Search Results (356)

This work presents the thermodynamic design and performance assessment of an integrated process line for the separation, liquefaction, storage, and valorization of carbon dioxide (CO₂) and nitrogen (N₂) from flue gas streams. The proposed system aims to combine carbon capture with cryogenic energy storage by exploiting the thermophysical properties of the main flue gas constituents. A representative flue gas derived from complete methane combustion (9.5% CO₂, 71.5% N₂, and 19% H₂O by volume) is considered as the feed stream. The process is developed and simulated in DWSIM v9.0.5, adopting a steady-state mass and energy balance framework coupled with rigorous thermodynamic modeling of phase equilibria and unit operations. The plant configuration is based on sequential cooling, compression, and expansion stages, enabling the selective condensation of H₂O, CO₂, and N₂ at different temperature levels. The system integrates heat exchangers, compressors, pumps, turboexpanders, phase separators, and cryogenic storage tanks, while a portion of the liquefied CO₂ is reused as an energy carrier through vaporization and expansion in a dedicated turbine. The results demonstrate that the process achieves a CO₂ capture ratio of 81.7%, with a specific electric consumption (SEC) of 10.44 kWh/kg_CO2 and 1.71 kWh/kg_N2. The overall net electric demand is 1.29 kWh/kg of treated flue gas, while the round-trip efficiency (η_RT,CO2) is 18.6%. A significant amount of energy can further be recovered from the “waste” exhaust water stream (12.94 kg_L-H2O/kg_flue-gas, at 91 °C and 1.2 bar) up to 800 Wh/kg_flue-gas, improving the performance of the entire process (SEC_CO2: 3.86 kWh/kg_CO2, η_RT,CO2: 69.8%). The study confirms the thermodynamic feasibility of the proposed configuration and identifies nitrogen liquefaction as the dominant energy-intensive step. Future optimization efforts should therefore focus on reducing exergy destruction in the deep cryogenic section through improved heat integration, enhanced cold-energy recovery, optimized compression–expansion staging, and reduced pressure losses. Full article

Conventional solar power tower (SPT) systems often suffer from significant heat transfer exergy destruction due to large temperature differences between the heat source and the working fluid during the heat exchange process. To overcome this limitation, a high–low dual-tower configuration based on segmented thermal utilization is proposed. In this arrangement, the high-temperature tower is mainly responsible for the evaporation, superheating, and reheating processes, whereas the low-temperature tower primarily handles feedwater preheating. Such a configuration improves the temperature matching characteristics during the heat exchange process. A comprehensive model integrating the heliostat field, receiver, thermal energy storage system, and power block was developed and validated against Solar Two experimental data, showing good agreement. Comparative analyses were conducted under identical solar resource and operating conditions. The results indicate that the proposed system achieves a comparable power output while reducing total heat transfer exergy destruction by approximately 24%, with a significant reduction of over 80% in the preheating section. Sensitivity analysis further reveals that optimizing the high tower outlet temperature can effectively reduce irreversibility and slightly enhance power output, although constrained by the pinch temperature difference. Dynamic simulations based on typical meteorological year data demonstrate that the system maintains stable operation and improves cycle efficiency. From an economic perspective, the proposed system reduces the levelized cost of electricity (LCOE) by about 6.6% and shortens the dynamic payback period, indicating enhanced long-term competitiveness. Overall, the high and low dual-tower system effectively improves thermodynamic and economic performance, providing a promising approach for high-efficiency concentrating solar power (CSP) development. Full article

This study presents a comparative thermodynamic assessment of molten salt thermal energy storage (MSTES) integrated with a 330 MW subcritical coal-fired power plant. Different charging and discharging configurations based on main steam, reheat steam, and hybrid steam extraction are evaluated using HITEC salt. Thermodynamic performance is rigorously assessed via exergy analysis and equivalent round-trip efficiency. The findings indicate that system configuration exerts a substantial influence on performance: the HITEC scheme H-C5-D1 achieves an optimal balance, attaining a round-trip efficiency of 44.0% and a peak-shaving capacity of 33.4 MW. Exergy analysis identifies molten salt heat exchangers as the main source of exergy destruction, governed primarily by the steam-salt temperature difference and throttling effects. HITEC salt is advantageous in medium- and low-temperature applications. Increasing main-steam utilization in hybrid schemes enhances round-trip efficiency and storage capacity, though this comes at the cost of increased heat exchanger investment. Overall, the MSTES system significantly enhances both operational flexibility and thermal efficiency of coal-fired units. Full article

Desalination by reverse osmosis (RO) of brackish water and seawater is a cost-competitive solution for supplying irrigation water in off-grid and water-stressed regions. This paper presents an experimental evaluation, thermodynamic analysis, and cost assessment of a solar photovoltaic brackish-water reverse osmosis (PV-BWRO) desalination system. Five feed salinity levels ranging from 993.6 to 3191.8 mg/L were tested. The results show that water production decreased with increasing feed salinity, from 3.29 m³/day at 24.6 mg/L to 1.48 m³/day at 152.9 mg/L. The calculated specific energy consumption values ranged from 1.80 to 3.61 kWh/m³ for solar irradiances of 1005.99 and 1018.47 W/m², respectively. An exergy analysis revealed that the solar panels and pump operated at efficiencies of 11.7% and 38.9%, while exergy destruction was mainly concentrated in the pretreatment stage (28.72%), membrane modules (42.5%), and reject stream (28.5%). Although the overall system efficiency remained low (maximum of 1.39%), the results highlight substantial potential for improvement through enhanced maintenance, optimized pretreatment, and exergy recovery strategies. The unit water production cost ranged from USD 0.49 at 993.6 mg/L to USD 1.87 at 3191.8 mg/L, assuming a target permeate total dissolved solids concentration of 500 mg/L. Full article

The Colombian Caribbean is a strategic area for avocado production, not only because of its favorable climatic conditions, but also because of the availability of varieties with a high content of compounds of industrial interest. The Creole-Antillean avocado grown in Montes de María represents a significant source of raw material with potential for processing, both because of the lipid fraction of its pulp and the chemical composition of its seed. However, the use of this resource has been limited by low technology incorporation and poor coordination of agro-industrial chains that would allow its valorization beyond fresh consumption. In view of this situation, the design of a plant for the simultaneous production of oil and biochar is proposed, with the aim of migrating from a linear model to a comprehensive biomass valorization scheme. The study analyzes the performance of the process from a thermodynamic perspective, applying an exergy analysis that allows for the evaluation of the quality of the energy used and the quantification of irreversibilities at each stage. The results indicate that the highest exergy destruction occurs during seed washing (12.37%), oil extraction and centrifugation (19.71%), distillation and condensation (20.64%), and pyrolysis with by-product separation (28.72%). Although the seed washing stage showed high exergy efficiency (99.81%) when integrated into biochar production, stage 12 recorded a significant loss of 2438.52 MJ/h, associated with the non-use of the volatile gases generated in pyrolysis. Overall, the exergy efficiency of the system reached 30.07%, reflecting the high thermodynamic demands involved in transforming the seed into a high-value product such as biochar. This type of assessment not only identifies critical points of exergy destruction, but also establishes technical bases for optimizing energy consumption, reducing losses, and moving towards a more efficient and sustainable process. Full article

The efficient and optimized operation of copper smelting processes is comprehensively governed by process flow characteristics and energy efficiency. This study establishes a game theory–based comprehensive evaluation framework and proposes a hybrid weighting-TOPSIS method. The optimal combined weights are determined by integrating subjective and objective approaches, including the analytic hierarchy process (AHP), entropy weight method (EWM), and CRITIC method. The proposed model is used to quantitatively evaluate the effects of flue gas and steam flow rates, and temperature differences, on overall system energy efficiency. Compared with single-weighting methods, the presented strategy demonstrates greater rationality and comprehensiveness. Furthermore, exergy analysis is conducted to investigate energy and exergy efficiencies and exergy destruction of key components. Results show that the energy and exergy efficiencies of waste heat boilers are both approximately 30%, with a maximum exergy destruction of 3646 kW, indicating significant potential for improvement. This finding is consistent with the comprehensive evaluation results obtained from the game theory-based weighting method, providing a reliable basis for energy efficiency optimization of copper smelting waste heat recovery systems. Full article

This study presents a comprehensive thermo-energetic and exergetic assessment of a 250 MW steam boiler in a Cuban thermal power plant, operating under partial load conditions (plant: 62–66%; boiler: 58–61%). An integrated diagnostic methodology was developed and implemented in Mathcad 15 to evaluate key performance indicators, including thermal efficiency (η_tGV); exergetic efficiency (η_ExGV); exergy destruction ratio (γ_ExGV); steam generation index (IG_v); and specific fuel consumption (B_Esp). The methodology was applied to two fuels with contrasting thermophysical and chemical properties: fuel oil and Enhanced Crude Oil 650. The results indicate superior performance with fuel oil due to its higher heating value; however, efficiency losses were mainly attributed to operational factors such as excessive air supply (22.7–26.4%), heat transfer surface fouling, and inadequate maintenance. The analysis revealed significant deviations from design values—thermal efficiency (90.27–90.59%) and exergetic efficiency (<60%)—highlighting an untapped potential for energy savings. Quantitative estimates indicate potential annual fuel cost savings of approximately 1.2 million USD through optimized combustion and maintenance practices. The proposed framework enables accurate diagnostics of complex boiler systems and provides actionable indicators to support combustion optimization and energy efficiency strategies in conventional thermal power plants. Full article

This study numerically investigates heat transfer and thermodynamic behavior in twisted square and rectangular air ducts while keeping a constant hydraulic diameter (D_h = 30 mm). Three aspect ratios are considered (AR = 1.00, 0.75, and 0.50). The heated test section (900 mm) is divided into three equal segments, and three pitch patterns are examined: a uniform pitch (400–400–400 mm, P444) and two axial gradients (300–400–500 mm, P345; 500–400–300 mm, P543). All results are compared to a standard reference, the straight square duct (SD-AR1.00), to ensure fair comparisons across all cases with Reynolds numbers between 5000 and 20,000. Among the twisted ducts, the strongest rectangularity combined with the increasing pitch sequence, TSD-AR0.50-P345, provides the best overall balance. Its heat transfer rises from Nu = 39.39 to 88.62, giving Nu/Nu₀ = 1.493 → 1.433, while the pressure penalty increases to f/f₀ = 1.345 → 1.405. Under cube-root weighting of friction, this case maintains the highest thermal performance factor, TPF = 1.352 at Re = 5000 and TPF = 1.279 at Re = 20,000. Second-law trends support the same ranking: exergy destruction decreases from 12.81 W (baseline) to 8.44 W at Re = 5000 (≈34% reduction) and from 6.54 W to 4.84 W at Re = 20,000 (≈26% reduction). The Bejan number remains high at low Reynolds numbers (≈0.998), indicating heat-transfer irreversibility dominance, but drops at higher Reynolds numbers (≈0.87) as frictional effects become more important. In general, the results show that adding a small axial pitch increase to rectangularity can improve near-wall mixing while reducing losses downstream. This leads to a clear improvement in both first-law performance and exergy-based measures. Full article

This study develops and optimizes a hybrid plant that couples a recompression sCO₂ Brayton cycle to a central-tower particle receiver with a bottoming Organic Rankine Cycle (ORC), including environmental and exergy balances. The two scenarios revealed Pareto points that raised the exergy efficiency to 0.65 in winter and reduced the fuel flow to 15 kg/s. Scenario number two achieves an overall thermal efficiency of 0.50 with total daily emissions of 2520 t CO₂ and 2850 kg NO_x, enabling nearly constant net power. Exergy destruction is concentrated in the high-temperature recuperator (HTR) and ORC turbines (27% each) and the ORC condenser (25%). Compared to a non-optimized baseline, the best solutions increased the ORC and Brayton efficiencies by 6.8–12.66% and 33.4–33.5%, respectively; cut gas-turbine power by 34% and ORC power to 10%; and lowered daily CO₂ and NO_x emissions by 52%. The gains stem from the coordinated adjustments of key levers: lower gas-turbine inlet temperature (about 10%), reduced Brayton mass flow (23%), and tuned ORC turbine inlet pressure. Full article

In multifunctional and high-energy-density integrated buildings, energy performance and environmental impacts are affected by the environmental conditions in which they are located. Entropy production, which is an output of exergy analysis in energy performance, offers a new evaluation area for energy management in this context. In the study developed for this purpose, the condensate line formed in the steam distribution lines of an integrated building was modeled, and the possible inefficiency potential of the condensate load formed and the usability of the approach developed over entropy production were suggested by energy management. Entropy production due to exergy destruction of distribution lines derived from condensate pump data in the integrated building was evaluated with two environmental indices developed. According to the analysis, the average exergy efficiency for the distribution lines of the integrated building system is 22%, with exergy extinction reaching 78%, indicating a high level of return level. The recovery potential associated with the total exergy flow was calculated as 50.8%, while the entropy generation potential due to the condensation load was 65.3%. From an environmental perspective, the potential for pollution based on entropy has reached 64.9%, while the target energy efficiency level associated with condensate management has been set at 33.5%. The findings suggest that this approach for energy management offers a quantitative evaluation opportunity between thermodynamic irreversibility and environmental performance in buildings. At the end of the study, a comparative analysis of this approach with the classical regression approach for energy management is also given. Full article

Desalination is an increasingly important element in the sustainable supply of potable water. To accurately predict costs, the efficiency of such systems requires accurate knowledge of seawater’s thermodynamic properties. Four models have been proposed for determining the thermophysical properties of salt water, pure water, an ideal mixture, and an aqueous sodium chloride solution, and empirical correlations, as would be expected, provide the precision necessary for accurate exergy calculations. This research began with a study of the most recent and accurate empirical investigations of the thermodynamic properties of seawater. It then employed AI techniques to develop a simpler, more accurate model for density, Gibbs free energy, specific enthalpy, and specific entropy for pressures extending up to 12 MPa, salinities from 0 to 80 g/kg, and the temperature range of 10 °C to 120 °C. The AI-based correlations achieved absolute errors of 1.5 kg/m³ for density, 0.185 kJ/kg for specific enthalpy, 0.005 kJ/kg·K for specific entropy, and 0.214 kJ/kg for Gibbs free energy. These values demonstrated at least equivalent, and even superior, accuracy to the existing state-of-the-art formulations, with the advantage of significantly reduced computational complexity, enhanced computational efficiency, and a more user-friendly implementation. Validation against experimental data demonstrated the exceptional accuracy of the predicted values for all the stated thermodynamic properties. In addition, an exergy-based assessment was conducted of the performance of a recently commissioned desalination plant in Kuwait. This was a large-scale multi-effect distillation plant with thermal vapour compression (MED-TVC), showing a second-law efficiency of 8.9%, with the primary source of exergy destruction identified as the evaporator units. Comparative assessment with a more conventional approach showed differences of less than 0.4% in total exergy destruction and less than 5% in exergetic efficiency. This is taken as a validation of the accuracy, reliability, and practical usefulness of the proposed AI framework for the performance evaluation of desalination systems. Full article

Thermal energy rejected through exhaust gases and cooling systems in marine propulsion units and conventional power plants represents a significant yet underutilized opportunity for improving energy efficiency and reducing carbon emissions. The Organic Rankine Cycle (ORC) has emerged as an effective technology for converting such waste heat into useful power using organic working fluids with favorable thermophysical properties. This study presents a comprehensive thermodynamic, economic, and exergo-economic evaluation of an ORC system incorporating single-stage and multistage turbine arrangements, using R245fa, R123, and R365mfc as working fluids. A validated cycle model is coupled with key economic indicators, including Net Present Value (NPV), Levelized Cost of Electricity (LCOE), and payback period, together with a simplified exergo-economic framework based on exergy destruction costs. The results demonstrate that implementing ORC-based waste heat recovery significantly enhances overall system performance by converting rejected thermal energy into electricity and improving thermal efficiency. Multistage turbine configurations further strengthen performance, increasing net power output and efficiency, with the multistage R245fa system generating more than 530,000 kWh annually. Economically, the single-stage R245fa configuration achieves the lowest LCOE (0.021 USD/kWh) and the shortest payback period, below eight years. Exergo-economic analysis shows that multistage turbines can reduce exergy destruction costs by more than 80%, with benefits becoming pronounced at heat source temperatures above 170 °C. Full article

Geothermal energy is recognized as one of the most reliable and environmentally sustainable energy sources. This study presents a comprehensive energy, exergy, economic, and exergoenvironmental assessment of the Mis I binary geothermal power plant (GPP) operating with a low-temperature geothermal resource. This study fills a critical gap in the literature by providing a four-dimensional (4-E) assessment—energy, exergy, economic, and exergoenvironmental—of the Mis I binary geothermal power plant (GPP). Unlike conventional studies that focus on theoretical models, this research utilizes real-time operational data to identify potential improvements at the component level by evaluating exergy-based environmental sustainability and economic performance. The energy efficiency of the n-Pentane Rankine cycle was calculated as 39.76%, indicating that a substantial portion of the geothermal heat is rejected as waste. The exergy input to the plant was determined to be 18,580.29 kW, while the net electrical power output was 8990 kW, resulting in an overall exergy efficiency of 48.38%. These results highlight the clear disparity between energy and exergy efficiencies and underline the importance of exergy-based performance evaluation for low-temperature geothermal power systems. Component-level exergy balance analyses were conducted using real operating data, revealing that the cooling towers are the dominant sources of exergy destruction, whereas the turbine units exhibit comparatively high thermodynamic effectiveness. Improvement potential analysis identified cooling towers I–II, evaporator II, and preheater I as key components requiring further optimization. Economic evaluation showed that approximately 64% of the total investment cost is associated with turbine units, with a total plant cost of about USD 6.7 million. The levelized cost of electricity was calculated as 0.0136 USD/kWh, and the payback period was approximately 1.5 years. Exergoenvironmental results indicate that the Mis I GPP achieves the highest sustainability index (1.94) among comparable plants, confirming its superior thermodynamic, economic, and environmental performance. Full article

Improving the thermodynamic and economic performance of industrial refrigeration systems is essential for reducing energy consumption and enhancing cold chain sustainability. This study presents an integrated energy, exergy, and exergoeconomic assessment of a full-scale two-stage ammonia (R717) vapor compression refrigeration system operating under real industrial conditions in Türkiye. Experimental data from 33 measurement points were used to perform component-level thermodynamic balances under steady-state conditions. The results showed that the evaporative condenser exhibited the highest heat transfer rate (426.7 kW), while the overall First Law efficiency of the system was 63.71%. Exergy analysis revealed that heat exchangers are the dominant sources of irreversibility (>45%), followed by circulation pumps with a notably low Second Law efficiency of 11.56%. The exergoeconomic assessment identified the circulation pumps as the components with the highest loss-to-cost ratio (2.45 W/USD). An uncertainty analysis confirmed that the relative ranking of system components remained robust within the measurement uncertainty bounds. The findings indicate that, although the existing NH₃ configuration provides adequate performance, significant improvements can be achieved by prioritizing pump optimization, maintaining higher compressor loading, and implementing advanced variable-speed fan control strategies. Full article

In cryogenic air liquefaction systems, a major share of the mechanical energy consumption is associated with exergy destruction caused by heat transfer in recuperative heat exchangers. This study investigated the exergetic optimization of cryogenic gas separation systems by focusing on the Claude–Heylandt cycle as an advanced structural modification of the classical Linde–Hampson scheme. An exergy-based analysis demonstrates that minimizing mechanical energy consumption requires a progressive reduction in the temperature difference between the hot forward stream and the cold returning stream toward the cold end of the heat exchanger. This condition was achieved by extracting a fraction of the high-pressure stream and expanding it in a parallel expander, thereby creating a controlled imbalance in the heat capacities between the two streams. The proposed configuration reduces the share of exergy destruction associated with heat transfer in the recuperative heat exchanger from 14% to 3.5%, leading to a fourfold increase in the exergetic efficiency, together with a 3.6-fold increase in the liquefied air fraction compared with the Linde–Hampson cycle operating under identical conditions. The effects of key decision parameters, including the compression pressure, imposed temperature differences, and expander inlet temperature, were systematically analyzed. The study was further extended by integrating an air separation column into the Claude–Heylandt cycle and optimizing its configuration based on entropy generation minimization. The optimal liquid-air feeding height and threshold number of rectification trays were identified, beyond which further structural complexity yielded no thermodynamic benefit. The results highlight the effectiveness of exergy-based optimization as a unified design criterion for both cryogenic liquefaction and separation processes. Full article