Search Results (4,186)

This scoping review mapped the clinical readiness of directly additively manufactured (AM) dental ceramics for single-unit definitive restorations (crowns, veneers, and partial-coverage restorations) using a predefined review-specific five-tier readiness framework (R1–R5) designed to organize evidence maturity from restoration-relevant foundational studies to comparative clinical evidence. MEDLINE (PubMed), Scopus, Web of Science Core Collection, EBSCO (Dentistry and Oral Sciences Sources), and ClinicalTrials.gov were searched from inception to February 2026, with citation tracking. Thirty-five sources were included: 31 in vitro studies and 4 clinical studies. Evidence clustered in preclinical tiers, with most studies classified as restoration-level in vitro investigations (R2, 22/35) or foundational specimen-level studies explicitly linked to restorative performance (R1, 9/35); only one feasibility study reached R3 (1/35), three studies provided comparative clinical evidence (R4, 3/35), and no R5-level evidence was identified. The additively manufactured definitive restorations evaluated were zirconia-based. Most restoration-level studies addressed zirconia crowns (18/35), with fewer studies focusing on veneers/laminates (5/35) and occlusal veneers/tabletops (2/35). Across AM routes (most commonly vat photopolymerization ceramic workflows and nanoparticle jetting) outcomes focused on fit/adaptation, manufacturing accuracy, mechanical performance, and aging simulations; clinical studies reported short- to mid-term performance using standardized evaluation criteria. Overall, the evidence suggests technical feasibility and increasing restoration-level evaluation under controlled conditions, but clinical applicability remains preliminary because higher-readiness clinical evidence is still limited. Future work should prioritize standardized reporting, clinically relevant aging/fatigue paradigms, and longer-term comparative clinical studies. Full article

The aim of this study was to evaluate the influence of prosthetic substrate type, resin cement shade, and opaquer liner application on the translucency and color matching of translucent zirconia- and lithium-based ceramics. Four A2-shade zirconia materials (Katana HTML Plus, STML, UTML, and YML), with and without an opaquer liner, lithium disilicate ceramics (Amber Mill LT and HT), and zirconia-reinforced lithium silicate (Celtra Duo) were investigated. Monolithic crowns and standardized rectangular specimens were fabricated using CAD/CAM technology and cemented with neutral, warm-shade, and opaque try-in pastes onto A2-shade composite resin and cobalt–chromium substrates. Color measurements were performed using a digital colorimeter based on the CIE L*a*b* system. Translucency parameters (TPs) and color differences (ΔE) relative to the A2 reference shade were calculated. Lithium-based ceramics exhibited significantly higher translucency than zirconia materials. Application of the opaquer liner on intaglio surface of crowns reduced their translucency. On A2-shade substrates, translucent zirconia luted with neutral or warm-shade paste demonstrated the most favorable color compatibility. In contrast, opaque try-in paste resulted in clinically unacceptable color deviations and loss of optical depth. On metallic substrates, most materials exhibited pronounced gray discoloration and substantial color mismatch, particularly lithium disilicate ceramics. These findings indicate that ceramic type, substrate color, opaquer liner application, and resin cement shade significantly influence the optical performance and final color outcome of all-ceramic restorations. Full article

Functional traits help to understand plant ecological strategies and play a determinant role in restoration. This study evaluated interspecific variability among 38 timber species of bioeconomic importance associated with natural forests and forest trials in the northern Colombian Amazon, identifying Plant Functional Types (PFTs) and their implications for productive restoration. Soft and hard traits were integrated, including tree morphological characteristics (diameter at breast height, total height, and crown cover) and wood functional traits (wood basic specific gravity, SG; maximum moisture content; fiber diameter and wall thickness; and vessel diameter and density). Correlations among these traits were also assessed. Five PFTs were identified. PFTs 1 and 2 grouped species with acquisitive strategies and high hydraulic efficiency, making them suitable for rapid vegetation cover recovery. In contrast, PFT 5 included conservative and hydraulically safe species, appropriate for enrichment processes once vegetation cover has been established. PFTs 3 and 4 represented intermediate strategies. Additionally, tree size was found to directly influence stem hydraulic architecture, and distinct anatomical configurations may occur within similar SG ranges, highlighting the need to integrate multi-trait approaches, as this trait alone does not fully capture the hydraulic and mechanical strategies of species. Full article

This Finite Element Analysis study evaluated the biomechanical responses associated with posterior tooth intrusion using clear aligners in conjunction with buccal and palatal mini-screw anchorage. Three-dimensional finite element models were reconstructed from cone beam computed tomography images obtained from patients without craniofacial anomalies. To assess the differential effects of buccal versus palatal attachment placement in combination with a mini-screw-supported closing coil spring, two configurations of the maxillary arch were created: Model A (right side) and Model B (left side). Biomechanical parameters—including stress distribution, patterns of tooth displacement, and anchorage stability—were systematically assessed using finite element analysis. Analysis of Model A revealed buccal crown inclination and moderate extrusion of the first premolar, whereas the first molar showed limited mesial displacement along with mild buccal tipping and extrusion. In contrast, Model B revealed palatal crown inclination of the first premolar, accompanied by buccal root torque and minor intrusion; the first molar demonstrated enhanced vertical control with palatal root torque. The incorporation of palatal mini-screw anchorage in Model A contributed to diminished stress levels and reduced tooth displacement, suggesting a tendency toward more favorable force distribution and anchorage stability under the simulated conditions. Conversely, Model B experienced increased mechanical loading and more pronounced displacement. Full article

Accurate individual tree crown identification is essential for urban forestry, yet existing datasets often lack exhaustive annotations and multi-temporal diversity. To address this limitation, an exhaustively annotated dataset was curated for crown instance segmentation, comprising 47,754 labeled individual crowns from approximately 110 species across three temporal phases. Anchored in a “crown geometry” labeling criterion focusing on upper-canopy individuals visible in the imagery, and the high-resolution imagery captured seasonal variations in shape, color, and texture, providing an empirical basis for within-site robustness. Utilizing this dataset, this study (1) compared five instance segmentation models; (2) evaluated their generalization capabilities across different temporal phases; and (3) tested a multi-temporal joint training strategy and a non-maximum suppression (NMS)-based fusion. The experiments revealed significant overfitting in single-temporal models. While ConvNeXt-V2 achieved a high segmentation mean Average Precision (Segm_mAP) of 0.852 within the same temporal phase, its performance dropped sharply to 0.361 across phases. Bi-temporal joint training significantly mitigated this issue, improving cross-temporal performance to 0.665 and further increasing within-phase accuracy to 0.874. In contrast, tri-temporal training reduced accuracy (0.748), demonstrating that effective generalizability depends on the strategic selection of complementary temporal phases rather than the mere accumulation of data. The multi-temporal training framework provided in this study could serve as a practical reference and a foundational benchmark for further urban forest structural monitoring research. Full article

Fusarium oxysporum f. sp. radicis-lycopersici (Forl) is the etiological agent of tomato Fusarium crown and root rot (FCRR), a devastating soil-borne disease that severely compromises global tomato production. The pathogenicity of Forl has been increasingly linked to its capacity to produce phytotoxic isocassadiene-type diterpenoids. In this study, Forl was cultured in rice medium to obtain Forl cultures, which were used for the separation and identification of secondary metabolites. After removing the known metabolites, two new isocassadiene-type diterpenoid compounds, namely fusariumic acids I (1) and J (2), were isolated from the ethyl acetate extract. Their structures were identified using spectroscopic data analyses and quantum chemical calculations. This is the first report of the fusariumic acid analogs containing a hydroxyl group at position C–1 in the molecule. Fusariumic acids I (1) and J (2) exhibited significantly inhibitory activities on the hypocotyl elongation of tomato (Solanum lycopersicum) and sesame (Sesamum indicum) seedlings, as well as on the coleoptile elongation of rice (Oryza sativa var. japonica) seedlings at concentrations from 10 to 100 µg/mL. The discovery of two new phytotoxic isocassadiene-type diterpenoids expanded the diversity of secondary metabolites of Forl. Meanwhile, it provided critical insights into Forl-tomato interactions and the candidate lead compounds for the development of new herbicides as well. Full article

Perylene bisimide derivatives are typical n-type semiconductors as well as redox-active materials. However, it has been difficult to produce thin films by solution processes because of their low solubilities in organic solvents. Perylene bisimide derivatives bearing oligosiloxane moieties exhibit columnar phases over wide temperature ranges, including room temperature and high solubilities in organic solvents. The columnar phases are stabilized by nanosegregation between crystal-like one-dimensional π-stacks and liquid-like mantle consisting of oligosiloxane moieties. The electron mobility at room temperature exceeded 0.1 cm²V⁻¹s⁻¹ in the ordered columnar phases of perylene bisimide derivatives bearing four disiloxane chains. Uniaxially aligned thin films of the perylene bisimide derivatives bearing oligosiloxane moieties could be produced by a spin-coating method. The spin-coated films of the perylene bisimide derivatives bearing cyclotetrasiloxane rings could be insolubilized via in situ ring-opening polymerization by the exposure of the thin films to trifluoromethanesulfonic acid vapors. Uniaxially aligned thin films of perylene bisimide derivatives bearing an ethylene oxide chain as well as cyclotetrasiloxane rings could be doped in an aqueous solution of sodium dithionate, resulting in an anisotropic electrical conductivity. Polymerized thin films of perylene bisimide derivatives bearing a crown ether ring exhibited electrochromism in electrolyte solutions. These compounds formed 1:1 complexes with lithium triflate, exhibiting columnar phases at room temperature. The nanostructures of the complexes were stabilized by the electrostatic interaction between cationic crown-metal units and triflate anions. Full article

This study investigated the feasibility of a wearable wind energy-harvesting system integrated into a motorcycle helmet that converts riding-induced airflow into storable electrical energy. A compact horizontal-axis turbine-based system was designed and optimized through staged experiments focusing on generator selection, housing geometry, rotor configuration, and circuit-connected performance. A medium-scale generator, diffuser-type housing (Hd), and eight-blade pinwheel rotor (Rb) were identified as the most suitable combination for helmet-scale integration. The final prototype incorporated two side-mounted turbine modules, a crown-mounted harvesting–boost circuit, and a detachable rechargeable battery pack within a full-face helmet platform. In a field-based riding experiment, the prototype produced mean outputs of 3.99 V, 39.51 mA, and 157.64 mW at 30 km/h; 4.43 V, 43.48 mA, and 192.61 mW at 40 km/h; and 5.45 V, 53.53 mA, and 291.73 mW at 50 km/h. A static wearability evaluation with six participants indicated no obvious discomfort under a quasi-riding posture. These findings support the practical feasibility of helmet-integrated wind energy harvesting as an auxiliary power source for low-power wearable electronics, while highlighting the need for future studies on aerodynamic validation, dynamic wearability, acoustic burden, and safety-oriented structural refinement. Full article

The object of the study is a single heated carbonaceous particle of relatively small size, 0.003 to 0.01 m. Main hypothesis: The formation of soot particles and black carbon particles is caused by the thermochemical destruction of dry organic matter of forest fuel and the mechanical fragmentation of coke residue. The aim of the study is to conduct numerical simulations of heat and mass transfer in a single heated carbonaceous particle, taking into account the soot formation process and assessing its fragmentation with regard to heat exchange with the external environment in a 2D setting. As part of this study, a new model of heat and mass transfer in a pyrolyzed carbonaceous particle was developed, taking into account its step-by-step fragmentation (fragmentation tree model with four secondary particle formations from the initial particle). The calculations resulted in the distributions of temperature and volume fractions of phases in the carbonaceous particle across various scenarios. Scenarios of surface fires (initial temperatures of 900 K and 1000 K), crown fires (1100 K), and a firestorm (1200 K) for typical vegetation (pine, spruce, birch) are considered. Cubic carbonaceous particles are considered in the approximation of a 2D mathematical model. To describe heat and mass transfer in the structure of the carbonaceous particle, a differential equation of thermal conductivity with corresponding initial and boundary conditions of the third type is used, taking into account the gross reaction in the kinetic scheme of pyrolysis and soot formation. Differential analogues of partial differential equations are solved using the finite difference method of second-order approximation. Options for using the developed mathematical model and probabilistic fragmentation criterion for assessing aerosol emissions are proposed. Recommendations: The suggested mathematical model must be incorporated with mathematical models of forest fire plume and aerosol transport in the upper layers of the atmosphere. Moreover, probabilistic criteria for health assessment must be developed for the practical use of the suggested mathematical model. Full article

The use of cementless concrete (geopolymer concrete (GPC)) incorporating fly ash and bundled steel fibers to produce full-scale precast concrete pipes is an economical, viable and sustainable solution for sewer infrastructure for decreasing the overall carbon impacts. This research explores the mechanical behavior of precast full-scale pipes (450 mm inner diameter) incorporating cementless concrete and bundled steel fibers. The GPC mixture was produced by completely substituting cement with fly ash generated by the local coal power plant. The bundled steel fibers were locally manufactured from long wires. The proportions investigated of the bundled steel fibers in the GPC pipes were 20 and 40 kg/m³. A total of six full-scale GPC pipes and two conventional cement concrete pipes were cast in a commercial precast pipe unit. The crushing strength under external load was evaluated using the three-edge bearing test (TEBT) on the pipes without fibers, showing comparable cracking and ultimate loads of GPC pipes and conventional cement concrete pipes. Both types of pipes satisfied the strength requirement of ASTM C76 class III. The use of bundled steel fibers in GPC pipes improved the cracking and ultimate loads by 18% and 22%, respectively, when 40 kg/m³ of bundled steel fibers were added. This upgraded the ASTM C76 strength class from class III to IV due to the improved crack resistance and ultimate load. Conventional cement concrete pipes and GPC pipes exhibited similar cracks at the critical regions (springlines, invert and crown). However, GPC pipes with bundled steel fibers showed a well distributed pattern of multiple secondary cracks along the longitudinal axis of the pipes. The final failure was governed by the flexure action and radial tension in the tested pipes. The economic analysis of cement concrete and GPC pipes showed comparable costs. However, the incorporation of fibers increased the cost of GPC pipes due to the limited local availability of proprietary fibers. This study highlights a new horizon of GPC for the manufacturing of sustainable and economical precast pipes as an environmentally friendly substitute to conventional cement concrete pipes for sustainable sewer infrastructure and adds novelty to the current state-of-the-art knowledge. Full article

Recurrent acidic exposure in patients with gastroesophageal reflux disease (GERD) accelerates the degradation of provisional restorative materials, whereas approaches to enhance the acid resistance of 3D-printed restorations remain inadequately characterized. This study aimed to evaluate the effect of graphene oxide (GO) incorporation on the surface properties and acid resistance of 3D-printed provisional restorative materials under simulated gastroesophageal reflux conditions. GO was synthesized using the Hummers’ method and characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and Raman spectroscopy. XRD analysis demonstrated a pronounced shift in the characteristic peak (2θ) from 26° to 12°, consistent with an expansion of interlayer spacing after oxidation. FTIR confirmed the presence of oxygen-containing functional groups (hydroxyl, carbonyl, and epoxy), while Raman spectroscopy identified the characteristic D and G bands, confirming successful GO synthesis. Temporary Crown & Bridge resin (TC100) was modified with GO at six concentrations (0, 0.025, 0.05, 0.1, 0.5, and 1.0 wt %) using a planetary ball milling technique. Standardized 3D-printed specimens (n = 24 per group) were fabricated. Surface roughness and Vickers microhardness were measured before and after 45 h of immersion in simulated gastric acid (pH 2). Data were analyzed using one-way ANOVA and paired t-tests (α = 0.05). After acid exposure, the control group (0 wt % GO) exhibited significant surface deterioration, showing the highest surface roughness and a marked reduction in hardness (p < 0.05). Conversely, GO-modified groups demonstrated a concentration-dependent improvement in resistance to acid-induced degradation. The 0.5 wt % GO group showed the most favorable performance, maintaining both surface roughness and hardness with no significant difference from baseline values (p > 0.05). These findings indicate that GO incorporation enhances the surface integrity and acid resistance of 3D-printed provisional resins, with 0.5 wt % identified as the optimal concentration for minimizing acid-induced surface deterioration. Full article

The Numidian cypress (Cupressus sempervirens var. numidica, C. numidica hereafter) is a rare, almost unknown, endemic taxon of Tunisia whose conservation has long been hampered by human activities, taxonomic uncertainty and limited ecological knowledge, with only 64.33 ha of its populations remaining. Although recent genetic studies have confirmed its native status and long-term isolation, detailed information on its distribution, population structure and threats remain lacking. This study provides the first comprehensive assessment of C. numidica across its remaining range. Field surveys revealed that the species persists in only three small, fragmented forests, Bou Abdallah, Sidi Amer, and Dir Satour, covering a total of 64.33 ha. Soil analysis revealed some differences among sites, with Bou Abdallah showing higher clay content and Dir Satou exhibiting the highest levels of nitrogen, organic carbon, Olsen P, and available Mn and Mo. Climatic analyses indicate a semi-arid Mediterranean environment with pronounced summer droughts and a clear warming trend. Trees showed widespread damages, due to intensive grazing, tree cutting, crown dieback (drought), and pest and pathogen attacks. Natural regeneration was limited, and the condition of affected trees ranged from moderate to severe, with Bou Abdallah showing the highest levels of degradation. Notably, the severe fungal pathogen Seiridium cardinale, causal agent of cypress canker, was detected on C. numidica for the first time, highlighting an urgent conservation concern. Our results point to a staged conservation approach over time. In the immediate term (within 1 year), urgent monitoring and management of S. cardinale is needed. In the short term, efforts should focus on protecting carefully selected areas, about 5–10 regeneration microsites per forest, from grazing to support natural regeneration, reduce ongoing soil degradation, and establish clonal and seed-production plantations along with long-term seed storage. In the long term, the survival of C. numidica will only be possible with the active involvement of local communities, through awareness campaigns, adapting traditional practices such as gdel, and developing small-scale ecotourism that provides sustainable livelihoods while reinforcing support for conservation. Full article

Background: Closing extraction spaces with clear aligners remains a significant biomechanical challenge, frequently involving difficulties in sagittal control, torque expression, and intra-arch anchorage. Although various sequential or phased retraction strategies exist, the Caterpillar Motion protocol has not yet been formally defined. This clinical report describes the Caterpillar Motion staging protocol and illustrates its application through representative extraction cases, rather than providing a systematic review or experimental comparison. Case Presentation: Two adult patients with extraction-based malocclusions were treated using the Caterpillar Motion staging protocol. Case 1 involved bimaxillary first-premolar extractions with maximum anchorage requirements and periodontal limitations in the mandibular incisors. Case 2 presented as a full Class II malocclusion requiring maxillary first-premolar extractions with moderate anchorage for sagittal camouflage. In both cases, tooth movement was organized into alternating functional groups, with waves limited to 2 mm of sagittal closure. Discussion: The Caterpillar Motion protocol reduces the risk of aligner bowing effect, increases effective crown engagement, and redistributes anchorage demands by preventing simultaneous shortening of both arch extremities. Both cases demonstrated controlled anterior retraction, stable posterior anchorage, and favorable root parallelism. Conclusions: Caterpillar Motion offers a biomechanically coherent and clinically reproducible staging strategy for clear aligner extraction therapy. Further controlled studies are needed to validate its advantages over traditional linear and en-masse protocols. Full article

The Draa Sfar polymetallic mine, located near Marrakech in Morocco, represents the deepest currently operating underground mine in North Africa, with workings extending beyond depths of −1200 m. At such depths, mining activities are conducted within weak, highly anisotropic foliated black pelites, where recurrent instability mechanisms, most notably rib buckling and crown deterioration, are frequently observed, especially in drifts developed parallel to the foliation planes. In this context, the present study integrates detailed structural field observations with two-dimensional finite-element modelling using RS2 in order to analyse excavation-scale stability within these schistose pelitic rocks. Both numerical simulations and field evidence indicate that increasing depth-related confinement, together with a dominant in situ stress regime, favours stress channelling and localized damage development, while the pronounced transverse weakness of the pelites exerts a primary control on failure kinematics, including schistosity-parallel spalling, asymmetric rib buckling, and shear along inclined foliation intersecting the excavation back. Instability processes are further intensified by excavation geometry and mine layout: angular, square-shaped profiles and foliation-parallel drift orientations generate steeper stress gradients and greater convergence compared to arched sections, while proximity to stopes and adjacent openings enhances mining-induced stress redistribution and associated deformation. Intersection areas emerge as the most critical configurations, where the superposition of stress perturbations and structurally controlled damage mechanisms accelerates wall convergence and roof sagging. Overall, these findings demonstrate that drift stability cannot be adequately evaluated using generic design criteria when excavation geometry, interaction effects, and structural anisotropy exert a dominant influence on mechanical behaviour. Consequently, a fully integrated approach that combines drift geometry optimisation, detailed structural mapping, site-calibrated numerical modelling, and in situ monitoring is required to achieve reliable stability assessment and control. Full article

Objectives: This study aimed to investigate preventive management strategies and optimal intervention timing for dental ankylosis of primary teeth complicated by suspected pre-eruptive intracoronal resorption (PEIR), providing an evidence-based framework for clinical diagnosis and management. Methods: This case retrospectively reports a 7-year-old patient with an ankylosed mandibular left second primary molar (tooth 75), exhibiting radiographic features suggestive of pre-eruptive intracoronal resorption. The patient was in the mixed dentition stage with dental crowding. Preventive and interceptive orthodontic management was implemented to address space deficiency and guide occlusal development. The timing of extraction and space maintenance of tooth 75 was guided by space regaining, PEIR lesion progression, and crown development of tooth 35. Results: The permanent successor of tooth 75 (tooth 35) erupted successfully, dental crowding was alleviated, and a favorable occlusion was established. Conclusions: Early diagnosis and timely, individualized intervention for ankylosed primary teeth play an important role in preventing malocclusion and promoting normal eruption of the permanent successor tooth. Full article