Search Results (178)

Hydrogen fuel-cell-powered all-electric aircraft are promising for decarbonizing short-range aviation, but the substantial low-temperature waste heat demands a compact thermal management system (TMS). This study presents a methodological framework for the integrated co-design of the TMS and powertrain using multi-objective optimization and holistic mission-level analysis to identify optimal TMS designs and operating strategies. Changes in TMS net drag translate into changes in required aircraft thrust, while changes in powertrain, TMS, and fuel mass affect the available payload under a constant maximum take-off mass assumption. This iterative process yields performance metrics across TMS cooling architectures (parallel or series), heat exchanger mass-drag characteristics, coolant temperature targets (50, 70, or 90 °C), and installation objectives (minimizing mass or ram-air duct length). The optimal design is a parallel cooling architecture that balances mass-specific heat rejection of 4.77 kW kg⁻¹ at hot-day take-off with drag-specific heat rejection of 1.29 kW N⁻¹ at standard-day cruise. A reduction in coolant temperature at standard-day missions entails no significant performance penalties and could improve the efficiency of electrical components. A shorter ram-air duct significantly decreases the available payload by 630 kg but may facilitate nacelle integration. The findings underscore that holistic TMS-powertrain co-design and optimization is essential for rigorous design of sustainable all-electric aircraft. Full article

This study experimentally investigates a novel hybrid system integrating thermoelectric generators (TEGs) with direct contact membrane distillation (DCMD) for simultaneous low-grade heat recovery, electricity generation, and water desalination. Commercial TEG modules were sandwiched between heat spreaders to transfer thermal energy from a source (approx. 140 °C) to a cooling sink, driving saline water evaporation through a hydrophobic membrane. A validated mathematical model showed strong agreement with the experimental results. The system achieved freshwater mass fluxes of 8–9.5 kg/m²/h and electrical power outputs density of 25–35 W/m². Increasing heat input (450–700 W) significantly enhanced freshwater production and electrical output, improving the Gain Output Ratio (GOR) and reducing Specific Energy Consumption (SEC). While higher feed salinity (up to 35,000 ppm) measurably declined mass flux and thermal efficiency, thermoelectric generation and thermal resistance remained largely unaffected. Energy and exergy efficiencies showed moderate sensitivity to operating conditions, while the Water–Electrical Energy Cogeneration Index (WEeCI) increased at high salinity, highlighting the robust contribution of electricity generation. These results demonstrate the potential of the TEG–DCMD system for the sustainable co-generation of water and power from industrial waste heat or renewable thermal sources. Full article

Considering the challenges associated with implementing emerging technologies and bacterial-derived antimicrobial metabolites at an industrial scale in the meat industry, this comprehensive review investigates the interactions between lactic acid bacteria-producing antimicrobial metabolites and emerging food preservation technologies applied to meat systems. By integrating evidence from microbiology, food engineering, and molecular physiology, the review characterizes how metabolites-derived compounds exert inhibitory activity through pH modulation, membrane permeabilization, disruption of proton motive force, and interference with cell wall biosynthesis. These biochemical actions are evaluated in parallel with the mechanistic effects of high-pressure processing, pulsed electric fields, cold plasma, irradiation, pulsed light, ultrasound, ohmic heating and nanotechnology. Across the literature, consistent patterns of synergy emerge: many emerging technologies induce structural and metabolic vulnerabilities in microbial cells, thereby amplifying the efficacy of antimicrobial metabolites while enabling reductions in process intensity. The review consolidates these findings to elucidate multi-hurdle strategies capable of improving microbial safety, extending shelf life, and preserving the physicochemical integrity of meat products. Remaining challenges include optimizing combinational parameters, ensuring metabolite stability within complex matrices, and aligning integrated preservation strategies with regulatory and industrial constraints. Full article

Hydrogen energy is vital for a clean, low-carbon society, and proton exchange membrane fuel cells (PEMFCs) represent a core technology for the conversion of hydrogen chemical energy into electrical energy. When PEMFC single cells are stacked under assembly force for high power output, their porous electrodes (gas diffusion layers, GDLs; catalyst layers, CLs) undergo compressive deformation, altering internal transport processes and affecting cell performance. However, existing microscale studies on PEMFC porous electrodes insufficiently consider compression (especially in CLs) and have limitations in obtaining compressed microstructures. This study proposes a combined framework from a microstructure perspective. It integrates the finite element method (FEM) with computational fluid dynamics (CFD). It reconstructs microstructures of GDL, CL, and GDL-bipolar plate (BP) interface. FEM simulates elastic compressive deformation, and CFD calculates transport properties (solid zone: heat/charge conduction via Laplace equation; fluid zone: gas diffusion/liquid permeation via Fick’s/Darcy’s law). Validation shows simulated stress–strain curves and transport coefficients match experimental data. Under 2.5 MPa, GDL’s gas diffusivity drops 16.5%, permeability 58.8%, while conductivity rises 2.9-fold; CL compaction increases gas resistance but facilitates electron/proton conduction. This framework effectively investigates compression-induced transport property changes in PEMFC porous electrodes. Full article

This work explores water hydrolysis using magnesium as a decentralized dihydrogen source for off-grid households. A dedicated reactor design enabled on-demand dihydrogen generation, coupled with a Proton Exchange Membrane Fuel Cell (PEMFC) for electricity and heat production. Different energy management strategies were compared, highlighting the limitations of single-purpose approaches and the benefits of converting surplus electricity to heat. The integration of photovoltaic generation further reduced magnesium demand by 30%, thus reducing storage requirements to close to 1565 kg of magnesium powder per year, i.e., a volume of 0.9 m³ to cover the heat and electricity needs of a four-person household. Results demonstrate that combining water hydrolysis with magnesium and renewables provides a feasible and sustainable solution for autonomous energy supply in isolated sites. Full article

A hollow fiber-supported polymeric mixed-matrix membrane, consisting of a Pebax-1657 matrix and graphene nanoplatelet (GNP) fillers as the selective layer, was tested for CO₂/CH₄ gas separation at transmembrane pressures up to 30 bar(a). Using a custom, novel, membrane module, we simultaneously performed permeability/selectivity and in situ electric impedance spectroscopy measurements. This in situ technique is proposed here for the first time. Furthermore, stable mixed-gas selectivities, for 10% CO₂ in CH₄ gas, reaching up to 61.4 (M0) and 68.5 after heat treatment (M2) were observed at 20–30 bar(a), whereas the stressed state (M1) dropped to ~22. Throughout the whole procedure of the three (initial, degraded, and restored) membrane testing assessments, a gradual decline in gas permeability coupled with a corresponding increase in the membrane’s AC resistance, due to membrane compaction, was evident. More specific, the membrane’s AC resistance, R₁, increased from ~96–147 ΜΩ (M0) to ~402–435 ΜΩ (M1) and ~5390–5700 ΜΩ (M2), while the peak-phase frequency f_p decreased from ~1.25 kHz (M0) to ~340 Hz (M1) and ~115 Hz (M2). Overall, this work proposes a new tool/method for connecting membrane’s deterioration phenomena with AC resistance and demonstrates that a facile heat treatment can restore selectivity following compaction, despite the absence of full permeance recovery. Full article

Mathematical modeling of unitized regenerative fuel cells (URFCs) faces significant challenges in reconciling parameter conflicts between fuel cell (FC) and electrolysis cell (EC) modes. This study establishes a COMSOL-based multi-physics framework coupling water–gas–heat–electric transport for both operational states. The critical factors associated with the model were identified through a systematic sensitivity analysis of structural and operational parameters, including temperature, exchange current density, conductivity, porosity, and flow rates. FC modes exhibited strong sensitivity to exchange current density (27.8–40.5% performance variation) and conductivity of membrane (10.1–35.6%), while temperature degraded performance (−4.2% to −4.0%). Spatial analysis revealed temperature-induced membrane dehydration and accelerated gas depletion at electrodes, thus explaining the negative correlation. EC modes were dominantly governed by temperature (8.6–9.4%), exchange current density (13.0–16.4%), and conductivity (2.5–13.3%). Channel simulations revealed that elevated temperature contributed to enhanced liquid water fluidity, while high flow rates had a relatively limited effect on mitigating species concentration gradients. Parameter optimization guided by sensitivity thresholds (e.g., porosity > 0.4 in FC GDLs, conductivity > 222 S/m in EC modes) enabled dual-mode calibration. The model achieved <4% error in polarization curve validation under experimental conditions, demonstrating robust prediction of voltage–current dynamics. This work resolves key conflicts of URFC modeling through physics-informed parameterization to provide a foundation for efficient dual-mode system design. Full article

Anodic aluminum oxide (AAO) is a well-known nanomaterial template formed under specific electrochemical conditions. By adjusting voltage, temperature, electrolyte type, and concentration, various microstructural modifications of AAO can be achieved within its hexagonally arranged pore array. To enable broader applications or enhance performance, post-treatment is often employed to further modify its nanostructure after anodization. Among these post-treatment techniques, AAO membrane detachment methods have been widely studied and can be categorized into traditional etching methods, voltage reduction methods, reverse bias voltage detachment methods, pulse voltage detachment methods, and further anodization techniques. Among various delamination processes, the mechanism is highly related to the selectivity of wet etching, as well as the Joule heating and stress generated during the process. Each of these detachment methods has its own advantages and drawbacks, including processing time, complexity, film integrity, and the toxicity of the solutions used. Consequently, researchers have devoted significant effort to optimizing and improving these techniques. Furthermore, through-hole AAO membranes have been applied in various fields, such as humidity sensors, nanomaterial synthesis, filtration, surface-enhanced Raman scattering (SERS), and tribo-electrical nano-generators (TENG). In particular, the rough and porous structures formed at the bottom of AAO films significantly enhance sensor performance. Depending on specific application requirements, selecting or refining the appropriate processing method is crucial to achieving optimal results. As a versatile nanomaterial template, AAO itself is expected to play a key role in future advancements in environmental safety, bio-applications, energy technologies, and food safety. Full article

Temperature control plays a critical role in mitigating the lifespan degradation mechanisms and ensuring thermal safety of lithium-ion batteries (LIBs) and proton exchange membrane fuel cells (PEMFCs). However, current energy management strategies (EMS) for fuel cell hybrid electric vehicles (FCHEVs) generally lack comprehensive thermal effect modeling and thermal runaway fault diagnosis, leading to irreversible aging and thermal runaway risks for LIBs and PEMFCs stacks under complex operating conditions. To address this challenge, this paper proposes a thermo-electrical co-optimization EMS incorporating thermal runaway fault diagnosis actuators, with the following innovations: firstly, a dual-layer framework integrates a temperature fault diagnosis-based penalty into the EMS and a real-time power regulator to suppress heat generation and constrain LIBs/PEMFCs output, achieving hierarchical thermal management and improved safety; secondly, the distributional soft actor–critic (DSAC)-based EMS incorporates energy consumption, state-of-health (SoH) degradation, and temperature fault diagnosis-based constraints into a composite penalty function, which regularizes the reward shaping and guides the policy toward efficient and safe operation; finally, a thermal safe constriction controller (TSCC) is designed to continuously monitor the temperature of power sources and automatically activate when temperatures exceed the optimal operating range. It intelligently identifies optimized actions that not only meet target power demands but also comply with safety constraints. Simulation results demonstrate that compared to DDPG, TD3, and SAC baseline strategies, DSAC-EMS achieves maximum reductions of 39.91% in energy consumption and 29.38% in SoH degradation. With the TSCC implementation, enhanced thermal safety is achieved, while the maximum energy-saving improvement reaches 25.29% and the maximum reduction in SoH degradation attains 20.32%. Full article

Application of low-emission hydrogen production methods in the decarbonization process remains a highly relevant topic, particularly in the context of sustainable hydrogen value chains. This study evaluates hydrogen applications beyond industry, focusing on its role as an energy carrier and applying multi-criteria decision analysis (MCDA) to assess economics, environmental impact, efficiency, and technological readiness. The analysis confirmed that hydrogen use for heating was the most competitive non-industrial application (ranking first in 66%), with favorable efficiency and costs. Power generation placed among the top two alternatives in 75% of cases. Transport end-use was less suitable due to compression requirements, raising emissions to 272–371 g CO₂/kg H₂ and levelizing the cost of hydrogen (LCOH) to 13–17 EUR/kg. When H₂ transport was included, new pipelines and compressed H₂ clearly outperformed other methods for short- and long-distances, adding only 3.2–3.9% to overall LCOH. Sensitivity analysis confirmed that electricity price variations had a stronger influence on LCOH than capital expenditures. Comparing electrolysis technologies yielded that, proton-exchange membrane and solid oxide reduced costs by 12–20% and CO₂ emissions by 15–25% compared to alkaline. The study highlights heating end-use and compressed hydrogen and pipeline transport, proving MCDA to be useful for selecting scalable pathways. Full article

The European Commission, through the REPowerEU plan and the “Fit for 55” package, aims to reduce fossil fuel dependence and greenhouse gas emissions by promoting electric and fuel cell hybrid electric vehicles (EV-FCHEVs). The transition to this mobility model requires energy systems that are able to provide both electricity and hydrogen while reducing the reliance of residential buildings on the national grid. This study analyses a poly-generative (PG) system composed of a Solid Oxide Fuel Cell (SOFC) fed by biomethane, a Photovoltaic (PV) system, and a Proton Exchange Membrane Electrolyser (PEME), with electric vehicles used as dynamic storage units. The assessment is based on simulation tools developed for the main components and applied to four representative seasonal days in Rende (Italy), considering different daily travel ranges of a 30-vehicle fleet. Results show that the PG system provides about 27 kW of electricity, 14.6 kW of heat, and 3.11 kg of hydrogen in winter, spring, and autumn, and about 26 kW, 14 kW, and 3.11 kg in summer; it fully covers the building’s electrical demand in summer and hot water demand in all seasons. The integration of EV batteries reduces grid dependence, improves renewable self-consumption, and allows for the continuous and efficient operation of both the SOFC and PEME, demonstrating the potential of the proposed system to support the green transition. Full article

This work explores the integration of Proton Exchange Membrane (PEM) electrolysis waste heat with district heating networks (DHN), aiming to enhance the overall energy efficiency and economic viability of hydrogen production systems. PEM electrolysers generate substantial amounts of low-temperature waste heat during operation, which is often dissipated and left unutilised. By recovering such thermal energy and selling it to district heating systems, a synergistic energy pathway that supports both green hydrogen production and sustainable urban heating can be achieved. The study investigates how the electrolyser’s operating temperature, ranging between 50 and 80 °C, influences both hydrogen production and thermal energy availability, exploring trade-offs between electrical efficiency and heat recovery potential. Furthermore, the study evaluates the compatibility of the recovered heat with common heat emission systems such as radiators, fan coils, and radiant floors. Results indicate that valorising waste heat can enhance the overall system performance by reducing the electrolyser’s specific energy consumption and its levelized cost of hydrogen (LCOH) while supplying carbon-free thermal energy for the end users. This integrated approach contributes to the broader goal of sector coupling, offering a pathway toward more resilient, flexible, and resource-efficient energy systems. Full article

Efficient thermal management is critical for sustaining the performance and durability of Proton Exchange Membrane Fuel Cells (PEMFCs), where excessive operating temperatures accelerate material degradation and reduce power output. Previous studies have explored various cooling channel designs; however, limited research integrates zigzag multi-fin geometries with both computational and experimental validation for fin width optimization under high-velocity cooling. This study presents a combined Computational Fluid Dynamics (CFD) simulation using ANSYS Fluent and experimental investigation of a multi-fin multi-channel cooling system for PEMFCs. The effects of fin widths (0.3–1.0 mm), inlet flow velocities (0.6–3.0 m/s), and cooling media (air, 20% ethylene glycol (EG) solution) were analyzed with respect to cathode surface temperature, power density, and cooling efficiency. Results show that a 0.3 mm fin width with 3.0 m/s inlet velocity reduced the cathode temperature by ~13 K and increased power density by ~40%. The optimized zigzag configuration improved heat transfer uniformity, achieving cooling efficiencies up to 67.0%. Experimental validation confirmed the CFD results with less than 3% deviation. The findings highlight the potential of optimized multi-fin designs to enhance PEMFC thermal stability and electrical output, offering a practical approach for advanced fuel cell thermal management systems. Full article

Non-thermal technologies (NTTs) such as ultrasound (US), pulsed electric fields (PEF), high-pressure processing (HPP), cold plasma (CP), and pulsed light (PL) are emerging as versatile tools in food fermentation, offering microbial control and process enhancement without the detrimental heat effects of conventional methods. Operating at ambient low temperatures, these techniques preserve heat-sensitive compounds, modulate microbial activity, and improve mass transfer, enabling both quality retention and functional enrichment. Recent studies highlight their potential to stimulate metabolic pathways and enhance the release of bioactive compounds, opening new opportunities for fermented food production. The bibliometric analysis of the recent literature further reveals a growing interest in NTT applications in fermentation, with HPP and PEF showing the highest industrial maturity. Each technology exhibits distinct mechanisms and optimal niches across upstream, midstream, and downstream stages: HPP for uniform volumetric treatment, US for fermentation intensification, CP for surface-selective oxidative chemistry, PEF for membrane permeability control, and PL for rapid, residue-free decontamination. While the degree of industrial readiness varies, critical barriers such as scale-up limitations, high capital costs, energy distribution uniformity, process standardization, and techno-economic feasibility remain to be overcome. Beyond technical aspects, the successful commercialization of NTTs will also depend on addressing regulatory approval pathways, ensuring consumer trust and acceptance, and demonstrating their contribution to sustainability goals through lower energy use, reduced food waste, and environmentally responsible processing. Strategic, stand-alone, or hybrid applications of NTTs can therefore act not only as technological alternatives but also as enablers of a more sustainable, consumer-centered, and innovation-driven food system. Full article

Under the accelerating global energy restructuring and the deepening carbon neutrality strategy, hydrogen energy has emerged with increasing strategic value as a zero-carbon secondary energy carrier. Water electrolysis technology based on renewable energy is regarded as an ideal pathway for large-scale green hydrogen production. However, polymer electrolyte membrane (PEM) conventional water electrolysis faces dual constraints in economic feasibility and scalability due to its high electrical energy consumption and reliance on noble metal catalysts. The mixed ionic-electronic conducting oxygen transport membrane (MIEC–OTM) reactor technology offers an innovative solution to this energy efficiency-cost paradox due to its thermo-electrochemical synergistic energy conversion mechanism and process integration. This not only overcomes the thermodynamic equilibrium limitations in traditional electrolysis but also reduces electrical energy demand by effectively coupling with medium- to high-temperature heat sources such as industrial waste heat and solar thermal energy. Therefore, this review, grounded in the physicochemical mechanisms of oxygen transport membrane reactors, systematically examines the influence of key factors, including membrane material design, catalytic interface optimization, and parameter synergy, on hydrogen production efficiency. Furthermore, it proposes a roadmap and breakthrough directions for industrial applications, focusing on enhancing intrinsic material stability, designing multi-field coupled reactors, and optimizing system energy efficiency. Full article