Search Results (994)

The ordinary Portland cement (OPC) manufacturing process is highly resource-intensive and contributes to over 5% of global CO₂ emissions, thereby contributing to global warming. In this context, researchers are increasingly adopting geopolymers concrete due to their environmentally friendly production process. For decades, industrial byproducts such as fly ash, ground-granulated blast-furnace slag, and silica fume have been used as the primary binders for geopolymer concrete (GPC). However, due to uneven distribution and the decline of coal-fired power stations to meet carbon-neutrality targets, these binders may not be able to meet future demand. The UK intends to shut down coal power stations by 2025, while the EU projects an 83% drop in coal-generated electricity by 2030, resulting in a significant decrease in fly ash supply. Like fly ash, slag, and silica fume, natural clays are also abundant sources of silica, alumina, and other essential chemicals for geopolymer binders. Hence, natural clays possess good potential to replace these industrial byproducts. Recent research indicates that locally available clay has strong potential as a pozzolanic material when treated appropriately. This review article represents a comprehensive overview of the various treatment methods for different types of clays, their impacts on the fresh and hardened properties of geopolymer concrete by analysing the experimental datasets, including 1:1 clays, such as Kaolin and Halloysite, and 2:1 clays, such as Illite, Bentonite, Palygorskite, and Sepiolite. Furthermore, this review article summarises the most recent geopolymer-based prediction models for strength properties and their accuracy in overcoming the expense and time required for laboratory-based tests. This review article shows that the inclusion of clay reduces concrete workability because it increases water demand. However, workability can be maintained by incorporating a superplasticiser. Calcination and mechanical grinding of clay significantly enhance its pozzolanic reactivity, thereby improving its mechanical performance. Current research indicates that replacing 20% of calcined Kaolin with fly ash increases compressive strength by up to 18%. Additionally, up to 20% replacement of calcined or mechanically activated clay improved the durability and microstructural performance. The prediction-based models, such as Artificial Neural Network (ANN), Multi Expression Programming (MEP), Extreme Gradient Boosting (XGB), and Bagging Regressor (BR), showed good accuracy in predicting the compressive strength, tensile strength and elastic modulus. The incorporation of clay in geopolymer concrete reduces reliance on industrial byproducts and fosters more sustainable production practices, thereby contributing to the development of a more sustainable built environment. Full article

Wildfires are a source of air pollution, which impacts air quality in proximity to and at great distances from fires. Wildfire smoke exposure is seasonal and episodic, with exposure levels and durations that can vary considerably. Exposure to wildfire smoke is associated with numerous health effects, including an increased risk of mortality and exacerbation of respiratory diseases. In Canada, the health risks of wildfire smoke are communicated to the public via air quality (AQ) alerts, when levels of wildfire smoke are currently or are forecasted to be relatively high, posing a risk to the general population. To better understand the population at risk due to wildfire smoke, a population-based exposure metric was developed based on geolocated AQ alerts and population data. This metric, measured in person-days, quantifies the number of people at risk of experiencing adverse health effects of wildfire smoke during a given time period. Data from the 2023 wildfire season were used to evaluate the metric. The greatest numbers of person-days were associated with population centres and regions that experienced periods of prolonged, intense smoke exposure. For example, Toronto, a large population centre, had 12 days with AQ alerts issued, corresponding to 33.5 M person-days. This approach could be expanded to other environmental or extreme weather conditions. Full article

Adaptive forest and fire management in parks and protected areas is becoming increasingly complex as climate change alters the frequency and intensity of disturbances (wildfires, pest and disease outbreaks, etc.), while park visitation and the number of people living adjacent to publicly managed lands continues to increase. Evidence-based, climate-adaptive forest and fire management practices are critical for the responsible stewardship of public resources and require the continued availability of long-term ecological monitoring data. The US National Park Service has been collecting long-term fire monitoring plot data since 1998, and has continued to add monitoring plots, but these data are housed in databases with limited access and minimal analytic capabilities. To improve the availability and decision support capabilities of this monitoring dataset, we created the Trends in Forest Fuels Dashboard (TFFD), which provides an implementation framework from data collection to web visualization. This easy-to-use and updatable tool incorporates data from multiple years, plot types, and locations. We demonstrate our approach at Rocky Mountain National Park using the ArcGIS Online (AGOL) software platform, which hosts TFFD and allows for efficient data visualizations and analyses customized for the end user. Adopting interactive, web-hosted tools such as TFFD allows the National Park Service to more readily leverage insights from long-term forest monitoring data to support decision making and resource allocation in the context of environmental change. Our approach translates to other data-to-decision workflows where customized visualizations are often the final steps in a pipeline designed to increase the utility and value of collected data and allow easier integration into reporting and decision making. This work provides a template for similar efforts by offering a roadmap for addressing data availability, cleaning, storage, and interactivity that may be adapted or scaled to meet a variety of organizational and management use cases. Full article

Energy-intensive sectors in emerging nations have the simultaneous difficulties of trying to diminish greenhouse gas emissions while maintaining a stable and cost-effective energy supply. Rooftop solar photovoltaic (PV) systems offer a viable solution, especially in tropical areas like Indonesia that have elevated solar irradiance. This study employs a comprehensive methodology to evaluate the structural, economic, and safety viability of rooftop photovoltaic adoption in the Fast-Moving Consumer Goods (FMCG) sector. Structural analysis utilizing the PMM Ratio verified that industrial rooftops can support a 599 kWp photovoltaic system with minimal reinforcements. The economic assessment revealed substantial feasibility, featuring a Levelized Cost of Energy (LCOE) of Rp 261.40/kWh (about USD 0.016/kWh), yearly savings of Rp 1.36 billion (approximately USD 89,000), a Return on Investment (ROI) of 570%, and a payback duration of 3.73 years. The safety evaluation utilizing the Hazard Identification and Risk evaluation (HIRA) technique found significant hazards—working at height, electrical faults, and fire risks—and recommended mitigation measures in accordance with IEC and Indonesian standards. The findings establish a replicable paradigm for assessing rooftop photovoltaic systems in energy-intensive sectors and furnish actionable recommendations for policymakers and industry executives to expedite the adoption of renewable energy in tropical emerging economies. Full article

Hanson (2022) evaluated thinning as a management tool to reduce wildfire tree mortality using thinning history and fire mortality data from the Goosenest Adaptive Management Area (GAMA) in California. The combination of on-the-ground measurements of thinning tree removal with remote sensing fire mortality data is questionable. Using his data, fire mortality in thinned stands was calculated and found to be less than mortality in unthinned (control) stands. Fire mortality in experimental plots does not properly represent the full benefits of density reduction because lower density provides a risk reduction that increases as more area is treated, due to the nature of fire spread. Thus, the conclusion that thinning is not beneficial is not supported by Hanson’s study and does not consider the importance of individual tree mortality vs. catastrophic forest loss and associated reductions in ecosystem services and loss of human infrastructure. Full article

Mediterranean ecosystems are highly susceptible to wildfires, and shifts in fire patterns pose a threat to biodiversity, soil stability, and overall ecosystem health resilience. Implementing prescribed burning as a management strategy to lower wildfire risk has been proposed, but its ecological impacts in Greece are not well understood. This study examines the relationship between fireline intensity during prescribed burning and plant water potential, as well as its effects on soil properties and plant biodiversity on Chios Island, Greece. Field experiments were carried out in representative ecosystems, where we measured flame length to determine fireline intensity. In addition, we gathered soil samples before and after the prescribed burning and evaluated plant diversity. Measuring leaf water potential gave us a better understanding of how plants respond physiologically to different seasonal and site conditions. Our findings revealed that prescribed burning typically boosted plant diversity after the fire, with Fabaceae and Asteraceae playing a key role in regeneration. However, the soil responses differed from one site to another. Some sites saw a decline in organic carbon and nitrogen, while others showed an increase in exchangeable cations like calcium and magnesium, highlighting the importance of site-specific results. Studies on plant water potential revealed seasonal fluctuations in stress, underscoring the importance of accounting for seasonality in prescribed burn planning. Overall, prescribed burning has the potential to enhance biodiversity and ecosystem recovery, while also reducing fuel loads. These results highlight the importance of ongoing, site-specific monitoring for developing sustainable fire management strategies in Mediterranean ecosystems. Full article

The global reliance on coal-fired power generation continues to produce vast quantities of fly ash, exceeding 500 million tons annually, with limited recycling rates. Given its high silica (SiO₂) and alumina (Al₂O₃) contents, fly ash represents a promising alternative raw material for sustainable refractory production. In this study, four aluminosilicate refractory castables were formulated using bauxite, calcined flint clay, kyanite, calcium aluminate cement, and microsilica, in which the fine fraction of flint clay was partially replaced by 0, 5, 10, and 15 wt.% fly ash. The specimens were dried at 120 °C and sintered at 850, 1050, and 1400 °C for 4 h. Their physical and mechanical properties were systematically evaluated, while phase evolution and microstructural development were analyzed through X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results revealed that the incorporation of 10 wt.% fly ash (10FAC) provided the optimal balance between densification and strength, achieving compressive strengths of 45.0 MPa and 65.3 MPa after sintering at 1050 °C and 1400 °C, respectively. This improvement is attributed to the formation of a SiO₂-rich liquid phase derived from fly ash impurities, which promoted the in-situ crystallization of acicular secondary mullite and enhanced interparticle bonding among corundum grains. The 10FAC castable also exhibited only a slight increase in apparent porosity (26.39%) compared with the reference (25.74%), indicating effective sintering without excessive vitrification. Overall, the study demonstrates the technical viability of using fly ash as a sustainable substitute for flint clay in refractory castables. The findings contribute to advancing circular economy principles by promoting industrial waste valorization and resource conservation, offering a low-carbon pathway for the development of high-performance refractory materials for structural and thermal applications in energy-intensive industries. Full article

In this study, we evaluate a phosphorus-based fire retardant (HR Prof) on Norway spruce using Simultaneous Thermal Analysis (STA: TG/DTG/DSC), Gas Chromatography–Mass Spectrometry (GC–MS), and bench-scale mass-loss measurements. Relative to the untreated reference, HR Prof re-routes decomposition toward earlier dehydration and transient char, simplifies the evolved gas mixture in the 150–250 °C range, and reduces burning intensity during 600 s of radiant exposure. Across 150/200/250 °C, identified components fell from 20/24/51 (reference) to 5/9/9 (HR Prof); no phosphorus-containing volatiles were detected in this window. Mass-loss tests showed a lower average burning rate (0.107 vs. 0.156%·s⁻¹) and a smaller cumulative loss at 600 s (64.2 ± 9.5% vs. 93.7 ± 2.1%; one-way ANOVA, p < 0.05 for percentage loss). STA was conducted in air; the transient char formed at an intermediate temperature is oxidized near ~600 °C, explaining the low final residue despite earlier charring. A count-based Poisson model corroborated the significant reduction in volatile component richness for HR Prof (p < 0.001). The cross-method correspondences—earlier condensed-phase dehydration/char → leaner volatile pool → lower and flatter burning-rate profiles—support a condensed-phase-dominated protection mechanism within the conditions studied. Full article

Localized employment gains from new or expanded fossil fuel development commonly are cited by its proponents in response to sustainability-related concerns raised by local drilling area residents. This paper analyzes local employment effects in drilling areas within the Marcellus shale formation in the state of Pennsylvania, USA. The Marcellus shale formation was one of the early natural gas fracking boom development areas globally, so these local employment outcomes can inform future policy decisions on not-yet-developed shale gas formations worldwide. As long-term sustainable jobs are a key part of any locale’s sustainable development program, the magnitude and persistence of employment gains in the local drilling area is highly relevant. The existing research literature on employment effects from increased shale gas extraction is dominated by usage of panel estimation on annual data at the U.S. state/county level. The innovative contribution of this paper is its use of monthly data, sub-state local areas (67 counties within PA), and a parsimonious vector autoregression model (VAR) estimated separately for each of the 67 counties. The estimated VAR models are used to ascertain whether Marcellus shale drilling activity in PA led to actual county-level employment above forecasted based on data prior to the shale boom. Actual versus forecasted employment is compared from 2010–2019. Higher than forecasted employment findings were much more likely to occur in approximately the top quarter of drilling counties, with the observed gains being modest. Most importantly, however, any employment gains above forecast were short-lived, gone within four years in most counties. Given the modest and temporary local employment gains found and the many known potential damages to local residents and the environment from intensive drilling, it is questionable that the local areas in the Marcellus shale formation most intensively drilled benefited overall from the shale gas extraction. These findings are germane to ongoing current debates about expanding natural-gas-fired electricity generation, versus solar plus storage, to meet anticipated large rises in electricity demand from rapid data center development globally. Full article

Wildfire risk assessment requires integrating heterogeneous geospatial data to capture complex environmental dynamics. This study develops a hierarchical multimodal fusion framework combining high-resolution aerial imagery, historical fire data, topography, meteorology, and vegetation indices within Google Earth Engine. We introduce three progressive fusion levels: a single-modality baseline (NAIP-WHP), fixed-weight fusion (FIXED), and a novel geographically adaptive dynamic-weight approach (FUSED) that adjusts feature contributions based on regional characteristics like human activity intensity or aridity. Machine learning benchmarking across 49 U.S. regions reveals that Support Vector Machines (SVM) applied to the FUSED dataset achieve optimal performance, with an AUC-ROC of 92.1%, accuracy of 83.3%, and inference speed of 1.238 milliseconds per sample. This significantly outperforms the fixed-weight fusion approach, which achieved an AUC-ROC of 78.2%, and the single-modality baseline, which achieved 73.8%, representing relative improvements of 17.8% and 24.8%, respectively. The 10 m resolution risk heatmaps demonstrate operational viability, achieving an 86.27% hit rate in Carlsbad Caverns, NM. SHAP-based interpretability analysis reveals terrain dominance and context-dependent vegetation effects, aligning with wildfire ecology principles. Full article

This research highlights the issue that large amount of sweat generated by metabolism cannot be discharged from the internal environment of traditional fire suits when firefighters are intensively operating in high-temperature environments. This is highly prone to bacterial growth, which brings much harm to their health. Therefore, this study aims to present a new fire-retardant fabric with both antibacterial and high hygroscopic properties. Blended fibers were used including aramid 1313 fibers with excellent flame retardancy and flame-retardant viscose fibers. By uniformly embedding antibacterial nanofibers into the microfiber aggregates and controlling the adhesion behavior at the cross-scale interfaces of micro–nano fibers, the fire-retardant yarns were endowed with both antibacterial and moisture-transporting properties. The bacterial inhibition rate was calculated by comparing colonies cultured on EF fabric versus NF fabric. Additionally, the antibacterial and moisture-wicking properties of the fabrics were verified through tests such as placing the fabrics vertically in liquid to measure the height of absorbed moisture. This prepared functionally integrated fabric has excellent antibacterial properties even after 50 washing cycles. Its antibacterial rate against Escherichia coli and Staphylococcus aureus kept a preferred result of 99%. Its moisture-transporting performance has also been significantly improved. Based on the above, this study has not only successfully developed a flame-retardant fabric with high antibacterial and moisture-wicking properties, but more importantly, the method demonstrates a degree of universal applicability. Full article

With the deepening of power market reform and the large-scale integration of bidirectional systems such as energy storage and electric vehicles, achieving sustainable carbon management has become increasingly urgent. Traditional carbon emission accounting methods face challenges, including insufficient dynamics and unclear responsibility boundaries. To address these issues, this paper proposes a sustainability-oriented accounting method for indirect carbon emissions from electricity in the context of bidirectional system integration in the power market environment. First, the dynamic carbon emission characteristics of bidirectional systems such as energy storage and vehicle-to-grid (V2G) systems are analyzed, and a carbon emission accounting model is constructed to address the fairness issue of emission responsibility allocation during charging and discharging. Second, on the basis of the theory of carbon emission flows and incorporating electricity trading contract data, an accounting method for indirect carbon emissions from electricity in green electricity trading, coal-fired electricity trading, and hybrid scenarios under bidirectional system integration is developed. Finally, the case study demonstrates that the proposed method accurately captures the temporal variation of carbon emission factors, ensures conservation of total emissions, and fairly redistributes carbon responsibility among users under different market scenarios, while revealing how bidirectional systems and green electricity trading reshape nodal carbon intensities and spatial emission distributions without causing double counting. Full article

Background and Clinical Significance: Hell’s Itch is a rare, intensely uncomfortable post-sunburn condition with burning pruritus emerging 24–72 h after UV exposure. This condition often goes unrecognized and is frequently misdiagnosed by healthcare providers due to a lack of knowledge and familiarity. Standard antipruritic measures are often ineffective, and patients frequently rely on anecdotal self-management. Case Presentation: Three healthy adult males between 23 and 28 years old experienced multiple episodes of delayed-onset intense pruritus following moderate-to-severe sun exposure. The patients experienced a burning or stinging pain which they described as “fire ants” or “thumbtacks,“ and their symptoms started between 24 and 72 h after sun exposure without any rash or fever symptoms. The patients did not achieve symptom relief from standard treatments which included oral antihistamines and topical lidocaine, NSAIDs, aloe vera, and cold compresses. The patients received β-alanine treatment through pre-workout supplements or pure powder after consulting non-clinical sources. Each patient ingested β-alanine and reported rapid relief (itch 8–10/10 → 1–2/10) lasting 2–3 h. The only adverse effect reported by one patient was mild paresthesia. Conclusions: This case introduces β-alanine as a potential off-label therapy for Hell’s Itch and emphasizes the psychological burden and clinical complexity of the condition. While anecdotal, further study is needed to elucidate the mechanism of action of β-alanine in relieving symptoms of Hell’s Itch, as well as assess safety and efficacy in controlled settings. Increased clinical awareness of Hell’s Itch may reduce patient distress and improve management strategies. Full article

The Neotropical Savanna (Cerrado) is a fire-prone biome characterized by seasonal climate, nutrient-poor soils, and variable fire regimes. While fire-induced germination responses are well documented in Cerrado plants, the role of seed size in mediating thermal tolerance remains poorly understood. Here, we investigate how seed size and fire-related heat treatments influence germination in Hymenaea stigonocarpa, a keystone Cerrado tree species. Specifically, we test the predictions that (i) low to moderate fire temperatures (<270 °C) do not impair seed germination and (ii) larger seeds exhibit greater heat tolerance than smaller seeds. We exposed 360 seeds from 30 individual trees to five heat-shock treatments (27, 100, 150, 200, and 270 °C) simulating fire intensities typically experienced in the Cerrado. Our results show that H. stigonocarpa produces relatively large seeds with an average germination rate of approximately 42%. The average time required for germination was 12.18 ± 0.43 (average ± standard error) days. The time required for seed germination varied significantly as a function of heat-shock treatment and seed mass, with seeds exposed to the highest temperature (270 °C) taking longer to germinate. Moreover, seed mass had a positive effect on the time required for seed germination. The germination percentage remains stable across heat treatments and seed sizes, indicating that H. stigonocarpa seeds exhibit characteristics typical of heat-tolerant species rather than those of heat-stimulated species. Our study showed that H. stigonocarpa trees produce large seeds that germinate quickly and are tolerant to moderate temperatures. These seed traits play a crucial role in the reproductive success of individual plants in fire-prone, nutrient-poor, and water-limited ecosystems. Furthermore, our results offer important guidance by emphasizing the role of seed size in effective restoration initiatives. Full article

Cuprate delafossite phases such as CuMnO₂ (crednerite) and CuFeO₂, as well as iron- and manganese-doped mcconnellite composites, were investigated as candidates for producing intense black ceramic pigments via conventional solid-state synthesis. Both electric kiln and fast dielectric (microwave) firing methods were employed, with mcconnellite (CuCrO₂) used as a reference pigment. Microwave firing led to a marked improvement in sample blackness compared to conventional electric firing. Among the delafossite phases, only mcconnellite subjected to microwave-assisted firing (R_Vis = 1.40%, corresponding to 98.60% visible light absorption) emerges, pending further optimization, as a promising candidate for an ultra-black ceramic pigment (R_Vis < 1%) under optimized glaze conditions (ZnO-free) and a firing temperature of 1000 °C. Considering the pigments in powder form, microwave-fired crednerite (R_Vis = 4.85%, 95.15% absorption) and iron- and iron–manganese-doped mcconnellite composites (R_Vis = 3.27% and 3.23%, respectively) appear as potential candidates for deep-black pigments (R_Vis < 3%), benefiting from the composite effect between the delafossite phase and the associated chromium spinel. Moreover, microwave-fired crednerite also demonstrates noteworthy potential for deep-black coloration in glazed samples (R_Vis = 4.27%, 95.73% absorption). Full article