Search Results (1,905)

Background: The addition of chlorhexidine in dental restorative materials is a promising strategy to reduce the recurrence of tooth decay lesions. However, the main challenge is to develop materials with antimicrobial activity in the long term. Objective: This study analyses the effect of filler type and concentration of resin composites supplemented with chlorhexidine loaded in carrier montmorillonite particles (MMT/CHX) regarding their chemical, physical, and short- and long-term antimicrobial proprieties. Materials: Experimental composites were synthesized with 0, 30, or 60% filler in two ratios, 70/30 and 80/20, of barium glass/colloidal silica, respectively, and 5 wt% MMT/CHX. Conversion was measured using near Fourier-transform infrared spectrometry. Sorption and solubility were determined by specimen weight before and after drying and immersing in water. Flexural strength (FS) and elastic modulus (E) were determined by three bending tests using a universal test machine. Chlorhexidine release was monitored for 50 days. Streptococcus mutans UA159 was used in all microbiological assays. Inhibition halo assay was performed for 12 months and, also, biofilm growth for the specimens and colony-forming unit (CFU). Remineralization assay was used on restored teeth using measurements of microhardness Knoop and CFUs. Results: Conversion, sorption, and solubility were not affected by filler type and concentration. FS and E increase with the filler concentration, independent from filler type. Chlorhexidine was significantly released for 15 days for all experimental materials, and the increase in filler concentration decreased its release. Halo inhibition was observed for a longer time (12 months) in materials with 60 wt% filler at 70/30 proportion. Also, 60 wt% filler materials, independent from the filler ratio, reduced the CFU in relation to the control group from 8 to 12 months. In the remineralization assay, besides the absence of differences in hardness among the groups, after biofilm growth, the CFU was also significantly lower in materials with 60 wt% filler. Conclusions: Materials with 60% filler, preferentially with 70% barium glass and 30% silica, and 5% MMT/CHX particles demonstrated long-term antimicrobial activity, reaching 12 months of effectiveness. Also, this formulation was associated with higher mechanical properties and similar conversion, sorption, and solubility compared to the other materials. Full article

Objective: This study aimed to evaluate the color stability and microhardness of two resin composites, a BPA-based composite (Luna) and a BPA-free composite (Luna 2), after immersion in chlorhexidine (CHX), using two different polishing protocols. Methods: Disks (7 mm diameter × 2 mm thickness) were prepared and divided into three groups per material: unpolished, Sof-Lex, and FlexiDisc polished (n = 20 per group). The specimens were immersed daily in either 0.12% CHX or distilled water for 21 days. Color change (ΔE) was measured at 7, 14, and 21 days using a spectrophotometer. Microhardness was evaluated at each time point using a Vickers hardness tester (200 g load, 10 s dwell time). Results: Luna 2 exhibited significant discoloration from day 14, while Luna showed significant color change on day 21 (p < 0.05). After 21 days of CHX immersion, unpolished Luna reached a ΔE value of 6.27 ± 1.69, exceeding the clinically acceptable threshold. At 14 days, Sof-Lex polishing significantly improved color stability compared to unpolished controls for both materials (p < 0.05). No significant differences were observed between the two polishing systems over time (p > 0.05). Luna 2 demonstrated significantly higher microhardness at all evaluated time points (p < 0.001). Both composites exhibited slight reductions in microhardness over time, which were more pronounced in Luna (p < 0.001). Conclusions: Polishing enhanced the color stability of both composites. Luna 2 exhibited superior microhardness compared to Luna, and polishing had no significant effect on this property. Given the increasing clinical shift toward BPA-free materials due to biocompatibility concerns, these findings offer relevant guidance for optimizing the long-term esthetic and mechanical performance of modern resin-based restorations. Full article

The recycling of polypropylene (PP) packaging films modified with biobased additives: biochar derived from the pyrolysis of natural fibers and diatomaceous earth was investigated. The aim was to assess the impact of these modifiers on the processing, rheological, mechanical, and thermal properties of the recycled material. The processing behavior was evaluated through extrusion with granulation to determine industrial applicability. Rheological properties, including viscosity and melt flow index (MFI), were measured to characterize flow behavior. Mechanical performance was assessed through tensile strength, hardness, three-point bending, and impact resistance tests. Thermal properties were analyzed using thermogravimetric analysis (TGA), Vicat softening temperature (VST), and differential scanning calorimetry (DSC). The results demonstrate that incorporating biochar and diatomaceous earth can modify and, in selected cases, enhance the processing and performance characteristics of recycled PP films, though their impact on thermal behavior is parameter-specific. While diatomaceous earth slightly increased the onset of thermal degradation (T₅), both fillers caused a slight decrease in the VST, indicating reduced heat resistance under load. Diatomaceous earth was found to effectively improve stiffness and impact strength, while biochar reduced viscosity and promoted finer crystalline structures. Both additives acted as nucleating agents, increasing crystallization temperatures, with diatomaceous earth additionally delaying thermal degradation onset. These findings highlight the potential of using sustainable, waste-derived additives in polymer recycling, supporting the development of environmentally responsible materials within circular economy frameworks. Full article

Orthoses are a vital part of treating gait disorders, especially in children and adolescents with neurological and neuromuscular conditions. For proper walking, the supporting leg must be stable to allow the other leg to swing forward and take a step. Stability is also essential for motor development. This stability depends on the inclination of the tibia, which needs to be kept upright during mid-stance in both the sagittal and coronal planes. Controlling the load axis in all planes and the foot in the transverse plane helps maintain proper tibial control. More studies are now examining the effects different orthoses and designs. While much focus has been on the sagittal plane, there is much less information about how orthoses influence the coronal plane or foot control. As a result, there is limited guidance from the existing literature. Children who find it hard to express discomfort or negative effects may simply reject orthoses altogether. This paper explains how important proper tibia inclination and control on the load axis are in all planes and how they affect stability. The foot acts as a lever for the gastrosoleus muscle, which controls the tibia. In case of foot instability or deformity, the foot requires support that takes into account the changing load when walking. I also emphasize that these points are regularly considered when studies are reported. Full article

This study proposes a novel non-destructive approach to assessing and predicting the quality of stored date fruits using a composite quality index (Qi) modeled via visible–near-infrared (VIS–NIR) spectroscopy and artificial neural networks (ANNs). Two leading cultivars, Sukkary and Khlass, were stored for 12 months using three temperature regimes (25 °C, 5 °C, and −18 °C) and five types of packaging. The samples were grouped into six moisture content categories (4.36–36.70% d.b.), and key physicochemical traits, namely moisture, pH, hardness, total soluble solids (TSSs), density, color, and microbial load, were used to construct a normalized, dimensionless Qi. Spectral data (410–990 nm) were preprocessed using second-derivative transformation and modeled using partial least squares regression (PLSR) and the ANNs. The ANNs outperformed PLSR, achieving the correlation coefficient (R²) values of up to 0.944 (Sukkary) and 0.927 (Khlass), with corresponding root mean square error of prediction (RMSEP) values of 0.042 and 0.049, and the relative error of prediction (REP < 5%). The best quality retention was observed in the dates stored at −18 °C in pressed semi-rigid plastic containers (PSSPCs), with minimal microbial growth and superior sensory scores. The second-order Qi model showed a significantly better fit (p < 0.05, AIC-reduced) over that of linear alternatives, capturing the nonlinear degradation patterns during storage. The proposed system enables real-time, non-invasive quality monitoring and could support automated decision-making in postharvest management, packaging selection, and shelf-life prediction. Full article

In this work, ethyl cellulose nanoparticles loaded with rosemary extract (RCL-NPs) were synthesized and utilized to reinforce high-density polyethylene (HDPE) packaging bags as a nanotechnological alternative for rabbit meat preservation. The synthesized RCL-NPs were characterized by DLS and for their stability. The analyzed variables of rabbit meat packaged samples included drained liquid, weight loss, color, pH, texture, and hardness. The total phenolic content (TPC) and antioxidant capacity of rosemary extract were also investigated. The results demonstrated that RCL-NPs were 117.30 nm in size with a negative surface charge (−24.59 mV) and low PDI (0.12). According to the Higuchi model, the release rate of RCL-NPs was sustained from 0 to 24 h. The encapsulation efficiency of the implemented synthesis route was 99.97%. The TPC of rosemary extract was 566.13 ± 1.72 mg GAE/L, whereas their antioxidant activity utilizing the DPPH and FRAP assays was 27.86 ± 0.32 mM Trolox/L and 0.31 mM Trolox/L, respectively. Contrary to control samples, rabbit meat samples conserved in HDPE packaging bags reinforced with RCL-NPs prevent drained liquid and weight loss, while preserving *L (60 ± 2.5–66.10 ± 2.0) and *b (10.67 ± 2.28–11.62 ± 2.39), pH (5.22 ± 0.05–5.80 ± 0.03), and texture (10.37 ± 0.82–0.70 ± 0.50). In the same regard, the developed material conserved the hardness of rabbit meat samples, exhibiting values that ranged from 27.79 ± 7.23 to 27.60 ± 3.05 N during the evaluated period (0–13 days). The retrieved data demonstrate the efficacy of RCL in preserving the quality of rabbit meat when integrated with additional food packaging materials. Full article

This paper presents the results of wear tests of two types of commercial low-carbon, low-alloy martensitic abrasion-resistant steels, Hardox 450 and XAR 450, which belong to the hardness class 450 HBW. These steels, due to their increased resistance to the abrasive wear mechanism, are used for machine parts for applications in intensive abrasion environments such as construction, mining, and agriculture. The scope of work included microstructure analysis on an optical microscope, chemical composition analysis, Vickers hardness measurements at different loads (HV0.2, HV1 and HV2), and wear testing. Wear tests were carried out by the standard method “dry sand—rubber wheel”, and tests on the Taber abrader device. Microstructure analysis revealed that both steels have a similar non-oriented, homogenous, fine-grained martensitic microstructure. The results of HV2 hardness measurements showed a similar trend for both steels in all examined sections of the plates. For both tested steels, the hardness values of HV0.2 and HV1 are slightly higher than HV2, but the scattering of the results is also greater. Abrasion resistance testing using the standard “dry sand—rubber wheel” method showed that Hardox 450 steel has a lower volume loss of about 8%, but a greater scattering of the results compared to XAR 450 steel. The results of the abrasion resistance test on the Taber abrader device confirmed approximately the same behavior. For both steels, a prediction model was established for a reliable assessment of the wear intensity concerning the grain size. Although examined steels belong to the same hardness class, Hardox steel seems to be a more appropriate choice for the manufacture of machine components exposed to abrasive wear. Full article

This study presents a comprehensive evaluation of the tribological behavior of cylinder liners and piston rings—key components in internal combustion engines (ICEs). Experiments were conducted using a pin-on-disc wear tester under varying loads (50–100 N) and speeds (175–350 rpm) to determine the coefficient of friction (μ) and wear rate. The selected pin and disc materials represent real engine components to ensure realistic operating conditions. Before and after each experiment, the cylinder liner-piston ring pair was cleaned with acetone to ensure accurate measurement of mass loss. Surface roughness (Ra, Rq, Rz, µm) was assessed using a Mahr M-1 profilometer, and Brinell hardness tests were carried out using a digital optical Brinell hardness testing machine to determine the mechanical properties of the contact surfaces. The results revealed that safflower oil achieved the lowest coefficient of friction at higher speeds, with an 18% reduction compared with conventional 20W-50 engine oil. Camelina oil, camelina biodiesel and safflower biodiesel each exhibited a reduction of approximately 12.5% in friction, highlighting their potential as viable alternatives to petroleum-based lubricants. Full article

Auxetic structures, also known as metamaterials, exhibit a negative Poisson’s ratio under applied load and have found use across a variety of applications. This behavior may arise from material properties or from the structural design itself. Depending on the intended application, such structures can be subjected to either static or dynamic loading conditions. New geometries that potentially enhance energy absorption or damping in both static and dynamic conditions were investigated in this work, using the well-known Reentrant design reported in earlier research articles as a benchmark. As an alternative to the cellular limb angles employed in the well-known Reentrant model, the effect of radial limb radius was analyzed in the novel cell designs called Arched-Reentrant. Four alternative designs have been proposed, and all analyses were conducted in ANSYS-2025-R1. The specimens were manufactured by using the 3D printing method with thermoplastic polyurethane (TPU) material having a shore hardness of 95A. In the evaluation of the outcomes resulting from different designs, the specimens were analyzed under static, impulsive, and harmonic loading conditions. The energy absorption capacities of the samples were examined in relation to their design modifications. Within the scope of the study, it was observed that Arched-Reentrant structures are capable of absorbing higher amounts of energy under static loading and exhibit greater stiffness under dynamic loads compared to conventional Reentrant structures. The impulse analysis’s findings demonstrate that the suggested Arched-Reentrant-V3 model performs better, with over 50% less displacement and comparable reaction forces. In addition, the harmonic analysis findings show that the Arched-Reentrant-V3 model has lower ground reaction forces and displacement values. As a result, the suggested model can be regarded as an efficient damping component when dynamic loading occurs. Full article

In this study, a duplex treatment combining carburizing, nitriding, and subsequent induction hardening (IH) was applied to JIS-SCM420 low-alloy steel. A comprehensive evaluation was conducted to assess surface characteristics, including microstructure, hardness, residual stress, and fatigue performance. The IH process successfully produced a high-nitrogen-content ε-Fe_2-3(N,C) compound layer (2–3 μm thick) and fine acicular martensite at the surface, significantly enhancing surface hardness (950 HV0.03) and inducing beneficial compressive residual stress (−477 MPa). The IH-treated material exhibited a plane-bending fatigue strength of approximately 775 MPa, notably higher than that of conventionally carbonitrided specimens (700 MPa). This improvement was primarily attributed to the formation of the hard ε-Fe_2-3(N,C) compound layer and refined martensitic structure resulting from induction hardening. Additionally, IH activated residual interstitial elements, promoting the precipitation of stable surface nitrides. These microstructural changes effectively suppressed fatigue crack initiation and propagation, thereby extending fatigue life under cyclic loading conditions. Full article

Achieving keyhole-free joints is critical in Friction Stir Spot Welding (FSSW). This study presents a new approach to eliminate this volumetric defect in AA6082-T6 FSSW sheet joints using a continuous multi-layer Friction Stir Deposition (CMFSD) technique, employing a newly designed AA6082-T6 consumable tool. FSSW was performed at various rotational speeds (350, 550, 750 and 950 rpm) with a 5 s dwell time. Comprehensive macro- and micro-scale evaluations, along with mechanical properties (hardness and tensile-shear load) of the produced joints, were conducted. Additionally, microstructures were examined using Optical Microscopy (OM), while fracture surfaces were analyzed via Scanning Electron Microscopy (SEM). Optimal FSSW conditions were identified at 550 rpm, yielding a stir zone (SZ) hardness of 94.6 ± 1.4 HV and a maximum tensile-shear load of 4.73 ± 0.27 kN. The keyhole was successfully refilled using AA6082-T6 rod material via CMFSD, resulting in a defect-free joint of the same base alloy. Electron Backscattered Diffraction (EBSD) technique was also used to examine the microstructural features. A comparative analysis revealed significant enhancements: the refilled FSSW joints exhibited a 46.5% increase in maximum tensile-shear load and a 66.66% improvement in elongation to failure compared to the highest-FSSW joint performance with the keyhole defect. Full article

Polytetrafluoroethylene (PTFE) is one of the alternative materials suitable for seawater-lubricated bearings, favored for its excellent corrosion resistance and good self-lubricating properties. As marine equipment develops towards higher load, higher reliability, and longer service life, more stringent requirements are imposed on the wear resistance of bearing materials. However, traditional PTFE materials struggle to meet the performance requirements for long-term stable operation in modern marine environments. To improve the wear resistance of PTFE, this study used alumina (Al₂O₃) particles with three different particle sizes (50 nm, 3 μm, and 80 μm) as fillers and prepared Al₂O₃/PTFE composites via the cold pressing and sintering process. Tribological performance tests were conducted using a ball-on-disk reciprocating friction and wear tester, with Cr12 steel balls as counterparts, under an artificial seawater lubrication environment, applying a normal load of 10 N for 40 min. The microstructure and wear scar morphology were characterized by scanning electron microscopy (SEM), and mechanical properties were measured using a Shore hardness tester. A systematic study was carried out on the microstructure, mechanical properties, friction coefficient, wear rate, and limiting PV value of the composites. The results show that the particle size of Al₂O₃ particles significantly affects the mechanical properties, friction coefficient, wear rate, and limiting PV value of the composites. The 50 nm Al₂O₃/PTFE formed a uniformly spread friction film and transfer film during the friction process, which has better friction and wear reduction performance and load bearing capacity. The 80 μm Al₂O₃ group exhibited poor friction properties despite higher hardness. The nanoscale Al₂O₃ filler was superior in improving the wear resistance, stabilizing the coefficient of friction, and prolonging the service life of the material, and demonstrated good seawater lubrication bearing suitability. This study provides theoretical support and an experimental basis for the design optimization and engineering application of PTFE-based composites in harsh marine environments. Full article

Powder metallurgy tool steels, such as Vanadis 4 Extra (1.2210), are increasingly used in cold-work applications due to their superior hardness, wear resistance, and microstructural uniformity. Despite their growing popularity, there is limited data regarding their machinability, especially in milling processes. In this study, experimental milling tests were performed on Vanadis 4 Extra steel using AlCrN-coated carbide tools. A full factorial experimental design (3⁴) was applied to investigate the effects of cutting speed, depth of cut, width of cut, and feed per tooth on cutting forces (Fx, Fy, Fz, Fc), surface roughness parameters (Ra, Rz), and tool wear. Cutting forces were measured using a Kistler dynamometer, and surface roughness was evaluated using a contact profilometer. Regression models were developed and statistically validated. The results indicate that depth of cut had the most significant influence on cutting force, while cutting speed had the greatest impact on surface roughness. Moderate correlation between cutting forces and roughness was observed, particularly under low-load conditions. SEM analysis revealed abrasive wear and chipping of the coating layer. The findings provide insights into the machinability of Vanadis 4 Extra and offer guidelines for optimizing milling parameters to enhance tool life and surface integrity. Full article

This study investigates the impact of arc-hardening parameters on a groove-shaped S45C steel tube, with a focus on surface hardness and microstructure. According to the findings, when arc quenching occurs, the tube’s surface hardness increases significantly compared to its original hardness. The surface layer hardness can increase to 50.3 HRC, which is 3.4 times greater than the untreated surface. Changing arc quenching parameters such as current intensity, gas flow rate, arc length, scan speed, heating angle, and cooling angle causes a variation in surface hardness due to the balance of heat input and cooling value. Moreover, the microhardness distribution is divided into three zones: the hardened zone (with a high hardness value), the heat-affected zone (HAZ), which has rapidly declining hardness, and the base metal (with a low hardness value). The hardened zone could have a hardness with a load of 0.3 N of 440 HV and a case depth of about 900 μm. The next zone is the HAZ, where the hardness with a load of 0.3 N drops significantly. The hardness in the base metal zone recovers to its original value of 152 HV. Interestingly, the microstructure, under the hardness distribution, illustrates the relationship between the hardness value and its phases. The hardened zone consists of martensite and residual austenite phases, resulting in a high hardness value. The bainite phase constitutes the HAZ, which correlates to the zone of rapid hardness reduction. Finally, the base metal zone has ferrite and pearlite microstructures, indicating the softest zone. The investigation’s findings may increase our understanding of the arc-hardening process and widen its industrial applications. Full article

Background: Mandibular defects caused by trauma or tumor resection pose significant challenges in both functional and aesthetic reconstruction. Additive manufacturing (AM) technologies offer promising solutions for surgical planning and personalized treatment. Objectives: This review aims to evaluate current trends in the application of AM technologies for mandibular resection and reconstruction, with a particular focus on material selection, clinical integration, and technology-specific advantages. Methods: A structured literature review was performed using PubMed, Scopus, Web of Science, and Google Scholar. Studies published between January 2020 and May 2025 were screened using the following inclusion criteria: original peer-reviewed English-language research involving AM in mandibular surgery. The exclusion criteria included review articles, non-English sources, and non-mandibular studies. A total of 77 studies met the inclusion criteria and were analyzed in this review. Results: Based on the literature review conducted from 2020 to 2025, the most common restorative methods for the mandible using additively manufactured models include reconstruction with a titanium surgical plate bent to the curvature of the edges and angle of the mandible or a personalized titanium or PEEK surgical plate made directly based on the patient’s diagnosis. Implants made of Ti-6AL-4V ELI and bioceramic scaffolds are also used in the reconstruction process. They are developed based on patient diagnostic data and effectively replace the loss of mandibular bone structure. In addition, based on models and surgical guides created using additive manufacturing techniques, the performance of autogenous grafts from the fibula or iliac crest has improved significantly when used with a titanium implant plate. Conclusions: Additive manufacturing supports highly personalized and accurate mandibular reconstruction. The advantages of these methods include a reduced overall duration of procedures, a lower health risk for patients due to less reliance on general anesthesia, a near perfect match between the implant and the remaining hard tissues, and satisfactory aesthetic outcomes. However, success depends on the appropriate selection AM technology and material, particularly in load-bearing applications. Full article