Search Results (3,776)

The ever-increasing number of discarded end-of-life dialysate polyamide thin-film composite membranes (DEoLMs) from presents both environmental and economic challenges for health centers. Traditional thermo-chemical cleaning techniques have been deployed for the rehabilitation of DEoLMs. This study further investigated the application of chemo-ultrasonication rehabilitation of dialysate-production-related DEoLM for potential reuse in spent dialysate recovery considering salt and creatinine—a typical uremic toxin-removal from water. The DEoLM was rehabilitated using low-concentration citric acid (CA) and sodium lauryl sulfate (SLS) under ultrasonic waves (45 kHz, 30 min agitation). Considering different rehabilitation protocols, the synergistic effects of heating (HT) and the chemical agents, with and without and ultrasonic waves (SC) were evaluated through FTIR, SEM, and EDX analyses, and the performance of the rehabilitated DEoLM was assessed via water flux and permeance, and efficiencies for conductivity and creatinine rejection. The fully integrated protocol chemo-ultrasonication (HT + SC + chemical agents) yielded the highest performance, achieving 93.56% conductivity and 96.83% creatinine removal, with water flux of 113.48 L m⁻² h⁻¹ and permeances of 6.31 L m⁻² h⁻¹ bar⁻¹, at markedly reduced pressures. The chemo-sonic-rehabilitated-DEoLM removed the organic–inorganic foulants beyond thermo-chemical cleaning. This suggests that the sonication waves had a great impact regarding rejuvenating the fouled DEoL dialysate membrane, offering a sustainable, cost-effective pathway for extending membrane life, and supporting sustainable water management to achieve circular economy goals within healthcare centers. Full article

Energy communities have recently gained significant attention as local entities that empower neighborhoods to contribute actively to the clean energy transition by adopting solar energy. However, the variability of weather conditions makes PV energy production highly unpredictable, emphasizing the need for accurate prediction and forecasting to ensure efficient operation and balance supply and demand. This study investigates the use of machine learning models to predict PV energy generation from multiple household rooftop photovoltaic (PV) systems within an energy community, with solar irradiance serving as the sole input parameter. Furthermore, various deep learning architectures were also explored to forecast solar radiation and determine the optimal model configuration. The results show that the Random Forest model performed better than the other models tested, achieving the lowest error metrics for PV energy prediction. For solar radiation forecasting, the GRU model demonstrates good performance compared the other models. Full article

This study aimed to evaluate the effect of rosemary and oregano extracts on the chemical composition, physicochemical parameters, and sensory characteristics of pork pâtés under cold storage for 1, 7, and 14 days. Five different experimental variants were developed: “k”—control sample (no extract added), “rr”—with 50% rosemary extract added, “rs”—with 100% rosemary extract added, “oo”—with 50% oregano extract added, and “os”—with 100% oregano extract added. The study showed that rosemary and oregano extracts did not cause significant changes in the basic chemical composition and pH. However, they significantly affected the oxidative stability, color characteristics, texture, and sensory acceptance of the pâtés. TBARS (lipid oxidation rate) values systematically increased during storage, with the lowest lipid oxidation rate observed in samples with rosemary extract. The extracts also limited the increase in oxidation-reduction potential compared to the control sample. Changes in texture parameters were also observed, but the additives significantly reduced their unfavorable character, particularly in terms of hardness and chewiness. Sensory evaluation results confirmed the positive impact of the extracts, particularly in terms of odor and taste, which were rated significantly higher than in the control sample. The conducted studies indicate that rosemary and oregano extracts may be a natural source of compounds with antioxidant properties and stabilize the quality of pork pâtés. Their use may provide an effective and consumer-acceptable alternative to synthetic preservatives, supporting the development of meat products aligned with the “clean label” trend. Full article

China’s rapid economic growth since its reform and opening-up has come at the cost of worsening atmospheric pollution. This study investigates the spatiotemporal evolution and driving mechanisms of PM_2.5 concentrations in Shandong province, a key industrial region, during 2014–2023, using comprehensive air quality monitoring, meteorological observations, and socioeconomic datasets. Through spatial analysis and geodetector methods, we identify that (1) The annual PM_2.5 concentration decreases significantly by 50.9%; spatially, heterogeneity is observed with the western urban agglomeration experiencing more severe pollution, while the eastern coastal urban agglomeration exhibits better air quality. (2) Gravity model analysis shows that the centroids of PM_2.5 pollution undergo distinct migration phases. (3) PM_2.5 levels show a distinct seasonal pattern, peaking in winter at a level 143.7% higher than the summer average. (4) The meteorological driving factors are primarily air temperature (r = 0.511) and wind speed (r = −0.487), while the socioeconomic factors are tertiary industry production (r = −0.971), particulate matter emissions (r = 0.956), and sulfur dioxide emissions (r = 0.938). Concurrently, the combined effect of tertiary industry production and PM emissions account for 99.5% of PM_2.5 variability. Notably, we validate an Environmental Kuznets Curve relationship (R² = 0.805) between economic development and air quality improvement, demonstrating that clean production policy integration can reconcile environmental and economic objectives. These findings provide empirical evidence supporting circular economy strategies for air pollution mitigation in industrializing regions. Full article

This study investigates the viability of using Ammonia as a carbon-free fuel for heat generation in terms of both reactive Nitrogen and Carbon emissions and production cost. As a carbon-free, environmentally friendly energy carrier, Ammonia has the potential to play a significant role in the sustainable, clean energy supply of the future. However, a major drawback of the steady combustion of ammonia for process heat generation is the extremely high levels of NO_x emissions it produces. In this pilot-scale study, the experimental results show that, through the oscillating combustion of NH₃, NO_x emissions can be reduced by as much as 80%. Production costs were compared to evaluate the economic feasibility of Ammonia-based heat; the results reveal the economic challenges associated with using Ammonia compared to natural gas, even when accounting for the development of CO₂ pricing. Only in terms of Carbon Capture and Storage requirements is Ammonia-based heat economically advantageous. This study also scrutinizes the economies of the production of gray and green Ammonia. Considering CO₂ certificate costs, the cost of green ammonia would be competitive in the near future. Full article

Tambatinga (Colossoma macropomum × Piaractus brachypomus), a hybrid Amazonian fish recognized for its superior growth performance, represents a valuable and sustainable source of collagen-rich raw material. Due to its tropical origin, the species’ skin may contain higher levels of amino acids, which can enhance the functional and structural properties of gelatin derived from it. The valorization of fish processing residues for biopolymer production not only mitigates environmental impacts but also reinforces the principles of the circular economy within aquaculture systems. This study explores the development of biopolymer films from Tambatinga skin, an abundant by-product of Brazilian aquaculture. The skins were cleaned and subjected to a hot water–acid extraction process to obtain gelatin. The extracted gelatin exhibited high proline and hydroxyproline contents (12.47 and 9.84 g/100 g of amino acids, respectively) and a Bloom strength of 263.9 g, confirming its suitability for film formation. Films were prepared using 2 g of gelatin per 100 g of film-forming solution, with glycerol added at 10 and 20 g/100 g of gelatin. The resulting films were transparent, flexible, and showed uniform surfaces. Increasing the glycerol concentration reduced tensile strength (from 59.4 to 37.9 MPa) but improved elongation at break (from 116% to 159.1%) and modified the films’ thermal behavior. Moreover, Tambatinga gelatin films demonstrated excellent UV-blocking performance (below 300 nm) and lower water vapor permeability compared to other gelatin-based films reported in the literature. These findings highlight the potential of fish skin—typically regarded as industrial waste—as a renewable and high-value raw material for the production of sustainable biopolymers. This approach supports resource efficiency, waste reduction, and the broader goals of sustainable development and circular bioeconomy. Full article

The rapid advancement of technologies such as artificial intelligence, big data, and cloud computing has driven continuous expansion of global data centers, resulting in increasingly severe energy consumption and carbon emission challenges. According to projections by the International Energy Agency (IEA), the global electricity demand of data centers is expected to double by 2030. The construction of green data centers has emerged as a critical pathway for achieving carbon neutrality goals and facilitating energy structure transition. This paper presents a systematic review of the role of waste heat recovery technologies in data centers for achieving low-carbon development. Categorized by aspects of waste heat recovery technologies, power production and district heating, it focuses on assessing the applicability of heat collection technologies, such as heat pumps, thermal energy storage and absorption cooling, in different scenarios. This study examines multiple electricity generation pathways, specifically the Organic Rankine Cycle (ORC), Kalina Cycle (KC), and thermoelectric generators (TEG), with comprehensive analysis of their technical performance and economic viability. The study also assesses the feasibility and environmental advantages of using data center waste heat for district heating. This application, supported by heat pumps and thermal energy storage, could serve both residential and industrial areas. The study shows that waste heat recovery technologies can not only significantly reduce the Power Usage Effectiveness (PUE) of data centers, but also deliver substantial economic returns and emission reduction potential. In the future, the integration of green computing power with renewable energy will emerge as the cornerstone of sustainable data center development. Through intelligent energy management systems, cascaded energy utilization and regional energy synergy, data centers are poised to transition from traditional “energy-intensive facilities” to proactive “clean energy collaborators” within the smart grid ecosystem. Full article

Glyphosate, a widely used non-selective herbicide, has been a subject of intense scientific debate due to its environmental persistence and potential health risks. This review examines glyphosate’s mechanisms of action, its effects on crop production, and its broader environmental impact, including soil degradation, water contamination, and biodiversity loss. Furthermore, it examines the expanding body of research linking glyphosate exposure to various human health concerns, including metabolic, neurological, reproductive, and oncological disorders. The review also assesses glyphosate’s role in hindering the achievement of the Sustainable Development Goals (SDGs), particularly those related to food security, health, access to clean water, and the protection of marine ecosystems. Finally, potential alternatives to glyphosate-based weed control, including organic and non-chemical methods, are discussed to promote sustainable agricultural practices that balance productivity with ecological and public health considerations. The evidence reviewed highlights glyphosate’s pervasive presence across ecosystems and its potential to disrupt both environmental and human health. The findings underscore the urgent need to regulate glyphosate use, prioritize soil and water protection, and accelerate the transition toward sustainable, low-toxicity weed management strategies that align with global sustainability objectives. Full article

The manufacturing of detergent products such as laundry detergents or household cleaners is of increasing interest to the chemical industry. Surfactants and fatty acids are the most important ingredients in detergent formulations, as they are responsible for the cleaning power and the antimicrobial efficiency of the cleaning product. Computational tools can play a key role in the design and performance optimization of detergent products as they allow for quick and efficient screening of candidate surfactants in detergent formulations. In the present study, an automated fragmentation and parametrization protocol is utilized to investigate the adsorption of candidate fatty acid surfactants towards bacterial inner membranes. The effect of the surfactant size, concentration, and tendency for micelle formation on the degree of their adsorption on the inner membrane is examined. Analysis demonstrates that surfactant–inner membrane interaction weakens with surfactant size and aggregation tendency, as confirmed by pertinent experimental and simulation studies. The outcome of this study demonstrates that the adopted multiscale protocol allows for an accurate and cost-effective description of the systems examined at timescales much shorter than those required in laboratory experiments and atomistic simulations. Full article

Syngas fermentation is a promising carbon capture and utilization (CCU) technology for producing carboxylic acids while transforming low-cost waste gas into high-value products. This study evaluates the two bioreactor feeding strategies for synthesis gas (syngas) fermentation by Eubacterium callanderi (formerly Butyribacterium methylotrophicum) strain Marburg—on-demand feeding (ODF) and continuous feeding (CF)—with a synthetic syngas mixture of 23 vol% CO₂, 29 vol% CO, 32 vol% H₂, and 16 vol% CH₄, mimicking the syngas from lignocellulosic gasification. The ODF assay achieved a maximum syngas consumption rate of 112 mL/h, yielding 24.1 g/L acids, namely 22.9 g/L acetate and 1.3 g/L butyrate. CF of syngas at 223 mL/h required more gas (62.9 L) to produce 22.7 g/L total acids, from which 19.0 g/L acetate and 3.7 g/L butyrate were achieved. The CF-specific production rate (g_product/g_{dry_cell_weight}/hour) reached 0.5 g/g_DCW/h (acetate) and 0.17 g/g_DCW/h (butyrate), outperforming ODF with 0.3 and 0.02 g/g_DCW/h, respectively. ODF minimized gas wastage and enabled CH₄ accumulation inside the bioreactor up to approximately 78 vol%, while CF led to CO₂ accumulation, indicating a need for more efficient CO₂ utilization strategies, such as sequential fermentations. This work highlights the critical impact of the two feeding options studied with regard to scaling up the carbon-efficient production of carboxylic acids, and indicates that both strategies can have potential applications. ODF is ideal for increasing carbon fixation and achieving, simultaneously, gas cleaning, while CF fermentations are better suited to maximizing the acid production rate. Full article

Coalbed methane (CBM) is a vital clean energy resource, yet its extraction efficiency is often hindered by rapid production decline and low production rates in medium-shallow reservoirs. This study investigates the potential of CO₂ huff-and-puff technology to enhance CBM recovery and achieve CO₂ storage in low-productivity wells. A comprehensive model, constructed based on the geological conditions of the Qinshui Basin, was developed. Numerical simulations revealed that CO₂ huff-and-puff significantly improves CH₄ production by displacing adsorbed CH₄ and maintaining reservoir pressure. Key findings indicate that higher CO₂ injection volumes yield substantial increases in both peak CH₄ production and cumulative production compared with conventional extraction. Optimal soaking times balance recovery efficiency and operational costs. Sensitivity analysis identified gas diffusion coefficients, initial permeability, and Langmuir volume constants as critical geological parameters influencing the performance. This study preliminarily demonstrates the feasibility of large-scale CO₂ huff-and-puff for enhancing production in low-productivity CBM wells and provides theoretical insights for revitalizing China’s underperforming CBM wells while advancing carbon neutrality goals, although further experimental validation is still required. Full article

Pharmaceuticals and personal care products (PPCPs) are among the most frequently detected emerging pollutants in aquatic sediments, raising increasing concerns due to their persistence, bioaccumulation potential, and ecological impact. As sediments act both as reservoirs and secondary sources of contamination, effective and environmentally responsible analytical methodologies are essential for accurate environmental monitoring and risk assessment. This review presents a critical evaluation of extraction-based workflows for PPCP determination in sediment matrices, covering literature published from 2015 to 2025. We systematically analyze each step of the analytical pipeline, including sample pre-treatment, extraction, clean-up, and instrumental analysis, while emphasizing how method selection and optimization affect recovery rates, sensitivity, and detection limits. Special attention is paid to the physicochemical characteristics of PPCPs that govern extraction behavior, as well as to the trade-offs between analytical efficiency and environmental sustainability, such as solvent type, energy demand, and method greenness. By consolidating current knowledge, this work aims to lay a theoretical foundation for researchers and practitioners in selecting suitable, robust, and sustainable analytical strategies for effective environmental protection. Full article

Galactooligosaccharides (GOS) typically consist of 2-8 D-galactose units linked together, terminating in a D-glucose unit. GOS are commonly used in dairy products, infant formulas, and functional foods. GOS offer beneficial properties for food processing, such as low caloric value, mild clean taste, and excellent solubility in water. Additionally, GOS function as non-digestible prebiotics, supporting microbiota balance and offering benefits such as promoting infant health, immune modulation, laxative effects, and potential metabolic advantages. β-galactosidase plays a key role in GOS production, catalyzing both hydrolysis and transglycosylation reactions. In this study, a putative GH2 family β-galactosidase from Kosakonia oryzendophytica (Koor β-gal) was identified. The enzyme exhibited optimal activity at pH 7.0 and 45–50 °C with the addition of 1 mM Mg²⁺, showing a specific activity of approximately 288.6 U/mg towards o-nitrophenyl-β-D-galactopyranoside (ONPG). After optimizing the reaction conditions, Koor β-gal successfully produced 124.7 g/L of GOS from 300 g/L D-lactose, achieving a GOS yield of 41.6%. LC-MS analysis revealed that the primary products consisted of GOS with degrees of polymerization (DP) ranging from 2 to 4. Additionally, Koor β-gal was heterologously expressed in Bacillus subtilis following comprehensive optimization of the promoter and 5′-UTR, resulting in an enzyme activity in culture filtrate of 106.2 U/mL after 60 h. Full article

The incorporation of bioactive compounds into food products represents a promising approach to enhance their functional and health-promoting properties. However, many bioactive compounds, such as polyphenols, essential oils, carotenoids, and omega-3 fatty acids, are highly sensitive to environmental factors, including temperature, oxygen, and light, which limits their direct application in the food industry. Microencapsulation has emerged as an innovative strategy to overcome these challenges by protecting bioactive compounds, improving their stability, controlling their release, and masking undesirable flavors or odors. This article reviews recent advances in microencapsulation techniques, including spray-drying, freeze-drying, coacervation, and innovative methods such as nanoencapsulation and electrospinning. Particular attention is given to the influence of encapsulated bioactive compounds on the physicochemical characteristics, texture, color, and sensory attributes of various food matrices. Furthermore, the paper highlights industrial perspectives, emphasizing the scalability of these techniques, regulatory considerations, and their role in the development of clean-label, functional, and sustainable food products. The findings underline the potential of microencapsulation as a key technology for the next generation of functional foods, bridging consumer expectations with industrial feasibility. Full article

Hydrogen is being increasingly recognized as a promising clean, renewable energy carrier. Among the available production pathways, biological processes, particularly dark fermentation of residual biomasses and agricultural by-products, represent an appealing approach aligned with circular economy principles. These feedstocks are abundant and low cost; however, their relatively low energy density constrains process efficiency. To mitigate this limitation, research efforts have concentrated on optimizing substrate composition and implementing pre-treatment strategies to enhance hydrogen yields. Numerous studies have explored the potential of agricultural and livestock residue, yet reported outcomes are often heterogeneous in terms of units, systems, and experimental conditions, complicating direct comparison. This review consolidates current knowledge and identifies effective strategies to optimize biohydrogen generation. Among the investigated substrates, corn stover emerges as the most promising, with hydrogen yields up to 200 [mL H₂/gVS (Volatile Solids)]. Evidence further suggests that inoculum processing, including enrichment or pre-treatment, can substantially improve performance, often more effectively than substrate processing alone. When both inoculum and substrate are treated, hydrogen yields may increase up to fourfold relative to untreated systems. Overall, integrating suitable feedstocks with targeted processing strategies is crucial to advancing sustainable biohydrogen production. Full article