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13 pages, 4780 KB  
Article
Structural Evaluation of the Historical Bridge in the Yukhari Bash Architectural Reserve: A Comparative Finite Element Analysis Before and After Restoration
by Erdal Dinç, Tahir Ateş, Ahmet Gökdemir and Rojat Aksoy Işık
Mathematics 2025, 13(20), 3254; https://doi.org/10.3390/math13203254 (registering DOI) - 11 Oct 2025
Abstract
This study investigates the structural behavior of the historical bridge located in the “Yukhari Bash” National Architectural Reserve Zone in Sheki, Azerbaijan, using finite element analysis (FEA) before and after its restoration. The primary objective is to evaluate the performance of the bridge [...] Read more.
This study investigates the structural behavior of the historical bridge located in the “Yukhari Bash” National Architectural Reserve Zone in Sheki, Azerbaijan, using finite element analysis (FEA) before and after its restoration. The primary objective is to evaluate the performance of the bridge under self-weight and seismic loads, following the standards of the Turkish Building Earthquake Code. The bridge, constructed primarily with limestone masonry, was analyzed using SAP2000 software. The results indicate that the structural integrity under compressive and shear stresses remained within acceptable limits both before and after restoration. However, post-restoration improvements in stress distribution and deformation were evident. This paper contributes to the preservation of historic structures through modern engineering analysis and provides insights into the appropriate restoration practices for masonry arch bridges. Full article
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23 pages, 2367 KB  
Article
Optimisation of 3D Printable Cement- and Lime-Based Mortars for Built Heritage Rehabilitation
by Manuel Jesus, Ricardo Dias, João Teixeira, João M. P. Q. Delgado, Jorge Lino Alves, Bárbara Rangel and Ana Sofia Guimarães
Buildings 2025, 15(19), 3464; https://doi.org/10.3390/buildings15193464 - 25 Sep 2025
Viewed by 384
Abstract
Three-dimensional printing (3DP) represents a significant innovation in the construction sector, offering substantial benefits in terms of efficiency, customisation, and sustainability. In the context of built heritage rehabilitation, it is capable of accurately reproducing architectural elements, facilitating conservation efforts, while minimising waste and [...] Read more.
Three-dimensional printing (3DP) represents a significant innovation in the construction sector, offering substantial benefits in terms of efficiency, customisation, and sustainability. In the context of built heritage rehabilitation, it is capable of accurately reproducing architectural elements, facilitating conservation efforts, while minimising waste and resource consumption. However, in this field, ensuring material compatibility with original structures is essential. This study explores the development and optimisation of lime and cement-based mortars for 3DP applications, focusing on their physical and mechanical performances (on moulded specimens) for use in replicating elements of a renowned Portuguese theatre. Laboratory testing supports the selection of suitable mortar compositions, aiming to balance performance and fidelity to historical construction practices. This research seeks to contribute to explore the potential of 3DP for heritage conservation, promoting innovative, durable, and culturally sensitive restoration strategies. Full article
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16 pages, 6300 KB  
Article
Multi-Analytical Study of Lime-Based Mortars from the 16th-Century Venetian Fortress of Bergamo (Italy)
by Renato Pelosato, Isabella Natali-Sora, Virna Maria Nannei and Giulio Mirabella Roberti
Heritage 2025, 8(10), 400; https://doi.org/10.3390/heritage8100400 - 23 Sep 2025
Viewed by 388
Abstract
Mortars taken from the 16th century Venetian Fortress of Bergamo (Italy) were characterized (binder-concentrated fractions and aggregate fractions as well as bulk samples) with a multi-analytical approach using X-ray diffraction (XRD), inductively coupled plasma optical emission spectrophotometry (ICP-OES), optical microscopy (OM), differential scanning [...] Read more.
Mortars taken from the 16th century Venetian Fortress of Bergamo (Italy) were characterized (binder-concentrated fractions and aggregate fractions as well as bulk samples) with a multi-analytical approach using X-ray diffraction (XRD), inductively coupled plasma optical emission spectrophotometry (ICP-OES), optical microscopy (OM), differential scanning calorimetry (DSC) and thermogravimetric analysis (TG). The results showed the presence of calcite, hydrocalumite and hydrotalcite-type compounds, brucite, aragonite, plombierite and a large fraction of amorphous phases (ranging between 14 and 27 wt%) in the binder. Quartz and carbonate-rich sands were used as aggregates. The mortar is a Mg-rich material containing 4–5 wt% brucite. No evidence of magnesite or hydromagnesite was found in any sample, although these phases are frequently detected in the binder of buildings from the Renaissance period that are located in Northern Italy. The large average amount (12–13 wt%) of reactive silicate, such as Mg-containing phyllosilicates that can react with lime, and the presence of carbonate-containing hydrocalumite and hydrotalcite indicate hydraulic interactions between lime and reactive silicate aggregates. The CO2/H2Obound ratio, evaluated from the weight loss referred to the finer fraction (<63 μm), ranges from 1.99 to 2.55, which suggests that the walls of Bergamo were constructed using lime-based mortar with hydraulic properties. Full article
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15 pages, 2285 KB  
Article
Development and Characterization of Colored Lime–Gypsum Mortars for Heritage Building Restoration in Humid Environments
by Faris J. Thyab, Zaid Hazim Al-Saffar, Anas Ghaiath Ibrahim and Helen Faris
Constr. Mater. 2025, 5(3), 65; https://doi.org/10.3390/constrmater5030065 - 11 Sep 2025
Viewed by 413
Abstract
Surface deterioration and paint peeling occur in historic buildings worldwide due to excessive moisture. Conventional coatings often fail to preserve these structures. In Mosul, Iraq, conventional paints often do not preserve historic structures. The article aims to use colored lime–gypsum mortar, which has [...] Read more.
Surface deterioration and paint peeling occur in historic buildings worldwide due to excessive moisture. Conventional coatings often fail to preserve these structures. In Mosul, Iraq, conventional paints often do not preserve historic structures. The article aims to use colored lime–gypsum mortar, which has significant potential to be used as a sustainable and appropriate candidate material for the restoration of historic structures. This is particularly relevant for the restoration of exterior elements or interior walls in humid environments. The flowability, strength (compressive, flexural, and tensile), and shrinkage cracking of several mortar mixtures with different lime–gypsum ratios and color additives were all part of the extensive testing. Every procedure closely followed the applicable international standards The mortar mixture identified as optimal (Mix A10), comprising a 1:1 lime-to-gypsum ratio with carefully calibrated pigment additives (0.5 g chromium oxide, 0.2 mL liquid oxide, and 0.5 g powder oxide), demonstrated superior mechanical properties and minimal shrinkage cracking. This composition was ideal due to its superior mechanical strength and reduced shrinkage cracking compared to pure gypsum mixtures. The colored lime–gypsum mortar is a sustainable material well-suited to the restoration of historic structures, and applicable to both interior and exterior elements in humid environments. Its low shrinkage cracking enhances durability and effectively prevents moisture ingress in moisture-sensitive cultural settings. Full article
(This article belongs to the Topic Green Construction Materials and Construction Innovation)
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21 pages, 1368 KB  
Article
Laterite-Based Low-Carbon Binder Supporting the Circular Economy in Yaoundé, Cameroon
by Louise Mazzoni Leduc, Bernadin Kenne Diffo, Jean Ambroise and Abdelkrim Bennani
Buildings 2025, 15(17), 3154; https://doi.org/10.3390/buildings15173154 - 2 Sep 2025
Viewed by 622
Abstract
This study formulates an efficient, affordable, and low-carbon binder based on locally excavated earth from Yaoundé, offering sufficient mechanical strength and water resistance for rendering applications. Through material characterization, a binary binder composed of Portland cement (PC) and calcined laterite (CL) was developed, [...] Read more.
This study formulates an efficient, affordable, and low-carbon binder based on locally excavated earth from Yaoundé, offering sufficient mechanical strength and water resistance for rendering applications. Through material characterization, a binary binder composed of Portland cement (PC) and calcined laterite (CL) was developed, reducing the PC content by up to 30%. The mortar used laterite sand with varying fine particle contents in place of river sand, and its mechanical strength and water absorption via capillarity action were evaluated. Due to the porosity of the laterite fines, all mixes were prepared at equivalent workability. The mechanical strength was the same as if the binder solely consisted of PC and reached 11 MPa when the laterite sand contained no fine particles. As the fine particle content increased, the mechanical strength decreased to a minimum value of 4 MPa when raw laterite was used, and the coefficient of water absorption via capillarity action decreased. Overall, the formulated class Wc2 mortar is suitable for rendering applications. The valorization potential of fine particles and coarse aggregates of the crushed mortar was assessed: the crushed mortar fines had pozzolanic properties and could serve as supplementary cementitious materials; the largest particles are suitable for lime stabilization. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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32 pages, 1239 KB  
Article
Research on a GA-XGBoost and LSTM-Based Green Material Selection Model for Ancient Building Renovation
by Yingfeng Kuang, Xiaolong Chen, Hongfeng Zhang and Cora Un In Wong
Buildings 2025, 15(17), 3094; https://doi.org/10.3390/buildings15173094 - 28 Aug 2025
Viewed by 503
Abstract
This study aims to address the challenge of balancing historical preservation and sustainable material selection in ancient building renovations, particularly in regions with unique climatic conditions like Hunan Province. The research proposes a hybrid model integrating Genetic Algorithm-optimized Extreme Gradient Boosting (GA-XGBoost) and [...] Read more.
This study aims to address the challenge of balancing historical preservation and sustainable material selection in ancient building renovations, particularly in regions with unique climatic conditions like Hunan Province. The research proposes a hybrid model integrating Genetic Algorithm-optimized Extreme Gradient Boosting (GA-XGBoost) and Long Short-Term Memory (LSTM) networks. The GA-XGBoost component optimizes hyperparameters to predict material performance, while the LSTM network captures temporal dependencies in environmental and material degradation data. A multi-objective optimization framework is developed to simultaneously prioritize preservation integrity and green performance. The methodology is validated through a case study on an ancient architectural complex in Rucheng, Hunan Province. Key results demonstrate that the hybrid model achieves superior accuracy in material selection, with an 18–23% reduction in embodied energy (compared to conventional AHP-TOPSIS methods) and a 21.9% improvement in prediction accuracy (versus standalone XGBoost with default hyperparameters). A multi-objective optimization framework is developed to simultaneously prioritize preservation integrity and green performance, with Pareto-optimal solutions identifying material combinations that balance historical authenticity (achieving 92% substrate compatibility) with substantial sustainability gains (18–23% embodied energy reduction). The model also identifies optimal material combinations, such as lime-pozzolan mortars with rice husk ash additives, which enhance moisture buffering capacity by 28% (relative to traditional lime mortar benchmarks) while maintaining 92% compatibility with original substrates (based on ASTM C270 compatibility tests). The findings highlight the model’s effectiveness in bridging heritage conservation and modern sustainability requirements. The study contributes a scalable and interpretable framework for green material selection, offering practical implications for cultural heritage projects worldwide. Future research directions include expanding the model’s applicability to other climate zones and integrating circular economy principles for broader sustainability impact. Preliminary analysis indicates the framework’s adaptability to other climate zones through adjustment of key material property weightings. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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30 pages, 6711 KB  
Article
Experimental Investigation on the Tensile and Bond Durability of Galvanized Steel Reinforced Grout
by Sara Fares, Pietro Meriggi, Stefano De Santis and Gianmarco de Felice
Buildings 2025, 15(17), 3020; https://doi.org/10.3390/buildings15173020 - 25 Aug 2025
Viewed by 455
Abstract
Steel reinforced grout (SRG) composites are widely used for strengthening existing structures. Galvanized (zinc-coated) ultra-high tensile strength steel cords are more durable than brass-coated and cheaper than stainless-steel ones, making them the most common in practice. While compliant with certification standards, corrosion may [...] Read more.
Steel reinforced grout (SRG) composites are widely used for strengthening existing structures. Galvanized (zinc-coated) ultra-high tensile strength steel cords are more durable than brass-coated and cheaper than stainless-steel ones, making them the most common in practice. While compliant with certification standards, corrosion may occur, potentially affecting tensile strength and bond capacity. The latter has, however, remained largely unexplored, highlighting a need to assess durability under different environmental exposures. This study investigated the durability of galvanized SRGs with four cord types and four mortar matrices (cement- and lime-based). Direct tensile, shear bond, and lap-tensile tests were conducted after immersion in saltwater or alkaline solutions, exposure to freeze–thaw or salt crystallization cycles, and high temperatures. Results highlighted salt exposure as the most critical condition, particularly with lime-based matrices. Zinc coating thickness proved essential for corrosion resistance, while freeze–thaw and salt crystallization led to bond degradation due to concentrated steel corrosion and mortar microcracking. The findings highlight the importance of considering appropriate protective measures and exposure-specific conditions when designing SRG reinforcements. Full article
(This article belongs to the Section Building Structures)
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19 pages, 1797 KB  
Article
Determination of Composition of Masonry Mortars for Conservation of Historical Constructions Using Artificial Neural Networks
by Filip Chyliński, Piotr Kupisz, Przemysław Więch and Lesław Brunarski
Materials 2025, 18(16), 3851; https://doi.org/10.3390/ma18163851 - 17 Aug 2025
Viewed by 485
Abstract
This study presents a novel approach to determine the composition of masonry mortars and their types from cement, lime, and cement–lime using an artificial neural network (ANN). It also allows the preparation of mortar recipes for the conservation of historical masonry objects with [...] Read more.
This study presents a novel approach to determine the composition of masonry mortars and their types from cement, lime, and cement–lime using an artificial neural network (ANN). It also allows the preparation of mortar recipes for the conservation of historical masonry objects with properties similar to the original ones, but using currently available raw materials. An ANN was trained using a set of cement, lime, and cement–lime mortars with known compositions. The properties chosen for the ANN’s analysis included total porosity, specific density, insoluble residue content, silicone (SiO2) content, calcium (CaO) content, Si/Ca ratio in grout, and compressive strength. The use of ANNs allows for the determination of mortar composition with a validation error of less than 5% and a method of classification of the type of mortar that gives correct answers in more than 93% of cases, proving the usefulness of ANNs in determining the type and composition of masonry mortars relevant for the conservation of historical masonry structures. Full article
(This article belongs to the Section Construction and Building Materials)
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17 pages, 2616 KB  
Article
Investigation of the Dynamic Characterization of Traditional and Modern Building Materials Using an Impact Excitation Test
by Anil Ozdemir
Buildings 2025, 15(15), 2682; https://doi.org/10.3390/buildings15152682 - 30 Jul 2025
Viewed by 475
Abstract
This study presents a comprehensive non-destructive evaluation of a broad range of construction materials using the impulse excitation of vibration (IEV) technique. Tested specimens included low- and normal-strength concrete, fiber-reinforced concrete (with basalt, polypropylene, and glass fibers), lime mortars (NHL-2 and -3.5), plaster, [...] Read more.
This study presents a comprehensive non-destructive evaluation of a broad range of construction materials using the impulse excitation of vibration (IEV) technique. Tested specimens included low- and normal-strength concrete, fiber-reinforced concrete (with basalt, polypropylene, and glass fibers), lime mortars (NHL-2 and -3.5), plaster, and clay bricks (light and dark). Compressive and flexural strength tests complemented dynamic resonance testing on the same samples to ensure full mechanical characterization. Flexural and torsional resonance frequencies were used to calculate dynamic elastic modulus, shear modulus, and Poisson’s ratio. Strong correlations were observed between dynamic elastic modulus and shear modulus, supporting the compatibility of dynamic results with the classical elasticity theory. Flexural frequencies were more sensitive to material differences than torsional ones. Fiber additives, particularly basalt and polypropylene, significantly improved dynamic stiffness, increasing the dynamic elastic modulus/compressive strength ratio by up to 23%. In contrast, normal-strength concrete exhibited limited stiffness improvement despite higher strength. These findings highlight the reliability of IEV in mechanical properties across diverse material types and provide comparative reference data for concrete and masonry applications. Full article
(This article belongs to the Special Issue Advanced Studies in Structure Materials—2nd Edition)
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17 pages, 6527 KB  
Article
Mechanical Properties of Bio-Printed Mortars with Bio-Additives for Green and Sustainable Construction
by Sotirios Pemas, Dimitrios Baliakas, Eleftheria Maria Pechlivani and Maria Stefanidou
Materials 2025, 18(14), 3375; https://doi.org/10.3390/ma18143375 - 18 Jul 2025
Cited by 1 | Viewed by 699
Abstract
Additive manufacturing (AM) has brought significant breakthroughs to the construction sector, such as the ability to fabricate complex geometries, enhance efficiency, and reduce both material usage and construction waste. However, several challenges must still be addressed to fully transition from conventional construction practices [...] Read more.
Additive manufacturing (AM) has brought significant breakthroughs to the construction sector, such as the ability to fabricate complex geometries, enhance efficiency, and reduce both material usage and construction waste. However, several challenges must still be addressed to fully transition from conventional construction practices to innovative and sustainable green alternatives. This study investigates the use of non-cementitious traditional mixtures for green construction applications through 3D printing using Liquid Deposition Modeling (LDM) technology. To explore the development of mixtures with enhanced physical and mechanical properties, natural pine and cypress wood shavings were added in varying proportions (1%, 3%, and 5%) as sustainable additives. The aim of this study is twofold: first, to demonstrate the printability of these eco-friendly mortars that can be used for conservation purposes and overcome the challenges of incorporating bio-products in 3D printing; and second, to develop sustainable composites that align with the objectives of the European Green Deal, offering low-emission construction solutions. The proposed mortars use hydrated lime and natural pozzolan as binders, river sand as an aggregate, and a polycarboxylate superplasticizer. While most studies with bio-products focus on traditional methods, this research provides proof of concept for their use in 3D printing. The study results indicate that, at low percentages, both additives had minimal effect on the physical and mechanical properties of the tested mortars, whereas higher percentages led to progressively more significant deterioration. Additionally, compared to molded specimens, the 3D-printed mortars exhibited slightly reduced mechanical strength and increased porosity, attributable to insufficient compaction during the printing process. Full article
(This article belongs to the Special Issue Eco-Friendly Materials for Sustainable Buildings)
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18 pages, 9768 KB  
Article
Impact of Mixed-In Polyacrylic- and Phosphonate-Based Additives on Lime Mortar Microstructure
by Dulce Elizabeth Valdez Madrid, Encarnación Ruiz-Agudo, Sarah Bonilla-Correa, Nele De Belie and Veerle Cnudde
Materials 2025, 18(14), 3322; https://doi.org/10.3390/ma18143322 - 15 Jul 2025
Viewed by 580
Abstract
Aminotris(methylene phosphonic acid) (ATMP) and poly(acrylic acid) sodium salt (PAA) have shown favorable results in the treatment of porous building materials against weathering damage, showing promising potential as mixed-in additives during the production of lime-based mortars. This study investigates the impact of these [...] Read more.
Aminotris(methylene phosphonic acid) (ATMP) and poly(acrylic acid) sodium salt (PAA) have shown favorable results in the treatment of porous building materials against weathering damage, showing promising potential as mixed-in additives during the production of lime-based mortars. This study investigates the impact of these additives on microstructure and mechanical properties. Additives were introduced in various concentrations to assess their influence on CaCO3 crystallization, porosity, strength, and carbonation behavior. Results revealed significant modifications in the morphology of CaCO3 precipitates, showing evidence of nanostructured CaCO3 aggregates and vaterite stabilization, thus indicating a non-classical crystallization pathway through the formation of amorphous CaCO3 phase(s), facilitated by organic occlusions. These nanostructural changes, resembling biomimetic calcitic precipitates enhanced mechanical performance by enabling plastic deformation and intergranular bridging. Increased porosity and pore connectivity facilitated CO2 diffusion towards the mortar matrix, contributing to strength development over time. However, high additive concentrations resulted in poor mechanical performance due to the excessive air entrainment capabilities of short-length polymers. Overall, this study demonstrates that the optimized dosages of ATMP and PAA can significantly enhance the durability and mechanical performance of lime-based mortars and suggests a promising alternative for the tailored manufacturing of highly compatible and durable materials for both the restoration of cultural heritage and modern sustainable construction. Full article
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27 pages, 21889 KB  
Article
Modulus of Elasticity and Mechanical Properties Assessment of Historical Masonry Elements After Elevated Temperature: Experimental Study and Numerical Analysis
by Ahmet Fazıl Kara, Ferit Cakir and Metehan Calis
Buildings 2025, 15(13), 2324; https://doi.org/10.3390/buildings15132324 - 2 Jul 2025
Viewed by 955
Abstract
Historical masonry structures deteriorate over time, requiring restoration and strengthening. Hydraulic lime-based mortars (HLMs), due to their compatibility with historical materials, are commonly used for this purpose. This study examines the fire resistance of masonry walls constructed with HLMs. Masonry prisms with clay [...] Read more.
Historical masonry structures deteriorate over time, requiring restoration and strengthening. Hydraulic lime-based mortars (HLMs), due to their compatibility with historical materials, are commonly used for this purpose. This study examines the fire resistance of masonry walls constructed with HLMs. Masonry prisms with clay bricks were prepared using HLMs in accordance with material testing standards. Specimens were subjected to high temperatures ranging from 200 °C to 800 °C, followed by flexural–compression tests for mortar and compression tests for masonry prisms. A total of 20 masonry prism specimens, 15 brick specimens, and 15 mortar specimens were tested, including reference specimens at room temperature. Experimental results indicate that masonry prisms, clay bricks, and HLMs progressively lose their mechanical properties as temperature increases. The elastic modulus of masonry prisms was evaluated according to relevant standards, and Finite Element Analysis (FEA) was conducted to validate temperature-dependent material properties. The stress–strain response of M15 HLM masonry prisms was determined, addressing the absence of such data in EN 1996-1-2. Additionally, compression test results were compared with digital image correlation (DIC) analyses to enhance measurement accuracy. This study provides critical insights into the thermal performance of masonry walls with HLMs, contributing to the development of fire-resistant restoration materials. Full article
(This article belongs to the Section Building Structures)
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21 pages, 3488 KB  
Article
Sample Origin Effect on Chemical Reactivity of Tajogaite Volcanic Ashes for Ancient Mortar Repair
by Imren Basar, David Torrens-Martín, Lucía Fernández-Carrasco, Cristhian Caiza, Joan Martínez-Bofill and Marcel Hürlimann
Sustain. Chem. 2025, 6(3), 18; https://doi.org/10.3390/suschem6030018 - 24 Jun 2025
Viewed by 1080
Abstract
Volcanic ashes (VA) ejected by the Tajogaite Volcano were studied to determine their potential as pozzolanic materials for construction applications. A representative number of VA samples (15 in total) were collected from different geolocations and altitudes during and immediately after the volcanic eruption, [...] Read more.
Volcanic ashes (VA) ejected by the Tajogaite Volcano were studied to determine their potential as pozzolanic materials for construction applications. A representative number of VA samples (15 in total) were collected from different geolocations and altitudes during and immediately after the volcanic eruption, in order to assess their reactivity as a function of position and environmental exposure. Various analytical techniques—XRD, FTIR, and SEM/EDX—were used to determine the initial microstructural composition of the VA samples. Additionally, saturated lime testing and the Frattini test were performed to evaluate their pozzolanic reactivity for use in historical mortars. The microstructural analyses revealed that the dominant mineral phases are aluminosilicates. The reactivity tests confirmed a good pozzolanic response, with the formation of C-A-S-H gels identified as the main hydration products at the studied curing times. Full article
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34 pages, 8454 KB  
Article
Architectural Heritage Conservation and Green Restoration with Hydroxyapatite Sustainable Eco-Materials
by Alina Moșiu, Rodica-Mariana Ion, Iasmina Onescu, Meda Laura Moșiu, Ovidiu-Constantin Bunget, Lorena Iancu, Ramona Marina Grigorescu and Nelu Ion
Sustainability 2025, 17(13), 5788; https://doi.org/10.3390/su17135788 - 24 Jun 2025
Cited by 2 | Viewed by 1080
Abstract
Sustainable architectural heritage conservation focuses on preserving historical buildings while promoting environmental sustainability. It involves using eco-friendly materials and methods to ensure that the cultural value of these structures is maintained while minimizing their ecological impact. In this paper, the use of the [...] Read more.
Sustainable architectural heritage conservation focuses on preserving historical buildings while promoting environmental sustainability. It involves using eco-friendly materials and methods to ensure that the cultural value of these structures is maintained while minimizing their ecological impact. In this paper, the use of the hydroxyapatite (HAp) in various combinations on masonry samples is presented, with the aim of identifying the ideal solution to be applied to an entire historical building in Banloc monument. The new solution has various advantages: compatibility with historical lime mortars (chemical and physical), increased durability under aggressive environmental conditions, non-invasive and reversible, aligning with conservation ethics, bioinspired material that avoids harmful synthetic additives, preservation of esthetics—minimal visual change to treated surfaces, and nanostructural (determined via SEM and AFM) reinforcement to improve cohesion without altering the porosity. An innovative approach involving hydroxiapatite addition to commercial mortars is developed and presented within this paper. Physico-chemical, mechanical studies, and architectural and economic trends will be addressed in this paper. Some specific tests (reduced water absorption, increased adhesion, high mechanical strength, unchanged chromatic aspect, high contact angle, not dangerous freeze–thaw test, reduced carbonation test), will be presented to evidence the capability of hydroxyapatite to be incorporated into green renovation efforts, strengthen the consolidation layer, and focus on its potential uses as an eco-material in building construction and renovation. The methodology employed in evaluating the comparative performance of hydroxyapatite (HAp)-modified mortar versus standard Baumit MPI25 mortar includes a standard error (SE) analysis computed column-wise across performance indicators. To further substantiate the claim of “optimal performance” at 20% HAp addition, independent samples t-tests were performed. The results of the independent samples t-tests were applied to three performance and cost indicators: Application Cost, Annualized Cost, and Efficiency-Cost-Performance (ECP) Index. This validates the claim that HAp-modified mortar offers superior overall performance when considering efficiency, cost, and durability combined. Full article
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14 pages, 2752 KB  
Article
Nuclear Magnetic Resonance in Tire Waste Mortars
by Marta Ioana Moldoveanu, Daniela Lucia Manea, Elena Jumate, Raluca Iștoan, Radu Fechete and Tudor Panfil Toader
Appl. Sci. 2025, 15(12), 6895; https://doi.org/10.3390/app15126895 - 18 Jun 2025
Viewed by 427
Abstract
This study aims to investigate the application of nuclear magnetic resonance (NMR) to characterize mortars containing recycled rubber waste as an eco-innovative material for sustainable construction. The primary objective was to analyze the way rubber granules influence hydration kinetics, microstructural development and pore [...] Read more.
This study aims to investigate the application of nuclear magnetic resonance (NMR) to characterize mortars containing recycled rubber waste as an eco-innovative material for sustainable construction. The primary objective was to analyze the way rubber granules influence hydration kinetics, microstructural development and pore structure. The innovative mortar formulations incorporated rubber granules, casein, natural hydraulic lime (NHL), and latex. NMR analysis revealed distinct T2 relaxation time distributions correlated with different pore sizes and water states: shorter T2 values demonstrate strongly bound water in small pores, while longer T2 values are associated with loosely bound or free water in larger pores. The formulation with 3.5% NHL and 5% rubber granules exhibited optimal microstructural characteristics. These results reveal that NMR is a valuable, non-destructive tool for monitoring cementitious material evolution and supporting the use of tire-derived waste in eco-innovative mortar designs. Full article
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