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Keywords = indium-tin oxide

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14 pages, 2817 KB  
Article
Light-Induced Heating of Microsized Nematic Volumes
by Dmitrii Shcherbinin, Denis A. Glukharev, Semyon Rudyi, Anastasiia Piven, Tetiana Orlova, Izabela Śliwa and Alex Zakharov
Crystals 2025, 15(9), 822; https://doi.org/10.3390/cryst15090822 - 19 Sep 2025
Viewed by 299
Abstract
The experimental study has been carried out using advanced computer vision methods in order to visualize the moment of excitation and further propagation of a non stationary isotropic domain in a hybrid aligned nematic (HAN) microsized volume under the effect of a laser [...] Read more.
The experimental study has been carried out using advanced computer vision methods in order to visualize the moment of excitation and further propagation of a non stationary isotropic domain in a hybrid aligned nematic (HAN) microsized volume under the effect of a laser beam focused on a bounding liquid crystal surface. It has been shown that, when the laser power exceeds a certain threshold value, in bulk of the HAN microvolume, an isotropic circular domain is formed. We also observed a structure of alternating concentric rings around the isotropic circular region, which increases with distance from the center of the isotropic domain. The formation of a sequence of rings in a polarizing microscopic image indicates the formation of a complex topology of the director field in the HAN cell under study. The following evolution of the texture can be represented by two modes. Firstly, the “fast” heating mode, which is responsible for the formation and explosive expansion of an isotropic zone in bulk of the HAN microvolume with characteristic time τ1 due to a laser spot heating on the upper indium tin oxide (ITO) layer. Secondly, the “slow” heating mode, when an isotropic zone and concentric rings slowly expand with characteristic time τ2 mainly due to the finite thermoconductivity of ITO layer. When the laser power significantly exceeds the threshold value, damped oscillations of the isotropic domain are observed. We also introduced the metrics that allows quantitatively estimate the behavior of texture observed. The results obtained form an experimental basis for further investigation of thermomechanical force appearing in the LC system with coupled gradients of temperature and director fields. Full article
(This article belongs to the Collection Liquid Crystals and Their Applications)
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17 pages, 6509 KB  
Article
Cost-Effective and Rapid Detection of Tetrodotoxin Using Indium Tin Oxide Electrodes via In Vitro Electrophysiology and Electrochemistry
by Naga Adithya Chandra Pandurangi, Manel M. Santafe, Angels Tudo, Nagihan Ozsoy, Fransesc X. Sureda, Mark L. Dallas and Ioanis Katakis
Toxins 2025, 17(9), 462; https://doi.org/10.3390/toxins17090462 - 13 Sep 2025
Viewed by 940
Abstract
The real-time, cost-effective detection of marine toxins like tetrodotoxin (TTX) remains a significant challenge for the scientific community. Traditional methods, including cell-based assays (CBAs), high-performance liquid chromatography (HPLC), and automated patch clamp (APC), are time-consuming, requiring expensive lab-based equipment and highly trained personnel. [...] Read more.
The real-time, cost-effective detection of marine toxins like tetrodotoxin (TTX) remains a significant challenge for the scientific community. Traditional methods, including cell-based assays (CBAs), high-performance liquid chromatography (HPLC), and automated patch clamp (APC), are time-consuming, requiring expensive lab-based equipment and highly trained personnel. Enzyme-linked immunosorbent assays (ELISAs), lateral flow assays (LFAs), and immunosensors may not be suitable for toxin analogues. Thus, a simplified approach has been developed in this study, which involves the electrophysiological and electrochemical interrogation of N2a cells grown on ITO-coated glass electrodes by measuring extracellular field potentials (EFP) in conjunction with whole-cell patch clamp recordings and electrochemical impedance spectroscopy (EIS) measurements both before and after incubation with TTX. The ITO substrate proved biocompatible and non-toxic for N2a cells. TTX exposure caused 102% inhibition in EFP values at 300 nM, confirmed by sodium current inhibition of 93% at 300 nM and 22% at 1 nM in patch clamp studies (IC50 = 6.7 nM). EIS measurements indicated concentration-dependent impedance changes in the range of 6–300 nM. This research aims to provide a proof-of-concept for integration of electrophysiological and electrochemical approaches to simplify toxin detection systems. Full article
(This article belongs to the Section Marine and Freshwater Toxins)
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17 pages, 4214 KB  
Article
Resistive Switching Behavior of Sol–Gel-Processed ZnMgO/ZnO Bilayer in Optoelectronic Devices
by Hee Sung Shin, Dong Hyun Kim, Donggu Lee and Jaehoon Kim
Nanomaterials 2025, 15(17), 1353; https://doi.org/10.3390/nano15171353 - 3 Sep 2025
Viewed by 765
Abstract
Sol–gel-processed zinc oxide (ZnO) and magnesium-doped zinc oxide (ZnMgO) are widely used in quantum dot light-emitting diodes (QLEDs) due to their excellent charge transport properties, ease of fabrication, and tunable film characteristics. In particular, the ZnMgO/ZnO bilayer structure has attracted considerable attention for [...] Read more.
Sol–gel-processed zinc oxide (ZnO) and magnesium-doped zinc oxide (ZnMgO) are widely used in quantum dot light-emitting diodes (QLEDs) due to their excellent charge transport properties, ease of fabrication, and tunable film characteristics. In particular, the ZnMgO/ZnO bilayer structure has attracted considerable attention for its dual functionality: defect passivation by ZnMgO and efficient charge transport by ZnO. However, while the effects of resistive switching (RS) in individual ZnO and ZnMgO layers on the aging behavior of QLEDs have been studied, the RS characteristics of sol–gel-processed ZnMgO/ZnO bilayers remain largely unexplored. In this study, we systematically analyzed RS properties of an indium tin oxide (ITO)/ZnMgO/ZnO/aluminum (Al) device, demonstrating superior performance compared to devices with single layers of either ZnMgO or ZnO. We also investigated the shelf-aging characteristics of RS devices with single and bilayer structures, finding that the bilayer structure exhibited the least variation over time, thereby confirming its enhanced uniformity and reliability. Furthermore, based on basic current–voltage measurements, we estimated accuracy variations in MNIST pattern recognition using a two-layer perceptron model. These results not only identify a promising RS device architecture based on the sol–gel process but also offer valuable insights into the aging behavior of QLEDs incorporating ZnMgO/ZnO bilayers, ITO, and Al electrodes. Full article
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12 pages, 2455 KB  
Article
Reconfigurable All-Optical Synapse Based on Photonic Crystal Nanobeam Cavities with Ferroelectric Carrier Injection Valve
by Duomao Li, Han Xie, Danyang Yao, Erqi Zhang, Jiaren Song, Youbin Wang, Yiwei Zhang, Xu Ran, Dongming Fang, Xiaoli Lu, Xiaohua Ma and Yue Hao
Photonics 2025, 12(9), 871; https://doi.org/10.3390/photonics12090871 - 29 Aug 2025
Viewed by 718
Abstract
Synaptic activity is fundamental to memory and learning in the nervous system. However, most artificial synaptic devices are limited to mimicking static plasticity, and tunable plasticity has not been achieved at the device level. Here, we introduce a dynamic all-optical synapse based on [...] Read more.
Synaptic activity is fundamental to memory and learning in the nervous system. However, most artificial synaptic devices are limited to mimicking static plasticity, and tunable plasticity has not been achieved at the device level. Here, we introduce a dynamic all-optical synapse based on photonic crystal nanobeam cavities with a ferroelectric carrier injection valve. By leveraging the nonlinear and ferroelectric electrostatic doping effects in silicon, integrated with Hf0.5Zr0.5O2 (HZO) film as the ferroelectric layer and indium tin oxide (ITO) as the top electrode, we enhance linearity and reduce power consumption. Increasing the bias voltage further improves linearity while decreasing power consumption. This innovation offers a promising pathway for developing energy-efficient nanophotonic devices in neuromorphic computing. Full article
(This article belongs to the Special Issue Silicon Photonics: From Fundamentals to Future Directions)
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26 pages, 5342 KB  
Article
Spectroscopy of ITO Films in Optical and Terahertz Spectral Ranges
by Vladimir V. Bassarab, Vadim A. Shalygin, Alexey A. Shakhmin and Grigory I. Kropotov
Appl. Sci. 2025, 15(16), 9121; https://doi.org/10.3390/app15169121 - 19 Aug 2025
Viewed by 486
Abstract
In the present study, the reflection and transmission of radiation in submicron indium tin oxide (ITO) films deposited on a borosilicate glass substrate are experimentally investigated for a wide spectral range, including ultraviolet, visible, infrared and terahertz regions. Theoretical modeling of the spectra [...] Read more.
In the present study, the reflection and transmission of radiation in submicron indium tin oxide (ITO) films deposited on a borosilicate glass substrate are experimentally investigated for a wide spectral range, including ultraviolet, visible, infrared and terahertz regions. Theoretical modeling of the spectra is performed using the transfer matrix method. The interaction of electromagnetic radiation with ITO is considered in the framework of the Drude model. The simulated spectra are in good agreement with the experimental ones. New non-destructive methods for determining the ITO film parameters (sheet resistivity, thickness, electron concentration and mobility) have been developed. They are based on a fitting procedure for reflectivity and/or transmittance spectra. Full article
(This article belongs to the Section Optics and Lasers)
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14 pages, 2905 KB  
Article
Optimal Design of a Lightweight Terahertz Absorber Featuring Ultra-Wideband Polarization-Insensitive Characteristics
by Yafeng Hao, Tengteng Li, Pu Zhu, Fupeng Ma, Huijia Wu, Cheng Lei, Meihong Liu, Ting Liang and Jianquan Yao
Photonics 2025, 12(8), 787; https://doi.org/10.3390/photonics12080787 - 4 Aug 2025
Cited by 1 | Viewed by 1285
Abstract
Metamaterial absorbers in terahertz (THz) based bands have garnered significant attention for their potential applications in military stealth, terahertz imaging, and other fields. Nevertheless, the limited bandwidth, low absorption rate, and heavy weight greatly reduce the further development and wide application of terahertz [...] Read more.
Metamaterial absorbers in terahertz (THz) based bands have garnered significant attention for their potential applications in military stealth, terahertz imaging, and other fields. Nevertheless, the limited bandwidth, low absorption rate, and heavy weight greatly reduce the further development and wide application of terahertz absorbers. To solve these problems, we propose a polystyrene (PS)-based ultra-broadband metamaterial absorber integrated with a polyethylene terephthalate (PET) double-sided adhesive layer and a patterned indium tin oxide (ITO) film through the simulation method, which operates in the THz band. The electromagnetic wave absorption properties and underlying physical absorption mechanisms of the proposed metamaterial absorbers are comprehensively modeled and rigorously numerically simulated. The research demonstrates the metamaterial absorber can achieve absorption performance of over 90% for fully polarized incident waves in the ultra-wideband range of 1.2–10 THz, especially achieving perfect absorption characteristics of over 99.9% near 1.8–1.9 THz and 5.8–6.2 THz. The proposed absorber has a lightweight physical property of 0.7 kg/m2 and polarization-insensitive characteristic, and it achieves a broad-angle that allows a range of incidence angles up to 60°. The simulation research results of this article provide theoretical support for the design of terahertz absorbers with ultra-wideband absorption characteristics. Full article
(This article belongs to the Special Issue Metamaterials and Nanophotonics: Fundamentals and Applications)
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24 pages, 1483 KB  
Review
Towards AZO Thin Films for Electronic and Optoelectronic Large-Scale Applications
by Elena Isabela Bancu, Valentin Ion, Stefan Antohe and Nicu Doinel Scarisoreanu
Crystals 2025, 15(8), 670; https://doi.org/10.3390/cryst15080670 - 23 Jul 2025
Viewed by 1159
Abstract
Transparent conductive oxides (TCOs) have become essential components in a broad range of modern devices, including smartphones, flat-panel displays, and photovoltaic cells. Currently, indium tin oxide (ITO) is used in approximately 90% of these devices. However, ITO prices continue to rise due to [...] Read more.
Transparent conductive oxides (TCOs) have become essential components in a broad range of modern devices, including smartphones, flat-panel displays, and photovoltaic cells. Currently, indium tin oxide (ITO) is used in approximately 90% of these devices. However, ITO prices continue to rise due to the limited supply of indium (In), making the development of alternative materials for TCOs indispensable. Therefore, this study highlights the latest advances in creating new, affordable materials, with a focus on aluminum-doped zinc oxide (AZO). Over the last few decades, this material has been widely studied to improve its physical properties, particularly its low electrical resistivity, which can affect the performance of various devices. Now, it is close to replacing ITO due to several advantages including cost-effectiveness, stability under hydrogen plasma, low processing temperatures, and lack of toxicity. Besides that, in comparison to other TCOs such as IZO, IGZO, or IZrO, AZO achieved a low electrical resistivity (10−5 ohm cm) while maintaining a high transparency across the visible spectrum (over 85%). Additionally, due to the increasing development of technologies utilizing such materials, it is essential to develop more effective techniques for producing TCOs on a larger scale. Additionally, due to the increasing development of technologies utilizing such materials, it is essential to develop more effective techniques for producing TCOs on a larger scale. This review emphasizes the potential of AZO as a cost-effective and scalable alternative to ITO, highlighting key advancements in deposition techniques such as pulsed laser deposition (PLD). Full article
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28 pages, 14374 KB  
Article
Novel Airfoil-Shaped Radar-Absorbing Inlet Grilles on Aircraft Incorporating Metasurfaces: Multidisciplinary Design and Optimization Using EHVI–Bayesian Method
by Xufei Wang, Yongqiang Shi, Qingzhen Yang, Huimin Xiang and Saile Zhang
Sensors 2025, 25(14), 4525; https://doi.org/10.3390/s25144525 - 21 Jul 2025
Viewed by 558
Abstract
Aircraft, as electromagnetically complex targets, have radar cross-sections (RCSs) that are influenced by various factors, with the inlet duct being a critical component that often serves as a primary source of electromagnetic scattering, significantly impacting the scattering characteristics. In light of the conflict [...] Read more.
Aircraft, as electromagnetically complex targets, have radar cross-sections (RCSs) that are influenced by various factors, with the inlet duct being a critical component that often serves as a primary source of electromagnetic scattering, significantly impacting the scattering characteristics. In light of the conflict between aerodynamic performance and electromagnetic characteristics in the design of aircraft engine inlet grilles, this paper proposes a metasurface radar-absorbing inlet grille (RIG) solution based on a NACA symmetric airfoil. The RIG adopts a sandwich structure consisting of a polyethylene terephthalate (PET) dielectric substrate, a copper zigzag metal strip array, and an indium tin oxide (ITO) resistive film. By leveraging the principles of surface plasmon polaritons, electromagnetic wave absorption can be achieved. To enhance the design efficiency, a multi-objective Bayesian optimization framework driven by the expected hypervolume improvement (EHVI) is constructed. The results show that, compared with a conventional rectangular cross-section grille, an airfoil-shaped grille under the same constraints will reduce both aerodynamic losses and the absorption bandwidth. After 100-step EHVI–Bayesian optimization, the optimized balanced model attains a 57.79% reduction in aerodynamic loss relative to the rectangular-shaped grille, while its absorption bandwidth increases by 111.99%. The RCS exhibits a reduction of over 8.77 dBsm in the high-frequency band. These results confirm that the proposed optimization design process can effectively balance the conflict between aerodynamic performance and stealth performance for RIGs, reducing the signal strength of aircraft engine inlets. Full article
(This article belongs to the Section Electronic Sensors)
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13 pages, 3688 KB  
Article
Layer-by-Layer Engineered Zinc–Tin Oxide/Single-Walled Carbon Nanotube (ZTO/SWNT) Hybrid Films for Thin-Film Transistor Applications
by Yong-Jae Kim, Young-Jik Lee, Yeon-Hee Kim, Byung Seong Bae and Woon-Seop Choi
Micromachines 2025, 16(7), 825; https://doi.org/10.3390/mi16070825 - 20 Jul 2025
Viewed by 828
Abstract
Indium-based oxide semiconductors have been commercialized because of their excellent electrical properties, but the high cost, limited availability, and environmental toxicity of indium necessitate the development of alternative materials. Among the most promising candidates, zinc–tin oxide (ZTO) is an indium-free oxide semiconductor with [...] Read more.
Indium-based oxide semiconductors have been commercialized because of their excellent electrical properties, but the high cost, limited availability, and environmental toxicity of indium necessitate the development of alternative materials. Among the most promising candidates, zinc–tin oxide (ZTO) is an indium-free oxide semiconductor with considerable potential, but its relatively low carrier mobility and inherent limitations in thin-film quality demand further performance enhancements. This paper proposes a new approach to overcome these challenges by incorporating single-walled carbon nanotubes (SWNTs) as conductive fillers into the ZTO matrix and using a layer-by-layer multiple coating process to construct nanocomposite thin films. As a result, ZTO/SWNTs (0.07 wt.%) thin-film transistors (TFTs) fabricated with three coating cycles exhibited a high saturation mobility of 18.72 cm2/V·s, a threshold voltage of 0.84 V, and a subthreshold swing of 0.51 V/dec. These values represent an approximately four-fold improvement in mobility compared to ZTO TFT, showing that the multiple-coating-based nanocomposite strategy can effectively overcome the fundamental limitations. This study confirms the feasibility of achieving high-performance oxide semiconductor transistors without indium, providing a sustainable pathway for next-generation flexible electronics and display technologies. Full article
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18 pages, 5775 KB  
Article
Precision Solar Spectrum Filtering in Aerogel Windows via Synergistic ITO-Ag Nanoparticle Doping for Hot-Climate Energy Efficiency
by Huilin Yang, Maoquan Huang, Mingyang Yang, Xuankai Zhang and Mu Du
Gels 2025, 11(7), 553; https://doi.org/10.3390/gels11070553 - 18 Jul 2025
Viewed by 456
Abstract
Windows are a major contributor to energy loss in buildings, particularly in hot climates where solar radiation heat gain significantly increases cooling demand. An ideal energy-efficient window must maintain high visible light transmittance while effectively blocking ultraviolet and near-infrared radiation, presenting a significant [...] Read more.
Windows are a major contributor to energy loss in buildings, particularly in hot climates where solar radiation heat gain significantly increases cooling demand. An ideal energy-efficient window must maintain high visible light transmittance while effectively blocking ultraviolet and near-infrared radiation, presenting a significant challenge for material design. We propose a plasma silica aerogel window utilizing the local surface plasmon resonance effect of plasmonic nanoparticles. This design incorporates indium tin oxide (ITO) nanospheres (for broad-band UV/NIR blocking) and silver (Ag) nanocylinders (targeted blocking of the 0.78–0.9 μm NIR band) co-doped into the silica aerogel. This design achieves a visible light transmittance of 0.8, a haze value below 0.12, and a photothermal ratio of 0.91. Building simulations indicate that compared to traditional glass, this window can achieve annual energy savings of 20–40% and significantly reduce the economic losses associated with traditional glass, providing a feasible solution for sustainable buildings. Full article
(This article belongs to the Section Gel Applications)
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14 pages, 3096 KB  
Article
Photoelectrochemical CO2 Reduction Measurements of a BiOI Coating Deposited onto a Non-Conductive Glass Support as a Platform for Environmental Remediation
by J. Manuel Mora-Hernandez and A. Hernández-Ramírez
Processes 2025, 13(7), 2292; https://doi.org/10.3390/pr13072292 - 18 Jul 2025
Viewed by 724
Abstract
Aiming to contribute to environmental remediation strategies, this work proposes a novel fabrication of photoelectrocatalytic electrodes containing a BiOI coating deposited onto non-conductive glass (NCG) for CO2 conversion applications. When BiOI electrodes are not deposited onto fluorine-doped tin oxide (FTO) or indium [...] Read more.
Aiming to contribute to environmental remediation strategies, this work proposes a novel fabrication of photoelectrocatalytic electrodes containing a BiOI coating deposited onto non-conductive glass (NCG) for CO2 conversion applications. When BiOI electrodes are not deposited onto fluorine-doped tin oxide (FTO) or indium tin oxide (ITO) conductive supports, the electrochemical measurements enable the registration of the (photo)electrochemical response for bare BiOI, thereby excluding remnant signals from the conductive supports and reporting an exclusive and proper photoelectrocatalytic BiOI response. A systematic procedure was carried out to improve the physicochemical properties of BiOI through a simple variation in the amount of reagents employed in a solvothermal synthesis, thus increasing the crystallite size and surface area of the resulting material (BiOI-X3-20wt.%). The tailored BiOI coating on a non-conductive support showed activity in performing CO2 photoelectroreduction under UV–Vis irradiation in aqueous media. Finally, the BiOI-X3-20wt.% sample was evaluated for photocatalytic CO2 conversion in gaseous media, producing CO as the primary reaction product. This study confirms that BiOI is a suitable and easily synthesized material, with potential applications for CO2 capture and conversion when employed as a photoactive coating for environmental remediation. Full article
(This article belongs to the Special Issue Advanced Application of Photoelectrocatalysis for Energy Conversion)
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33 pages, 7442 KB  
Review
Transparent Electrodes Based on Crack-Templated Metallic Networks for Next-Generation Optoelectronics
by Eleonora Sofia Cama, Mariacecilia Pasini, Francesco Galeotti and Umberto Giovanella
Materials 2025, 18(13), 3091; https://doi.org/10.3390/ma18133091 - 30 Jun 2025
Viewed by 946
Abstract
Transparent conductive electrodes (TCEs) are essential components in modern optoelectronic devices, including organic light-emitting diodes and solar cells, sensors, and flexible displays. Indium tin oxide has been the dominant material for TCEs due to its high transparency and conductivity. However, its brittleness, high [...] Read more.
Transparent conductive electrodes (TCEs) are essential components in modern optoelectronic devices, including organic light-emitting diodes and solar cells, sensors, and flexible displays. Indium tin oxide has been the dominant material for TCEs due to its high transparency and conductivity. However, its brittleness, high cost, and increasingly limited availability pose significant challenges for electronics. Crack-template (CT)-assisted fabrication has emerged as a promising technique to develop metal mesh-based TCEs with superior mechanical flexibility, high conductivity, and excellent optical transmittance. This technique leverages the spontaneous formation of random and continuous microcrack networks in sacrificial templates, followed by metal deposition (e.g., Cu, Ag, Al, etc.), to produce highly conductive, scalable, and low-cost electrodes. Various crack formation strategies, including controlled drying of polymer suspensions, mechanical strain engineering, and thermal processing, have been explored to tailor electrode properties. Recent studies have demonstrated that crack-templated TCEs can achieve transmittance values exceeding 85% and sheet resistances below 10 Ω/sq, with mesh line widths as low as ~40 nm. Moreover, these electrodes exhibit enhanced stretchability and robustness under mechanical deformation, outperforming ITO in bend and fatigue tests. This review aims to explore recent advancements in CT engineering, highlighting key fabrication methods, performance metrics across different metals and substrates, and presenting examples of its applications in optoelectronic devices. Additionally, it will examine current challenges and future prospects for the widespread adoption of this emerging technology. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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14 pages, 3702 KB  
Article
A High-Sensitivity U-Shaped Optical Fiber SPR Sensor Based on ITO Coating
by Chuhan Ye, Zhibo Li, Wenhao Kang and Lei Hou
Sensors 2025, 25(13), 3911; https://doi.org/10.3390/s25133911 - 23 Jun 2025
Viewed by 639
Abstract
This paper proposes a high-sensitivity U-shaped optical fiber sensor based on indium tin oxide (ITO) for surface plasmon resonance (SPR) sensing. Finite element simulations reveal that introducing ITO enhances the surface electric field strength by 1.15× compared to conventional designs, directly boosting sensitivity. [...] Read more.
This paper proposes a high-sensitivity U-shaped optical fiber sensor based on indium tin oxide (ITO) for surface plasmon resonance (SPR) sensing. Finite element simulations reveal that introducing ITO enhances the surface electric field strength by 1.15× compared to conventional designs, directly boosting sensitivity. The U-shaped structure optimizes evanescent wave–metal film interaction, further improving performance. In an external refractive index (RI) range of 1.334–1.374 RIU, the sensor achieves a sensitivity of 4333 nm/RIU (1.85× higher than traditional fiber sensors) and a figure of merit (FOM) of 21.7 RIU−1 (1.68× improvement). Repeatability tests show a low relative standard deviation (RSD) of 0.4236% for RI measurements, with a maximum error of 0.00018 RIU, confirming excellent stability. The ITO coating’s strong adhesion ensures long-term reliability. With its simple structure, ease of fabrication, and superior sensitivity/FOM, this SPR sensor is well-suited for high-precision biochemical detection in intelligent sensing systems. Full article
(This article belongs to the Special Issue Feature Papers in Optical Sensors 2025)
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21 pages, 4516 KB  
Article
Exploring the Electrochemical Signatures of Heavy Metals on Synthetic Melanin Nanoparticle-Coated Electrodes: Synthesis and Characterization
by Mohamed Hefny, Rasha Gh. Orabi, Medhat M. Kamel, Haitham Kalil, Mekki Bayachou and Nasser Y. Mostafa
Appl. Nano 2025, 6(3), 11; https://doi.org/10.3390/applnano6030011 - 23 Jun 2025
Viewed by 1005
Abstract
This study investigates the development and sensing profile of synthetic melanin nanoparticle-coated electrodes for the electrochemical detection of heavy metals, including lead (Pb), cadmium (Cd), cobalt (Co), zinc (Zn), nickel (Ni), and iron (Fe). Synthetic melanin films were prepared in situ by the [...] Read more.
This study investigates the development and sensing profile of synthetic melanin nanoparticle-coated electrodes for the electrochemical detection of heavy metals, including lead (Pb), cadmium (Cd), cobalt (Co), zinc (Zn), nickel (Ni), and iron (Fe). Synthetic melanin films were prepared in situ by the deacetylation of diacetoxy indole (DAI) to dihydroxy indole (DHI), followed by the deposition of DHI monomers onto indium tin oxide (ITO) and glassy carbon electrodes (GCE) using cyclic voltammetry (CV), forming a thin layer of synthetic melanin film. The deposition process was characterized by electrochemical quartz crystal microbalance (EQCM) in combination with linear sweep voltammetry (LSV) and amperometry to determine the mass and thickness of the deposited film. Surface morphology and elemental composition were examined using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). In contrast, Fourier-transform infrared (FTIR) and UV–Vis spectroscopy confirmed the melanin’s chemical structure and its polyphenolic functional groups. Differential pulse voltammetry (DPV) and amperometry were employed to evaluate the melanin films’ electrochemical activity and sensitivity for detecting heavy metal ions. Reproducibility and repeatability were rigorously assessed, showing consistent electrochemical performance across multiple electrodes and trials. A comparative analysis of ITO, GCE, and graphite electrodes was conducted to identify the most suitable substrate for melanin film preparation, focusing on stability, electrochemical response, and metal ion sensing efficiency. Finally, the applicability of melanin-coated electrodes was tested on in-house heavy metal water samples, exploring their potential for practical environmental monitoring of toxic heavy metals. The findings highlight synthetic melanin-coated electrodes as a promising platform for sensitive and reliable detection of iron with a sensitivity of 106 nA/ppm and a limit of quantification as low as 1 ppm. Full article
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12 pages, 1611 KB  
Article
Influence of Deposition Time on Properties of Se-Doped CdTe Thin Films for Solar Cells
by Ibrahim M. Beker, Francis B. Dejene, Lehlohonolo F. Koao, Jacobus J. Terblans and Habtamu F. Etefa
Crystals 2025, 15(7), 589; https://doi.org/10.3390/cryst15070589 - 22 Jun 2025
Viewed by 496
Abstract
Se-doped CdTe thin films were grown employing a simple two-electrode electrochemical deposition method using glass/tin-doped indium oxide (glass/ITO). Cadmium acetate dihydrate [Cd (CH3CO2)2. 2H2O], selenium dioxide (SeO2), and tellurium dioxide (TeO2) [...] Read more.
Se-doped CdTe thin films were grown employing a simple two-electrode electrochemical deposition method using glass/tin-doped indium oxide (glass/ITO). Cadmium acetate dihydrate [Cd (CH3CO2)2. 2H2O], selenium dioxide (SeO2), and tellurium dioxide (TeO2) were used as precursors. Instruments including X-ray diffraction for structural investigation, UV-Vis spectrophotometry for optical properties, and scanning probe microscopy for morphological properties were employed to investigate the physico-chemical characteristics of the resulting Se-doped CdTe thin-film. The films are polycrystalline with a cubic phase, according to X-ray diffraction (XRD) data. More ions are deposited on the substrate, which makes the material more crystalline and intensifies the characteristic peaks that are seen. It is observed from the acquired optical characterization that the film’s bandgap is greatly influenced by the deposition time. The bandgap dropped from 1.92 to 1.62 as the deposition period increased from 25 to 45 min, making the film more transparent and absorbing less light at shorter deposition durations. Images from scanning electron microscopy (SEM) show that the surface morphology is homogenous with closely packed grains and that the grain forms become less noticeable as the deposition time increases. This work is novel in that it investigates the influence of the deposition time on the structural, optical, and morphological properties of Se-doped CdTe thin films deposited using a cost-effective, simplified two-electrode electrochemical method—a fabrication route that remains largely unexplored for this material system. Full article
(This article belongs to the Section Materials for Energy Applications)
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