Search Results (104)

The Mangyahedong gold deposit—recently discovered in the Qimantage segment of the East Kunlun orogenic belt—is a high-priority exploration target. Key unknowns include its mineralization age, the sources of sulfur and gold, and the tectonic–magmatic–hydrothermal controls on formation. These gaps have hindered genetic classification and stage-specific research. We addressed them through integrated petrography, TIMA mineral mapping, in situ LA-ICP-MS analysis of pyrite from three mineralization stages, and U-Pb dating of hydrothermal apatite spatially and temporally linked to the main sulfide-precipitation event. The stages are: (I) early sericite–quartz alteration; (II) main ore stage—carbonate–chlorite–sulfide + native gold; and (III) late calcite–pyrite veins. Pyrite zoning shows that early pyrite cores are enriched in As and Au. In contrast, the main-stage pyrite has As-poor cores, with As, Au, and Co progressively enriched toward the rims. This zoning pattern indicates evolving fluid redox conditions and metal complexation during ore deposition. A ²⁰⁷Pb/²⁰⁶Pb age of 406 ± 13 Ma from apatite in gold-bearing quartz–sulfide veins constrains gold deposition to the Late Silurian–Early Devonian transition. Age, texture, and geochemistry collectively support a regional metamorphic–deformational origin, consistent with the orogenic gold model. Isotopic and elemental data point to the Qimantage Group volcanic rocks as the dominant source of ore-forming elements—indicating strong potential for discovery along strike and at depth. Full article

The Bastielieke W-polymetallic deposit, located in the Xinjiang Altay metallogenic belt, records a complex hydrothermal history critical to understanding multi-stage metallogenic processes in the southern Altay. This study integrates in situ U-Pb dating of hydrothermal titanite and zircon with textural and compositional analyses of titanite to reconstruct this history. Three types of hydrothermal titanite, identified from pyroxene skarn (TtnI), epidote skarn (TtnII), and quartz–sulfide ore (TtnIII), display dissolution–reprecipitation textures and systematic compositional variations, indicating distinct fluid compositions and origins. TtnI, TtnII, and TtnIII yield U-Pb ages of 244.7 ± 7.8 Ma, 252.4 ± 5.5 Ma, and 250.6 ± 3.0 Ma, respectively, and hydrothermal zircon from pyroxene skarn yields an age of 249.9 ± 2.1 Ma, constraining the hydrothermal event to the latest Permian to Early Triassic. These ages are interpreted to record the timing of U-Pb system resetting during regional shear–thrust movements. Compositional variations among the three titanite types reveal a two-stage hydrothermal history. The earlier stage involved W–Cu mineralization and protolith titanite precipitation related to magmatic–hydrothermal fluids exsolved from Permian granites. The later stage was driven by regional shear–thrust movements and metamorphic–hydrothermal processes, which reset the titanite U-Pb systems, partially altered TtnI and TtnII, precipitated TtnIII, and remobilized metals. This model links the Bastielieke deposit to multi-stage hydrothermal processes and provides insights into similar metallogenic events along the southern margin of Xinjiang Altay. Full article

The No. VI ore block of the Galinge skarn system in the Qimantagh metallogenic belt, East Kunlun, contains proximal Fe-oxide mineralization and distal Pb–Zn sulfide mineralization that are spatially zoned and locally overprinted along faults and interlayer fracture zones. To constrain the controls on Fe–Pb–Zn zonation and overprinting within this ore block, we integrated LA–ICP–MS zircon U–Pb dating, zircon Lu–Hf isotopes, whole-rock major and trace elements, and in situ trace elements of magnetite, pyrite, chalcopyrite, pyrrhotite, and arsenopyrite. Zircon U–Pb ages indicate two Indosinian intrusive pulses: an early granodiorite at 235.1 ± 0.51 Ma and a younger granodiorite–quartz diorite at 229.52 ± 0.46 Ma. Excluding the hydrothermally altered sample ZK26804-805, the intrusive rocks are metaluminous, medium- to high-K calc-alkaline I-type granitoids mainly derived from remelting of ancient crustal material, with a greater juvenile crustal or mantle contribution in the younger phase. Magnetite is generally Zn-rich and Pb-poor, whereas late pyrite and chalcopyrite are enriched in Pb, Ag, Cd, and Bi; local Sb–As anomalies in magnetite and arsenopyrite indicate late hydrothermal overprinting. The Fe and Pb–Zn mineralization is best interpreted as staged products of one multipulse magmatic–hydrothermal system controlled not only by intrusive pulses but also by inherited structural pathways, host-rock reactivity, and evolving redox-sulfidation conditions. The interpretation of Sb–As enrichment in magnetite is therefore used cautiously because these elements may occur as lattice substitutions and/or micro- to nano-inclusions introduced or modified during retrograde alteration. Full article

The Donggou Pb-Zn deposit in the Qimantagh region is stratabound, with ore bodies occurring as stratoid and lenticular forms within clastic rocks and andesites of the Qimantagh Group. To constrain the mineralization age, ore genesis, and ore-forming conditions, this study conducted zircon U-Pb dating, sulfur isotope analysis, and LA-ICP-MS trace element analysis of sphalerite. Zircon U-Pb dating of the overlying andesite yields an age of 437.1 ± 1.9 Ma, which provides an upper age constraint for mineralization. Sulfur isotope values (δ³⁴S range from −5.98‰ to +12.01‰) suggest a mixed sulfur source, dominated by magmatic sulfur with a minor seawater contribution. Trace element analysis of sphalerite (Sp1) shows enrichment in Fe, Mn, Co, Cd, and In, and depletion in Ni, Ga, and Ge. The estimated mineralization temperature, based on the sphalerite geothermometer, is approximately 327–344 °C. Volcanic rocks in the deposit are mainly andesite with minor dacite and rhyolite, indicating an island arc setting, and the clastic rocks point to a continental arc provenance and a shallow marine environment. Collectively, these features suggest that the Donggou Pb-Zn deposit is a VMS-type deposit formed during the late subduction stage of the Qimantagh Ocean. This study provides new constraints on the Early Silurian Pb-Zn mineralization in the Qimantagh region and has implications for exploration targeting in similar volcanic-hosted settings. Full article

The Huomaxie granite in Ningdu, southern Jiangxi Province, is located in the central part of the Cathaysia Block. Previous studies assigned this pluton to the Huitong batholith as S-type granite, but lacked precise geochronological and petrogenetic constraints. This paper presents systematic petrography, whole-rock geochemistry, zircon U–Pb dating, in situ Hf isotopic analysis, and electron microprobe analysis (EPMA) of muscovite from the muscovite monzogranite of the pluton. The weighted mean ²⁰⁶Pb/²³⁸U age is 420.1 ± 3.1 Ma. The rocks are silicic, high-K calc-alkaline, and peraluminous S-type granites. Zircon ε_Hf(t) values range from −15.0 to −11.8, with two-stage Hf model ages (T_DM2) of 2360–2150 Ma. Geochemical characteristics and muscovite composition data indicate that the magma was derived from high-temperature partial melting of psammitic sedimentary rocks. Tectonic discrimination diagrams suggest that the pluton formed in a post-orogenic extensional setting. It was generated by lower crustal melting induced by asthenospheric upwelling. Full article

Current research suggests that the uranium enrichment in the Qianjiadian deposit, southwestern Songliao Basin (China), is closely related to hydrocarbon dissipation and deep thermal fluids. However, previous investigations have not carried out systematic in-depth research on the abundant calcite veins hosted in diabase within the ore district, especially regarding their types, genetic mechanisms, formation ages, and genetic links to uranium enrichment. In particular, whether their genesis is associated with the two critical ore-controlling factors (hydrocarbon dissipation and thermal fluid activities) remains poorly constrained and to be elucidated. Through analyses of major and trace element geochemistry, scanning electron microscopy, and fluid inclusion microthermometry on calcite veins within fractures of Lower Cretaceous diabase, this study confirms that the veins are products of epigenetic fluid infill with a medium-to-low temperature hydrothermal nature (115–215 °C). The direction of fluid migration was from north to south, consistent with the trend of hydrocarbon dissipation. In situ U-Pb dating yields Eocene (~42.9 Ma) and Pleistocene (1.57–2.82 Ma) ages for the calcite veins, which are highly consistent with the timing of diabase intrusion (early Eocene) and the main episodes of uranium mineralization (Eocene–Oligocene and Pleistocene). Carbon and oxygen isotope compositions and inclusion components indicate that the carbon source was mainly derived from dissipated hydrocarbons, rather than from sedimentary diagenesis or direct source rock generation. The C-O isotopic signatures reflect further carbon isotope fractionation following the interaction between dissipated hydrocarbons and groundwater, and the inclusion fluids, composed mainly of hydrocarbon gases and water, suggest that the carbon source for calcite vein formation was provided by dissipated hydrocarbons. The temporal coupling of hydrocarbon dissipation, calcite vein formation, uranium mineralization, and thermal input from diabase intrusion reflects the dynamic processes of basin evolution and tectonic reworking. The key dynamic backgrounds for this series of diagenetic and metallogenic events include Late Cretaceous tectonic inversion, Eocene–Oligocene tectonic uplift and erosion, and Pleistocene differential uplift and subsidence. The thermal effects from hydrocarbon dissipation and diabase intrusion were the primary factors driving the anomalous uranium enrichment that formed this super-large deposit. The formation of the calcite veins, along with their characteristics indicative of medium-to-low temperature hydrothermal activity and hydrocarbon dissipation, provides a critical window for understanding these processes and offers robust scientific evidence for this genetic model. This study, for the first time, systematically reveals that the calcite veins within the diabase of the Qianjiadian uranium mining area are of medium-to-low temperature hydrocarbon-bearing hydrothermal origin, and constrains their formation ages to the Eocene (~42.9 Ma) and Pleistocene (1.57–2.82 Ma), which are highly coupled with diabase intrusion and two episodes of uranium mineralization events. C-O isotopic and fluid inclusion evidence indicates that the formation of calcite veins directly records the process of hydrocarbon dissipation–groundwater mixing, providing a new mineralogical and geochronological evidence chain for thermal–hydrocarbon–uranium-coupled mineralization. Full article

Deep-to-ultra-deep marine carbonate reservoirs represent an important frontier for hydrocarbon exploration in the Tarim Basin, yet fluid sources and accumulation processes in the Ediacaran (Sinian) succession remain poorly constrained due to extreme burial depth and complex tectono-thermal evolution. Here, we investigate fracture–vug reservoirs of the Sinian Qigebulake Formation in Well LT3 (Tabei Uplift) using an integrated dataset including petrography and cathodoluminescence, fluid-inclusion microthermometry, fluorescence and Raman spectroscopy, in situ major/trace element analysis and C–O–Sr isotope geochemistry, and LA-ICP-MS carbonate U–Pb dating of authigenic minerals. The paragenetic sequence comprises early dolomite (Dol-I), later dolomite (Dol-II), co-precipitated calcite (Cal-I) and quartz (Qtz-I), and late solid bitumen (Bit). Dolomite veins show PAAS-normalized REE patterns and 87Sr/86Sr ratios (0.70918–0.70984; average 0.70942) comparable to the surrounding Sinian marine wall rocks, indicating precipitation from diagenetic fluids dominated by closed-system water–rock interaction. In contrast, Cal-I displays LREE enrichment, pronounced positive Eu anomalies (δEu = 4.91–7.21), radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.71161–0.71417; average 0.71256), and negative δ¹⁸O_VPDB values (down to −9.439‰), suggesting a large-scale influx of deep-seated, high-temperature, Sr-rich hydrothermal fluids likely linked to fault-assisted fluid circulation. Fluid inclusions record four hydrocarbon charging episodes, evolving from lower- to higher-maturity oils and ultimately to dry gas. Dol-II hosts pale-yellow to pale-blue oil inclusions, whereas Cal-I and Qtz-I predominantly contain deep-blue oil inclusions and methane-rich gas inclusions (Raman peak near 2917 cm⁻¹). Carbonate U–Pb ages constrain dolomite precipitation to the Middle Ordovician (~468–463 Ma) and hydrothermal-related carbonate filling to the Early Triassic (~247–244 Ma). Collectively, these results support a time-resolved evolution in which early diagenetic fluid circulation in a marine carbonate system was overprinted by a later hydrothermal pulse that modified pore structures and thermal conditions, followed by late-stage deep burial leading to cracking of retained liquids, widespread bitumen formation, and methane charging. This framework provides new information on the constraints for fluid–rock interaction and hydrocarbon evolution in deep marine carbonate successions. Full article

Gem-quality garnets exhibit significant potential for U-Pb geochronological applications due to their advantageous characteristics, including high closure temperatures (750–850 °C), optical transparency, chemical homogeneity, and low inclusion content. This study focuses on the gem-quality yellow-green grossular garnet variety (commonly termed Mali garnet), a unique gemstone exclusively occurring in contact metamorphic deposits of Western Africa’s Republic of Mali. Despite its mineralogical significance, fundamental aspects, including precise age determination and chromophore mechanisms of Mali garnet, remain poorly constrained. Here, we conducted standard gemological characterization, spectroscopic analyses (UV–Vis, FTIR, and Raman), electron probe microanalysis (EPMA), micro-X-ray fluorescence (μ-XRF) elemental mapping, and in situ trace element and laser ablation U-Pb geochronological analysis on Mali garnets. The spectral data and chemical composition studies reveal that the coloration of Malian garnets is primarily attributed to the presence of iron and chromium. Our U-Pb geochronological results yield a crystallization age of 197 ± 3 Ma for the Mali garnet samples. The robustness of garnet U-Pb systems in preserving crystallization ages through multiple thermal events supports their application to Precambrian polymetamorphic terranes, where zircon systems are frequently reset. Full article

Pegmatites with miarolitic cavities have not previously been reported from the Larsemann Hills, East Antarctica, and their age and origin remain poorly constrained. We report the first geochemical and geochronological data for fluorapatite from a newly discovered pegmatite with miarolitic cavities in the Larsemann Hills. Large Fe-rich fluorapatite crystals (up to 5 cm) contain abundant oriented monazite-(Ce) inclusions and display elevated REE (1397–7966 ppm), relatively high Y (945–4192 ppm), and low Sr (52.2–83.5 ppm). Their trace-element signatures plot within the fields of partial melts, high-grade metamorphic rocks, and evolved fluid-rich magmatic systems. U–Pb dating of fluorapatite yields concordant ages of 519 ± 4 Ma (ID-TIMS) and 521 ± 31 Ma (LA-ICP-MS), indicating crystallization during the D₄ stage of the Pan-African orogeny. The isotopic equilibrium between apatite and monazite inclusions suggests synchronous formation and late-stage fluid overprinting. Combined geological, geochemical, and isotopic evidence shows that the pegmatite formed in situ as a product of anatexis of the Broknes paragneisses and evolved within a volatile-rich magmatic–hydrothermal system. These results provide the first direct age constraints on pegmatites with miarolitic cavities in Antarctica and shed new light on the final stages of East Gondwana assembly. Full article

The Nanping pegmatite-type Nb-Ta deposit is one of the large-scale Li-Cs-Ta (LCT)-type pegmatite deposits in Southeast China. Nevertheless, the mineralization mechanism of this ore deposit remains unclear, primarily due to the lack of systematic research on the characteristics of ore-forming fluids and mineralization processes. To address this issue, analyses of the fluid inclusion characteristics, hydrogen–oxygen isotope compositions and in situ U-Pb geochronology of Nb-Ta minerals were performed on the No. 31 vein of the Nanping pegmatite deposit. In situ U-Pb dating of the Nb-Ta minerals with varying textures from different zones yields main mineralization ages clustered between 390 and 370 Ma, along with isolated younger ages around 270 Ma in specific mineral zones, indicating multiple mineralization episodes. The fluid inclusion homogenization temperatures of different zones range from 130 to 382 °C, and salinities between 2 and 16 wt% NaCl eqv, consistent with a medium-to-low temperature and salinity fluid system. Hydrogen and oxygen isotope data show that the ore-forming fluids were predominantly derived from magmatic fluids, mixed with later meteoric waters. This study clarifies the multistage mineralization history and fluid evolution of the Nanping pegmatite-type Nb-Ta deposit, providing key constraints for metallogenic models of pegmatite-hosted rare-metal deposits. Full article

Determining the age and origin of the “Huoshan Sandstone” holds significant geological implications for the stratigraphic division and correlation of Precambrian sequences in the North China Craton, provenance analysis, reconstruction of tectonic–sedimentary patterns, and paleogeographic settings restoration. This paper investigates the petrology, zircon U-Pb dating, Hf isotopes analysis, and zircon microzonation geochemistry of the “Huoshan Sandstone”. The “Huoshan Sandstone” is grayish-white, light gray, light yellow, purplish-red quartzitic sandstone and quartz sandstone, with a quartz content ranging from 85.5% to 97.8%. The quartz grains exhibit relatively straight contact edges, characteristic of low-grade metamorphosed quartzite. The protolith of the “Huoshan Sandstone” is a medium-grained quartz sandstone with dominant grain sizes of 0.30~0.50 mm, exhibiting well-rounded to subrounded grains and highly developed siliceous cementation characterized by secondary overgrowth. The zircon Th/U ratio confirms that the zircons in the “Huoshan Sandston” are mainly magmatic zircons. Most zircons exhibit extreme HREE enrichment and left-sloping REE patterns, and show significant positive Ce anomalies (Ce/Ce* of 1.06~290.68) and negative Eu anomalies (Eu/Eu* of 0.065~0.61). The age range of zircon ²⁰⁷Pb/²⁰⁶Pb is 1770 ± 20~2732 ± 16 Ma, and there are two obvious peaks at 1800 and 2500 Ma in the U-Pb age frequency histogram, the age of the intersection point on the concordia line is 2521 ± 31 Ma, and the age of the intersection point on the lower part of the line is 1829 ± 22 Ma. These two ages correspond to the timing of Neoarchean TTG gneiss formation through oceanic crust partial melting in the central North China Craton, and the ~1.85 Ga Paleoproterozoic thermal metamorphic event recorded in the Zhongtiao Group of the same region, respectively. The maximum depositional age of the “Huoshan Sandstone”, constrained by the youngest detrital zircon U-Pb ages at 1770 ± 20 Ma, indicates that its sedimentation occurred after 1770 ± 20 Ma (Late Late Paleoproterozoic). Furthermore, as it underlies the red shales of the Cambrian Mantou Formation as a distinct tectonic layer, it must have formed prior to the deposition of the Cambrian Mantou Formation. In addition, in situ Lu-Hf isotopic analyses of these zircons yielded two-stage model ages, mainly between 2.5 and 2.8 Ga, suggesting the provenance to be the Precambrian basement of the Zhongtiao Mountain region in the central North China Craton. It is inferred that the Precambrian strata in the Zhongtiao Mountain area were involved in the process of subduction, collage, and collision of the two continental blocks of the eastern and western parts of the North China Craton, and further confirmation is provided that the final collision of the two continental blocks to form the central orogenic belt occurred in the late Palaeoproterozoic. Full article

The Yawan gold deposit, located in the Western Qinling Orogen, contains gold mineralisation that is predominantly controlled by approximately east-west-trending fault systems. This study integrates field geology, petrography, cathodoluminescence imaging, electron probe microanalysis of gold-bearing minerals (pyrite and arsenopyrite), and in situ laser ablation U-Pb dating of calcite to constrain the timing of mineralisation and to elucidate the mechanisms of gold enrichment. This study reveals that the deposit is significantly structurally controlled and comprises two discrete mineralisation stages: a quartz-pyrite (Py1)-arsenopyrite (Apy1)-chalcopyrite assemblage (Stage 1), and a quartz-calcite-pyrite (Py2)-arsenopyrite (Apy2)-stibnite-sphalerite-galena assemblage (Stage 2). Py1 displays distinct zonation, with rim As contents notably higher than core values, while Co and Ni contents gradually decrease from core to rim. Py2 is characterised by high As (0.00%–4.72%), low Fe/S ratios, and a porous texture, containing gold and arsenopyrite inclusions. Invisible gold occurs in lattice-bound form in both Py1 and Py2. The As-Fe-S ternary diagram of pyrite indicates that Au⁺ likely entered the crystal lattice as a solid solution. Arsenopyrite geothermometry yields a mineralisation temperature of 389 ± 44 °C, and sulfur fugacity (ƒS₂) decreased markedly from Stage 1 to Stage 2. Combined with the S and Fe characteristics of pyrite, these features support a medium-temperature metamorphic hydrothermal environment. U-Pb dating of calcite from Stage 2 yields an age of 215.6 ± 7.1 Ma. In summary, the Yawan gold deposit belongs to the orogenic gold system, with its gold precipitation and enrichment controlled by sulfidation triggered by Late Triassic tectono-fluid activity. Full article

Natural fractures in marine shales are crucial storage spaces and migration pathways for oil and gas, making the study of their formation mechanisms and distribution patterns essential for hydrocarbon exploration and development. This review systematically evaluates the progress in natural fracture studies, transitioning from qualitative to quantitative approaches, with a focus on the genetic mechanisms, distribution patterns, and methodological advancements of fracture types. The review finds that: (1) Integrated “geological-geophysical-dynamic” analyses significantly improve the prediction accuracy of tectonic fracture networks compared to traditional stress-field models. Bedding-parallel fracture development is primarily controlled by the interplay between diagenetic evolution and in situ stress, with their critical opening conditions now being quantifiable; (2) Crucially, the application of micro-scale in situ techniques (e.g., Laser Ablation Inductively Coupled PlasmaMass Spectrometer, laser C-O isotope analysis, carbonate U-Pb dating) has successfully decoded the geochemical signatures and absolute timing of fracture fillings, revealing multiple episodes of fluid activity directly tied to hydrocarbon migration. (3) The combined application of multiple techniques holds promise for deepening the understanding of the coupling mechanisms between fractures. The combined application of these techniques provides a robust framework for deciphering the coupling mechanisms between fracture dynamic evolution and hydrocarbon migration, offering critical insights for future exploration. Full article

Cr and Platinum-Group Elements (PGEs), critical metallic elements, are mainly hosted in mafic and ultramafic rocks, but determining these rocks’ mineralization age has long been challenging. Zircon, the primary geochronological mineral, is scarce and fine-grained in such rocks, hindering conventional separation techniques (heavy liquid separation, magnetic separation, manual hand-picking) with low efficiency, poor recovery, and significant sample bias. This study develops an integrated workflow: mixed acid leaching enrichment (120 °C), powder stirring for mount preparation, automated mineral identification, and in situ Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA–ICP–MS) dating. Validated on the Xiugugabu diabase in the western Yarlung–Tsangpo Suture Zone (southern Tibet), the workflow yielded weighted mean ²⁰⁶Pb/²³⁸U ages of 120.5 ± 3.3 Ma (MSWD = 0.13) and 120.5 ± 2.0 Ma (MSWD = 3.2) for two samples. Consistent with the published Yarlung–Tsangpo Suture Zone (YTSZ) diabase formation ages (130–110 Ma), these confirm the Xiugugabu diabase as an Early Cretaceous Neo–Te–thys oceanic lithosphere residual recording mid-stage spreading. The workflow overcomes traditional limitations: single-sample analytical cycles shorten from 30–50 to 10 days, fine–grained zircon recovery is 15x higher than manual picking, and U–Pb ages are stable. Suitable for large-scale mafic–ultramafic geochronological surveys, it can extend to in situ zircon Hf isotope and trace element analysis, offering multi-dimensional constraints on petrogenesis and tectonic evolution. Full article

Determining the timing of hidden faults that terminate beneath the subsurface remains a significant challenge. For this contribution, seismic fault interpretation, fracture diagenesis analysis, and U-Pb dating of fracture cements are integrated to constrain the activity of hidden thrust faults in the southeastern Sichuan Basin. The results show that the EW- and NW-trending hidden thrust faults developed in the Permian, while the NE-trending faults have inherited later fault activity till the Cenozoic. The hidden thrust fault propagates upward from the top of the Upper Permian to the Lower Triassic strata. Fault inversion within the Permian is firstly identified by the thickness variation between the two fault walls. Core-based fracture diagenesis analysis indicates that multiple fractures and associated dissolution porosity developed within the tight matrix reservoir. In situ U-Pb dating of fracture cements yields ages of 247.4 ± 2 Ma and 234.8 ± 9.1 Ma, indicating that the hidden fault activity predates the Early Triassic. The absence of strata, evidence of structural uplift, and fault inversion collectively suggest that the first faulting in the eastern Sichuan Basin occurred at the end of the Middle Permian. The findings highlight that fracture–cave reservoir along the hidden thrust fault zone has been controlled by the coupling of the fracturing and karstification at the end of the Middle Permian, and is the key target for high gas production. Full article