Search Results (1,934)

We explored the effects of different solution treatment temperatures on the microstructure, mechanical properties and wear resistance of alloyed high-manganese steel, as well as the correlations among the three parameters. The results indicated that the average grain size of high-manganese steel first decreases and then gradually increases with an increasing solution temperature. After solution treatment, the surface hardness of the high-manganese steel is lower than that of untreated steel. At a solution treatment temperature of 1050 °C, the surface hardness value is lowest, at 253.1 HV. In addition, the optimal combination of tensile strength, yield strength and work hardening rate is observed at a solution treatment temperature of 950 °C. The friction performance test results revealed that the average friction coefficient on the surface of the high-manganese steel first decreased and then increased with the increase in solution treatment temperature. After solution treatment at 950 °C, it reached a minimum value 0.273 due to oxidation friction. Meanwhile, the hardness of the steel after friction increased rapidly because of its excellent work hardening ability, so the wear rate was relatively low, approximately 0.223 × 10⁻¹³ m²/N, demonstrating optimal wear resistance. After solution treatment, the average grain size of high-manganese steel changed, and there was a transformation of the wear mechanism; the friction and wear mechanism shifted from a combination of particle wear and fatigue wear to adhesive wear, with particle wear as the auxiliary. Full article

Polytetrafluoroethylene (PTFE) is one of the alternative materials suitable for seawater-lubricated bearings, favored for its excellent corrosion resistance and good self-lubricating properties. As marine equipment develops towards higher load, higher reliability, and longer service life, more stringent requirements are imposed on the wear resistance of bearing materials. However, traditional PTFE materials struggle to meet the performance requirements for long-term stable operation in modern marine environments. To improve the wear resistance of PTFE, this study used alumina (Al₂O₃) particles with three different particle sizes (50 nm, 3 μm, and 80 μm) as fillers and prepared Al₂O₃/PTFE composites via the cold pressing and sintering process. Tribological performance tests were conducted using a ball-on-disk reciprocating friction and wear tester, with Cr12 steel balls as counterparts, under an artificial seawater lubrication environment, applying a normal load of 10 N for 40 min. The microstructure and wear scar morphology were characterized by scanning electron microscopy (SEM), and mechanical properties were measured using a Shore hardness tester. A systematic study was carried out on the microstructure, mechanical properties, friction coefficient, wear rate, and limiting PV value of the composites. The results show that the particle size of Al₂O₃ particles significantly affects the mechanical properties, friction coefficient, wear rate, and limiting PV value of the composites. The 50 nm Al₂O₃/PTFE formed a uniformly spread friction film and transfer film during the friction process, which has better friction and wear reduction performance and load bearing capacity. The 80 μm Al₂O₃ group exhibited poor friction properties despite higher hardness. The nanoscale Al₂O₃ filler was superior in improving the wear resistance, stabilizing the coefficient of friction, and prolonging the service life of the material, and demonstrated good seawater lubrication bearing suitability. This study provides theoretical support and an experimental basis for the design optimization and engineering application of PTFE-based composites in harsh marine environments. Full article

Protective coatings are essential for extending the service life of components exposed to harsh conditions, such as pipes used in industrial systems, where wear and corrosion remain constant challenges. This study explores the development of a nano-sized TiO₂-reinforced electroless nickel-based ternary (Ni-W-P) alloy and composite coating on API X60 steel, a high-strength carbon steel pipe grade widely used in oil and gas pipelines, using an alkaline hypophosphite-reduced bath. The surface morphology, microstructure, elemental composition, structure, phase evolution, adhesion, and roughness of the coatings were analyzed using optical microscopy, FESEM, EDS, XRD, AFM, cross-cut tape test, and 3D profilometry. The tribological performance was evaluated via Vickers microhardness measurements and reciprocating wear tests conducted under dry conditions at a 5 N load. The TiO₂ nanoparticle-reinforced composite coating achieved a consistent thickness of approximately 24 µm and exhibited enhanced microhardness and reduced coefficient of friction (COF), although the addition of nanoparticles increased surface roughness (S_a). Annealing the electroless composites at 400 °C led to a significant improvement in their tribological properties, primarily owing to the grain growth, phase transformation, and Ni₃P crystallization. XRD analysis revealed phase evolution from an amorphous state to crystalline Ni₃P upon annealing. Both the alloy and composite coatings exhibited excellent adhesion performances. The combined effect of TiO₂ nanoparticles, tungsten, and Ni₃P crystallization greatly improved the wear resistance, with abrasive and adhesive wear identified as the dominant mechanisms, making these coatings well suited for high-wear applications. Full article

In response to the demand for advanced materials in extreme environments, researchers have developed a variety of bulk and thin-film materials. One of the best-known processes for altering the mechanical and tribological properties of materials is surface engineering techniques. These involve various approaches to synthesize thin-film coatings, along with post-deposition treatments. The need for self-lubricating materials in extreme situations such as high-temperature applications, cryogenic temperatures, and vacuum systems has attracted the attention of researchers. They have fabricated several types of thin films using CVD and PVD techniques to meet this demand. Among the various techniques used for fabricating self-lubricating coatings, sputtering stands out as a special one. It contributes to developing smooth, homogeneous, and crack-free dense microstructures, which further enhance the coatings’ properties. This review explains the need for self-lubricating materials and the different techniques used to synthesize them. It discusses and summarizes the concept of synthesizing various types of self-lubricating films. It shows the different types of self-lubricating material systems, like transition metal-based nitrides and carbides, diamond-like carbon-based materials, and so on. This work also reflects the governing factors like the deposition temperature, doping elements, thickness of the film, deposition pressure, gas flow rate, etc., that influence the deposition results and, consequently, the properties of the film, as well as their advanced applications in different areas. This work reflects the self-lubricating properties of different kinds of films exposed to various environments in terms of their coefficient of friction and wear rate, emphasizing how the friction coefficient affects the wear rate. Full article

M50 steel is widely used in the manufacturing of high-end bearing components for aero-engine shafts, where an excellent surface performance is required to withstand harsh service conditions. In this study, plasma carburizing at different temperatures varying from 410 to 570 °C was performed on pre-nitrided M50 steel to investigate the influence of the temperature on the structural evolution and mechanical behavior of the self-lubricating functional layer. The microstructure, phase composition, hardness, and wear resistance of the carburized samples were fully characterized using scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Raman spectroscopy, a nano-indenter, and other analytical techniques. The carbon-rich film with nano-domains contains a significant amount of sp³ bonds at low carburizing temperatures, exhibiting a Diamond-like carbon (DLC) film character. With the rise in the carburizing temperature, the initially distinct interface between the carbon-rich film and the compound layer gradually disappears as the nitrides are progressively replaced by carbides; the sp³ bond of the film is decreased, which reduces the hardness and wear resistance. Samples carburized at 490 °C with a homogeneous surface layer consisting of DLC film and a compound layer showed a low friction coefficient (about 0.22) and a 60% reduction in the wear rate compared with the nitrided specimen. The formation of a surface carbon-enriched layer also plays a role in avoiding oxidative wear. Full article

In this study, a diamond/diamond-like carbon (DLC) composite coating was designed and fabricated utilizing a combination of chemical vapor deposition (CVD) and magnetron-sputtering-assisted ion beam deposition. This was designed to cope with severe problems such as high wear due to insufficient lubrication under dry sliding conditions with a single diamond. The tribological properties of the fabricated coatings under dry conditions were comparatively evaluated. The results demonstrate that the diamond/DLC composite coatings significantly enhance the tribological performance relative to their single-layer diamond counterparts. Specifically, a 33.73% reduction in the average friction coefficient and a 39.55% decrease in the average wear rate were observed with the MCD (microcrystalline diamond/DLC coating. Similarly, a 16.85% reduction in the average friction coefficient and a 9.69% decrease in the average wear rate were observed with the UNCD (ultrananocrystalline diamond)/DLC coating. Analysis of the worn track morphology and structure elucidated the underlying friction mechanism. It is proposed that the DLC top layer reduces the surface roughness of the underlying diamond coating and mitigates abrasive wear in the dry environment. Furthermore, the presence of the DLC film promotes graphitization via phase transition during sliding, which enhances lubricity and facilitates the establishment of a smooth friction interface. Full article

The variety of fiber types embedded in fiber-reinforced polymer (FRP) composites determines different tribology performance properties. In this work, the tribological properties under dry sliding conditions of glass fiber-reinforced polymer (GFRP) and basalt fiber-reinforced polymer (BFRP) were investigated and compared. Laminated composite specimens with different fiber content were manufactured by vacuum bagging and autoclave curing. Tensile and flexural mechanical properties, as well as pin-on-disk tribological properties of the composite specimens, were analyzed. A design of experiments was performed considering the influence of fiber weight fraction, fiber type, and sliding speed on the coefficient of friction (COF), specific wear rate (K), and contact temperature. A multifactorial ANOVA was performed to identify the significance and contribution percentage of each factor. Deep investigations to understand the wear mechanisms were performed using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). The results of the statistical analysis showed that the interaction between fiber type and sliding speed had the most significant influence on the COF (31.36%), while the fiber weight fraction had the predominant effect on the specific wear rate (22.04%), and the sliding speed was the most influential factor affecting temperature (82.88%). BFRP composites consistently performed better than GFRP in all tribological metrics, such as coefficient of friction, specific wear rate, and contact temperature. Full article

Cu–graphite composites are widely used in pantograph sliders and crane brushes. Conventional sintering protocols, however, mandate processing temperatures above 860 °C with prolonged holding periods, which inevitably introduce defects within copper matrices. Drawing inspiration from ultrasonic machining, this study presents an innovative ultrasonic-assisted hot-press sintering (UAHP) technique. Using this novel method, Cu–graphite composites with graphite contents ranging from 0 to 30 vol.% were fabricated at a reduced temperature of 700 °C and a short holding time of 10 min, achieving a ca. 160 °C reduction in densification temperature. Aside from the high densification efficiency, enhanced mechanical properties were also obtained for UAHP-sintered Cu–graphite composites. The Cu–15 vol.% graphite composite exhibited a yield strength of 232 MPa, showing only a 7.2% decrease compared to pure Cu. The friction coefficient decreased with increasing graphite content, reaching a plateau value of 0.140 at 15 vol.% graphite, representing a 77.16% reduction compared to pure Cu. The wear rate initially decreased but gradually increased with the increase in graphite content. The superior tribological performance is attributed to the insitu-formed graphite lubricating film, while the primary wear mechanisms are deemed to be oxidative and abrasive wear. The ultrasonic vibration provides additional sintering driving force and enhances elemental diffusion, establishing UAHP as an innovative technical route for fabricating composites with an optimized microstructure and superior comprehensive properties. Full article

Ti-Mo-N coatings were deposited on GCr15 bearing steel using arc ion plating. The effect of deposition bias on the coating microstructure, mechanical properties, tribological behavior, and electrochemical corrosion resistance was systematically investigated. The coating prepared at −120 V bias showed optimal overall performance. It achieved the lowest friction coefficient (0.308) and lowest wear rate (1.99 × 10⁻⁶ mm³/N·m). The significant improvement in tribological performance is attributed to the lubricating phase formed during the friction process. XPS analysis confirmed the layered MoO₃ formation within the wear scar. Deposition bias also significantly influenced the coating texture. At −120 V, the coating exhibited the strongest (111) crystal plane preferred orientation. This texture strongly correlated with performance enhancement. Regarding electrochemical corrosion, the −120 V coating displayed the lowest corrosion current density (3.62 × 10⁻⁹ A/cm²) and best corrosion resistance. Its corrosion morphology showed no obvious pitting, grooves, or other damage features. The results demonstrate the critical role of deposition bias in tailoring Ti-Mo-N coating properties. This research provides essential experimental support and a theoretical basis for designing wear- and corrosion-resistant protective coatings on bearing steel. Full article

The objective of this paper was to determine the interactive effects of multiple synthesis parameters on annealed PVA hydrogel properties and assess these hydrogels for the application of cartilage replacement. PVA hydrogels were synthesized at two different molecular weight ranges (89–98 kDa and 146–186 kDa), two polymer concentrations (10% PVA and 20% PVA), and four different annealing temperatures (120 °C, 135 °C, 150 °C, and 165 °C). The compressive, tensile, and wear mechanical properties were measured, and the crystalline structure of these hydrogels was assessed via differential scanning calorimetry. Hydrogels showed increasing polymer weight percent, tensile modulus, and compressive modulus with increasing annealing temperature. Depending on synthesis parameters, the hydrogels matched or exceeded the previously published compressive and tensile properties of native cartilage. Higher molecular weight PVA hydrogels (146–186 kDa) exhibited less wear, but greater friction, compared to lower molecular weight PVA (89–98 kDa). The PVA hydrogels exhibited crystallinity in the range of 53–78%, but no consistent differences in crystallinity were detected between hydrogel variants. It was concluded that the (10% PVA, 146 kDa, 165 °C) annealed PVA hydrogel demonstrated the most appropriate balance of high tensile strength and compressive compliance comparable to cartilage. Full article

To enhance the wear resistance of laser-clad coatings, this study investigates the underlying modulation mechanisms of scanning speed on the microstructure and properties of TiC-TiB₂-reinforced 316L stainless steel composite coatings. TiC/TiB₂ particle-reinforced 316L stainless steel composite coatings were fabricated on 45# steel substrates via laser cladding. Our analysis reveals that scanning speed critically governs the thermal cycle of the melt pool, thereby modulating the coating’s microstructure and properties: Lower scanning speeds prolong melt pool duration, consequently intensifying ceramic particle dissolution, coarsening, and tendencies toward agglomeration and settling. Conversely, higher scanning speeds promote rapid solidification, which both preserves ceramic particles and refines the matrix grains. With increasing scanning speed, accelerated melt pool cooling rates drive a microstructural transition from coarse dendrites to refined equiaxed grains, accompanied by dramatically enhanced uniformity in ceramic particle distribution. Coatings deposited at higher scanning speeds exhibit a 22% increase in hardness compared to those at lower speeds. Wear resistance evolution parallels this hardness trend: at 480 mm/min scanning speed, wear reduction can be expected, with the wear volume decreasing by 58.60% and the friction coefficient reducing by 42.1% relative to 120 mm/min. Full article

Nanoparticle-based lubricants, or nanolubricants, can exhibit superior tribological properties compared to unmodified base oils. However, these performance gains are highly dependent on the nanoparticle surface chemistry, particularly in maintaining stable colloidal dispersions. This study explores the influence of oleic acid (OA) and oleylamine (OAm) functionalization on the tribological and colloidal properties of CuO nanoparticles dispersed in an SAE 20W50 base oil. We present a hybrid optimization framework combining Response Surface Methodology (RSM) with Bayesian Optimization (BO) to identify the optimal OA to OAm ratio (OA–OAm) for CuO nanolubricants. Unlike prior studies that employed either RSM alone or trial-and-error approaches, this integrated method enables precise tuning of ligand ratios, achieving balanced tribological performance and colloidal stability. Characterization techniques, including UV–vis spectroscopy, FTIR, Raman spectroscopy, and TGA, were employed to investigate dispersion stability. Results demonstrate that OA/OAm-functionalized CuO nanoparticles exhibit improved dispersion stability and reduced sedimentation compared to non-functionalized counterparts. Tribological evaluations using the four-ball test revealed that the ligand-tuned CuO nanolubricants maintained their tribological enhancements under a variety of additive loadings and ligand combinations, with an improvement ranging from 44.9% to 60.6% in the coefficient of friction (COF) and from 29.2% to 63.9% in the specific wear rate (SWR). For the colloidal stability, OA/OAm-functionalized CuO nanoparticles exhibited a 75% reduction in sedimentation rate (k = 0.003 day⁻¹) compared to unfunctionalized CuO (k = 0.012 day⁻¹). Finally, the high thermal stability of the functionalized nanoparticles ensures their suitability for high-performance applications. Overall, this work represents a crucial step towards commercial applications of CuO-enhanced lubricants. Full article

Shape memory alloys (SMAs) are known for their exceptional mechanical properties, particularly their superior wear resistance compared to conventional alloys with similar surface hardness. Rare earth oxides are often used as additives to further improve these characteristics. This study investigates the effects of different CeO₂ (cerium dioxide) concentrations (0.01 wt.%, 0.1 wt.%, 0.5 wt.%, and 1.0 wt.%) on the properties of CuAlMnFe alloys produced via powder metallurgy (PM). Various analyses were performed, including scanning electron microscopy (SEM), Energy Dispersive Spectroscopy (EDS), X-ray diffraction (XRD), as well as hardness, wear, and corrosion tests. The increase in wear rate is closely related to the formation of precipitates from CeO₂ addition. Improvements in wear resistance and hardness are attributed to the effects of grain refinement and solid solution strengthening due to CeO₂. Specifically, the wear rate increased from 1.5 × 10⁻³ mm³/(Nm) to 3.4 × 10⁻³ mm³/(Nm) with higher CeO₂ content. Additionally, the friction coefficient of the CuAlMnFe alloy was reduced with CeO₂ addition, indicating enhanced frictional properties. The optimal CeO₂ concentration of 0.5% was found to improve grain uniformity, resulting in better wear resistance. Incorporating CeO₂ particles into CuAlMnFe alloy enhances hardness and reduces wear rate when used in appropriate amounts. Additionally, it exhibits superior corrosion resistance, as evidenced by a positive shift in corrosion potential in Tafel measurements in solutions and a decrease in corrosion current density. The C0.5 specimen showed the highest corrosion potential (E_corr, −588 V) and the lowest corrosion current density (i_corr, 6.17 μA/cm²) during electrochemical corrosion in 3.5 wt.% NaCl solution. Full article

This paper investigates the effect of Ti₃AlC₂-MAX phase addition as a solid lubricant to Al₂O₃. The composites were prepared using powder metallurgy and consolidated by Spark Plasma Sintering (SPS). The influence of Ti₃AlC₂ addition on phase composition and mechanical and tribological properties was evaluated. The use of MAX phase allows for the fabrication of sintered materials characterized by high density, a hardness close to 2000 HV5, and a fracture toughness of 5.5 MPa*m^0.5 for the sample containing 10 wt.% Ti₃AlC₂. Moreover, a significant reduction in wear of the composites was observed for friction tests conducted at 700 °C compared to the unreinforced sample. The research demonstrates that Ti₃AlC₂ can serve as a solid lubricant and exhibits the best performance at high temperatures. Full article

Composite materials have been increasingly used in various branches of industry, transport, construction, and medicine—as well as in other sectors of the economy and science—in recent decades. A significant advancement in the improvement of composite material characteristics has been achieved through the use of nanoparticles, which substantially enhance the properties of the base material, whether it is the matrix or the reinforcing phase in hybrid composites. The broad application of polymers and polymer composites in many areas of engineering has had a significant impact on reducing friction and wear, improving the thermal characteristics of individual components and entire technical systems, enhancing electrical conductivity, reducing the specific weight of components, lowering noise and vibration levels, and ultimately decreasing fuel consumption, production costs, and the costs of operation and maintenance of technical systems. This paper explores the potential applications of polymer composites in various assemblies and components of conventional vehicles, as well as in hybrid and electric vehicles. Furthermore, their use in medicine and the defense industry is examined—fields in which some authors believe composites were first pioneered. Finally, aviation represents an indispensable domain for the application of such materials, presenting unique exploitation boundary conditions, including dynamic environmental changes such as variations in temperature, pressure, velocity, and direction, as well as the need for high levels of protection. Future research can be unequivocally focused on the structural and technological advancement of polymer composites, specifically through optimization aimed at reducing waste and lowering production costs. Full article