Search Results (1,386)

Methane (CH₄) is a potent greenhouse gas with a significant impact on short- and medium-term climate forcing, and its atmospheric concentration has been increasing rapidly in recent decades. This study aims to analyze spatio-temporal patterns of atmospheric methane concentrations between 2019 and 2025, focusing on comparisons between regions characterized by high and low emission intensities. Level-3 XCH₄ data from the TROPOspheric Monitoring Instrument (TROPOMI) onboard the Sentinel-5 Precursor satellite were used, which were aggregated into seasonal and annual composites. High-emission regions, such as the Mekong Delta, Nile Delta, Eastern Uttar Pradesh and Bihar, Central Thailand, Lake Victoria Basin, and Eastern Arkansas, were contrasted with low-emission areas including Patagonia, the Mongolian Steppe, Northern Scandinavia, the Australian Outback, the Sahara Desert, and the Canadian Shield. The results show that high-emission regions exhibit substantially higher seasonal amplitude in XCH₄ concentrations, with an average seasonal variation of approximately 30.00 ppb, compared to 17.39 ppb in low-emission regions. Methane concentrations generally peaked at the end of the year (Q4) and reached their lowest levels during the first half of the year (Q1 or Q2), particularly in agriculturally dominated regions. Principal component and cluster analyses further confirmed a strong spatial differentiation between high- and low-emission regions based on both temporal trends and seasonal behavior. These findings demonstrate the potential of satellite remote sensing to monitor regional methane dynamics and highlight the need for targeted mitigation strategies in major agricultural and wetland zones. Full article

Harmful Raphidiopsis raciborskii blooms threaten aquatic ecosystems via toxin production, hypoxia induction, and biodiversity loss. To elucidate the synergistic regulatory mechanisms of Fe³⁺ and phosphorus (P) in cyanobacterial growth, we used a sterile pure culture system under laboratory conditions. We set different phosphorus sources (organic phosphorus and inorganic phosphorus) and low phosphorus concentration of R. raciborskii culture medium for culture, and set different Fe³⁺ addition amount to determine the basic growth index of cyanobacteria cells and the phosphorus content of different components. The results revealed that under conditions of sufficient inorganic phosphorus, there was a logarithmic relationship between ferric ammonium citrate (Fe³⁺) and the specific growth rate of R. raciborskii. Fe³⁺ > 2 mg/L enhanced IPS enrichment and biomass accumulation. However, in oligotrophic or mesotrophic environments with low inorganic phosphorus concentrations, the effect of Fe³⁺ on the growth of R. raciborskii contrasted with that observed in high-IP (eutrophic) environments, exhibiting a pattern of ‘low promotion and high inhibition’. Under organic phosphorus conditions, R. raciborskii converted phosphorus by increasing alkaline phosphatase activity (APA), but this metabolic compensation failed to restore physiological functions, resulting in growth suppression and enhanced cellular phosphorus reserves. Our results establish quantitative linkages between Fe³⁺-P co-limitation thresholds and algal adaptive responses, providing mechanistic insights for controlling bloom dynamics through targeted manipulation of Fe-P bioavailability. Full article

Leonardite (LEO), a microbial derived product rich in humic and fulvic acids, has been tested, due to its beneficial properties for health and well-being, as a feed additive, mainly in non-ruminant species. Although there are some reports of LEO supplementation in ruminants fed with high-to medium-forage based diets, there is no information available of the potential effects of LEO in ruminants fed, under sub-tropical climate conditions, with high-energy diets during long-term fattening. For this reason, the objective of the present experiment was to evaluate the effects of LEO levels inclusion in diets for feedlot lambs finished over a long-term period. For this reason, 48 Pelibuey × Katahdin lambs (initial weight = 20.09 ± 3.55 kg) were fed with a high-energy diet (88:12 concentrate to forage ratio) supplemented with LEO (with a minimum of 75% total humic acids) for 130 days as follows: (1) diet without LEO, (2) diet supplemented with 0.20% LEO, (3) diet supplemented with 0.40% LEO, and (4) diet supplemented with 0.60% LEO. For each treatment, Leonardite was incorporated with the mineral premix. Lambs were blocked by weight and housed in 24 pens (2 lambs/pen). Treatment effects were contrasted by orthogonal polynomials. The average climatic conditions that occurred during the experimental period were 31.6 ± 2.4 °C ambient temperature and 42.2 ± 8.1% relative humidity (RH). Those values of ambient temperature and RH represent a temperature humidity index (THI) of 79.07; thus, lambs were finished under high heat load conditions. The inclusion of LEO in diet did not affect dry matter intake (p ≥ 0.25) and average daily gain (p ≥ 0.21); therefore, feed to gain ratio was not affected (p ≥ 0.18). The observed to expected dietary net energy averaged 0.96 and was not affected by LEO inclusion (p ≥ 0.26). The lower efficiency (−4%) of dietary energy utilization is an expected response given the climatic conditions of high ambient heat load presented during fattening. Lambs that were slaughtered at an average weight of 49.15 ± 6.00 kg did not show differences on the variables measured for carcass traits (p ≥ 0.16), shoulder tissue composition (p ≥ 0.59), nor in visceral mass (p ≥ 0.46) by inclusion of LEO. Under the climatic conditions in which this experiment was carried out, LEO supplementation up to 0.60% in diet (equivalent to 0.45% of humic substances) did not did not help to alleviate the extra-energy expenditure used to dissipate the excessive heat and did not change the gained tissue composition of the lambs that were fed with high-energy diets during long-term period under sub-tropical climate conditions. Full article

The Maillard reaction is a complex chemical reaction that occurs between nucleophilic groups, such as thiolates or amino groups primarily from amino acids, peptides, proteins, and carbonyl groups, particularly from reducing sugars. The pH value of the medium is a key parameter controlling the kinetics of the Maillard reaction, as it influences the concentration of nucleophilic groups. Other specific conditions of reaction medium such as temperature, reaction time (or residence time in a process), and water activity also significantly influence the Maillard reaction. Understanding the impact of these parameters is essential for optimizing the Maillard reaction to enhance sensory attributes, nutritional qualities, and product stability during the storage and distribution of the final products. The Maillard reaction is responsible for the formation of desirable sensory qualities such as flavor, aroma, color, and texture in cooked and thermally processed foods, in addition to the improvement of nutritional value and shelf life of foods. In contrast, there are limitations in its industrial applications, as it can also generate harmful compounds such as acrylamide, N(6)-carboxymethyllysine, furans, and heterocyclic amines, as well as undesired changes in the nutritional value of the food. This review provides an overview of the Maillard reaction’s mechanism, influencing parameters, pros and cons, as well as some food industrial applications. Full article

Traditional villages in the Yellow River Basin of China are vital carriers of cultural heritage, ecological sustainability, and socio-economic development. This study employs spatial econometric analysis to examine the distribution patterns and influencing factors of 888 traditional villages in the region. The findings reveal a clustering pattern, with high-density areas in Shanxi and medium-density clusters in Shaanxi and Qinghai, while northern and southern regions remain sparse. Over time, the spatial center of village distribution has shifted along a north–south–north–east–west trajectory. The spatial distribution of traditional villages exhibits distinct regional characteristics and differences, shaped by several key influencing factors. These include elevation, precipitation, river proximity, road density, and the presence of cultural heritage units. Results show that in the upper reaches of the Yellow River Basin, natural factors primarily determine village locations. In contrast, economic development and infrastructure factors play a larger role in shaping village transformation in the middle and lower reaches. Policy interventions, such as cultural heritage protection, have a greater impact on remote upper areas. The influence of these factors varies spatially, highlighting the importance of region-specific conservation strategies. Based on these findings, this study proposes targeted strategies for the conservation and development of traditional villages, including multi-type protection systems, cultural corridor construction, watershed-based governance, and enhanced infrastructure and policy support. These strategies aim to support the sustainable development and long-term preservation of traditional villages in the Yellow River Basin. By integrating geographic, economic, and cultural perspectives, this research provides valuable insights into the spatial evolution of traditional villages and informs policy recommendations for achieving balanced rural development. Full article

The rapid urbanization in the Kabul River Basin has increased the demand for water for both drinking and commercial purposes, leading to domestic and industrial water insecurity. Assessing the groundwater potential of the Kabul River Basin is highly crucial for effective water management. The aim of this paper is to identify potential zones for groundwater by employing a Geographic Information System and an Analytical Hierarchy Process approach to formulate a cumulative score based on seven thematic images—rainfall, geology, lineament density, drainage density, land use/land cover, soil type, and slope—within the Kabul River, with assigned weightages of 32%, 27%, 12%, 10%, 8%, 6%, and 5%, respectively, with a consistency ratio of 0.053 (5%), demonstrating the reliability of the results. The study shows that the first three factors contribute more to the percentages of Groundwater Potential Zones. The identified groundwater potential is classified into very good, good, medium, poor, and very poor zones, covering 35.45% (19,989 km²), 37.2% (20,978 km²), 23.16% (13,063 km²), 4.13% (2332 km²), and 0.06% (19 km²), respectively. Groundwater potential in the basin is predominantly classified as good to medium; however, there are notable variations across sub-basins. The Swat sub-basin and western parts of the Kabul River Basin, encompassing the Panjshir and Parwan districts, exhibit exceptionally high groundwater potential. In contrast, the Panjkora sub-basin (Dir district) and southwestern areas of the Kabul River Basin, covering parts of the Ghazni and Wardak districts, have very limited groundwater potential. Full article

Women entrepreneurs in small to medium enterprises (SMEs) in emerging countries play an essential role in the economy of developing countries such as Indonesia. Drawing on the resource-based view and entrepreneurship effectuation theory, this study examines how women’s entrepreneurial effectuation (WEE) modeled as a higher-order construct (HOC) comprising its four dimensions (LOCs)—namely, flexibility, experimentation, affordable loss, and pre-commitment—can influence employee performance (EMPRF) mediated by structural (STREM) and psychological empowerment (PSYEM). Using a disjointed two-stage PLS-SEM approach with data from 218 female SME employees, our results confirm that flexibility is the most salient effectuation dimension. WEE strongly predicts both STREM and PSYEM but shows no direct impact on EMPRF, highlighting that effectuation must be activated via empowerment mechanisms. PSYEM emerges as the strongest mediator of WEE on EMPRF, with STREM also contributing significantly and being amplified by gender equality practices; market orientation, by contrast, fails to moderate any paths. Theoretically, these findings enrich resource-based view (RBV) theory by integrating entrepreneurial effectuation dimensions and empowerment as human resource capabilities that generate inimitable performance gains. Practically, they suggest that women-led SMEs should integrate effectuation heuristics with targeted empowerment programs to realize the full potential of their human capital. Full article

The metabolic activity of fermentative microorganisms plays a critical role in determining the flavor profile of fermented meat products. Modulating carbon and nitrogen sources represents a promising strategy for enhancing product quality. In this study, Debaryomyces hansenii strains isolated from dry-cured ham were assessed in a sterile sausage model to evaluate the effects of different carbon sources (sucrose, corn starch) and nitrogen sources (leucine, soy protein isolate) on colony growth, enzyme activity, and physicochemical properties. These nutritional factors significantly affected the fermentation performance of D. hansenii. Corn starch and soy protein isolate increased colony count by 14.94% and 90%, respectively, and enhanced protease activity by 2-fold and 4.5-fold. Both treatments maintained high lipase activity (>50 U/g). Both supplements improved the water-holding capacity and decreased the water activity. Carbon sources reduced the medium pH, whereas nitrogen sources contributed to the maintenance of pH stability. A further analysis indicated that corn starch promoted the accumulation of aldehydes and ketones, which intensified the sourness and suppressed the saltiness. In contrast, soy protein isolate increased the abundance of free amino acids associated with umami and sweetness, and stimulated the formation of esters, ketones, and pyrazines, thereby enhancing flavor richness and umami intensity. Both ingredients also reduced saturated fatty acid levels and increased the unsaturated to saturated fatty acid ratio. Soy protein isolate exhibited a more pronounced effect on D. hansenii fermentation. This study provides a technical reference for enhancing the flavor characteristics of fermented meat products via the adjustment of carbon and nitrogen sources to regulate D. hansenii fermentation. Full article

The geopolitical and economic situation impacts raw materials demand. As principal ore deposits reach exhaustion, the study of new sources of raw materials becomes essential. Therefore, mining wastes emerge as alternative sources of raw materials. Their physicochemical properties, such as small particle size or concentration of some metals of interest, enhance reprocessing. A number of critical raw materials (As, Co, Cu, Sb) and base metals (Pb, Zn), as well as precious metals (Ag), were found present in an abandoned tailing deposit composed by finely grounded washed roasted pyrites within the Iberian Pyrite Belt. Copper leaching from a sample of this deposit was investigated. Two hydrometallurgical approaches were studied: acidic leaching with and without activated carbon; and alkaline leaching with glycine solutions. Leaching tests were carried out during 24 h at ambient and moderate temperatures (60 °C). In acidic medium, the maximum copper extraction varied from 88 to 92.5%, while in alkaline medium, the maximum copper extraction was in the range of 71%–76%. Using activated carbon and H₂O₂ seemed to slightly promote the copper extraction with the maximum extraction (92.5%) after 2 h of leaching at 60 °C. Complementarily, above 50% of the zinc and cobalt contained were extracted. In contrast, temperature in alkaline conditions played a key role in reaction speed, but also in precipitation of copper insoluble compounds. In addition, the glycine solution at pH 10–10.5 showed high selectivity for copper over zinc, iron, lead, arsenic, and antimony. Two extra tests at pH above 12 showed arsenic dissolution (up to 51% at pH 12.5). Full article

The seepage diffusion of cement grouting materials into a sandy medium is influenced by the skeleton’s adsorption and the pore channels’ tortuosity, resulting in heterogeneous retention of cement particles during migration. This study established a theoretical model for the filtration coefficient based on the mass balance equation and linear filtration law. Grouting tests were conducted to determine the density of the cement slurry at various diffusion positions, and the filtration coefficient was calculated using the theoretical model. Results indicate that the filtration coefficient varies dynamically along the diffusion distance rather than remaining constant. The surface filtration range of Grade 42.5 Portland Cement slurry in sample S1 is approximately 30 cm, with a final diffusion distance of 190 cm. In contrast, the surface filtration ranges for the 800 mesh superfine cement in S2 and the 1250 mesh superfine cement in S3 are less than 10 cm, resulting in final diffusion distances of 69 cm and 87 cm, respectively. This demonstrates that a longer surface filtration range in the sand sample corresponds to a farther final diffusion distance of the slurry. Additionally, a larger ratio of sand pore diameter to cement particle size results in a smaller filtration coefficient and a greater slurry diffusion distance. Under a constant water–cement ratio, smaller cement particle sizes are associated with decreased slurry fluidity, which reduces the diffusion of cement slurry within the sandy medium. The research findings provide valuable insights for designing borehole spacing in grouting treatment for sandy media. Full article

This study investigates the interfacial reactions of FeCoNiCr and FeCoNiMn medium-entropy alloys (MEAs) with Sn and Sn-3Ag-0.5Cu (SAC305) solders at 250 °C. The evolution of interfacial microstructures is analyzed over various aging periods. For comparison, the FeCoNiCrMn high-entropy alloy (HEA) is also examined. In the Sn/FeCoNiCr system, a faceted (Fe,Cr,Co)Sn₂ layer initially forms at the interface. Upon aging, the significant spalling of large (Fe,Cr,Co)Sn₂ particulates into the solder matrix occurs. Additionally, an extremely large, plate-like (Co,Ni)Sn₄ phase forms at a later stage. In contrast, the Sn/FeCoNiMn reaction produces a finer-grained (Fe,Co,Mn)Sn₂ phase dispersed in the solder, accompanied by the formation of the large (Co,Ni)Sn₄ phase. This observation suggests that Mn promotes the formation of finer intermetallic compounds (IMCs), while Cr facilitates the spalling of larger IMC particulates. The Sn/FeCoNiCrMn system exhibits stable interfacial behavior, with the (Fe,Cr,Co)Sn₂ layer showing no significant changes over time. The interfacial behavior and microstructure are primarily governed by the dissolution of the constituent elements and composition ratio of the HEAs, as well as their interactions with Sn. Similar trends are observed in the SAC305 solder reactions, where a larger amount of fine (Fe,Co,Cu)Sn₂ particles spall from the interface. This behavior is likely attributed to Cu doping, which enhances nucleation and stabilizes the IMC phases, promoting the formation of finer particles. The wettability of SAC305 solder on MEA/HEA substrates was further evaluated by contact angle measurements. These findings suggest that the presence of Mn in the substrate enhances the wettability of the solder. Full article

Two-dimensional transition metal dichalcogenides have attracted considerable attention in electrocatalytic hydrogen evolution due to their unique layered structures and tunable electronic properties. However, prior research has predominantly focused on the intrinsic catalytic activity of planar few-layer structures, which offer limited exposure of edge-active sites due to their restricted two-dimensional geometry. Moreover, van der Waals interactions between layers impose substantial barriers to electron transport, significantly hindering charge transfer efficiency. To overcome these limitations, this study presents the innovative synthesis of high-quality single-screw WS₂ with a 5° dislocation angle via physical vapor deposition. Second harmonic generation measurements revealed a pronounced asymmetric polarization response, while the selected area electron diffractionand atomic force microscopy elucidated the material’s distinctive screwed dislocation configuration. In contrast to planar monolayer WS₂, the conical/screw-structured WS₂—formed through screw-dislocation-mediated growth—exhibits a higher density of exposed edge-active catalytic sites and enhanced electron transport capabilities. Electrochemical performance tests revealed that in an alkaline medium, the screwed WS₂ nanosheets exhibited an overpotential of 310 mV at a current density of −10 mA/cm², with a Tafel slope of 204 mV/dec. Additionally, under a current density of 18 mA/cm², the screwed WS₂ can sustain this current density for at least 30 h. These findings offer valuable insights into the design of low-cost, high-efficiency, non-precious metal catalysts for hydrogen evolution reactions. Full article

The growing demand for the sustainable production of high-value compounds, such as biofuels, lipids, and pigments like carotenoids and phycobilin, has become the subject of numerous investigations. Furthermore, this has led to the exploration of renewable methods utilizing microalgae as feedstock to mitigate the challenges associated with producing these valuable compounds. Nevertheless, despite the numerous advantages of microalgae, the development of a microalgal biorefinery that employs sustainable, environmentally friendly, and economically efficient technologies remains a necessity. To address this challenge, the bio-flocculation process, and more specifically self-flocculation, is presented as a cost-effective and energy-efficient solution. This method is as easy and effective as chemical flocculation, which is applied at an industrial scale; however, in contrast, it is sustainable and cost-effective as no costs are involved in the pre-treatment of the biomass for oil extraction or in the pre-treatment of the medium before it can be re-used. In addition, microalgae possess molecular tools that would allow the efficiency of these processes to be increased. In the present review, we summarize the microalgal harvesting technologies used, with a particular focus on bio- and self-flocculation processes, and identify the improvements that could be made to enhance the production of high-added-value compounds while simultaneously reducing costs in microalgae biorefineries. Full article

In response to the limitations of experimental methods for detecting oil and gas well tubing leaks, this study developed a full-scale indoor simulation system for oil tubing leakage. The system consists of three components: a wellbore simulation device, a dynamic leakage simulation module, and a multi-parameter monitoring system. The wellbore simulator employs a jacketed structure to replicate real-world conditions, while the leakage module incorporates a precision flow control device to regulate leakage rates. The monitoring system integrates high-sensitivity acoustic sensors and pressure sensors. Through multi-condition experiments, the system simulated complex scenarios, including leakage apertures of 1–5 mm, different leakage positions relative to the annular liquid level, and multiple leakage point combinations. A comprehensive acoustic signal processing framework was established, incorporating time–domain features, frequency–domain characteristics, and time–frequency joint analysis. Experimental results indicate that when the leakage point is above the annular liquid level, the acoustic signals received at the wellhead exhibit high-frequency characteristics typical of gas turbulence. In contrast, leaks below the liquid level produce acoustic waves with distinct low-frequency fluid cavitation signatures, accompanied by noticeable medium-coupled attenuation during propagation. These differential features provide a foundation for accurately identifying leakage zones and confirm the feasibility of using acoustic detection technology to locate concealed leaks below the annular liquid level. The study offers experimental support for improving downhole leakage classification and early warning systems. Full article

Population aging–weakening has become a critical constraint on rural sustainability in China’s Yellow River Basin (YRB), posing substantial challenges to ecological conservation and high-quality development. This study develops a multidimensional evaluation framework categorizing rural aging–weakening into four typologies: general development type (GDT), shallow aging–weakening type (SAT), medium aging–weakening type (MAT), and deep aging–weakening type (DAT). Then, the XGBoost model is used to assess the factors influencing the spatial diversity of aging–weakening types in the rural population at different spatial and temporal scales. The key findings reveal the following: (1) The proportion of aging–weakening areas increased from 65% (2000) to 72% (2020), exhibiting distinct regional trajectories. Upper reaches demonstrate severe manifestations (34% combined MAT/DAT in 2020), contrasting with middle reaches dominated by GDT/SAT (>80%). Lower reaches show accelerated deterioration (MAT/DAT surged from 10% to 31%). (2) Spatial differentiation primarily arises from terrain-habitat conditions, industrial capacity, urbanization, and agricultural income. While most factors maintained stable directional effects, agricultural income transitioned from positive to negative correlation post-2010. Upper/middle reaches are predominantly influenced by geographical environment, with the role of socioeconomic factors gradually increasing. Lower reaches exhibit stronger economic–environmental interactions. (3) This research provides actionable insights for differentiated regional strategies: upper reaches require ecological migration programs, middle areas need industrial transition support, while lower regions demand coordinated economic–environmental governance. Our typological framework offers methodological advancements for assessing demographic challenges in vulnerable watersheds, with implications extending to similar developing regions globally. Full article