Search Results (23)

This paper demonstrates the application of eutectic welding to Ce³⁺:YAG transparent ceramics for reliable detection and imaging of UV emission, particularly focusing on demanding conditions, such as high repetition rate, high energy, and high vacuum. A series of Ce³⁺:YAG transparent ceramics with different Ce³⁺ doping concentrations (0.1 at%, 0.3 at%, 0.5 at%, and 1.0 at%) were prepared via vacuum sintering. Their crystal microstructure, luminescence properties, transmittance, and fluorescence lifetime were studied. It was found that the optimal Ce³⁺ doping concentration is 0.3 at%. The measured ultraviolet-to-visible energy conversion efficiency of the 0.3 at% Ce³⁺:YAG transparent ceramics with a thickness of 1.0 mm is 3.9%. Compared with silicone encapsulated Ce³⁺:YAG transparent ceramic samples, the eutectic-soldered samples exhibited excellent resistance to temperature quenching of the luminescence, which indicates that eutectic welding can effectively improve the fluorescence performance of Ce³⁺:YAG transparent ceramics for the application of deep ultraviolet light detection. Full article

In this study, in situ piezoelectricity was incorporated into the photoactive region to prepare a self-powered deep-ultraviolet photodetector based on a mixture of polyvinylidene fluoride (PVDF)@Ga₂O₃ and polyethyleneimine (PEI)/carbon quantum dots (CQDs). A ferroelectric composite layer was prepared using β-Ga₂O₃ as a filler, and the β-phase of PVDF was used as the polymer matrix. The strong piezoelectricity of β-PVDF can facilitate the separation and transport of photogenerated carriers in the depletion region and significantly reduce the dark current when the device is biased with an external bias, resulting in a high on/off ratio and high detection capability. The self-powered PD exhibited specific detectivity (D* = 3.5 × 10¹⁰ Jones), an on/off ratio of 2.7, and a response speed of 0.11/0.33 s. Furthermore, the prepared PD exhibits excellent photoresponse stability under continuous UV light, with the photocurrent retaining 83% of its initial value after about 500 s of irradiation. Our findings suggest a new approach for developing cost-effective UV PDs for optoelectronic applications in related fields. Full article

Ozone (O₃) is a critical gas in various industrial applications, particularly in semiconductor manufacturing, where it is used for wafer cleaning and oxidation processes. Accurate and reliable detection of ozone concentration is essential for process control, ensuring product quality, and safeguarding workplace safety. By studying the UV absorption characteristics of O₃ and combining the specific operational needs of semiconductor process gas analysis, a pressure-insensitive ozone gas sensor has been developed. In its optical structure, a straight-through design without corners was adopted, achieving a coupling efficiency of 52% in the gas chamber. This device can operate reliably in a temperature range from 0 °C to 50 °C, with only ±0.3% full-scale error across the entire temperature range. The sensor consists of a deep ultraviolet light-emitting diode in a narrow spectrum centered at 254 nm, a photodetector, and a gas chamber, with dimensions of 85 mm × 25 mm × 35 mm. The performance of the sensor has been meticulously evaluated through simulation and experimental analysis. The sensor’s gas detection accuracy is 750 ppb, with a rapid response time (t₉₀) of 7 s, and a limit of detection of 2.26 ppm. It has the potential to be applied in various fields for ozone monitoring, including the semiconductor industry, water treatment facilities, and environmental research. Full article

In this study, we synthesized a coumarin–hemicyanine-based deep red fluorescent dye that exhibits an intramolecular charge transfer (ICT). The probe had a large Stokes shift of 287 nm and a large molar absorption coefficient (ε = 7.5 × 10⁵ L·mol⁻¹·cm⁻¹) and is best described as a deep red luminescent fluorescent probe with λ_em = 667 nm. The color of probe W changed significantly when it encountered cyanide ions (CN⁻). The absorption peak (585 nm) decreased gradually, and the absorption peak (428 nm) increased gradually, so that cyanide (CN⁻) could be identified by the naked eye. Moreover, an obvious fluorescence change was evident before and after the reaction under irradiation using 365 nm UV light. The maximum emission peak (667 nm) decreased gradually, whilst the emission peak (495 nm) increased gradually, which allowed for the proportional fluorescence detection of cyanide (CN⁻). Using fluorescence spectrometry, the fluorescent probe W could linearly detect CN⁻ over the concentration range of 1–9 μM (R² = 9913, RSD = 0.534) with a detection limit of 0.24 μM. Using UV-Vis spectrophotometry, the linear detection range for CN⁻ was found to be 1–27 μM (R² = 0.99583, RSD = 0.675) with a detection limit of 0.13 μM. The sensing mechanism was confirmed by ¹H NMR spectroscopic titrations, ¹³C NMR spectroscopy, X-ray crystallographic analysis and HRMS. The recognition and detection of CN⁻ by probe W was characterized by a rapid response, high selectivity, and high sensitivity. Therefore, this probe provides a convenient, effective and economical method for synthesizing and detecting cyanide efficiently and sensitively. Full article

Ultraviolet (UV) photodetectors are key devices required in the industrial, military, space, environmental, and biological fields. The Schottky barrier (SB)-MOSFET, with its high hole and electron barrier, and given its extremely low dark current, has broad development prospects in the optoelectronics field. We analyze the effects of trap states on the output characteristics of an inversion mode n-channel GaN SB-MOSFET using TCAD simulations. At the oxide/GaN interface below the gate, it was demonstrated that shallow donor-like traps were responsible for degrading the subthreshold swing (SS) and off-state current density (I_off), while deep donor-like traps below the Fermi energy level were insignificant. In addition, shallow acceptor-like traps shifted the threshold voltage (V_t) positively and deteriorated the SS and on-state current density (I_on), while deep acceptor-like traps acted on a fixed charge. The output characteristics of the GaN SB-MOSFET were related to the resistive GaN path and the tunneling rate due to the traps at the metal (source, drain)/GaN interface. For the UV responses, the main mechanism for the negative V_t shift and the increases in the I_on and spectral responsivity was related to the photo-gating effect caused by light-generated holes trapped in the shallow trap states. These results will provide insights for UV detection technology and for a high-performance monolithic integration of the GaN SB-MOSFET. Full article

A novel simple optical sensor based on fast protein liquid chromatography was developed and tested for monitoring end stage renal disease (ESRD) patients treated with continuous ambulatory peritoneal dialysis (CAPD). The device provides direct determination of proteins and lower molecular weight metabolites in effluent peritoneal dialysate using ultraviolet (UV) photometric detection at the wavelengths 285 nm or 260 nm with deep ultraviolet light-emitting diodes. The sensor was calibrated with bovine serum albumin and nucleotides standard solutions. Chromatograms of peritoneal dialysate samples taken from a group of 28 ESRD patients were processed and approximated by a set of split-Gaussian functions. All chromatograms show three overlapping peaks: the first one represents proteins; the other two peaks probably correspond to mid- and low molecular weight metabolites. Strong correlation was reveled between the area of the first peak and total protein concentration determined by a standard biochemical assay, this makes possible estimation of peritoneal protein loss with a reasonable precision less than 15%. The area of the second peak correlated with dialysate optical density at a wavelength 355–365 nm, associated with the UV absorption of advanced glycation end (AGE) products. The third peak correlated with the optical density of the eluate at a wavelength 255–265 nm, associated with the UV absorption of purines and pyrimidines. Thus, we demonstrated the possibility of estimation of proteins and lower molecular weight metabolites in effluent peritoneal dialysate with the compact and affordable chromatographic optical sensor. Full article

We present a novel sensing approach for ambient ozone detection based on deep-ultraviolet (DUV) cavity-enhanced absorption spectroscopy (CEAS) using a laser driven light source (LDLS). The LDLS has broadband spectral output which, with filtering, provides illumination between ~230–280 nm. The lamp light is coupled to an optical cavity formed from a pair of high-reflectivity (R~0.99) mirrors to yield an effective path length of ~58 m. The CEAS signal is detected with a UV spectrometer at the cavity output and spectra are fitted to yield the ozone concentration. We find a good sensor accuracy of <~2% error and sensor precision of ~0.3 ppb (for measurement times of ~5 s). The small-volume (<~0.1 L) optical cavity is amenable to a fast response with a sensor (10–90%) response time of ~0.5 s. Demonstrative sampling of outdoor air is also shown with favorable agreement against a reference analyzer. The DUV-CEAS sensor compares favorably against other ozone detection instruments and may be particularly useful for ground-level sampling including that from mobile platforms. The sensor development work presented here can also inform of the possibilities of DUV-CEAS with LDLSs for the detection of other ambient species including volatile organic compounds. Full article

The Neil Gehrels Swift Observatory has proven to be an extraordinary supernova (SN) observatory. The clearest application of Swift’s unique strengths is obtaining very early UV and X-ray data of young SNe, which enables robust constraints on their progenitor systems. As part of a year-long Swift Guest Investigator Key Project, we initiated a follow-up program to rapidly observe all of the nearest (distance < 35 Mpc or roughly z < 0.008) extragalactic transients without waiting for them to be spectroscopically classified as supernovae. Among the possible results were to measure any UV-bright radiative cooling following the shock breakout from core-collapse SNe and shock emission from the interaction of thermonuclear Type Ia SNe with a non-degenerate companion. Just as importantly, uniformly following up and analyzing a significant sample can constrain the fraction of events for which the shock emission is not seen. Here we present the UV and X-ray measurements performed during our campaign. Our sample of 24 observed triggers included three SNe Ia, six SNe II, three stripped-envelope, core-collapse SNe, five galactic transients, three extragalactic SN imposters, and four unconfirmed transients. For our sample, the median delay time from the discovery image to the first Swift image was 1.45 days. We tabulate the X-ray upper limits and find they are sufficiently deep to have detected objects as X-ray luminous as GRB060218/SN2006aj. Other X-ray-detected SNe such as SNe 2006bp, 2008D, and 2011dh would have been detectable in some of the observations. We highlight the spectroscopically classified Type II SN 2018hna with UV-optical light curves indicating a luminosity and flux evolution very similar to SN 1987A. Full article

This paper presents a more systematic study of steady-state and time-resolved autofluorescence spectroscopy of collagen isolated from bovine Achilles tendon. In steady-state fluorescence measurements, the excitation and emission spectra of collagen powder, recorded at different fluorescence excitation and detection wavelengths, were compared with the fluorescence excitation and emission spectra of the amino acids phenylalanine, tyrosine, and tryptophan, as well as with similar spectra for 13 autofluorescent collagen cross-links, which have been identified and described in the literature so far. In time-resolved studies, fluorescence was excited by the pulsed light of different wavelengths, and for each excitation wavelength, fluorescence decay was recorded for several detection wavelengths. Data analysis allowed recovery of the fluorescence decay times for each experimental excitation detection event. The obtained information on the decay times of the measured fluorescent signals was discussed, taking into account the available literature data from similar studies of isolated collagen and collagen-rich tissues. Based on the obtained results, it was found that the shape and position of the measured fluorescence excitation and emission spectra of collagen strongly depend on the emission and excitation wavelengths selected in the measurements. From the recorded excitation and emission bands of collagen, it can be concluded with high probability that there are additional, so far unidentified, collagen cross-links, which can be excited at longer excitation wavelengths. In addition, the collagen excitation spectra were measured at longer emission wavelengths at which the collagen cross-links emit fluorescent light. In addition to the emission spectra obtained for excitation in the deep-UV region, the results of time-resolved fluorescence studies with excitation in the deep-UV region and detection at longer wavelengths suggest that fluorescence excitation energy transfer processes occur from the amino acids to the collagen cross-links, and also between the cross-links themselves. Full article

Constitutive engineering by adding halide anions is one effective way to improve the performance of photodetectors by adjusting the bandgap. In this study, a mixed-anion perovskite thin film was facile fabricated by post-processing of a pure FAPbI₃ film with a formamidinium bromide (FABr) solution. In addition, the manufactured thin film was used as the light absorption layer, SnO₂-SDBS as the electron transport layer, and spiro-OMeTAD as the hole injection layer to fabricate a deep ultraviolet(UV) photodetector. The device exhibited a response of 43.8 mA/W⁻¹, a detectability of 3.56 × 10¹³ Jones, and an external quantum efficiency of 38%. Therefore, this study is promising for various applications in the deep-UV wavelength region. Full article

Deep-ultraviolet (UV) sensing has attracted significant interest because of its wide range of applications. A mixed-cation halide perovskite-based photodetector prepared by mixing CH₃NH₃PbX₃ (X = I, Br, and Cl) and HC(NH₂)PbX₃ (X = I, Br, and Cl) exhibits high stability and excellent light absorption. In this study, perovskite was prepared by mixing CH₃NH₃⁺ (FA⁺) and HC(NH₂)₂⁺ (MA⁺) cations using I⁻, Br⁻, and Cl⁻ halide anions. The bandgaps of the prepared perovskites increased to 1.48, 2.25, and 2.90 eV with I-, Br-, and Cl-, respectively, and the light absorption spectra shifted to shorter wavelengths. An increase in the redshift of the light absorption led to an increase in the photocurrent. The FAPbCl₃-MAPbCl₃-based photodetector showed a high responsivity of 5.64 mA/W, a detectivity of 4.03 × 10¹¹, and an external quantum efficiency of 27.3%. The results suggested that the FAPbCl₃-MAPbCl₃ perovskite is suitable for deep-UV light sensing and is an excellent candidate for the fabrication of a sensitive photodetector. Full article

All-inorganic perovskites, with their low-cost, simple processes and superior heat stability, have become potential candidate materials for photodetectors (PDs). However, they have no representative responsivity in the deep-ultraviolet (UV) wavelength region. As a new-generation semiconductor, gallium oxide (Ga₂O₃), which has an ultrawide bandgap, is appropriate for solar-blind (200 nm–280 nm) deep-UV detection. In this work, ultrawide-bandgap Ga₂O₃ was introduced into an inorganic perovskite device with a structure of sapphire/β-Ga₂O₃/Indium Zinc Oxide (IZO)/CsPbBr₃. The performance of this perovskite PD was obviously enhanced in the deep UV region. A low-cost, vacuum-free Mist-CVD was used to realize the epitaxial growth of β-Ga₂O₃ film on sapphire. By introducing the Ga₂O₃ layer, the light current of this heterojunction PD was obviously enhanced from 10⁻⁸ to 10⁻⁷, which leds its detectivity (D*) to reach 1.04 × 10¹² Jones under a 254 nm light illumination with an intensity of 500 μW/cm² at a 5 V bias. Full article

Considering practical application and commercialization, the research of non-toxic and stable halide perovskite and its application in the field of photoelectric detection have received great attention. However, there are relatively few studies on deep ultraviolet photodetectors, and the perovskite films prepared by traditional spin-coating method have disadvantages such as uneven grain size and irregular agglomeration, which limit their device performance. Herein, uniform and ordered Cs₃Cu₂I₅ nanonet arrays are fabricated based on monolayer colloidal crystal (MCC) templates prepared with 1 μm polystyrene (PS) spheres, which enhance light-harvesting ability. Furthermore, the performance of the lateral photodetector (PD) is significantly enhanced when using Cs₃Cu₂I₅ nanonet compared to the pure Cs₃Cu₂I₅ film. Under deep ultraviolet light, the Cs₃Cu₂I₅ nanonet PD exhibits a high light responsivity of 1.66 AW⁻¹ and a high detection up to 2.48 × 10¹² Jones. Meanwhile, the unencapsulated PD has almost no response to light above 330 nm and shows remarkable stability. The above results prove that Cs₃Cu₂I₅ nanonet can be a great potential light-absorbing layer for solar-blind deep ultraviolet PD, which can be used as light absorption layer of UV solar cell. Full article

In addition to the numerous health effects caused by the COVID-19 pandemic, the scientific community has considered other emerging effects such as water-related impacts worthy of deep investigation. In this regard, the transmission cycles of the SARS-CoV-2 virus from fecal, vomiting, and sputum routes to sewage have led health authorities to diagnose, prevent, and use novel wastewater treatment technologies. Once they enter the gastrointestinal canal of a healthy person, viral particles can infect via the nominal amount of Angiotensin-Converting Enzyme 2 (ACE2) present in alimentary canal epithelial cell surfaces and further infect lung, heart, kidney, and other organs. The current review highlights the detection, status, and fate of SARS-CoV-2 from sewage treatment facilities to water bodies. Besides, it addresses the potential wastewater treatment processes to cope with various viruses, especially SARS-CoV-2. Many processes can manage contaminated wastewater and solid wastes over the long term, including membrane technologies, disinfectants, UV-light and advanced oxidation methods like photocatalysis, ozonation, hydrogen peroxide, nanomaterials, and algae. Future work must focus on implementing the selected actions for the treatment of the wastewater released from the COVID-19 hospitals and self-quarantine centers to better regulate future waves of SARS-CoV-2. Full article

Due to its high thermal and chemical stability, excellent dielectric properties, unique optical properties, corrosion resistance, and oxidation resistance, the two-dimensional hexagonal boron nitride (h-BN) is often used in a thermal conductor protective layer in deep ultraviolet light-emitting detector fields. However, due to the complicated growth conditions of h-BN, it is often necessary to prepare h-BN by the CVD method in a high vacuum environment, which is limited to a certain extent in terms of film size and production cost. In order to solve this problem, we proposed a method to prepare h-BN thin films by atmospheric CVD (APCVD). This method does not need a vacuum environment, which reduces energy consumption and cost, and makes the operation simpler and the experimental environment safer. The preparation of high-quality h-BN film was carried out using a Cu-Ni alloy as the growth substrate. The growth process of h-BN film was studied, and the influence of growth parameters on the structure of the h-BN film was explored. The morphological features and elemental composition pairs of the samples were characterized and analyzed, which confirmed that the high-quality h-BN film could be successfully grown on the Cu-Ni alloy substrate by APCVD. The UV detection device prepared by using the prepared h-BN film as the photoresponse material had good photoresponse characteristics and performance stability. It provides a new idea for the low-cost preparation of large-scale h-BN. Full article