Search Results (4,398)

Element doping and functional group modification engineering serve as efficient approaches that contribute to the improvement of the functional efficiency in graphitic carbon nitride (CN) materials. A CN photocatalyst co-modified with sulfur (S) and cyano moieties was prepared through thermal condensation polymerization. The introduced S species modulated the band structure, increased charge carrier mobility, and significantly promoted charge separation and transport. Additionally, the introduction of cyano groups extended light absorption range and improved the material’s selective adsorption of reactant molecules. The as-prepared sulfur-modified CN photocatalyst obtained after a 6 h thermal treatment, which was capable of degrading organic pollutants and producing hydrogen (H₂) efficiently and stably, exhibited excellent catalytic performance. The photocatalyst’s photocatalyst exhibited a significantly enhanced photocatalytic activity, with a Rhodamine B (RhB) removal efficiency reaching 97.3%. Meanwhile, the H₂ production level reached 1221.47 μmol h⁻¹g⁻¹. Based on four-cycle experiments, the photocatalyst exhibited excellent recyclability and stability in both H₂ production processes and photocatalytic organic pollutant degradation. In addition, mechanistic studies confirmed the dominant role of ·OH and ·O₂⁻ as active species responsible for the reaction system’s performance. This study highlights that the co-decoration of heteroatoms and functional groups can markedly enhance the photocatalytic performance of CN-based materials, offering considerable potential for future applications in energy conversion and environmental remediation. Full article

This paper proposes a Fresnel-based Modified Moiré Varifocal Metalens (MMVL) addressing the inherent defocus at 0° rotation and significant focal quality degradation during varifocal operation in Traditional Moiré Varifocal Metalenses (TMVLs). The transmission function of the Fresnel-modified Moiré metalens combines a static term with a dynamic term, allowing the MMVLs to effectively overcome these limitations. Meanwhile, to minimize energy losses arising from polarization conversion and diffraction between the two metalenses, the nano-units on the metalenses are optimized by Particle Swarm Optimization (PSO) with FDTD simulations, maximizing the polarization conversion efficiency and transmittance. The simulation results demonstrate superior focal quality and stability in the MMVL throughout full rotational cycles, with super-diffraction-limited focusing maintained across all varifocal states. MMVLs have advantages in robustness; under axial distance variation (d = 0–20$d_0$, 0–3 $\mathsf{\mu }$m), they maintain on-axis focus without deviation; with centering error (p = 0–10$p_0$, 0–3 $\mathsf{\mu }$m), they sustain a clear focus at >36% efficiency. These results confirm that MMVLs have enhanced tolerance to manufacturing/assembly errors compared to TMVLs, delivering significantly stabilized optical performance. This advancement enables new possibilities for integrated micro-optics and optical tweezer applications. Full article

The integrated process of CO₂ hydrogenation and catalytic methanol synthesis under plasma conditions holds great potential for CO₂ conversion from waste gases. This process connects a dielectric barrier discharge (DBD) plasma reactor and a methanol synthesis fixed-bed reactor through a pressurization device, achieving the stepwise conversion of CO₂ to CO and then to methanol, thereby establishing a low-carbon and high-efficiency energy conversion system. This study experimentally investigated the key parameters influencing the CO₂ hydrogenation process in the DBD plasma reactor and the methanol synthesis process in the fixed-bed reactor. The results show that in the plasma reaction, discharge power, discharge gap, gas flow rate, and gas composition significantly affect CO₂ conversion efficiency. In the methanol synthesis process, the CO/CO₂ mixed feed exhibits superior catalytic performance compared to pure CO₂. The optimal operating conditions for the integrated process are a plasma voltage of 40 V and a downstream reaction temperature of 240 °C, under which the system achieves the best overall performance. Full article

This study addresses the performance optimization of piezoelectric cantilever beam energy harvesters by proposing a design method based on surface arrayed groove modulation. Through systematic investigation of the effects of single grooves (upper surface, lower surface, and double-sided grooves) and arrayed grooves on the power generation performance of piezoelectric cantilever beams, the coupling mechanism of stiffness modulation, Local resonance instability phenomenon, and energy conversion in groove design is revealed. The results show that while single grooves can improve the output voltage by altering the neutral axis position, groove widths exceeding 20 mm induce Local resonance instability phenomenon, leading to energy dissipation. In contrast, arrayed grooves effectively suppress Local resonance instability phenomenon by uniformly distributing the grooves, significantly enhancing energy conversion efficiency. The optimized arrayed groove configuration (groove width: 4 mm, depth: 1 mm, number: 7) achieves a peak voltage of 549.525 mV, representing a 17.3% improvement over the ungrooved structure, without inducing narrow-bandwidth effects. Additionally, this design exhibits excellent process compatibility and can be fabricated using conventional machining methods, reducing costs by 30–45% compared to additive manufacturing. This study provides important optimization directions and technical references for the design of piezoelectric cantilever beam energy harvesters. Full article

Lead-free perovskite solar cells (PSCs) provide a viable alternative to lead-based versions, thereby reducing significant environmental issues related to toxicity. MASnIBr₂ has emerged as a very attractive lead-free perovskite material due to its environmentally friendly characteristics and advantageous optoelectronic capabilities. However, more tuning is required to achieve superior conversion efficiencies (PCEs). This study uses SCAPS-1D simulations to systematically develop and optimize the electron and hole transport layers (ETLs/HTLs) in MASnIBr₂-based perovskite solar cells (PSCs). Iterative simulations are used to carefully examine and optimize critical parameters, including electron affinity, energy bandgap, layer thickness, and doping density. Additionally, the thickness of the MASnIBr₂ absorber layer is optimized to enhance charge extraction and light absorption. Our findings showed a maximum power conversion efficiency of 20.42%, an open-circuit voltage of 1.38 V, a short-circuit current density of 17.91 mA/cm², and a fill factor of 82.75%. This study establishes a basis for future progress in sustainable photovoltaics and offers essential insights into the design of efficient lead-free perovskite solar cells. Full article

Equivalent energy consumption minimization methods of energy management systems have been implemented as a rule-based strategy to enhance electric propulsion system efficiency. This study compares the efficiencies of different systems by applying variable- and constant-speed generators with battery hybrid systems, measuring fuel consumption. In the same scenario, the variable-speed operation showed a notable improvement of 10.36% compared to the conventional system. However, in the verification of hybrid system efficiency, onshore charged energy cannot be considered a reduction in fuel consumption. Instead, when converting onshore energy usage into equivalent fuel consumption for comparative analysis, both hybrid constant- and variable-speed operation modes achieved efficiency enhancements ranging from 5.5% to 9.79% compared to the conventional, nonequivalent constant-speed operation mode. Conversely, the nonequivalent variable-speed operation mode demonstrated an efficiency that was 5.41% higher than that of the hybrid constant-speed operation mode. In contrast, the battery-integrated variable-speed operation mode indicated a system efficiency approximately equal to that of the nonequivalent variable-speed operation mode. For vessels with load profiles characterized by prolonged periods of idling or low-load operations, a battery-integrated hybrid system could be a practical solution. This study demonstrates the necessity of analyzing load profiles, even when aiming for the optimal operational set points of the generator engine. Full article

Hydrogen is gaining significant interest from researchers because of its renewable and clean nature. In this study, we explored the effects of promoters and oxygen addition on biogas reforming. The promotion of catalysts with alkaline earth metals (Ca and Mg) improved the basicity of the catalyst, leading to enhanced catalytic activity and stability. The promotion of the Ni/TiO₂ catalyst with Ca showed higher CH₄ conversion and H₂ yield compared to the bare and Mg-Ni/TiO₂ catalysts. The enhanced activity of Ca-Ni/TiO₂ could be attributed to its high dispersion, small particulate size, and strong metal–support interaction. Adding oxygen to the reactor feed improved the activity and stability of the catalyst due to the simultaneous occurrence of dry and partial oxidative reforming. The maximum CH₄ conversion and H₂ yield of 81.13 and 37.5% were obtained at 800 °C under dry reforming conditions, which increased to 96 and 57.6% under dry-oxidative reforming (O₂/CH₄ = 0.5). The CHNS analysis of the spent Ca-Ni/TiO₂ catalyst also showed carbon deposition of only 0.58% after 24 h of continuous dry-oxidative reforming compared to 25.16% under continuous dry reforming reaction. XRD analysis of the spent catalyst also confirmed the formation of carbon deposits under dry reforming. Adding oxygen to the feed resulted in the simultaneous removal of carbon species formed over the catalytic surface through gasification. These findings demonstrate that Ca promotion combined with oxygen addition significantly improves the catalyst efficiency and durability, offering a promising pathway for stable, long-term hydrogen generation. The results highlight the potential of Ca–Ni/TiO₂ catalysts for integration into biogas reforming units at an industrial scale, supporting renewable hydrogen production and carbon mitigation in future energy systems. Full article

The advancement of efficient energy conversion and storage technologies is fundamentally linked to the development of electrochemical systems, including fuel cells, batteries, and electrolyzers, whose performance depends on key electrocatalytic reactions: hydrogen evolution (HER), oxygen evolution (OER), oxygen reduction (ORR), carbon dioxide reduction (CO₂RR), and nitrogen reduction (NRR). Beyond catalyst design, the electrolyte microenvironment significantly influences these reactions by modulating charge transfer, intermediate stabilization, and mass transport, making electrolyte engineering a powerful tool for enhancing performance. This review provides a comprehensive analysis of how fundamental electrolyte properties, including pH, ionic strength, ion identity, and solvent structure, affect the mechanisms and kinetics of these five reactions. We examine in detail how the electrolyte composition and individual ion contributions impact reaction pathways, catalytic activity, and product selectivity. For HER and OER, we discuss the interplay between acidic and alkaline environments, the effects of specific ions, interfacial electric fields, and catalyst stability. In ORR, we highlight pH-dependent activity, selectivity, and the roles of cations and anions in steering 2e⁻ versus 4e⁻ pathways. The CO₂RR and NRR sections explore how the electrolyte composition, local pH, buffering capacity, and proton sources influence activity and the product distribution. We also address challenges in electrolyte optimization, such as managing competing reactions and maximizing Faradaic efficiency. By comparing the electrolyte’s effects across these reactions, this review identifies general trends and design guidelines for enhancing electrocatalytic performance and outlines key open questions and future research directions relevant to practical energy technologies. Full article

With the rapid advancement of electronic devices, Internet of Things (IoT) technology has become increasingly integrated into everyday life. However, its broader development has been restricted by challenges related to long-term maintenance and the frequent need for power source replacements. Among the available power supply solutions, thermoelectric power generation has garnered significant interest due to its high reliability. Nevertheless, the widespread application of thermoelectric generators (TEGs) in IoT remains limited due to their relatively low conversion efficiency and structural fragility. This review systematically summarizes recent strategies aimed at enhancing the output performance and durability of TEGs through improvements in manufacturing processes and performance optimization techniques. It highlights several fabrication methods capable of endowing devices with superior flexibility and reliability, including screen printing, chemical vapor deposition (CVD), and electrospray deposition. Additionally, we discuss two key approaches for improving power generation performance: advanced material selection and multi-mechanism hybridization. Finally, the article explores the applications of TEGs in thermal energy harvesting from wearable devices, ambient environments, and aerospace fields, demonstrating their substantial potential to provide sustainable energy for IoT devices. Full article

To further improve the economic benefits of operators and the low-carbon performance within the system, this paper proposes a hierarchical distributed low-carbon economic dispatch strategy for regional integrated energy systems (RIESs) based on the Alternating Direction Method of Multipliers (ADMM). First, the energy coupling relationships among conversion devices in RIESs are analyzed, and a structural model of RIES incorporating an energy generation operator (EGO) and multiple load aggregators (LAs) is established. Second, considering the stepwise carbon trading mechanism (SCTM) and the average thermal comfort of residents, economic optimization models for operators are developed. To ensure optimal energy trading strategies between conflicting stakeholders, the EGO and LAs are embedded into a master–slave game trading framework, and the existence of the game equilibrium solution is rigorously proven. Furthermore, considering the processing speed of the optimization problem by the operators and the operators’ data privacy requirement, the optimization problem is solved in a hierarchical distributed manner using ADMM. To ensure the convergence of the algorithm, the non-convex feasible domain of the subproblem bilinear term is transformed into a convex polyhedron defined by its convex envelope so that the problem can be solved by a convex optimization algorithm. Finally, an example analysis shows that the scheduling strategy proposed in this paper improves the economic efficiency of energy trading participants by 3% and 3.26%, respectively, and reduces the system carbon emissions by 10.5%. Full article

With the progressive depletion of conventional oil and gas resources and the increasing demand for alternative energy, organic-rich sedimentary rock—oil shale—has attracted widespread attention as a key unconventional hydrocarbon resource. Pyrolysis is the essential process for converting the organic matter in oil shale into recoverable hydrocarbons, and a detailed understanding of its behavior is crucial for improving development efficiency. This review systematically summarizes the research progress on the pyrolysis characteristics of oil shale under laboratory conditions. It focuses on the applications of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) in identifying pyrolysis stages, extracting kinetic parameters, and analyzing thermal effects; the role of coupled spectroscopic techniques (e.g., TG-FTIR, TG-MS) in elucidating the evolution of gaseous products; and the effects of key parameters such as pyrolysis temperature, heating rate, particle size, and reaction atmosphere on product distribution and yield. Furthermore, the mechanisms and effects of three distinct heating strategies—conventional heating, microwave heating, and autothermic pyrolysis—are compared, and the influence of inherent minerals and external catalysts on reaction pathways is discussed. Despite significant advances, challenges remain in quantitatively describing reaction mechanisms, accurately predicting product yields, and generalizing kinetic models. Future research should integrate multiscale experiments, in situ characterization, and molecular simulations to construct pyrolysis mechanism models tailored to various oil shale types, thereby providing theoretical support for the development of efficient and environmentally friendly oil shale conversion technologies. Full article

Wave energy is a highly concentrated energy resource with five times higher energy density than wind and at least ten times the power density of solar energy. It is expected to make a major contribution to addressing climate change and to help end our dependency on fossil fuels. Many ingenious wave energy conversion methods have been put forward, and a large number of wave energy converters (WECs) have been developed. However, to date, wave energy conversion technology is still in the demonstration application stage. Key issues such as survivability, reliability, and efficient conversion still need to be solved. The major hurdle is the fact that ocean waves provide a slow-moving, high-magnitude force, whereas most electric generators operate at high rotary speed and low torque. Coupling the slow-moving, high-magnitude force of ocean waves normally requires conversion to a high-speed, low-magnitude force as an intermediate step before a rotary generator is applied. This, in general, tends to severely limit the overall efficiency and reliability of the converter and drives the capital cost of the converter well above an acceptable commercial target. Magnetohydrodynamic (MHD) wave energy conversion makes use of MHD generators in which a conducting fluid passes through a very strong magnetic field to produce an electric current. In contrast to alternatives, the relatively slow speed at which the fluid traverses the magnetic field makes it possible to directly couple to ocean waves with a high-magnitude, slowly moving force. The MHD generator provides an excellent match to the mechanical impedance of an ocean wave, and therefore, an MHD WEC has no rotating mechanical parts with high speeds, no complex control process, and has good response to low sea states and high efficiency under all working conditions. This review introduces the system composition, working process, and technical features of WECs based on MHD generators first. Then, the research development, key points, and issues of wave energy conversion technology based on MHD generators are presented in detail. Finally, the problems to be solved and the future research directions of wave energy conversion based on MHD generators are pointed out. Full article

As the core component of photovoltaic (PV) power generation systems, PV cells are susceptible to subtle surface defects, including thick lines, cracks, and finger interruptions, primarily caused by stress and material brittleness during the manufacturing process. These defects substantially degrade energy conversion efficiency by inducing both optical and electrical losses, yet existing detection methods struggle to precisely identify and localize them. In addition, the complexity of background noise and other factors further increases the challenge of detecting these subtle defects. To address these challenges, we propose a novel PV Cell Surface Defect Detector (PSDD) that extracts subtle defects both within the backbone network and during feature fusion. In particular, we propose a plug-and-play Subtle Feature Refinement Module (SFRM) that integrates into the backbone to enhance fine-grained feature representation by rearranging local spatial features to the channel dimension, mitigating the loss of detail caused by downsampling. SFRM further employs a general attention mechanism to adaptively enhance key channels associated with subtle defects, improving the representation of fine defect features. In addition, we propose a Background Noise Suppression Block (BNSB) as a key component of the feature aggregation stage, which employs a dual-path strategy to fuse multiscale features, reducing background interference and improving defect saliency. Specifically, the first path uses a Background-Aware Module (BAM) to adaptively suppress noise and emphasize relevant features, while the second path adopts a residual structure to retain the original input features and prevent the loss of critical details. Experiments show that PSDD outperforms other methods, achieving the highest $mA{P}_{50}$ scores of 93.6% on the PVEL-AD. Full article

Nanocomposites, which combine various nanomaterials, offer immense potential in the design of advanced materials for energy-related applications. These materials, engineered at the nanoscale, exhibit enhanced properties compared to their bulk counterparts, such as improved electrical conductivity, mechanical strength, and thermal stability. Nanocomposites have emerged as promising candidates for use in energy storage systems, including batteries and supercapacitors, by improving energy density, cycle life, and charge–discharge rates. In renewable energy technologies such as fuel cells, nanocomposites play a crucial role in enhancing efficiency and stability, which are vital for reducing costs and promoting the adoption of clean energy solutions. The unique properties of nanocomposites, such as high surface area and tunable composition, allow for the integration of multiple functionalities, making them ideal for multifunctional catalysts in energy conversion and environmental remediation. Additionally, nanocomposites enable the development of energy harvesting systems with improved performance and durability. These materials can be tailored by adjusting the composition of the nanomaterials, opening new opportunities for energy applications. The increasing research into nanocomposites continues to drive innovation in energy-related technologies, positioning them as a key enabler for sustainable energy solutions and future advancements in renewable energy systems. Full article

Asymmetric nanomotors are a class of self-propelled nanoparticles that exhibit asymmetries in shape, composition, or surface properties. Their unique asymmetry, combined with nanoscale dimensions, endows them with significant potential in environmental and biomedical fields. For instance, glutathione (GSH) induced chemotactic nanomotors can respond to the overexpressed glutathione gradient in the tumor microenvironment to achieve autonomous chemotactic movement, thereby enhancing deep tumor penetration and drug delivery for efficient induction of ferroptosis in cancer cells. Moreover, self-assembled spearhead-like silica nanomotors reduce fluidic resistance owing to their streamlined architecture, enabling ultra-efficient catalytic degradation of lipid substrates via high loading of lipase. This review focuses on three core areas of asymmetric nanomotors: scalable fabrication (covering synthetic methods such as template-assisted synthesis, physical vapor deposition, and Pickering emulsion self-assembly), propulsion mechanisms (chemical/photo/biocatalytic, ultrasound propelled, and multimodal driving), and functional applications (environmental remediation, targeted biomedicine, and microelectronic repair). Representative nanomotors were reviewed through the framework of structure–activity relationship. By systematically analyzing the intrinsic correlations between structural asymmetry, energy conversion efficiency, and ultimate functional efficacy, this framework provides critical guidance for understanding and designing high-performance asymmetric nanomotors. Despite notable progress, the prevailing challenges primarily reside in the biocompatibility limitations of metallic catalysts, insufficient navigation stability within dynamic physiological environments, and the inherent trade-off between propulsion efficiency and biocompatibility. Future efforts will address these issues through interdisciplinary synthesis strategies. Full article