions corresponding to the sulfate–sulfide transition field at 1 GPa pressure. The reaction results in the production of FeO, SO₄²⁻, H₂, H₂S and di- and tri-sulfur radical ions, (S₂⁻ or S₃⁻) in fluid/melt. The calculated sulfur diffusion coefficient implies extremely fast sulfur diffusion in the hydrous hybrid melt. The production of S-rich magma is controlled by the fastest-ever-recorded chemical diffusion of sulfur in the form of S₂⁻ or S₃⁻ in hybrid magma under sulfate-sulfide transition conditions. I demonstrate that such dissolution reactions can be responsible for triggering explosive volcanic eruptions (e.g., the 1991 Mount Pinatubo eruption) in volcanic arc settings. The sulfide dissolution reaction can also promote the production of chalcophile metal (sulfur-loving Au, Cu and Pt) ore deposits associated with the formation of volcanic arcs. Full article

It has been experimentally proved that microorganisms in soils are able to remove atmospheric methane (CH₄), particularly through experiments with radioelements such as ¹⁴CH₄. However, a curious question arises: are these microorganisms the only responsible sink for all atmospheric CH₄ uptake attributed to soils, or do non-microbial (e.g., chemical) processes also contribute part of it? In this perspective article, we propose that atmospheric methane removal (AMR) in soils may result from a combination of microbial and non-microbial processes. In addition to oxidation by MOB, we analyzed the potential roles of photocatalytic reactions on soil minerals, Fenton-like chemistry in water droplets, chlorine radical pathways in chloride-rich soils and ozone/VOCs-driven •OH generation. These chemical mechanisms may act independently or intertwined with microbial activity under specific environmental conditions. We suggest that future studies use experimental approaches to explore and quantify the relative contributions of these pathways and to help refine our understanding of the soil CH₄ sink in the global methane budget. Full article

This paper reviews the apparent impact of how changes in nitrate, sulphate activities, and moisture affect the surface pH of rock art paintings at Cueva del Ratón, in the Sierra de San Francisco in Baja California Sur, Mexico. The data was collected after atypical weather events caused rain and mist in this normally arid area. The rock art paintings had been previously examined over several years and observed the unexpected formation of silica skins over some surfaces; such coatings are not often experienced in arid environments. The local geology of the cave and the availability of moisture can dramatically alter the microbiological activity on faecal material and development of surface acidity from such reactions which interacts with both the host rock and the pigments. Through a series of surface pH measurements and localised measurements on chloride, sulphate and nitrate it appears that both nitrate and sulphate concentrations have a significant impact on the surface pH, which is controlled by a diffusion-based movement of moisture from the closed to the open end of the shelter. The exfoliation of the rock surface and formation of the silica skins involves chemical reactions as contrasted with diffusion-controlled reactions which distribute the metabolites of the yeasts, moulds and bacteria, which are dominated by the availability of water through drip lines. The results are particularly relevant due to changing weather patterns in the last decade, caused by climate change, with an increase in hurricanes directly affecting the Baja California peninsula. The use of disposable test strips for semi-quantitative assessment of how these major anions impact on the decay mechanisms was a novel response to budget constraints and the remoteness of the location. Full article