Search Results (707)

Battery electric vehicle (BEV) fires in road tunnels can intensify thermal, smoke transport, visibility, and CO exposure hazards under confined ventilation. This study evaluated the combined mitigation performance of water mist and semi-transverse mechanical ventilation. A three-dimensional PyroSim/FDS model of a 200 m × 10 m × 5 m tunnel was established with a 7 MW BEV design fire at the midpoint. The prescribed-source model was assessed against a reduced-scale lithium-ion battery tunnel experiment; at the representative monitoring location, the simulated temperature history reproduced the main trend, with deviations of approximately 7% and 10% at the first and second peaks. Thirty-six coupled cases examined ventilation mode, nominal opening velocity, nozzle arrangement and spacing, flow rate input, droplet diameter, and spray cone angle. Supply ventilation improved hot-smoke-layer cooling and visibility, whereas exhaust ventilation more effectively reduced the local CO volume fraction. Under the baseline weighting scheme, the highest-ranked case reduced the peak local ceiling-region and near-fire gas temperatures by 77.8% and 82.2%, increased average visibility during 200–500 s by 42.9%, and achieved a comprehensive relative mitigation index (CRMI) of 56.6%. Two supplementary nominal 10 MW simulations showed that this case retained substantial thermal control, reducing the two peak temperatures by 65.7% and 74.1%, but did not improve local visibility or CO. Thus, the thermal-mitigation trend persisted at the higher nominal input, whereas the full multi-hazard ranking was not transferable across fire sizes. Full article

Masu salmon (Oncorhynchus masou) is an ecologically and economically important cold-water salmonid in East Asia that exhibits diverse life-history forms. To compare population-level genomic variation and patterns of homozygosity among fish from different sources, we analyzed whole-genome resequencing data from 465 individuals representing one field-collected Tumen River population (TM) and two landlocked cultured populations from Chicheng (CC) and Yanji (YJ). After quality control, 6,220,980 high-quality SNPs were retained. Population-specific filtering identified 5,589,828, 3,545,209, and 4,975,751 polymorphic SNPs in CC, TM, and YJ, respectively; although SNP numbers differed, approximately 91% of variants in each population were located in intronic or intergenic regions. Principal component analysis, ADMIXTURE, and distance-based neighbor-joining analysis clearly distinguished the three populations, with CC and YJ showing the closest genetic relationship. Pairwise $F_{\mathrm{ST}}$ was lowest between CC and YJ and highest between TM and YJ. CC exhibited the highest linkage disequilibrium, whereas TM showed the fastest LD decay and the lowest nucleotide diversity and heterozygosity. Runs of homozygosity (ROH) burden was highest in TM, intermediate in CC, and lowest in YJ. TM had the highest number of ROHs, cumulative ROH length, and $F_{\mathrm{ROH}}$, and ROHs longer than 5 Mb were detected only in this population. CC had an intermediate ROH burden dominated by short segments, whereas YJ had the lowest ROH-based genomic inbreeding. The high and heterogeneous ROH burden in TM indicates elevated genome-wide homozygosity among the sampled fish but does not, by itself, demonstrate recent inbreeding throughout the population. Candidate ROH islands and their annotated genes showed limited overlap among populations. Candidate genes in TM were primarily associated with ion regulation, neural processes, and energy metabolism, whereas those in CC and YJ shared broad functional categories involving development, muscle organization, nutrient transport, and neural regulation but differed in most specific genes. These regions and genes should be regarded as exploratory, hypothesis-generating candidates rather than evidence of selection or causality. Overall, this study reveals distinct population genomic characteristics and ROH patterns among masu salmon populations of different origins and provides a basis for future germplasm conservation and genetic management. Full article

Deep eutectic solvents (DESs) are promising electrolyte media for solar redox flow batteries, but their high viscosity and sluggish ion transport can limit redox-species diffusion, interfacial charge transfer, and photocharging performance. This study aimed to regulate a TEMPO/VCl₃-based DES electrolyte by controlled water addition for a Yb,Er-doped TiO₂–g-C₃N₄ photoanode solar redox flow battery. DES electrolytes containing 0, 5, 10, and 15 wt% added water were evaluated by physicochemical, electrochemical, and photoelectrochemical measurements, while full-cell tests compared pristine DES with the half-cell-selected 10 wt% electrolyte. While water incorporation systematically enhanced bulk redox-species transport, the optimal photoelectrochemical performance was achieved at 10 wt% water, rather than 15 wt%. Although the 15 wt% electrolyte exhibited the highest bulk diffusivity, the 10 wt% composition provided the most favorable balance between mass transport and interfacial charge transfer kinetics. The Raman spectra supported water-induced reorganization of the bulk DES hydrogen-bonding network. Full-cell tests confirmed that the 10 wt% water-containing electrolyte delivered higher and more stable photocharging responses than pristine DES over 20 cycles. These results indicate that moderate water regulation is an effective strategy for improving DES-based solar redox flow batteries. Full article

Xylem, a critical vascular tissue extensively distributed in stems and roots, plays indispensable roles in horticultural plant development. It facilitates water and mineral transport, provides mechanical support through secondary cell wall lignification, and precisely modulates ion homeostasis (e.g., Na⁺/K⁺ balance), thereby enhancing plant resilience to abiotic stresses. Consequently, xylem function directly impacts crop yield and quality. Recent breakthroughs in molecular biology have significantly advanced our understanding of the regulatory networks governing xylem development, including key transcription factors, hormonal signaling pathways (particularly auxin, cytokinin, and brassinosteroids), and their interactions with environmental cues. This review systematically summarizes current progress on the molecular mechanisms underlying xylem differentiation, secondary wall biosynthesis, and stress-responsive vascular adaptation in horticultural species. We further discuss emerging research frontiers, existing technical challenges, and prospective directions, aiming to provide a theoretical framework for genetic improvement and precision cultivation of horticultural crops. Full article

This study presents a first-principles dynamic model for the electrochemical production of lithium hydroxide (LiOH) in a bench-scale cation exchange membrane (CEM) cell. Its distinguishing feature is a single, dynamically coupled description of the whole cell, in which the lumped Ordinary Differential Equation (ODE) dynamics of the anodic and cathodic chambers are coupled to a spatially resolved Nernst–Planck (PDE) model of membrane ion transport. The model resolves the transient induction period of ion crossover and captures the association kinetics of Li⁺ and ${\mathrm{OH}}^{-}$, cathodic water reduction, and the back-migration and neutralization of ${\mathrm{OH}}^{-}$ at the anode, with the local electric field represented by a non-linear potential gradient. Solved by the Method of Lines and reduced through symbolic treatment of the Robin boundary conditions to a consistent ODE system, it yields a numerically robust framework for this stiff, strongly coupled problem. Two process-level results emerge: the membrane strongly attenuates cross-chamber disturbances, largely decoupling the anode and cathode, and it reaches a quasi-steady state far faster than the bulk chambers—a separation of time scales expected to widen at larger volume-to-surface-area ratios. These insights inform scale-up strategies and multiscale control architectures for the cell. Full article

The efficient removal of antibiotic contaminants from aquatic systems remains a significant challenge due to their persistence and complex environmental matrices. In this study, a CuO-loaded biochar (CuO–BC) composite was developed as an efficient catalyst for peroxydisulfate (PDS) activation toward ciprofloxacin (CIP) degradation. The CuO–BC exhibited superior catalytic performance, achieving rapid CIP removal over a wide pH range with strong resistance to coexisting ions. Mechanistic investigations revealed that both radical (SO₄•⁻ and •OH) and non-radical pathways (¹O₂ and electron transfer) contributed to CIP degradation. Quenching experiments, electron paramagnetic resonance (EPR), and probe analyses confirmed the coexistence of multiple reactive oxygen species (ROS), with interfacial electron transfer between Cu species and biochar appearing to play a significant role. The synergistic coupling of Cu²⁺/Cu⁺ redox cycling and the conductive biochar matrix facilitated efficient electron transport and selective ROS generation. Furthermore, the system was successfully applied in a simulated permeable reactive barrier (PRB), exhibiting stable degradation performance under continuous-flow conditions. This study provides new insights into interfacial PDS activation mechanisms and offers a promising strategy for designing efficient catalytic systems for antibiotic removal in complex water environments. Full article

The growing use of PET strapping in packaging has increased plastic waste, prompting interest in its reuse in cement-based materials. This study evaluates waste PET strapping powder as a partial replacement for natural sand in cement mortar. Mortars were prepared with three water–cement ratios (0.4, 0.5, and 0.6) and four replacement levels (0%, 5%, 10%, and 15%). Slump, flow, compressive strength, flexural strength, ultrasonic pulse velocity (UPV), four-point resistivity, and sulphate resistance were examined at different curing ages. Increasing PET content reduced slump and flow, indicating lower workability. It also decreased compressive and flexural strengths, with flexural strength showing a greater reduction. UPV declined as PET replacement increased, which was attributed to the combined effects of acoustic-property contrast between PET and the cementitious matrix, interfacial wave scattering, and local microstructural defects. However, PET increased electrical resistivity and reduced sulphate-related weight loss, indicating lower continuity of ion-conducting pathways and potentially improved resistance to the transport of aggressive ions under the adopted test conditions. SEM observations showed limited interfacial defects at 5% PET, whereas higher contents produced a more porous interfacial transition zone. Overall, the mix with 5% PET and W/C = 0.5 showed the best balance of properties, supporting the reuse of PET strapping powder as a sustainable sand replacement. Full article

Concentration polarization is a common phenomenon in membrane separation processes and generally impairs mass transfer efficiency. Electrodialysis (ED) is considered a promising technology for concentrating high-salinity solutions used in air-conditioning systems; however, concentration polarization under high-concentration operating conditions remains insufficiently understood. In this study, a numerical framework combining a simplified model and a coupled transport model was developed to characterize concentration distributions within an ED concentrate channel. The effects of flow velocity, current density, and feed concentration on concentration profiles were systematically investigated. The results show that transmembrane water transport plays an important role in concentration polarization, and neglecting this effect leads to significant overestimation of ion concentration near the membrane surface. Although ion concentration increases markedly in the vicinity of the ion-exchange membranes, it remains nearly constant in the bulk region along the flow direction. Based on this non-uniform concentration distribution, a conceptual ED configuration with separated flow channels was proposed and evaluated. The results indicate that selectively extracting the enriched boundary-layer region can enhance the outlet concentration of the product stream, whereas increasing the intermediate channel width reduces volumetric yield, revealing a clear trade-off between concentration enhancement and production capacity. Full article

Collagen is widely used in the cosmetics industry as an active ingredient in skin-care formulations due to its biocompatibility, biodegradability, low antigenicity, and high biological activity. As a natural humectant, collagen binds water molecules within the skin, reduces transepidermal water loss, and helps maintain skin elasticity and hydration. Despite its broad application, the influence of collagen on epithelial ion transport remains insufficiently understood. This study evaluated the effect of a gel containing triple-helical collagen on sodium and chloride ion transport in the isolated rabbit skin. The collagen gel was applied to 25 skin specimens for 24 h and compared with 30 untreated control specimens. Electrophysiological analyses included measurements of transepithelial electrical potential (PD), electrical resistance (R), and potential changes during stimulation (PDmin and PDmax). Collagen gel significantly decreased R compared with control tissues, indicating altered tissue permeability. Collagen gel-treated tissues also exhibited a significantly more electropositive PDmin than controls, whereas PDmax values remained comparable between groups, suggesting that electrophysiological responsiveness was maintained under the experimental conditions. The observed electropositive shift in PDmin may reflect altered sodium ion transport. Whether these electrophysiological changes are associated with changes in tissue hydration requires direct investigation. Full article

The transport of metal ions from highly saline matrices remains challenging due to the elevated ionic strength and complex chemical speciation that characterize seawater and desalination brines. In this work, the influence of membrane composition on Cd(II) transport through polymer inclusion membranes (PIMs) was evaluated using cellulose triacetate (CTA), poly(vinyl chloride) (PVC), and poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) membranes containing Aliquat 336. Membranes were tested using model NaCl solutions, seawater, and desalination brine, and the effects of membrane mass, polymer matrix, carrier/plasticizer composition, and receiving phase were investigated. Reducing the CTA membrane mass by 50% did not significantly affect transport efficiency, indicating that membrane composition had a greater influence on Cd(II) transport than membrane mass under the conditions evaluated. Among the evaluated formulations, the optimum PVDF-HFP membrane contained 60 wt.% PVDF-HFP, 30 wt.% Aliquat 336, and 10 wt.% butyl stearate (BTS), achieving a transport efficiency of 95.5% and an initial flux of 2.7 × 10⁻⁶ mol m⁻² s⁻¹ in desalination brine. The use of 0.5 M HNO₃ as the receiving phase markedly improved Cd(II) transport in both synthetic saline solutions and real seawater and desalination brine compared with ultrapure water. These results highlight the importance of polymer–plasticizer interactions in controlling Cd(II) transport and demonstrate the potential of PVDF-HFP/Aliquat 336/BTS membranes for metal recovery from complex saline media. Full article

Inorganic scale deposition in crude oil–water transport trunklines is a formidable flow assurance challenge, uniquely exacerbated in extensive gathering networks where multiple production flowlines commingle multiphase fluids. As some fields experience progressively higher water cuts, the mixing of incompatible waters, characterized by diverse thermodynamic profiles and varying concentrations of scaling ions (Ca²⁺, Ba²⁺, Sr²⁺, ${\mathrm{SO}}_4^{2-}$, ${\mathrm{CO}}_3^{2-}$, etc.) triggers severe precipitation. This comprehensive literature review synthesizes seminal and contemporary studies to critically evaluate the state-of-the-art methodologies for assessing scaling risks in these intricate systems. Progressing chronologically and thematically, the analysis details the transition from static, bulk-fluid thermodynamic equilibrium calculations to dynamic, high-fidelity deterministic and probabilistic approaches. These advanced frameworks include Reactive Transport Modeling (RTM), Computational Fluid Dynamics (CFD), and Machine Learning (ML) architectures. Special emphasis is placed on the mathematical governing equations that dictate trunkline-specific phenomena: multi-stream commingling, non-isothermal gradients, probabilistic kinetic induction, and the profound impact of turbulent transport (turbophoresis) on crystal attachment and wall shear detachment. Finally, an integrated, multi-tier flow assurance workflow is proposed to guide future field-scale risk management and digital twin deployment. Full article

A simple and cost-effective graphite paste electrode modified with 5-(4-aminophenyl)-4-amino-1,2,4-triazole-3(2H)-thione was developed for the selective voltammetric determination of Cu(II) ions in environmental water samples. The N,S-donor ligand was incorporated into a graphite–polystyrene matrix without the use of nanomaterials, providing a reproducible and straightforward electrode fabrication route. Scanning electron microscopy revealed a rough, porous surface morphology with an enhanced electroactive surface area of 0.065 cm², approximately twice the geometric area. Electrochemical impedance spectroscopy confirmed diffusion-controlled mass transport, while cyclic voltammetry indicated quasi-reversible behaviour of the Cu(II)/Cu(0) redox system with a linear dependence of peak current on the square root of the scan rate. Differential pulse voltammetry under optimised conditions (0.1 mol·L⁻¹ H₂SO₄, pH 1.0–1.2) yielded a linear analytical response over the concentration range of 0.01–0.4 μmol·L⁻¹ (R² = 0.99507), with a limit of detection of 0.02 μmol·L⁻¹ and a limit of quantification of 0.06 μmol·L⁻¹—well below the WHO guideline for copper in drinking water. The sensing mechanism involves selective N,S-bidentate coordination of Cu(II) at the electrode surface, followed by electrochemical reduction, as supported by FT-IR spectroscopic evidence. The sensor demonstrated good selectivity toward Cu(II) in the presence of common interfering metal ions at up to 20-fold excess. The method was successfully validated against ICP-OES (recovery 99.8%, RSD < 0.33%) and confirmed by spike–recovery experiments (99.0–99.5%), confirming its practical applicability for trace-level environmental monitoring. The modified electrode retained approximately 93% of its initial response after 30 consecutive measurements and 91% after 14 days of storage, demonstrating good operational stability. Full article

Saline–alkali stress severely restricts cucumber (Cucumis sativus L.) growth by disrupting ion balance, water status, photosynthesis, and redox homeostasis. Here, we examined the effects of exogenous selenium (Se) on cucumber seedlings exposed to NaHCO₃ stress. Se supplementation improved plant growth and root activity and partly restored photosynthetic performance by maintaining chlorophyll content, gas exchange, and chlorophyll fluorescence. Se reduced oxidative injury through lower ROS and MDA levels and by enhancing antioxidant enzyme activities together with the AsA–GSH cycle. In parallel, Se moderated ion toxicity by limiting Na⁺ accumulation, increasing K⁺, Ca²⁺, and Mg²⁺ uptake, and stimulating H⁺-ATPase and H⁺-PPase activities. Enhanced TCA cycle activity and organic acid accumulation suggested improved energy metabolism and ionic regulation. Se also promoted osmotic adjustment via soluble sugars and proline, and upregulated aquaporin genes (PIP1;2 and PIP2;4) to sustain water transport. Moreover, Se increased salicylic acid levels by upregulating CsPAL and CsICS, pointing to a role of SA signaling in Se-induced tolerance. Full article

Open-surface coalescence of microdroplets is essential for droplet-based microreactors, emulsion processing, and multiphase microfluidics, yet existing methods often require closed channels or patterned electrodes. Here, we report a corona-driven open-oil-film platform that achieves voltage-regulated coalescence of aqueous microdroplets in a simple needle–plate electrode configuration. Positive corona discharge induces coupled electrohydrodynamic effects—including ion transport, interfacial charge redistribution, and Maxwell stresses—that drive oil-film contraction and charge-regulated droplet bouncing, thereby reducing inter-droplet spacing and promoting successive merging. The coalescence rate and final droplet size are tunable via the applied voltage and oil volume: complete coalescence into a single droplet is achieved at 12 kV, and an optimal oil volume of 60 μL maximizes confinement efficiency. To enable quantitative, frame-by-frame analysis, we develop an improved YOLOv5–OC-SORT framework that yields an overall mAP@0.5 of 0.905 for automatic droplet detection and tracking. As a proof-of-concept, the platform achieves electro-demulsification of a surfactant-stabilized water-in-oil emulsion, increasing the average droplet diameter from ~0.005 mm to ~0.2 mm and enabling effective oil–water separation. This work provides a simple, electrode-pattern-free strategy for controllable droplet coalescence and open-surface emulsion breaking. Full article

Seawater intrusion (SWI) increasingly threatens coastal aquifers that serve growing communities, emphasizing the need for generalizable, process-based diagnostics. We evaluate SWI in a multilayer coastal aquifer system in southern Alabama, USA, by integrating three groundwater sampling campaigns during spring–early summer 2025 (March, April, and June), hydrogeochemical–isotopic analyses, and variable-density SEAWAT modeling. This study couples HFE–Gibbs–isotope diagnostics with hydraulic-head-constrained SEAWAT modeling to characterize seawater intrusion extent and process state in a multilayer coastal setting. Groundwater major ions and δ¹⁸O/δ²H indicate dominantly meteoric, rock-weathering waters (Ca–HCO₃ inland) with localized Na–Cl near the coast; most samples plot in the rock dominance field, and stable isotope values cluster near the meteoric water line. A 3-D SEAWAT model (seven layers, 150 × 150 m cells), calibrated to available groundwater head observations using PEST, indicates that modeled intrusion is concentrated at depth in confined Miocene units, whereas shallow groundwater sampled from the unconfined zone remains largely fresh based on hydrogeochemical and isotopic evidence. Because chloride observations were used primarily for interpretation rather than direct transport calibration, the modeled deep salinity distribution is treated as a process-based estimate rather than a uniquely calibrated chloride field. To quantify exposure and process state, we introduce two indicators: a Depth-Weighted Intrusion Index (DWII) integrating the extent and intensity of the transition zone across layers, and an Ion-Exchange Departure Index (IEDI) capturing normalized Na–Cl departures from conservative mixing due to cation exchange. Predominantly negative IEDI values indicate reverse exchange with weaker intensity during spring freshening and only localized forward exchange episodes. Beyond the site-specific findings, the DWII and IEDI introduced in this study provide practical tools for detecting and quantifying subtle seawater intrusion in low-salinity coastal aquifers and may be applicable to other coastal aquifer systems with similar hydrogeological settings. Full article