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Keywords = hazard quotient (HQ)

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30 pages, 1548 KB  
Article
Hydrogeochemical Controls and Anthropogenic Impacts on Water Quality in an Arid Wadi-Dam System, Saudi Arabia
by Mohammed Benaafi, Ali Q. Alorabi, Ali Y. Alzahrani, Husam Musa Baalousha and Mahfuzur Rahman
Earth 2026, 7(4), 107; https://doi.org/10.3390/earth7040107 (registering DOI) - 25 Jun 2026
Abstract
The Wadi Al-Ahsaba watershed is an arid to semi-arid catchment situated in southwestern Saudi Arabia, characterized by intermittent surface flow, high evaporation and low rainfall, and a dam reservoir built for flood control. The work aims to assess hydrological and anthropogenic controls on [...] Read more.
The Wadi Al-Ahsaba watershed is an arid to semi-arid catchment situated in southwestern Saudi Arabia, characterized by intermittent surface flow, high evaporation and low rainfall, and a dam reservoir built for flood control. The work aims to assess hydrological and anthropogenic controls on surface and groundwater quality, pollution status, and human health risks using an integrated approach of hydrogeochemical analysis, multivariable statistics, and water quality and contamination indices. A total of 21 water samples (15 surface water, 6 groundwater) were analyzed for general chemistry, major ions, and trace elements. Hydrogeochemical analysis and principal component analysis (PCA) were implemented to differentiate the geogenic from anthropogenic control on water quality. The pollution status and associated risk were evaluated using water quality index (WQI), contamination degree (Cd), Hazard Quotient (HQ), and Hazard Index (HI). Results suggest limited surface–groundwater interaction, with surface water dominated by Ca–Mg–HCO3 facies, indicating recent recharge and limited water–rock interaction, whereas groundwater exhibits mixed Ca–Mg–Cl and Ca–Na–Cl–SO4 types, revealing longer residence time and water–rock interaction. Nitrate (9.5–109 mg/L) and TDS (522–1003 mg/L) exceeded drinking water standards in 90% and 95% of tested samples, respectively, and WQI ranged from 43 to 134, reflecting excellent to poor water. High non-carcinogenic risk from nitrate was observed, especially for infants. The study concluded that the geogenic processes (water–rock interaction, evaporation, and mineral dissolution) control the general chemistry of tested water, while anthropogenic input from wastewater and agriculture input are likely contributors to nitrate contamination. The study contributes to the understanding of arid wadi-dam systems by revealing how limited recharge, hydrological connectivity, and episodic flow control contaminant transport and persistence, underscoring the critical role of integrated hydrological analysis and land use management in safeguarding freshwater resources in arid environments. Full article
22 pages, 3609 KB  
Article
Drinking Water Quality and Health Risk Assessment in Rural Ghana: Evidence from North-East and North Gonja Districts in the Savannah Region
by Elvis Kichana, Solomon A. Minyila, Braimah Apambire, Collins Gbeti, Abukari Wumbei and Fati Alhassan
Int. J. Environ. Res. Public Health 2026, 23(6), 821; https://doi.org/10.3390/ijerph23060821 (registering DOI) - 22 Jun 2026
Viewed by 166
Abstract
Background: Access to safe drinking water remains a critical public health concern in rural Ghana, particularly in climatically vulnerable and underserved settings. This study assessed the microbiological and chemical quality of drinking water and evaluated nitrate-related health risks in the North Gonja and [...] Read more.
Background: Access to safe drinking water remains a critical public health concern in rural Ghana, particularly in climatically vulnerable and underserved settings. This study assessed the microbiological and chemical quality of drinking water and evaluated nitrate-related health risks in the North Gonja and North-East Gonja Districts of the Savannah Region. Methods: A cross-sectional study was conducted between January and March 2025. A total of 460 water samples were collected from groundwater sources and household storage containers. Microbial analyses targeted total coliforms and Escherichia coli. Physicochemical and chemical parameters included nitrate-nitrogen, pH, residual chlorine, major ions, and trace metals. Data was analyzed using descriptive statistics, chi-square tests, spatial interpolation, and non-carcinogenic health risk assessment based on the hazard quotient (HQ) approach. Results: Widespread microbial contamination was observed, with 91.5% of household water samples positive for total coliforms and 46.6% for E. coli. Contamination of source water was significantly higher in North Gonja than in North-East Gonja. Overall, 49.1% (n = 55) of groundwater sources exceeded the World Health Organization guideline value for nitrate-nitrogen, with exceedances predominantly occurring in North Gonja. Additionally, 67.0% (n = 75) of samples were outside the acceptable pH range (6.5–8.5), including 74 samples below 6.5 and one above 8.5. Residual chlorine was not detected in any of the samples. Health risk assessment indicated potential non-carcinogenic risks associated with nitrate exposure, particularly among infants and children. Conclusions: The study demonstrates significant microbial contamination and nitrate-related health risks in the study area, particularly in North Gonja. Interventions such as improved source protection, routine water quality monitoring, chlorination, household water treatment, and implementation of Water Safety Plans are recommended to enhance drinking water safety and reduce associated public health risks. Full article
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14 pages, 1261 KB  
Article
Monitoring-Based Assessment of Fluoride Exposure and Health Risks via Drinking Water in the Taruo Lake Region, Tibetan Plateau
by Weimin Xie, Bingyang Wang, Jianghuan Hua, Mingyang Li, Gezi Li, Fan Xia, Tao Zuo and Xiaochen Wang
Water 2026, 18(12), 1518; https://doi.org/10.3390/w18121518 (registering DOI) - 19 Jun 2026
Viewed by 253
Abstract
Excessive fluoride intake from drinking water remains a public health concern in geogenic high-fluoride regions, yet direct evidence linking environmental fluoride levels to internal exposure in remote high-altitude areas is limited. This study integrated environmental monitoring with human biomonitoring to assess fluoride exposure [...] Read more.
Excessive fluoride intake from drinking water remains a public health concern in geogenic high-fluoride regions, yet direct evidence linking environmental fluoride levels to internal exposure in remote high-altitude areas is limited. This study integrated environmental monitoring with human biomonitoring to assess fluoride exposure and health risks in the Taruo Lake region of the Tibetan Plateau. Surface water (n = 45 for Taruo Lake; n = 8 for its tributaries) and groundwater samples (n = 4) were collected and analyzed for fluoride concentrations, and blood ionic fluoride (BIF) levels were measured in 122 local residents (47 adults, 75 children). The results showed that fluoride concentrations in most surface water tributaries of Taruo Lake and groundwater sources were below China’s drinking water standard, whereas those in Taruo Lake exceeded this limit (routine monitoring mean 2.54 mg/L; multi-site mean 2.79 mg/L). BIF levels were significantly higher in adults (0.126 ± 0.041 mg/L) than in children (0.075 ± 0.032 mg/L) and showed a positive correlation with age (r = 0.533, p < 0.001). Notably, 23.4% of adults and 1.3% of children exceeded 0.15 mg/L, an empirical threshold typical for healthy populations in non-endemic areas. Based on the hazard quotient (HQ) model recommended by the US EPA, most drinking water sources posed acceptable non-carcinogenic risks (HQ < 1). In contrast, Taruo Lake water presented an elevated risk (HQ > 1) in 2024 primarily due to the regional geological background, and although not used for daily drinking, this finding offers an indicative reference for local water management and risk prevention. This preliminary monitoring and biomonitoring assessment provides baseline data for future studies and underscores the necessity of continuous surveillance and evaluation of total dietary fluoride intake to protect the health of this vulnerable high-altitude population. Full article
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19 pages, 470 KB  
Article
Dietary Intake of Essential Elements from African Foods Available in the UK Market
by Eid I. Brima, Parvez I. Haris and Michael Frei
Foods 2026, 15(12), 2171; https://doi.org/10.3390/foods15122171 - 16 Jun 2026
Viewed by 226
Abstract
Background: Foods containing essential elements are important to human health. There is concern regarding micronutrient deficiency in the African population, and there is a need to identify foods that can address this public health issue. This study focuses on the determination of essential [...] Read more.
Background: Foods containing essential elements are important to human health. There is concern regarding micronutrient deficiency in the African population, and there is a need to identify foods that can address this public health issue. This study focuses on the determination of essential elements (EEs) in four African food categories: plant-based agricultural products (PBAPs), spices (SPs), fishery products (FPs), and non-food items/additives (NFAs) on sale in the UK market. Methods: Inductively coupled plasma mass spectrometry (ICP-MS) was used for measuring trace essential elements (TEEs—Mn, Fe, Cu, Zn, Se) and major essential elements (MEEs—Na, Mg, K, Ca) in the four categories of the African foods. Results: Mean concentrations (µg/g) for the TEEs were Cu 5.3, 7.3, 23.5, and 7.4; Fe 79.0, 263, 107.7, and 1311.3; Mn 23.4, 28.5, 15.9, and 47.4; Se 0.3, 0.1, 1.6, and 0.6; Zn 8.9, 11.4, 26.8, and 6.2 (PBAPs, SPs, FPs, NFAs, respectively). Mean concentrations of the MEEs (mg/g) were Na 0.6, 11.2, 13.3, and 32.9; Mg 1.6, 1.9, 2.4, and 5.5; K 9.2, 14.6, 9.6, and 8.3; Ca 4.1, 3.3, 27.5, and 127.8. All elements were below the upper intake limits (ULs) established by WHO/EFSA. When expressed as a percentage of the recommended daily allowance (%RDA) for adult males/females, 100% or more of the requirement was achieved for Cu (107.1%) and Ca (112.8%) in FPs. Excess index (EI), hazard quotient (HQ) and hazard index (HI) values for all TEEs were <1, indicating there is no non-cancerogenic health concern across all food categories. Conclusions: These findings demonstrate that African foods available in the UK are substantial sources of essential micronutrients. The fishery products contain high levels of nutrients that are often deficient in African diets. However, before recommending these foods for nutritional interventions, a comprehensive risk–benefit assessment, considering potential toxic metal contamination and microbial hazards must be undertaken. Future studies should expand the sample pool to include a broader range of African foodstuffs and national representation, coupled with integrated risk-benefit analyses. Full article
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25 pages, 5064 KB  
Article
Riverine Ecosystem Contamination and Ecological Risk Assessment Following Cyanide Leakage from In Situ Rare Earth Mining in Northern Laos
by Somchith Phetmany, Bounmy Keohavong, Bounlue Douangdy, Xaythavone Bounyasone and Xuewei Hu
Earth 2026, 7(3), 96; https://doi.org/10.3390/earth7030096 - 3 Jun 2026
Viewed by 367
Abstract
In situ leaching is increasingly used for rare earth element (REE) extraction because of its operational efficiency; however, acidic and chemically reactive leaching solutions may generate substantial environmental risks in riverine systems. This study evaluated water contamination and screening-level ecological risk following a [...] Read more.
In situ leaching is increasingly used for rare earth element (REE) extraction because of its operational efficiency; however, acidic and chemically reactive leaching solutions may generate substantial environmental risks in riverine systems. This study evaluated water contamination and screening-level ecological risk following a cyanide leakage incident associated with a pilot REE mining operation in Houaphanh Province, northern Lao PDR. Surface water samples were collected from 12 downstream monitoring locations between February and April 2024. Physicochemical parameters, free cyanide (CN), and dissolved metals, including arsenic (As), lead (Pb), copper (Cu), manganese (Mn), aluminum (Al), zinc (Zn), and iron (Fe), were analyzed using portable multiparameter probes, colorimetric cyanide determination, and ICP-OES. Contamination severity was interpreted using Pollution Index (PI) and Hazard Quotient (HQ) indicators based on Lao national standards and international guideline values. Results showed severe downstream contamination, with free cyanide and several dissolved metals substantially exceeding permissible thresholds. Observed elevated concentrations of As (30.29 mg/L), Pb (10.38 mg/L), Cu (14.97 mg/L), and CN (0.51 mg/L) indicated elevated ecological risk conditions, while acidic pH conditions may have enhanced metal mobilization and downstream transport. Descriptive spatial observations indicated apparent downstream contaminant dispersion within affected downstream river communities reliant on river water for domestic use, irrigation, and fisheries. Field observations additionally documented fish mortality, reduced irrigation usability, and deterioration of river water quality conditions in affected downstream communities. The findings suggest the potential vulnerability of Mekong-connected river systems to chemically intensive REE extraction activities and highlight the importance of preventive environmental governance, continuous monitoring, and operational risk management in emerging rare earth mining regions. Full article
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15 pages, 10488 KB  
Article
Evaluating the Influence of Food Trade on Human Exposure to Heavy Metals via Crops in China
by Bo Tang, Xuhua Miao, Jianyuan Ma, Wenxiu Liu, Qingbao Gu and Fujun Ma
Toxics 2026, 14(6), 474; https://doi.org/10.3390/toxics14060474 - 28 May 2026
Viewed by 444
Abstract
Crops can accumulate heavy metals (HMs) from soil, leading to human exposure through dietary intake. However, the influence of interregional food trade on dietary HMs exposure remains underexplored. In this study, using data derived from existing literature, the occurrence and distribution patterns of [...] Read more.
Crops can accumulate heavy metals (HMs) from soil, leading to human exposure through dietary intake. However, the influence of interregional food trade on dietary HMs exposure remains underexplored. In this study, using data derived from existing literature, the occurrence and distribution patterns of six HMs, namely arsenic (As), cadmium (Cd), chromium (Cr), nickel (Ni), lead (Pb), and zinc (Zn), in soil and crops across China were investigated. Furthermore, the influence of food trade on human exposure to soil-derived HMs was assessed. The average total concentration of the six HMs in soil was 234.01 ± 29.54 mg/kg, while concentrations in rice and wheat were 16.06 ± 2.91 mg/kg and 22.48 ± 4.22 mg/kg, respectively. The hazard quotients (HQs) for As in rice exceeded 1 in the Central, Central Coast, South Coast, Southwest, and Northeast regions, indicating potential health risks. Interregional food trade significantly redistributed these risks. Through rice consumption, the Central and Northeast regions accounted for up to 36.78% and 45.08% of the daily intakes of As and Cd in other regions, respectively. Similarly, through wheat consumption, the Central and Southwest regions accounted for up to 51.33% and 25.97% of the daily intakes of As and Cd, respectively. This redistribution is largely attributed to the concentration of major crop production in the Central, Northeast, and Southwest regions. Overall, this study highlights the critical role of interregional food trade in modulating population health risks associated with contaminants, providing a more accurate and comprehensive assessment of dietary HMs exposure. Full article
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15 pages, 886 KB  
Article
Health Risk Assessment Through Inhalation of Chemical Elements in Particulate Matter: A Case Study of Occupational Exposure in Highway Toll Plazas
by Gabriel Pinheiro Machado, Marina Smidt Celere Meschede, Danilo Vitorino dos Santos, Guilherme Sgobbi Zagui, Murilo D. M. Innocentini, Carlos Eduardo Formigoni, Jordi Sierra, Joaquim Rovira, Martí Nadal, José Luis Domingo and Susana Inés Segura-Muñoz
Green Health 2026, 2(2), 13; https://doi.org/10.3390/greenhealth2020013 - 27 May 2026
Viewed by 173
Abstract
(1) Background: Highway toll plazas are environments impacted by atmospheric pollutants that may affect workers’ health. However, there are still few studies on these environments. This study evaluated particulate matter (PM) concentrations by size fraction (PM10–9.0 to PM0.43) and associated [...] Read more.
(1) Background: Highway toll plazas are environments impacted by atmospheric pollutants that may affect workers’ health. However, there are still few studies on these environments. This study evaluated particulate matter (PM) concentrations by size fraction (PM10–9.0 to PM0.43) and associated arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb) and vanadium (V) at two toll plazas in Brazil. (2) Methods: PM and trace element concentrations were compared between dry and rainy seasons, and a health risk assessment was conducted for toll collectors based on inhalation exposure. (3) Results: PM10–2.5 concentrations ranged from 31.8 to 360 µg m−3 in the dry season and from non-detectable to 287 µg m−3 in the rainy season. PM2.5 levels varied between 14.9 and 150 µg m−3 (dry) and 3.46–174 µg m−3 (rainy). Although trace element concentrations were within Occupational Safety and Health Administration (OSHA) limits, the hazard quotient (HQ) for manganese and arsenic exceeded unity (HQ > 1), indicating potential health risks. (4) Conclusions: These findings suggest that toll plaza workers may experience increased inhalation-related risk under the exposure assumptions used. Improved ventilation and protective measures, including the use of protective screens, are recommended to reduce occupational exposure. Full article
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25 pages, 10980 KB  
Article
Human Health and Ecological Risk Assessment of Heavy Metal Contamination in the Tigris River (Mosul, Iraq): A Spatial–Temporal Analysis Using CCME-WQI and HPI
by Zena Altahaan and Daniel Dobslaw
Toxics 2026, 14(6), 463; https://doi.org/10.3390/toxics14060463 - 25 May 2026
Viewed by 624
Abstract
River water quality assessments are commonly conducted under conventional anthropogenic pressures; however, the long-term environmental impacts of armed conflicts remain insufficiently understood. This study addresses this gap by evaluating the persistence of war-related heavy metal contamination and its associated human health risks in [...] Read more.
River water quality assessments are commonly conducted under conventional anthropogenic pressures; however, the long-term environmental impacts of armed conflicts remain insufficiently understood. This study addresses this gap by evaluating the persistence of war-related heavy metal contamination and its associated human health risks in the Tigris River, Mosul, a post-conflict urban system. The results revealed that Cd, Pb, Cr, and Ni concentrations exceeded WHO guideline values across most sites, while Zn remained within acceptable limits. The highest contamination levels were observed in the central urban zone (Zone 3), which was directly affected by military activities. Hazard quotient (HQ) values for Cd and Pb exceeded the safe threshold (HQ > 1) at all sites, identifying them as dominant contributors to toxicity. The cumulative hazard index (HI) reached extremely high levels (>300 in 2022 and >200 in 2023), indicating severe non-carcinogenic health risks despite a slight temporal improvement. Spatially, contamination increased from upstream to downstream, with midstream and downstream areas acting as critical hotspots. Temporally, although pollutant levels declined in 2023, they remained significantly above safe limits, demonstrating limited natural recovery. Overall, the findings provide clear evidence of the long-term persistence of conflict-related contamination and its sustained risks to human health. This study highlights the need for targeted remediation strategies and offers a transferable framework for assessing water quality in conflict-affected river systems.: Full article
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28 pages, 3030 KB  
Article
Environmental Impact Assessment of the Soyuz-2.1a Launch Vehicle with the Progress MS-29 Cargo Spacecraft in Kazakhstan: A One-Time Monitoring with Retrospective Comparison of Data from 2020–2023
by Aliya Kalizhanova, Murat Kunelbayev, Anar Utegenova, Ainur Kozbakova and Serik Daruish
Atmosphere 2026, 17(6), 532; https://doi.org/10.3390/atmos17060532 - 22 May 2026
Viewed by 325
Abstract
The relevance of this study is determined by the need for a scientifically grounded assessment of environmental risks associated with rocket launches and by the necessity of ensuring environmental safety in areas potentially affected by space activities. Comprehensive monitoring of rocket-stage impact zones [...] Read more.
The relevance of this study is determined by the need for a scientifically grounded assessment of environmental risks associated with rocket launches and by the necessity of ensuring environmental safety in areas potentially affected by space activities. Comprehensive monitoring of rocket-stage impact zones and adjacent populated areas is especially important because pollutant distribution depends on natural, climatic, and spatial factors. This study assesses the environmental impact of the “Soyuz-2.1a” launch with the “Progress MS-29” cargo spacecraft in Kazakhstan using integrated field monitoring, laboratory analysis, and geoinformation methods. The work should be interpreted as a single-event environmental monitoring assessment, while historical monitoring data from 2020–2023 were used only as a retrospective comparative background for the U-25 impact area and were not included in the main BACI statistical analysis. The study covered the launch site, adjacent populated areas, and the U-25 stage impact zone. A before–after control-impact (BACI) design with distance stratification and consideration of wind direction was applied to identify post-launch changes. Measurements below the limit of detection and limit of quantification were processed using censored-data methods, including Regression on Order Statistics (ROS) and the Kaplan–Meier estimator. Spatial analysis was used to generate concentration fields, contour maps, and risk zones, revealing an anisotropic distribution of environmental stress in the downwind sector. An integrated hazard quotient (HQ) metric was applied to compare air, water, and soil conditions on a unified scale. The results indicate that the post-launch impact was localized and time-limited, with the greatest sensitivity observed in the soil component of the U-25 zone during the early post-launch period. Atmospheric air and water indicators remained within regulatory limits in populated areas. The proposed approach combines BACI monitoring, censored-data analysis, spatial modeling, and GIS-based visualization, providing a reproducible framework for the environmental assessment of rocket-stage impact areas. The practical recommendations include staged post-launch monitoring, temporary restriction of access to high-stress zones, primary reclamation of contaminated soil, and the use of WebGIS tools to support environmental decision-making. Full article
(This article belongs to the Section Air Quality)
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18 pages, 2447 KB  
Article
Integrated Machine Learning and Health Risk Assessment for Groundwater Nitrate Contamination in Handan City, China
by Yuanchao Zhao, Jing Liu, Xiaokai Zhang, Qun Li and Jin Wu
Water 2026, 18(10), 1174; https://doi.org/10.3390/w18101174 - 13 May 2026
Viewed by 375
Abstract
Groundwater nitrate (NO3) pollution is a critical environmental challenge with direct implications for human health. In this work, we propose a comprehensive analytical framework that integrates multi-model intercomparison, interpretable machine learning techniques, and quantitative health risk evaluation to tackle the [...] Read more.
Groundwater nitrate (NO3) pollution is a critical environmental challenge with direct implications for human health. In this work, we propose a comprehensive analytical framework that integrates multi-model intercomparison, interpretable machine learning techniques, and quantitative health risk evaluation to tackle the pressing groundwater nitrate governance dilemmas in Handan City, a representative urban area in North China. Based on 157 groundwater samples and 17 hydrochemical parameters, comparative analysis of three state-of-the-art machine learning algorithms showed that the Light Gradient Boosting Machine (LightGBM) algorithm outperformed all counterparts, delivering the optimal predictive performance (R2 = 0.753, RMSE = 3.67). SHapley Additive exPlanations (SHAP) analysis identified F, Ca2+, Cl, K+, total hardness, and Mg2+ as dominant factors influencing groundwater NO3 concentrations, reflecting the combined effects of carbonate dissolution, nitrification, and anthropogenic inputs. Subsequently, we performed a health risk assessment based on the standard methodological framework issued by the United States Environmental Protection Agency (USEPA), and the results indicated that children were the most vulnerable group, with hazard quotient (HQ, a non-carcinogenic risk indicator) values reaching 1.07 in the western mountainous region, exceeding the safety threshold (HQ > 1). These findings clarify the pollution mechanisms and spatial heterogeneity, and provide targeted policy guidance for groundwater protection as well as the safeguarding of public health. Full article
(This article belongs to the Section Hydrogeology)
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26 pages, 10776 KB  
Article
Redox Controls on Dissolved Metal Distribution and Screening-Level Health Risks in Groundwater of the Chiang Mai Basin, Northern Thailand
by Rungroj Benjakul, Sutthipong Taweelarp, Morrakot Khebchareon, Schradh Saenton and Nipada Santha
Toxics 2026, 14(5), 390; https://doi.org/10.3390/toxics14050390 - 30 Apr 2026
Viewed by 2039
Abstract
Groundwater contamination by dissolved metals and metalloids in the Chiang Mai Basin is an important drinking-water concern, yet the coupled depth patterns, hydrogeochemical controls, composite contamination status, and screening-level health implications have not previously been assessed in an integrated basin-scale framework. This study [...] Read more.
Groundwater contamination by dissolved metals and metalloids in the Chiang Mai Basin is an important drinking-water concern, yet the coupled depth patterns, hydrogeochemical controls, composite contamination status, and screening-level health implications have not previously been assessed in an integrated basin-scale framework. This study evaluated 120 groundwater samples from alluvial wells classified by depth as shallow (≤30 m, n = 40), intermediate (31–60 m, n = 35), and deep (>60 m, n = 45). Samples were analyzed for nine dissolved metals and metalloids (Fe, Mn, As, Cd, Pb, Cr, Zn, Hg, and Se) together with pH, Eh, and total dissolved solids (TDS). The highest exceedance frequencies were observed for Fe (72.5% of samples, >0.3 mg/L acceptability threshold), Mn (65.0%, >0.08 mg/L), and As (45.8%, >10 μg/L). Fe and Mn increased significantly with depth, whereas As was enriched in deep wells but showed no statistically significant depth dependence. Pearson correlation and principal component analysis consistently identified a dominant redox-associated component in which Fe, Mn, and As covaried negatively with Eh, supporting redox-sensitive co-enrichment in deeper groundwater. Contamination factors calculated relative to selected global groundwater background values were >6 for all seven evaluated metals (Fe, Mn, As, Cd, Pb, Cr, and Zn), and the overall pollution load index (PLI) was 9.11, with the highest depth-specific PLI in deep wells (10.42). These indices are interpreted here as background-relative screening tools rather than stand-alone regulatory measures. A screening-level ingestion risk assessment identified arsenic as the dominant toxicological driver, with hazard quotients (HQ) of 1.97 for adults and 4.60 for children, and an estimated lifetime cancer risk (LCR) of 8.87 × 10–4. The results support targeted monitoring of deeper wells, routine screening for As and Mn, and treatment strategies that can address the co-occurring Fe–Mn–As assemblage in alluvial groundwater. Full article
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20 pages, 3790 KB  
Article
Bioaccumulation and Trophic Transfer of Potentially Toxic Elements (As, Pb, and Cd) in Environmental Matrices and Sheep Tissues and Screening-Level Human Health Risk Assessment in the Ite Coastal Mining Wetland (Tacna, Peru)
by Abrahan Erasmo Apaza-Canqui, Diego Enrique Kassuha, Williams Sergio Almanza Quispe, María Elena Rodrigo Rojas, Nataniel Mario Linares-Gutiérrez, Carlos Genaro Morales-Aranibar, Álvaro Herrera Villanueva, Jorge González Aguilera, Alan Mario Zuffo and Luis Morales-Aranibar
Sustainability 2026, 18(9), 4334; https://doi.org/10.3390/su18094334 - 28 Apr 2026
Viewed by 809
Abstract
Potentially toxic elements (PTEs) in mining-impacted wetlands can transfer from soil and water to forage and grazing livestock, resulting in dietary exposure for nearby communities. In this study, arsenic (As), lead (Pb), and cadmium (Cd) were quantified in key environmental matrices (soil, surface [...] Read more.
Potentially toxic elements (PTEs) in mining-impacted wetlands can transfer from soil and water to forage and grazing livestock, resulting in dietary exposure for nearby communities. In this study, arsenic (As), lead (Pb), and cadmium (Cd) were quantified in key environmental matrices (soil, surface water, and forage) and in sheep tissues (liver, kidney, and muscle) from six georeferenced grazing sites in the Ite coastal wetland (Tacna, Peru) during the dry season. Samples were acid-digested following U.S. EPA protocols and analyzed by atomic absorption spectrometry (AAS) under QA/QC procedures (certified reference materials, blanks, duplicates, and matrix spikes); matrix-specific detection and quantification limits are reported. Arsenic dominated the contamination profile (forage: 428.6 mg kg−1, dry weight; soil: 48.61 mg kg−1; water: 0.97 mg L−1) and was detected in sheep tissues (kidney: 0.1577 mg kg−1; muscle: 0.1538 mg kg−1; liver: 0.0644 mg kg−1). Lead and cadmium were <LOQ in muscle and liver but were measurable in kidney (Pb: 0.0415 mg kg−1; Cd: 0.0011 mg kg−1). To support the interpretation of trophic transfer, screening transfer/bioaccumulation metrics (soil-to-forage, forage-to-tissue, and water-to-tissue) were calculated. Human dietary exposure was screened using estimated daily intake (EDI), hazard quotient (HQ), and margin of exposure (MOE). Because arsenic speciation was not measured, inorganic arsenic (iAs) risk was evaluated as a conservative upper bound (100% iAs) and through sensitivity scenarios (10–50% iAs). Under a high-meat-consumption scenario (300 g day−1), the upper-bound assumption yielded HQ = 2.2 and MOE = 0.46; however, scenario analyses indicate that risk conclusions are highly dependent on the assumed iAs fraction. Overall, the results identify arsenic as a priority contaminant and support targeted grazing management, the provision of low-arsenic water sources, and remediation and monitoring actions to reduce exposure in vulnerable rural communities. Full article
(This article belongs to the Special Issue Impact of Heavy Metals on the Sustainable Environment—2nd Edition)
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22 pages, 9778 KB  
Article
Pollution Characteristics and Assessment of Carcinogenic and Non-Carcinogenic Risks of Volatile Halogenated Hydrocarbons in a Medium-Sized City of the Sichuan Basin, Southwest China
by Xia Wan, Xiaoxin Fu, Zhou Zhang, Yao Rao, Mei Yang, Jianping Wang and Xinming Wang
Toxics 2026, 14(5), 370; https://doi.org/10.3390/toxics14050370 - 25 Apr 2026
Viewed by 1133
Abstract
Volatile halogenated hydrocarbons (VHHs) are critical air toxic pollutants, with some ozone-depleting substances (ODSs) strictly regulated by the Montreal Protocol. However, current understanding of the pollution characteristics, sources, and health risks of atmospheric VHHs in Southwest China remains insufficient. This study performed field [...] Read more.
Volatile halogenated hydrocarbons (VHHs) are critical air toxic pollutants, with some ozone-depleting substances (ODSs) strictly regulated by the Montreal Protocol. However, current understanding of the pollution characteristics, sources, and health risks of atmospheric VHHs in Southwest China remains insufficient. This study performed field observations of atmospheric VHHs in summer in Mianyang, a medium-sized industrial city in the Sichuan Basin. Freon-12 (563 ± 20 ppt) and Freon-11 (264 ± 15 ppt) were the most abundant chlorofluorocarbons (CFCs); chloromethane (785 ± 261 ppt) and methylene chloride (563 ± 505 ppt) dominated among VSLSs. The mean concentration of regulated ODSs (1037 ± 33 pptv) was notably lower than unregulated very short-lived chlorinated substances (1887 ± 745 pptv), reflecting effective ODSs phase-out locally, yet enhancements relative to Northern Hemisphere background implied potential leakage from residual tanks. Methylene chloride and trichloroethylene concentrations exceeded global background levels by over 10 times, indicating strong anthropogenic industrial influences. Phased-out CFCs displayed negligible diurnal variation due to stringent emission controls, whereas unregulated VSLSs exhibited a distinct U-shaped diurnal cycle, with peaks driven by morning boundary layer dynamics and evening accumulation. Positive matrix factorization revealed that industrial sources, including electronic solvents (28.6%), industrial processes (27.8%), and solvent usage (23.7%), accounted for 80.1% of total VHHs. The total carcinogenic risk (2.3 × 10−5) surpassed the acceptable threshold (1 × 10−6), dominated by 1,2-dichloroethane, chloroform, carbon tetrachloride, and 1,2-dichloropropane. All individual compounds exhibited mean hazard quotients (HQs) below the non-carcinogenic risk threshold. The cumulative hazard index reached 1.5, suggesting combined non-carcinogenic risks to the local population. These results support VHHs health risk management and ODSs control in Southwest Chinese industrial cities. Full article
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22 pages, 3178 KB  
Article
Nitrate Contamination in Groundwater of the Nansi Lake Region: Source Apportionment, Driving Mechanisms, and Health Risk Assessment
by Hengyi Zhao, Wenqi Zhang, Min Wang, Chengyuan Song and Xinyi Shen
Sustainability 2026, 18(8), 3981; https://doi.org/10.3390/su18083981 - 16 Apr 2026
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Abstract
To identify the sources and driving mechanisms of nitrate contamination in pore water around Nansi Lake, 54 pore water samples were analyzed via hydrogeochemical analysis, Gibbs diagrams, ionic ratios, and principal component analysis (PCA). The pore water is predominantly slightly alkaline, with dominant [...] Read more.
To identify the sources and driving mechanisms of nitrate contamination in pore water around Nansi Lake, 54 pore water samples were analyzed via hydrogeochemical analysis, Gibbs diagrams, ionic ratios, and principal component analysis (PCA). The pore water is predominantly slightly alkaline, with dominant cations Ca2+ and Na+, and anions HCO3 and SO42−. Nitrate-nitrogen (NO3-N) concentrations range from 0.82 to 54.31 mg·L−1, with a coefficient of variation of 1.41 and an exceedance rate of 18.52%, indicating significant external inputs. A positive correlation between NO2 and NO3 suggests denitrification in some areas. Nitrate concentrations exhibit distinct spatial heterogeneity: high concentrations occur in agricultural/aquaculture lakeside plains and urban areas, low concentrations near coal mining subsidence zones, and transitional zones showing outward diffusion. Nitrate sources are predominantly anthropogenic. High Cl and low NO3/Cl ratios indicate domestic and aquaculture wastewater infiltration, whereas low Cl and high NO3/Cl ratios indicate agricultural fertilizer input. Industrial and natural sources are minor. PCA identified three controlling factors (cumulative variance 69.81%): coal mining and industrial/domestic pollution (39.82%), carbonate rock weathering (19.44%), and agricultural activities (10.55%). Health risk assessment shows no significant risk for adults (hazard quotient (HQ) < 1), but children face localized risks at nine sites (HQs of 1.25–2.26) in intensive farming, urban, and transitional zones. Excessive fertilizer application and sewage leakage are the primary causes, posing methemoglobinemia risks to infants. This study provides a scientific basis for nitrate pollution control and sustainable water management in the Nansi Lake Basin and offers methodological insights for similar lacustrine plain regions. Full article
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24 pages, 6248 KB  
Article
Sustainable Management of Groundwater Resources in Central Tunisia: Nitrate Pollution and Health Risk Assessment
by Rim Missaoui, Matteo Gentilucci, Malika Abbes, Anouar Hachemaoui, Younes Hamed, Salem Bouri and Gilberto Pambianchi
Sustainability 2026, 18(8), 3759; https://doi.org/10.3390/su18083759 - 10 Apr 2026
Cited by 1 | Viewed by 511
Abstract
Degraded groundwater quality, characterized by elevated salinity and nitrate concentrations, poses significant public health concerns, particularly for vulnerable populations such as children. High content of nitrate in drinking water may lead to non-carcinogenic health risks, highlighting the urgent need for sustainable groundwater management [...] Read more.
Degraded groundwater quality, characterized by elevated salinity and nitrate concentrations, poses significant public health concerns, particularly for vulnerable populations such as children. High content of nitrate in drinking water may lead to non-carcinogenic health risks, highlighting the urgent need for sustainable groundwater management strategies to protect both human health and environmental integrity. This study assesses the suitability of groundwater resources in the Regueb Basin for irrigation and drinking purposes, with particular attention paid to nitrate contamination. The Irrigation Water Quality Index (IWQI) indicates considerable spatial variability in groundwater quality, with values varying between 15.86 and 89.55 and a median of 41.69, reflecting differing levels of suitability for irrigation across the basin. Similarly, the Drinking Water Quality Index (DWQI) ranges from 149.16 to 982.42, with a median value of 445.71, suggesting significant concerns regarding groundwater suitability for drinking purposes. The health risk assessment (HHRA) based on the Nitrate Pollution Index (NPI) and the nitrate hazard quotient (HQ_nitrate) reveal substantial risks to human health. NPI values vary between 0.45 and 5.5, with a median of 1.65 indicating varying levels of nitrate pollution. The HQ_nitrate results show that all groundwater samples (100%) pose health risks for children (HQ > 1). For women, 75.61% of HQ values exceed the safe threshold, affecting approximately 80% of the study area, whereas for men, 48.48% of HQ values exceed 1, impacting about 36.67% of the area. Overall, these findings highlight the urgent need for effective groundwater management strategies to mitigate nitrate contamination and ensure the safe and sustainable use of the groundwater resources in the Regueb Basin. Full article
(This article belongs to the Special Issue Circular Economy and Sustainable Water Treatment)
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