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47 pages, 13626 KB  
Review
Multifunctional Roles of Medicinal Plants in the Meat Industry: Antioxidant, Antimicrobial, and Color Preservation Perspectives
by Alexandra Cristina Tocai (Moțoc), Cristina Adriana Rosan, Andrei George Teodorescu, Alina Cristiana Venter and Simona Ioana Vicas
Plants 2025, 14(17), 2737; https://doi.org/10.3390/plants14172737 - 2 Sep 2025
Abstract
There is growing interest from researchers, the food industry, and consumers in reducing or eliminating synthetic preservatives such as nitrites in meat products. In this context, medicinal plants have emerged as promising sources of natural compounds with multifunctional roles. This review summarizes recent [...] Read more.
There is growing interest from researchers, the food industry, and consumers in reducing or eliminating synthetic preservatives such as nitrites in meat products. In this context, medicinal plants have emerged as promising sources of natural compounds with multifunctional roles. This review summarizes recent advances in the application of medicinal plant extracts as natural antioxidants, antimicrobials, and color-preserving agents in the meat industry. A systematic literature search was conducted using the PubMed and Lens databases, complemented by a bibliometric analysis with the VOS viewer, to identify research trends and key contributors in the field. The incorporation of plant-based ingredients in meat and meat analogues has the potential to enhance flavor, nutritional value, and shelf life while responding to the demand for clean-label and health-oriented products. Particular attention is given to the phytochemical composition, bioactivity, and practical application of selected medicinal plants that have demonstrated efficacy in preserving the oxidative stability, microbial safety, and visual quality of meat. Furthermore, the review highlights emerging plant species with potential in meat preservation and discusses the challenges related to their incorporation into meat matrices. These findings support the strategic use of plant-based bioactive compounds as sustainable and functional alternatives to synthetic additives in meat systems. Full article
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18 pages, 1534 KB  
Article
Designing Spoonable Milk Kefir Gels: From Fermentation Optimization to Clean-Label Gel Structuring with Psyllium
by María Cardenete-Fernández, Alicia Castillo-Rivas, M. Montaña Durán-Barrantes, Luis A. Trujillo-Cayado and Jenifer Santos
Gels 2025, 11(9), 693; https://doi.org/10.3390/gels11090693 - 1 Sep 2025
Viewed by 31
Abstract
Kefir is a fermented dairy product whose structural properties can be modified to enhance its nutritional and sensory profile. The objective of this study was to develop spoonable milk kefir gels by optimizing fermentation conditions and incorporating psyllium and calcium chloride as structuring [...] Read more.
Kefir is a fermented dairy product whose structural properties can be modified to enhance its nutritional and sensory profile. The objective of this study was to develop spoonable milk kefir gels by optimizing fermentation conditions and incorporating psyllium and calcium chloride as structuring agents. In the initial phase of the study, a full factorial design was employed to conduct a comparative analysis of whole milk and skimmed milk during the fermentation process of kefir. The study encompassed the evaluation of the impact of various parameters, including inoculum level, temperature, and fermentation time, on the acidification kinetics of the fermentation process. This evaluation was facilitated through the measurement of pH and total acidity levels. Skimmed milk demonstrated accelerated acidification, consistently attaining a final pH of 4.08 and a total acidity of 9.99 g·L−1 lactic acid equivalents under optimized conditions (5.5% weight:weight grains, 26 °C, 24 h). In the subsequent phase, kefir obtained under these conditions was gelled with varying concentrations of psyllium and calcium chloride. Rheological characterization revealed that psyllium markedly strengthened the gel network: at 3.06% w:w psyllium, the elastic modulus increased up to 209.6 Pa, while the critical stress improved from 0.64 Pa at low psyllium/Ca2+ to 10.42 Pa at high psyllium content. Furthermore, zero-shear viscosity increased substantially, exceeding 1500 Pa·s in high-psyllium, low-calcium formulations. The findings demonstrate that combining fermentation optimization with clean-label structuring agents enables the development of low-fat kefir gels with enhanced textural and processing properties, supporting their potential as synbiotic, functional dairy products. Full article
(This article belongs to the Special Issue Food Gel-Based Systems: Gel-Forming and Food Applications)
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26 pages, 9891 KB  
Article
Real-Time Energy Management of a Microgrid Using MPC-DDQN-Controlled V2H and H2V Operations with Renewable Energy Integration
by Mohammed Alsolami, Ahmad Alferidi and Badr Lami
Energies 2025, 18(17), 4622; https://doi.org/10.3390/en18174622 - 30 Aug 2025
Viewed by 233
Abstract
This paper presents the design and implementation of an Intelligent Home Energy Management System in a smart home. The system is based on an economically decentralized hybrid concept that includes photovoltaic technology, a proton exchange membrane fuel cell, and a hydrogen refueling station, [...] Read more.
This paper presents the design and implementation of an Intelligent Home Energy Management System in a smart home. The system is based on an economically decentralized hybrid concept that includes photovoltaic technology, a proton exchange membrane fuel cell, and a hydrogen refueling station, which together provide a reliable, secure, and clean power supply for smart homes. The proposed design enables power transfer between Vehicle-to-Home (V2H) and Home-to-Vehicle (H2V) systems, allowing electric vehicles to function as mobile energy storage devices at the grid level, facilitating a more adaptable and autonomous network. Our approach employs Double Deep Q-networks for adaptive control and forecasting. A Multi-Agent System coordinates actions between home appliances, energy storage systems, electric vehicles, and hydrogen power devices to ensure effective and cost-saving energy distribution for users of the smart grid. The design validation is carried out through MATLAB/Simulink-based simulations using meteorological data from Tunis. Ultimately, the V2H/H2V system enhances the utilization, reliability, and cost-effectiveness of residential energy systems compared with other management systems and conventional networks. Full article
(This article belongs to the Section A1: Smart Grids and Microgrids)
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31 pages, 4184 KB  
Article
Investigating the Neuroprotective, Hepatoprotective, and Antimicrobial Effects of Mushroom Extracts
by Menna-Allah E. Abdelkader, Hatungimana Mediatrice, Zhanxi Lin, Christopher Rensing, Mohamed M. Yacout, Dongmei Lin and Sarah A. Aggag
Int. J. Mol. Sci. 2025, 26(17), 8440; https://doi.org/10.3390/ijms26178440 - 29 Aug 2025
Viewed by 155
Abstract
Mushrooms, renowned for their nutritional value and bioactive compounds, offer potential health benefits, including antioxidants and anti-aging properties. Aging, characterized by cellular and tissue decline, is often associated with autophagy dysfunction, a crucial cellular cleaning process. This study aimed to investigate the neuroprotective, [...] Read more.
Mushrooms, renowned for their nutritional value and bioactive compounds, offer potential health benefits, including antioxidants and anti-aging properties. Aging, characterized by cellular and tissue decline, is often associated with autophagy dysfunction, a crucial cellular cleaning process. This study aimed to investigate the neuroprotective, hepatoprotective, and antimicrobial properties of extracts from four medicinal and edible mushrooms: Ganoderma lucidum, Hericium erinaceus, Pleurotus ostreatus, and Agaricus bisporus. The protein, total phenol, and flavonoid content of mushroom extracts were determined. Aging was induced with 120 mg/kg D-galactose and treated with 500 mg/kg mushroom extracts. The study evaluated liver enzyme levels, histopathological changes in liver and brain tissues, gene expression correlated to neurodegeneration (SEPT5-SV2B-ATXN2-PARK2), telomere length, and immunomodulatory and pro-inflammatory (IL-2-IL-4-IL-6) gene expression pathways. Additionally, the antimicrobial potential of mushroom extracts was assessed against several bacteria (Lysinibacillus odyssey, Lysinibacillus fusiformis, Klebsiella oxytoca, and Escherichia coli) using agar well diffusion and lowest minimum inhibitory concentration (MIC) methods. By exploring these diverse aspects, this study aimed to provide a foundation for a better understanding of the potential of mushrooms as natural neuroprotective, hepatoprotective, and antimicrobial agents and their potential applications in human health. Results indicated that all mushroom extracts effectively mitigated oxidative stress. Agaricus bisporus exhibited the highest protein and flavonoid content, and Pleurotus ostreatus displayed the highest phenolic content. Notably, Hericium erinaceus and Ganoderma lucidum extracts demonstrated significant neuroprotective and hepatoprotective properties against D-galactose-induced aging, as evidenced by histopathological examination. All extracts exhibited a significant decrease (p < 0.001) in liver function (serum levels of aspartate aminotransferase (GOT) and alanine aminotransferase (GPT)) and showed immunomodulatory and anti-inflammatory effects, characterized by upregulated IL-2 and IL-4 gene expression and downregulated IL-6 gene expression. Hericium erinaceus demonstrated the most pronounced upregulation (p < 0.001) of SEPT5, SV2B, and telomere length gene expression, suggesting potential anti-aging effects. Furthermore, all mushroom extracts displayed antimicrobial activity against the tested bacterial strains, except Hericium erinaceus, which exhibited antibacterial activity solely against E. coli. Agaricus bisporus exhibited the largest inhibition zones (22 ± 0.06 mm) against Lysinibacillus odyssey, while Hericium erinaceus displayed the largest inhibition zone against E. coli. The MIC value was observed with Agaricus bisporus extract against Lysinibacillus odyssey (1.95 ± 0.16 mg/mL). Lysinibacillus fusiformis exhibited the highest resistance to the tested mushroom extracts. These findings suggest that these edible and medicinal mushrooms possess a wide range of health-promoting properties, including neuroprotective, hepatoprotective, and antimicrobial activities. Further research is needed to fully understand the underlying mechanisms and optimize applications. However, our results provide a strong foundation for exploring these mushrooms as potential natural agents that promote overall health and combat age-related decline. Full article
(This article belongs to the Section Bioactives and Nutraceuticals)
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25 pages, 5646 KB  
Article
Isolation of Cellulose Nanofibers from Kombucha Beverage By-Product by Chemo-Mechanical Routes
by Cătălina-Diana Uşurelu, Gabriela-Mădălina Oprică, Denis Mihaela Panaitescu, Adriana Nicoleta Frone, Celina Maria Damian, Cristian Andi Nicolae, Ştefan-Ovidiu Dima, Florin Oancea and Mircea Teodorescu
Polymers 2025, 17(17), 2307; https://doi.org/10.3390/polym17172307 - 26 Aug 2025
Viewed by 509
Abstract
In a world where the negative consequences of natural resources’ overexploitation for the environment are increasingly evident, repurposing waste to obtain high-value goods becomes essential. This study proposes the isolation of cellulose nanofibers from the bacterial cellulose (BC) membrane that results as a [...] Read more.
In a world where the negative consequences of natural resources’ overexploitation for the environment are increasingly evident, repurposing waste to obtain high-value goods becomes essential. This study proposes the isolation of cellulose nanofibers from the bacterial cellulose (BC) membrane that results as a by-product during the fermentation of Kombucha tea by chemical treatment with sodium hydroxide (NaOH), sodium hypochlorite (NaClO), hydrogen peroxide (H2O2), sulfuric acid (H2SO4) or citric acid, followed by mechanical fibrillation via high-speed homogenization and microfluidization. Treatments with NaOH, NaClO, and H2O2 were effective in the purification of Kombucha-derived BC, while H2SO4 and citric acid exhibited a rather weak cleaning action, as revealed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Besides their cleaning effect, the applied chemical pretreatments had an important effect on the degree of fibrillation attained, as indicated by the scanning electron microscopy images. This study proposes simple and effective routes to obtain bacterial cellulose nanofibers from an inexpensive and abundant source, commonly regarded as a waste material, which can be further applied in medical and packaging applications as reinforcing agents, adsorbent materials, or scaffolds. Full article
(This article belongs to the Special Issue New Progress in the Polymer-Based Biomaterials)
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14 pages, 4654 KB  
Article
Evaluation of Temperature- and Salt-Resistant Foam Acid and Study of Foam Diversion Mechanism
by Xiangsong Hu, Hui Ma, Ya Xu, Fuhua Chang, Jiabao Fan and Chao Zhang
Processes 2025, 13(9), 2704; https://doi.org/10.3390/pr13092704 - 25 Aug 2025
Viewed by 309
Abstract
Foam acidification is often employed as a clean and efficient method to remove blockages from wells and promote oil and gas production. In order to effectively control the diffusion of H+ in the acid solution into the rock surface, reduce the acid–rock [...] Read more.
Foam acidification is often employed as a clean and efficient method to remove blockages from wells and promote oil and gas production. In order to effectively control the diffusion of H+ in the acid solution into the rock surface, reduce the acid–rock reaction rate, and achieve deep acidification, a foam-retarding acid with foam stability, temperature and salt resistance, and excellent retarding performance was prepared by studying the synergistic effect of the foaming agent and foam stabilizer. ZG-A was used as the foaming agent, and ZG-B was added as a foam stabilizer to achieve foam stabilization. When the ZG-A/ZG-B ratio was 0.67%/0.33%, the foam exhibited the best comprehensive performance. By measuring and comparing the acid–rock reaction rate under different conditions, the results showed that the average acid–rock reaction rate of the 10% compound acid was 1.412 × 10−3 mg/(cm2·s), while the average acid–rock reaction rate of the foam-retarding acid system was reduced to 6.622 × 10−5 mg/(cm2·s), representing a reduction of two orders of magnitude, and the slow rate reached 95.31%. Foam fluid diversion experiments were carried out on cores with different permeabilities. The results showed that the foam could increase the diversion flow rate of low-permeability cores and reduce the diversion flow rate of high-permeability cores. Thus, the foam fluid could be uniformly propelled in cores with different permeabilities. Based on this principle, foam acid acidification can increase the amount of acid injection into the low-permeability layer and reduce the amount of acid absorption in the high-permeability layer, thereby improving the acidification effect. Full article
(This article belongs to the Section Chemical Processes and Systems)
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11 pages, 1946 KB  
Article
Influence of Surface Treatments on the Pull-Off Performance of Adhesively Bonded Polylactic Acid (PLA) Specimens Manufactured by Fused Deposition Modeling (FDM)
by Gianluca Parodo, Giuseppe Moffa, Alessandro Silvestri, Luca Sorrentino, Gabriel Testa and Sandro Turchetta
Materials 2025, 18(17), 3965; https://doi.org/10.3390/ma18173965 - 24 Aug 2025
Viewed by 543
Abstract
This study investigates the influence of different surface treatments (namely, mechanical abrasion and solvent cleaning with isopropyl alcohol and acetone) on the adhesive bonding performance of polylactic acid (PLA) substrates produced by Fused Deposition Modeling (FDM). Pull-off tests revealed that the isopropanol-cleaned specimens [...] Read more.
This study investigates the influence of different surface treatments (namely, mechanical abrasion and solvent cleaning with isopropyl alcohol and acetone) on the adhesive bonding performance of polylactic acid (PLA) substrates produced by Fused Deposition Modeling (FDM). Pull-off tests revealed that the isopropanol-cleaned specimens achieved the highest bond strength, with an average pull-off value exceeding 8.5 MPa, compared to approximately 5.6 MPa for untreated PLA. Conversely, acetone cleaning resulted in the lowest performance (about 3.5 MPa), while mechanical abrasion yielded intermediate values of about 6 MPa. FTIR analysis confirmed that no chemical reactions occurred, although acetone and abrasion induced significant physical surface changes, unlike isopropanol, which acted as an effective cleaning agent. These findings demonstrate that surface cleanliness plays a dominant role over morphological alterations in enhancing the adhesion of PLA-based 3D-printed joints. Full article
(This article belongs to the Special Issue Advanced Machining and Technologies in Materials Science)
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15 pages, 6518 KB  
Article
Research on Damage Characteristics of Clean Fracturing Fluid in Deep Coal Seam
by Jinqiao Wu, Anbang Liu, Fengsan Zhang, Yiting Liu, Le Yan, Yenan Jie and Chen Wang
Processes 2025, 13(9), 2669; https://doi.org/10.3390/pr13092669 - 22 Aug 2025
Viewed by 370
Abstract
This study focuses on investigating the damage characteristics and mechanisms of Slickwo clean fracturing fluid to the reservoir by using the deep coal seam in the Yan’an gas field as the research subject. During the experiment, fracturing fluids with varying A content were [...] Read more.
This study focuses on investigating the damage characteristics and mechanisms of Slickwo clean fracturing fluid to the reservoir by using the deep coal seam in the Yan’an gas field as the research subject. During the experiment, fracturing fluids with varying A content were employed to displace coal and rock cores. The impact of these fluids on the permeability and pore structure of coal and rock was analyzed using a combination of nuclear magnetic resonance and high-pressure mercury injection technology. The findings indicate that the permeability damage rates of cores Y-1 and Y-2 post-displacement are 48.4% and 53.6% correspondingly, with the damage worsening as the agent A content increases. NMR data reveals that the fracturing fluid exhibits the highest retention in small pores, followed by medium-sized pores, and the least in large pores. The rise in agent A content enhanced the retention degree in individual pore throats and overall, increasing from 62.24% to 68.74%. The escalation in agent A content results in higher macromolecular residues, causing seepage channel blockages and enhancing the adsorption properties between fracturing fluid and coal rock. This phenomenon leads to inadequate backflow, primarily in smaller apertures. Simultaneously, the interaction between the gel breaker and clay minerals triggers particle migration, blockage, and expansion, consequently diminishing the permeability of coal and rock and inducing specific damages. Full article
(This article belongs to the Section Chemical Processes and Systems)
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15 pages, 2219 KB  
Article
Feasibility Assessment of Hydrophobic Surface Creation via Digital Light Processing: Influence of Texture Geometry, Composition, and Resin Type
by Saher Mohammed Abo Shawish, Mohsen Barmouz and Bahman Azarhoushang
J. Compos. Sci. 2025, 9(8), 447; https://doi.org/10.3390/jcs9080447 - 19 Aug 2025
Viewed by 377
Abstract
This study explores the fabrication of hydrophobic surfaces on polymer components via Digital Light Processing (DLP), with emphases on how texture geometry, feature dimensions, and resin type influence surface wettability. Square and cylindrical microtextures were fabricated and evaluated using static contact angle measurements. [...] Read more.
This study explores the fabrication of hydrophobic surfaces on polymer components via Digital Light Processing (DLP), with emphases on how texture geometry, feature dimensions, and resin type influence surface wettability. Square and cylindrical microtextures were fabricated and evaluated using static contact angle measurements. Square-shaped structures demonstrated enhanced hydrophobicity, with contact angles reaching 133.6°, compared to approximately 100° for cylindrical counterparts of identical dimensions. Increasing pillar height to 521 µm enhanced hydrophobicity by approximately 15%, while decreasing pillar spacing to 150 µm increased contact angles from 86.8° to 106°, highlighting the role of microstructure density. For square-shaped structures, the addition of a hydrophobic agent at 3 wt.% resulted in a contact angle of 123.4°, representing a 44% improvement over the untreated sample. These findings underscore the combined influence of resin chemistry, surface texture design, and dimensional parameters on wettability behavior. Although superhydrophobicity (contact angle > 150°) was not achieved, the study demonstrates notable advancements in optimizing hydrophobicity through DLP printing. Overall, the results support DLP as a scalable and cost-effective approach for engineering functional surfaces suited to self-cleaning, biomedical, and anti-fouling applications. Full article
(This article belongs to the Special Issue Functional Composites: Fabrication, Properties and Applications)
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19 pages, 5302 KB  
Article
Localized Ultrasonic Cleaning for Injection Mold Cavities: A Scalable In Situ Process with Surface Quality Monitoring
by Deviprasad Chalicheemalapalli Jayasankar, Thomas Tröster and Thorsten Marten
Technologies 2025, 13(8), 354; https://doi.org/10.3390/technologies13080354 - 11 Aug 2025
Viewed by 394
Abstract
As global industries seek to reduce energy consumption and lower CO2 emissions, the need for sustainable, efficient maintenance processes in manufacturing has become increasingly important. Traditional mold cleaning methods often require complete tool disassembly, extended downtime, and heavy use of solvents, resulting [...] Read more.
As global industries seek to reduce energy consumption and lower CO2 emissions, the need for sustainable, efficient maintenance processes in manufacturing has become increasingly important. Traditional mold cleaning methods often require complete tool disassembly, extended downtime, and heavy use of solvents, resulting in high energy costs and environmental impact. This study presents a novel localized ultrasonic cleaning process for injection molding tools that enables targeted, in situ cleaning of mold cavities without removing the tool from the press. A precisely positioned ultrasonic transducer delivers cleaning energy directly to contaminated areas, eliminating the need for complete mold removal. Multiple cleaning agents, including alkaline and organic acid solutions, were evaluated for their effectiveness in combination with ultrasonic excitation. Surface roughness measurements were used to assess cleaning performance over repeated contamination and cleaning cycles. Although initial tests were performed manually in the lab, results indicate that the method can be scaled up and automated effectively. This process offers a promising path toward energy-efficient, low-emission tool maintenance across a wide range of injection molding applications. Full article
(This article belongs to the Section Manufacturing Technology)
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36 pages, 13501 KB  
Review
Research Progress on Risk Prevention and Control Technology for Lithium-Ion Battery Energy Storage Power Stations: A Review
by Weihang Pan
Batteries 2025, 11(8), 301; https://doi.org/10.3390/batteries11080301 - 6 Aug 2025
Viewed by 713
Abstract
Amidst the background of accelerated global energy transition, the safety risk of lithium-ion battery energy storage systems, especially the fire hazard, has become a key bottleneck hindering their large-scale application, and there is an urgent need to build a systematic prevention and control [...] Read more.
Amidst the background of accelerated global energy transition, the safety risk of lithium-ion battery energy storage systems, especially the fire hazard, has become a key bottleneck hindering their large-scale application, and there is an urgent need to build a systematic prevention and control program. This paper focuses on the fire characteristics and thermal runaway mechanism of lithium-ion battery energy storage power stations, analyzing the current situation of their risk prevention and control technology across the dimensions of monitoring and early warning technology, thermal management technology, and fire protection technology, and comparing and analyzing the characteristics of each technology from multiple angles. Building on this analysis, this paper summarizes the limitations of the existing technologies and puts forward prospective development paths, including the development of multi-parameter coupled monitoring and warning technology, integrated and intelligent thermal management technology, clean and efficient extinguishing agents, and dynamic fire suppression strategies, aiming to provide solid theoretical support and technical guidance for the precise risk prevention and control of lithium-ion battery storage power stations. Full article
(This article belongs to the Special Issue Advanced Battery Safety Technologies: From Materials to Systems)
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28 pages, 2266 KB  
Review
Uncovering Plastic Pollution: A Scoping Review of Urban Waterways, Technologies, and Interdisciplinary Approaches
by Peter Cleveland, Donna Cleveland, Ann Morrison, Khoi Hoang Dinh, An Nguyen Pham Hai, Luca Freitas Ribeiro and Khanh Tran Duy
Sustainability 2025, 17(15), 7009; https://doi.org/10.3390/su17157009 - 1 Aug 2025
Viewed by 663
Abstract
Plastic pollution is a growing environmental and social concern, particularly in Southeast Asia, where urban rivers serve as key pathways for transporting waste to marine environments. This scoping review examines 110 peer-reviewed studies to understand how plastic pollution in waterways is being researched, [...] Read more.
Plastic pollution is a growing environmental and social concern, particularly in Southeast Asia, where urban rivers serve as key pathways for transporting waste to marine environments. This scoping review examines 110 peer-reviewed studies to understand how plastic pollution in waterways is being researched, addressed, and reconceptualized. Drawing from the literature across environmental science, technology, and social studies, we identify four interconnected areas of focus: urban pollution pathways, innovations in monitoring and methods, community-based interventions, and interdisciplinary perspectives. Our analysis combines qualitative synthesis with visual mapping techniques, including keyword co-occurrence networks, to explore how real-time tools, such as IoT sensors, multi-sensor systems, and geospatial technologies, are transforming the ways plastic waste is tracked and analyzed. The review also considers the growing use of novel theoretical frameworks, such as post-phenomenology and ecological materialism, to better understand the role of plastics as both pollutants and ecological agents. Despite progress, the literature reveals persistent gaps in longitudinal studies, regional representation, and policy translation, particularly across the Global South. We emphasize the value of participatory models and community-led research in bridging these gaps and advancing more inclusive and responsive solutions. These insights inform the development of plastic tracker technologies currently being piloted in Vietnam and contribute to broader sustainability goals, including SDG 6 (Clean Water and Sanitation), SDG 12 (Responsible Consumption and Production), and SDG 14 (Life Below Water). Full article
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16 pages, 4017 KB  
Article
Recyclable Platinum Nanocatalyst for Nitroarene Hydrogenation: Gum Acacia Polymer-Stabilized Pt Nanoparticles with TiO2 Support
by Supriya Prakash, Selvakumar Ponnusamy, Jagadeeswari Rangaraman, Kundana Nakkala and Putrakumar Balla
ChemEngineering 2025, 9(4), 81; https://doi.org/10.3390/chemengineering9040081 - 30 Jul 2025
Viewed by 343
Abstract
Platinum has emerged as an optimal catalyst for the selective hydrogenation of nitroarenes owing to its high hydrogenation activity, selectivity, and stability. In this study, we report the fabrication of platinum nanoparticles stabilized on a composite support consisting of gum acacia polymer (GAP) [...] Read more.
Platinum has emerged as an optimal catalyst for the selective hydrogenation of nitroarenes owing to its high hydrogenation activity, selectivity, and stability. In this study, we report the fabrication of platinum nanoparticles stabilized on a composite support consisting of gum acacia polymer (GAP) and TiO2. It was engineered for the targeted reduction of nitroarenes to arylamines via selective hydrogenation in methanol at ambient temperature. The non-toxic and biocompatible properties of GAP enable it to act as a reducing and stabilizing agent during synthesis. The synthesized nanocatalyst was characterized using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Morphological and structural analyses revealed that the fabricated catalyst consisted of minuscule Pt nanoparticles integrated within the GAP framework, accompanied by the corresponding TiO2 nanoparticles. Inductively coupled plasma optical emission spectrometry (ICP-OES) was employed to ascertain the Pt content. The mild reaction conditions, decent yields, trouble-free workup, and facile separation of the catalyst make this method a clean and practical alternative to nitroreduction. Selective hydrogenation yielded an average arylamine production of 97.6% over five consecutive cycles, demonstrating the stability of the nanocatalyst without detectable leaching. Full article
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18 pages, 2981 KB  
Article
Development and Evaluation of Mesoporous SiO2 Nanoparticle-Based Sustained-Release Gel Breaker for Clean Fracturing Fluids
by Guiqiang Fei, Banghua Liu, Liyuan Guo, Yuan Chang and Boliang Xue
Polymers 2025, 17(15), 2078; https://doi.org/10.3390/polym17152078 - 30 Jul 2025
Viewed by 376
Abstract
To address critical technical challenges in coalbed methane fracturing, including the uncontrollable release rate of conventional breaker agents and incomplete gel breaking, this study designs and fabricates an intelligent controlled-release breaker system based on paraffin-coated mesoporous silica nanoparticle carriers. Three types of mesoporous [...] Read more.
To address critical technical challenges in coalbed methane fracturing, including the uncontrollable release rate of conventional breaker agents and incomplete gel breaking, this study designs and fabricates an intelligent controlled-release breaker system based on paraffin-coated mesoporous silica nanoparticle carriers. Three types of mesoporous silica (MSN) carriers with distinct pore sizes are synthesized via the sol-gel method using CTAB, P123, and F127 as structure-directing agents, respectively. Following hydrophobic modification with octyltriethoxysilane, n-butanol breaker agents are loaded into the carriers, and a temperature-responsive controlled-release system is constructed via paraffin coating technology. The pore size distribution was analyzed by the BJH model, confirming that the average pore diameters of CTAB-MSNs, P123-MSNs, and F127-MSNs were 5.18 nm, 6.36 nm, and 6.40 nm, respectively. The BET specific surface areas were 686.08, 853.17, and 946.89 m2/g, exhibiting an increasing trend with the increase in pore size. Drug-loading performance studies reveal that at the optimal loading concentration of 30 mg/mL, the loading efficiencies of n-butanol on the three carriers reach 28.6%, 35.2%, and 38.9%, respectively. The release behavior study under simulated reservoir temperature conditions (85 °C) reveals that the paraffin-coated system exhibits a distinct three-stage release pattern: a lag phase (0–1 h) caused by paraffin encapsulation, a rapid release phase (1–8 h) induced by high-temperature concentration diffusion, and a sustained release phase (8–30 h) attributed to nano-mesoporous characteristics. This intelligent controlled-release breaker demonstrates excellent temporal compatibility with coalbed methane fracturing processes, providing a novel technical solution for the efficient and clean development of coalbed methane. Full article
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17 pages, 2885 KB  
Article
Silanization-Modified Lignin Nanoparticles for Paper Coating with Enhanced Liquid and Vapor Barriers, Frication Resistance, and Self-Cleaning Properties
by Wen Chen, Ren’ai Li, Yunfeng Cao, Chunjie Ye, Zhulan Liu and Huining Xiao
Polymers 2025, 17(15), 2066; https://doi.org/10.3390/polym17152066 - 29 Jul 2025
Viewed by 515
Abstract
Paper’s inherent hydrophilicity and porosity cause inadequate barrier properties, failing under high humidity/temperature. This study successfully developed a hydrophobic nanocoating agent (xLNPs-OTS) through silanization modification using D276 (lignin nanoparticles with a diameter of 276 nm) as the substrate and OTS (octadecyltrichlorosilane) as the [...] Read more.
Paper’s inherent hydrophilicity and porosity cause inadequate barrier properties, failing under high humidity/temperature. This study successfully developed a hydrophobic nanocoating agent (xLNPs-OTS) through silanization modification using D276 (lignin nanoparticles with a diameter of 276 nm) as the substrate and OTS (octadecyltrichlorosilane) as the functionalizing agent. By applying the coating to paper surfaces followed by a hot-pressing process, the paper achieved comprehensive performance enhancements, including superior water, oil, and vapor barrier properties, thermal stability, mechanical strength, frictional resistance, and self-cleaning capabilities. The Cobb 60 value of LOTSC3.5T120t30 (the coating made from the OTS silanized lignin with the coating amount of 3.5 g/m2 and a hot-pressing at 120 °C for 30 min) coated paper is as low as 3.75 g/m2, and can withstand hot water at 100 °C for 60 min. The Cobb 60 value of the LOTSC20T120t30 (the coating made from the OTS silanized lignin with the coating amount of 20 g/m2 and a hot-pressing at 120 °C for 30 min) coated paper is reduced to 0.9 g/m2, the Kit grade is 6, and all coated papers are endowed with self-cleaning features. This study advances lignin’s high-value utilization, driving sustainable packaging and supporting eco-friendly paper material development. Full article
(This article belongs to the Special Issue Advances in Lignocellulose Research and Applications)
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