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Keywords = giant-scale graphene

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11 pages, 21792 KB  
Article
Origin of Giant Rashba Effect in Graphene on Pt/SiC
by Anna A. Rybkina, Alevtina A. Gogina, Artem V. Tarasov, Ye Xin, Vladimir Yu. Voroshnin, Dmitrii A. Pudikov, Ilya I. Klimovskikh, Anatoly E. Petukhov, Kirill A. Bokai, Chengxun Yuan, Zhongxiang Zhou, Alexander M. Shikin and Artem G. Rybkin
Symmetry 2023, 15(11), 2052; https://doi.org/10.3390/sym15112052 - 12 Nov 2023
Cited by 3 | Viewed by 2346
Abstract
Intercalation of noble metals can produce giant Rashba-type spin–orbit splittings in graphene. The spin–orbit splitting of more than 100 meV has yet to be achieved in graphene on metal or semiconductor substrates. Here, we report the p-type graphene obtained by Pt intercalation of [...] Read more.
Intercalation of noble metals can produce giant Rashba-type spin–orbit splittings in graphene. The spin–orbit splitting of more than 100 meV has yet to be achieved in graphene on metal or semiconductor substrates. Here, we report the p-type graphene obtained by Pt intercalation of zero-layer graphene on SiC substrate. The spin splitting of ∼200 meV was observed at a wide range of binding energies. Comparing the results of theoretical studies of different models with the experimental ones measured by spin-ARPES, XPS and STM methods, we concluded that inducing giant spin–orbit splitting requires not only a relatively close distance between graphene and Pt layer but also the presence of graphene corrugation caused by a non-flat Pt layer. This makes it possible to find a compromise between strong hybridization and increased spin–orbit interaction. In our case, the Pt submonolayer possesses nanometer-scale lateral ordering under graphene. Full article
(This article belongs to the Section Physics)
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11 pages, 3086 KB  
Article
Temperature Dependence of Thermal Conductivity of Giant-Scale Supported Monolayer Graphene
by Jing Liu, Pei Li, Shen Xu, Yangsu Xie, Qin Wang and Lei Ma
Nanomaterials 2022, 12(16), 2799; https://doi.org/10.3390/nano12162799 - 15 Aug 2022
Cited by 1 | Viewed by 2278
Abstract
Past work has focused on the thermal properties of microscale/nanoscale suspended/supported graphene. However, for the thermal design of graphene-based devices, the thermal properties of giant-scale (~mm) graphene, which reflects the effect of grains, must also be investigated and are critical. In this work, [...] Read more.
Past work has focused on the thermal properties of microscale/nanoscale suspended/supported graphene. However, for the thermal design of graphene-based devices, the thermal properties of giant-scale (~mm) graphene, which reflects the effect of grains, must also be investigated and are critical. In this work, the thermal conductivity variation with temperature of giant-scale chemical vapor decomposition (CVD) graphene supported by poly(methyl methacrylate) (PMMA) is characterized using the differential transient electrothermal technique (diff-TET). Compared to the commonly used optothermal Raman technique, diff-TET employs joule heating as the heating source, a situation under which the temperature difference between optical phonons and acoustic phonons is eased. The thermal conductivity of single-layer graphene (SLG) supported by PMMA was measured as 743 ± 167 W/(m·K) and 287 ± 63 W/(m·K) at 296 K and 125 K, respectively. As temperature decreased from 296 K to 275 K, the thermal conductivity of graphene was decreased by 36.5%, which can be partly explained by compressive strain buildup in graphene due to the thermal expansion mismatch. Full article
(This article belongs to the Special Issue Energy Transport at the Micro/Nanoscale)
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