Search Results (74)

The thermal conductivity (λ) of porous rocks as a function of total porosity, grain size, and fluid saturation is measured and modeled by combining high-precision experiments with a Staged Differential Effective Medium (SDEM) modeling framework. A 1-D divided-bar apparatus with computer-controlled guard heaters with an integrated ultrasonic pulse-transmission system was developed to measure the thermal conductivity and P and S-wave velocities simultaneously. Measurements were made on Fontainebleau sandstone cores and quartz sand packs of varying grain size and effective stresses up to 2000 psi. The sample properties were measured in both dry and water-saturated states. The SDEM model performs significantly better at predicting the saturated thermal conductivities in the sand packs. For the sand packs, the thermal conductivity and compressional velocity are the highest and most stress-sensitive for the fine-grained material. In contrast, the shear velocity is largest in the coarse-grained material. The SDEM model is adapted from previous acoustic models for use in understanding thermal conductivity. These joint models accurately reproduce the evolution of both thermal conductivity and bulk modulus during increasing compaction and varying saturation. A single parameter fits both the dry and saturated data, which allows Gassmann-style fluid substitution for the thermal conductivity. This model improves the prediction of in situ thermal conductivity from sonic well logs. Full article

The conservation of tuff- and coral rock-built architectural heritage structures (AHS) is challenging because access to original tuff and coral rock has become difficult and severely limited due to urbanization, land reclamation, the depletion of stone quarries, anti-mining and anti-quarrying legislation. An emerging approach to address this issue is to create compatible “replacement” rocks via geopolymerization, a process that is more sustainable and greener than the use of conventional cement and concrete. To explore the potential of geopolymers for AHS conservation strategies, the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines were implemented; 103 eligible articles were identified and classified into geopolymers for AHS (34 articles), tuff-built AHS (60 articles), and coral rock-built AHS (9 articles). Tuff substrates in AHSs appear in a variety of colors (yellowish-brown, grayish-cream, reddish-brown, pale greenish-gray and pink hues), densities (1.0–2.5 g/m³), and compressive strengths (3–100 MPa). Meanwhile, coral rock substrates in AHSs appear in whitish-cream color and are coarse-pored (1–5 MPa), fine-grained (8–15 MPa), and calcarenite (50–60 MPa). In terms of geopolymer formulation, metakaolin was reported as the most popular main precursor or admixture, while NaOH and Na₂SiO₃ were used simultaneously as alkaline activators. Aggregates used in geopolymer formulations depended on local availability, including quartz sand, river sand, crushed stones, carbonate stones, volcanic rock, volcanic sand, tuff, brick, ceramic tiles, and waste materials. Aesthetics, chemical composition, physical attributes, and mechanical properties have been identified as key criteria to ensure geopolymer compatibility for AHS conservation application. To date, geopolymers have been applied for AHS conservation as repair mortars, consolidants (i.e., grout and adhesives), and masonry strengthening (i.e., fiber-reinforced mortar). Finally, geopolymers formulated for AHS conservation have similar durability as the original substrate based on accelerated aging tests (i.e., salt mist, wet-dry, and freeze–thaw) and long-term outdoor exposure experiments. Full article

In engineered cementitious composites (ECCs), the use of fine quartz sand is associated with high cost and is unfavorable for reducing ECC shrinkage. Moreover, the mining and processing of fine quartz sand impose negative environmental impacts. At the same time, the polyethylene (PE) or polyvinyl alcohol (PVA) fibers added to ensure ECC ductility are expensive, which limits the widespread application of ECCs. With the aim of waste utilization and cost reduction while improving efficiency, this study employs geopolymer aggregate (GPA) as an alternative to fine quartz sand and partially replaces PE fibers with steel fibers to develop an economical and environmentally friendly geopolymer aggregate ECC. Six groups of ECC specimens with different mix proportions were designed and tested under uniaxial compression, flexural loading, and uniaxial tension. Different aggregate types (fine quartz sand and geopolymer aggregate) and volume fraction ratios of PE fibers to steel fibers (0:2.0, 0.5:1.5, 1.0:1.0, 1.5:0.5, and 2.0:0) were adopted to investigate their effects on mechanical properties, microstructural characteristics, and material sustainability. The experimental results reveal the failure process and deformation characteristics of the ECCs at different loading stages. The results indicate that geopolymer aggregate, owing to its lower stiffness and fracture energy, can promote multiple cracking behavior in ECCs. Although the complete replacement of quartz sand with porous GPA initially causes a slight reduction in the compressive and flexural strengths of the matrix, the hybridization strategy—partially replacing PE fibers with steel fibers—effectively compensates for this strength loss while maintaining excellent ductility. By comparing sustainability indicators with those of conventional ECCs, the results demonstrate that hybrid fiber geopolymer aggregate ECCs can effectively reduce material costs and carbon dioxide emissions. These findings verify the sustainability of producing green ECCs using industrial solid waste as an aggregate and provide guidance for the application of environmentally friendly geopolymer aggregate ECCs. Full article

This study investigates the preparation and performance of ultra-high-performance concrete (UHPC) incorporating manufactured sand as a full replacement for quartz sand. The mix design was optimized by integrating the compressible packing model (CPM) with an orthogonal experimental design. The influence of stone powder content in manufactured sand—0, 5, 10, and 15% by mass of fine aggregate—on fresh-state fluidity and 7d-mechanical properties was systematically evaluated. Hydration products and microstructural features were analyzed using X-ray diffraction (XRD), scanning electron microscope (SEM), and mercury intrusion porosimetry (MIP). Results show that the manufactured sand-based UHPC achieved a fresh-state fluidity of 185 mm and a 7-day compressive strength of 152.4 MPa. Both fluidity and compressive strength exhibited a unimodal trend with increasing stone powder content, reaching maxima at 10%. Microstructural analysis revealed intimate interfacial bonding between unhydrated particles and calcium silicate hydrate (C–S–H) gel; notably, the UHPC matrix with 10% stone powder displayed the densest microstructure. MIP results further demonstrated that an optimal stone powder content effectively reduced total porosity, with the lowest overall porosity and the highest volume fractions of harmless (≤20 nm) and less harmful (20–100 nm) pores observed at 10%. These microstructural refinements collectively underpin the superior mechanical performance of manufactured sand-based UHPC. Full article

Traditional enzyme-induced carbonate precipitation (EICP) technology for brick crack rehabilitation is commonly plagued by solution clogging and low repair efficiency. To overcome these technical limitations, a novel centrifugal cementation method was proposed in this study, with its core innovation lying in decoupling the EICP reaction from the masonry reinforcement process. After the complete reaction of urease with the cementation solution, a high-concentration calcium carbonate colloid was extracted via centrifugation, which was then mixed with fine sand to prepare a repair mortar for direct injection into brick cracks. The experimental results, based on a single-factor design with a fixed soybean powder concentration (180 g/L, peak urease activity), showed that the maximum flexural strength of the repaired bricks reached 2.31 MPa, recovering as much as 122.9% of that of the cracked unrepaired bricks. Furthermore, the flexural strength of the repaired bricks exhibited a significant positive correlation with the calcium carbonate content (20–100%) and curing time (3–28 days). Phase analysis indicated that the repair mortar was primarily composed of calcite and quartz. The high shear force generated by centrifugation triggered explosive nucleation of calcium carbonate, and spherical calcite particles were formed through Ostwald ripening, exhibiting a distinct characteristic of decoupling between the spherical morphology and calcite crystal phase. The centrifugal cementation method proposed in this study achieves excellent short-term repair effects for masonry structures under laboratory conditions, thus providing a novel technical approach for the crack rehabilitation of masonry structures. Full article

This study evaluates the feasibility of utilizing manufactured sand as a full or partial replacement for river sand in mass concrete production, motivated by the growing scarcity of natural river sand and stringent environmental regulations on mining. The influence of the manufactured sand replacement level, water-to-cement ratio, and fly ash content on key properties including workability, mechanical strength, early-age shrinkage, and thermal stress was systematically investigated. The results demonstrate that, while the incorporation of manufactured sand marginally impairs workability, it contributes to an improved particle size distribution of the fine aggregate. At 100% replacement, the 56-day compressive, flexural, and tensile strengths, as well as the elastic modulus of manufactured sand concrete, exceed those of river sand concrete, accompanied by a notable reduction in early-age shrinkage. A decrease in the water–binder ratio enhances mechanical performance but concurrently elevates the risk of cracking due to the increased autogenous shrinkage and adiabatic temperature rise associated with a higher cement content. The addition of an optimal amount of fly ash (e.g., 25%) effectively improves both workability and mechanical properties while substantially mitigating hydration heat, thereby reducing temperature differentials and the associated cracking risks. Microscopic analysis reveals that unhydrated particles, including fly ash and quartz, may act as initial defects within the microstructure. Overall, the replacement of river sand with manufactured sand in mass concrete is technically feasible, and an appropriate mix design optimization can achieve a desirable balance between performance and crack resistance. Full article

The advancement of reactive powder concrete (RPC) technology primarily focuses on modifications to its conventional composition. This involves substituting Portland cement (CEM I) with alternative cement types and finely ground mineral additives, as well as replacing quartz aggregate with another type of aggregate. The paper presents an analysis of the properties of RPC obtaining using waste sand and powder generated during the processing of aggregates from migmatite-amphibolite rock. Research into RPC mixtures revealed that in one scenario, replacing quartz powder with waste powder resulted in a significant increase in flexural strength by 23%, although there was a slight decrease in compressive strength by 7%. However, when both quartz powder and quartz sand were substituted with waste powder and waste sand, there was a 14% reduction in compressive strength, while flexural strength increased, albeit to a much lesser extent. The analysis of mineral composition and microstructure of migmatite-amphibolite waste powder and sand revealed that the primary factor contributing to the increase in flexural strength is the presence of biotite in a flake shape form. The microscopy images clearly show hydration products gathering mainly at the rims of biotite flakes and not on their smooth surfaces. The reason could be better availability for hydration products attachment and lower steric hindrance to the rims of single biotite flakes instead of its large packets. Conversely, the reduction in RPC compressive strength, resulting from the substitution of quartz sand with migmatite-amphibolite waste sand, can be attributed mainly to the lower compressive strength of the waste sand itself. Test results indicate that the waste powder generated during the production of migmatite-amphibolite aggregates, which contains fine flakes of biotite, can be utilised as a mineral admixture in concrete, thereby enhancing its flexural strength. Full article

Various methods for classifying and evaluating the shape, size, and surface texture of sand particles are examined, highlighting their impact on concrete mixture properties. This study emphasizes the role of particle morphology in determining concrete workability and segregation, particularly in glass-fiber-reinforced (GRC) thin-layer concrete for building facade panels. The effects of different aggregate types on concrete workability and segregation are analyzed, showing that aggregates with spherical particles and a lower elongation index improve mixture consistency and reduce segregation. Three types of fine aggregates were used (instead of quartz sand in the mixtures, natural sand and granite screenings were chosen, which would be a sustainable alternative to quartz sand), and thin-layer glass-fiber-reinforced concrete using aggregates of different shapes was characterized by layering the mixture. The workability and segregation of fine-grained fiberglass-reinforced concrete mixtures depend on the aggregate particles’ shape. Up to 50% of quartz sand can be replaced with granite siftings or natural sand, as measured by the segregation index, as calculated according to the method proposed in this paper. Increasing the amount of natural sand from 10% to 50% also increases the segregation index from 1.9 to 2.6, and when using granite sifting aggregates, it rises from 2.6 to 3.5. Aggregates with spherical particles are more suitable for this thin-layer GRC concrete, if we examine the consistency parameters of fresh concrete and the possibilities of working with it in real production conditions. Full article

Capillary barrier covers (CBCs) have gained widespread application as engineered surface layers in landfill systems, agricultural water retention infrastructures, and slope protection designs due to their superior water storage capacity and lateral drainage characteristics. During the long-term service of CBCs, fine particles may enter into the coarse-grained layer, which affects the water storage capacity and even causes CBCs to fail. Therefore, this study investigated the influence of admixing different types of soils (into the coarse-grained layer) and their proportions on water storage capacity through laboratory soil column experiments. The results indicate the following: (1) A method is proposed to determine the failure of the capillary barrier by utilizing the variation pattern of volumetric water content (VWC) at the fine–coarse-grained layer interface. (2) An effective capillary barrier can only be formed if the saturated permeability coefficient of the coarse-grained layer is at least one order of magnitude greater than that of the fine-grained layer. (3) When the saturated hydraulic conductivity of the fine particles incorporated into the coarse-grained layer is less than 10⁻⁵ cm/s, the matric potential of the fine-grained layer consistently exhibits a CBC line type. When the saturated hydraulic conductivity of the fine particles is greater than 10⁻⁵ cm/s, the matric potential of the fine-grained layer shows a homogeneous line type at an incorporation ratio of 1:0.6. (4) When the particle size of the fine particles mixed into the coarse-grained layer (quartz sand, silt, and diatomite with admixture ratios of 1:0.1, 1:0.3, 1:0.6, and 1:1) is smaller than that of the particles in the fine-grained layer, the water storage capacity of CBCs is only affected by the proportion of fine particles added to the coarse-grained layer and is independent of the type of fine particle used. Full article

The mineralogical, geochemical, and statistical characteristics of recent fluvial deposits from the Brahmaputra–Jamuna River, Bangladesh, were examined to determine their provenance, transport dynamics, and depositional environment. Sediments were analyzed using X-ray diffraction (XRD), wavelength dispersive X-ray fluorescence (WD-XRF), field emission scanning electron microscopy (FE-SEM), and electron probe microanalysis (EPMA). Grain size analysis revealed a predominance of medium-to-fine sand (mean grain size 1.77–3.43 ϕ), with moderately well-sorted textures (sorting: 0.33–0.77 ϕ), mesokurtic to leptokurtic distributions, and skewness values ranging from −0.21 to +0.30. Mineralogical results show a high quartz content with minor feldspar, mica, zircon, rutile, and iron-bearing minerals. Geochemical data indicates high SiO₂ (63.39%–70.94%) and Al₂O₃ (12.25%–14.20%) concentrations and calculated chemical index of alteration (CIA) values ranging from 60.90 to 66.82. The microstructural study revealed angular to sub-angular grains with conchoidal fractures and stepped microcracks, indicating brittle deformation under high-energy conditions, which is consistent with short transport distances, limited sedimentary recycling, and a derivation from mechanically weathered source rocks. Multivariate analyses (PCA and K-means clustering) of grain size parameters reveal two distinct sedimentary regimes, namely Cluster 1 as finer-grained (2.36 ϕ), poorly sorted sediments, and Cluster 2 as coarser (2.98 ϕ), well-sorted deposits. Discriminant function values (Y₂: 78.82–119.12; Y₃: −6.01 to −2.56; V₁: 1.457–2.442; V₂: 1.409–2.323) highlight shallow water, fluvial/deltaic aspects, and turbidite depositional environments. These findings advance the understanding of sedimentary dynamics within large, braided river basins and support future investigations into the sustainable management of fluvial depositional environments. Full article

The utilization of hydrocyclones dates back more than a century. As the key channel for multiphase flow, the inlet chamber exerts a notable influence on the separation efficiency of hydrocyclones. Conventional feed bodies mainly adopt straight lines as guidelines. During the transition of fluid from linear motion to circumferential motion, significant kinetic energy loss and particle misalignment are exhibited, resulting in relatively low classification accuracy of the hydrocyclone. Therefore, in this study, a hydrocyclone featuring a complex curved inlet chamber structure was designed, and numerical analysis was employed to examine the particle distribution and aggregation characteristics within both the inlet chamber and the hydrocyclone. Supplemented with RSM/VOF/TFM simulations and quartz sand experimental validation, this study compares the separation performance of the complex curved inlet with the conventional linear inlet. The results indicate the following: when particle sizes are small, particles are dispersed throughout the hydrocyclone and inlet chamber, exhibiting a disordered state, which leads to poor classification performance. As particle size increases, particles gradually form layers along the radial direction; larger particles tend to accumulate on the hydrocyclone wall. When the particle concentration is maintained within a specific range, it promotes the migration of fine particles toward the center, thereby reducing the likelihood of fine particles entering the outer vortex and allowing for more precise classification of fine particles. As the particle concentration increases, the cutting ability of the hydrocyclone progressively diminishes; when the concentration exceeds 20%, the maximum underflow recovery rate for particles smaller than 50 µm is only 60%, resulting in significant coarse overflow and a notable decrease in classification precision. Furthermore, as the inlet concentration increases, the dispersion index for 0.5 µm particles ranges from 0.6 to 1.6, for 4 µm particles from 0.6 to 1.4, and for 60 µm particles from 0.6 to 1. The decreasing dispersion index indicates an increasing classification force, which aids in the formation of a coarse particle layer on the wall. The conclusions and data obtained provide a theoretical foundation and empirical support for the design of innovative inlet chamber structures. Full article

The texture and composition of river sediments are key to understanding the characteristics of source rocks, chemical weathering in the source area, physical modifications during transport, and human impacts within watersheds. This study analyzes 47 very fine to coarse size sands from the Lancang (Upper Mekong) River in China to monitor compositional variations and assesses the contribution of different geological units to trunk-river sediments. Lancang River sands are mostly feldspatho-quartzo-lithic in composition, with quartz content increasing downstream at the expense of lithic fragments (especially of carbonate lithics). Sand is mostly generated from the Lincang and Baoshan blocks, with subordinate contributions from the Simao and Changdu blocks. This study provides new insights into erosional and depositional processes in the Lancang River and emphasizes the impact of human activities on river sediment transport. Full article

High-performance geopolymer concrete (HPGC) is an eco-friendly type of concrete that is traditionally made of slag, silica fume (SF), and quartz sand. Recycling industrial waste in HPGC presents an eco-friendly approach for maximizing sustainability in the construction sector. This study evaluates the impact of incorporating recycled fine aggregates like crumb rubber (CR), glass waste (GW), and ceramic waste (CW) as partial replacements for quartz sand in HPGC at 10%, 20%, and 40% by volume. GW and CW were also used in binder size as full replacements for SF. The novelty of this research lies in its comprehensive evaluation of waste-integrated HPGC under diverse conditions, including mechanical performance, durability (water absorption, sulfate/chloride/acid resistance), thermal stability (up to 600 °C), and microstructure analysis, while addressing critical gaps in eco-friendly construction materials. The results indicate that CW significantly enhanced compressive strength, increasing by 24–29% at 10% and 40% replacement levels, whereas CR reduced strength by 69.2–83.5%. GW effectively decreases water absorption by 66–72% compared to CW and CR. Both CW and GW improved chemical resistance, reducing compressive strength loss by 15–33% under sulfate and acid attacks. CW exhibited superior residual strength at 600 °C, reaching 96.4 MPa, compared to 54.5 MPa for GW. However, fully replacing SF with GW or CW as a binder resulted in performance deterioration, making it unsuitable. This study demonstrates that incorporating recycled waste materials in HPGC enhances its mechanical and durability properties, making it a viable option for sustainable construction. The findings support the integration of CW and GW as eco-friendly alternatives in HPGC applications. Full article

This study illustrates the complex interaction between environmental parameters and carbonate distribution in marine sediments along the Tarfaya–Boujdour coastline (26–28° N) of Northwest Africa. Analysis of 21 surface sediment samples and their associated bottom water properties (salinity, temperature, dissolved oxygen, nutrients) reveals CaCO₃ content ranging from 16.8 wt.% to 60.5 wt.%, with concentrations above 45 wt.% occurring in multiple stations, especially in nearshore deposits. Mineralogy indicates a general decrease in quartz, with an arithmetic mean and standard deviation of 52.5 wt.% ± 19.8 towards the open sea, and an increase in carbonate minerals (calcite ≤ 24%, aragonite ≤ 10%) with depth. Sediments are predominantly composed of fine sand (78–99%), poorly classified, with gravel content reaching 6.7% in energetic coastal stations. An inverse relationship between organic carbon (0.63–3.23 wt.%) and carbonates is observed in upwelling zones, correlated with nitrate concentrations exceeding 19 μmol/L. Hydrological gradients show temperatures from 12.41 °C (offshore) to 21.62 °C (inshore), salinity from 35.64 to 36.81 psu and dissolved oxygen from 2.06 to 4.21 mL/L. The weak correlation between carbonates and depth (r = 0.10) reflects the balance between three processes: biogenic production stimulated by upwelling, dilution by Saharan terrigenous inputs, and hydrodynamic sorting redistributing bioclasts. These results underline the need for models integrating hydrology, mineralogy and hydrodynamics to predict carbonate dynamics in desert margins under upwelling. Full article

The Elfeija Dune Field (EDF) is a continental aeolian system in an arid region of southeastern Morocco. Studying this system is critical for understanding the effects of mounting climatic and anthropogenic pressures. This study provides a comprehensive characterization of the EDF’s morphology, sedimentology, aeolian dynamics, genesis, and recent evolution. A multi-scale, multidisciplinary approach was adopted, integrating field observations, sedimentological analyses, MERRA-2 reanalysis wind data, cartographic analysis, digital terrain modeling, and morphometric measurements. The results reveal an active 30 km² dune field, elongated WSW-ENE, which is divisible into three morphodynamic zones with a high dune density (80–90 dunes/km²). The wind regime is predominantly from the W to WSW, driving a net ENE sand transport and creating conditions conducive to barchan formation (RDP/DP > 0.78). Sediments are quartz dominated, with significant calcite and various clay minerals (illite, kaolinite, and smectite). Dune sands are primarily fine- to medium-grained and well sorted, in contrast to the more poorly sorted interdune deposits. The landscape is dominated by barchans (mean height H = 2.5 m; mean length L = 50 m) and their coalescent forms, indicating sustained aeolian activity. The potential sand flux was estimated at 1.7 kg/m/s, with a dune collision probability of 32%. The field’s genesis is hypothesized to be controlled by a topographically induced Venturi effect, with an initiation approximately 1000 years ago, potentially linked to the Medieval Climatic Optimum. Significant anthropogenic impacts from expanding irrigated agriculture are observed at the dune field margins. By providing a detailed characterization of the EDF and its sensitivity to natural and anthropogenic forcings, this study establishes a critical baseline for the sustainable management of arid environments. Full article