Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (80)

Search Parameters:
Keywords = linear birefringence

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
14 pages, 4679 KB  
Article
Rapid Dynamic Separation of Radial and Azimuthal Polarization Components in Circular Airy Vortex Beams via Linear Electro-Optic Effect in Uniaxial Crystals
by Guoliang Zheng, Tiefeng He, Zikun Xu, Jiawen Li, Xuhui Zhang, Lili Wan and Qingyang Wu
Photonics 2025, 12(9), 894; https://doi.org/10.3390/photonics12090894 - 5 Sep 2025
Viewed by 338
Abstract
This paper presents a rapid approach for the dynamic separation of radial polarization (R-pol) and azimuthal polarization (A-pol) components in circular Airy vortex beams (CAVBs) by utilizing the linear electro-optic (EO) effect in uniaxial crystals. By applying an external electric field along the [...] Read more.
This paper presents a rapid approach for the dynamic separation of radial polarization (R-pol) and azimuthal polarization (A-pol) components in circular Airy vortex beams (CAVBs) by utilizing the linear electro-optic (EO) effect in uniaxial crystals. By applying an external electric field along the z-axis of a strontium barium niobate (SBN) crystal, tunable spatial separation of the R-pol and A-pol components is achieved. Under positive electric fields, the crystal maintains negative uniaxial properties with increased birefringence, extending the focal separation distance. Conversely, negative electric fields initially reduce the birefringence of the crystal; further increases in negative field strength will transition the crystal to a positive uniaxial state, subsequently enhancing birefringence and restoring focal separation. Experimental simulations demonstrate a focal separation of 1.4 mm at ±15 kV/mm, with R-pol focusing first at +15 kV/mm and A-pol preceding at −15 kV/mm. The polarization distributions at the foci confirm the successful separation of the two components. This approach overcomes the static limitation of conventional polarization splitters in separating R-pol and A-pol components, showing significant potential for optical manipulation, high-resolution imaging, and quantum information processing. Full article
(This article belongs to the Section Optical Interaction Science)
Show Figures

Figure 1

11 pages, 2248 KB  
Communication
Extra-Cavity Modulation of a Quartic Soliton with Negative Fourth-Order Dispersion
by Dayu Wang, Daqian Tang, Yangyang Peng, Junxiao Zhan, Haoming Wang and Yan Zhou
Photonics 2025, 12(9), 858; https://doi.org/10.3390/photonics12090858 - 26 Aug 2025
Viewed by 389
Abstract
Quartic solitons in ultrafast fibre lasers (intra-cavity optical fibre modulation systems) have been theoretically and experimentally analysed in recent years. However, there are few reports about extra-cavity modulating quartic solitons. In this situation, the purpose of this work is to investigate a quartic [...] Read more.
Quartic solitons in ultrafast fibre lasers (intra-cavity optical fibre modulation systems) have been theoretically and experimentally analysed in recent years. However, there are few reports about extra-cavity modulating quartic solitons. In this situation, the purpose of this work is to investigate a quartic soliton’s extra-cavity modulation. In this paper, we theoretically simulate an extra-cavity-modulating quartic soliton with negative fourth-order dispersion at 1550 nm. The simulation relies on a physical model of a single-mode optical fibre system. Through controlling soliton parameters in an extra-cavity modulation system, a quartic soliton’s orthogonal polarisation modes will show unique characteristics depending on which kind of parameter is changed (seven parameters are considered for variation). For example, through the variation in the projection angle, only a horizontally polarised quartic soliton pulse is generated. These results explore the dynamics of quartic solitons in single-mode optical fibre modulation systems and are applicable to optical soliton transmission techniques in the field of optical fibre communication. Full article
(This article belongs to the Section Lasers, Light Sources and Sensors)
Show Figures

Figure 1

15 pages, 1917 KB  
Article
Temperature-Dependent Polarization Characterization and Birefringence Inversion in Super-Twisted Nematic Liquid Crystals
by Houtong Liu, Bin Wang, Minjuan Mao, Yuanyuan Qian and Dan Wang
Photonics 2025, 12(7), 683; https://doi.org/10.3390/photonics12070683 - 7 Jul 2025
Viewed by 399
Abstract
The temperature-dependent polarization performance of super-twisted nematic liquid crystals (STN-LCs) when used as polarizers has garnered considerable scholarly attention. In this study, the transmittance of an STN-LC cell was measured under incident light wavelengths of 650 nm, 532 nm, and 405 nm over [...] Read more.
The temperature-dependent polarization performance of super-twisted nematic liquid crystals (STN-LCs) when used as polarizers has garnered considerable scholarly attention. In this study, the transmittance of an STN-LC cell was measured under incident light wavelengths of 650 nm, 532 nm, and 405 nm over the temperature range of 30 °C to 100 °C. The STN-LC cell was employed both as the sample under test and as an analyzer in a rotational measurement setup to investigate how its polarization properties vary with temperature. The results indicate that the LC cell exhibits the characteristics of a linear polarizer under red light (650 nm) and violet laser (405 nm) across the full temperature range. However, under green laser (532 nm), when the temperature exceeds 60 °C, its extinction ratio is poor, suggesting its unsuitability for polarization applications under such conditions. A birefringence inversion formula was derived using the transmittance difference method, which effectively eliminates the influence of the glass substrates on the measured transmittance of the LC layer. Utilizing this method, a simple optical setup consisting of a polarizer and photodetector was constructed to accurately extract the birefringence of the LC. The birefringence of super-twisted nematic liquid crystal can be obtained by the transmittance difference method, which is low-cost, has a simple optical path, and is convenient for temperature-controlled experimental measurements of the liquid crystal cell. The findings of this study provide methodological support for the precise determination of birefringence in LCs exhibiting linear polarization characteristics. Full article
Show Figures

Figure 1

17 pages, 4413 KB  
Article
Impact of Fatty Acid Types and Microwave Post-Treatment on the Physicochemical Properties of Water Caltrop Starch–Lipid Complexes
by Pei-Chang Lee and Lih-Shiuh Lai
Foods 2025, 14(13), 2254; https://doi.org/10.3390/foods14132254 - 25 Jun 2025
Viewed by 848
Abstract
This study investigates the effects of microwave post-treatment and fatty acid type on the physicochemical properties of starch–lipid complexes derived from water caltrop (Trapa taiwanensis Nakai) starch. Complexes were prepared using stearic acid (C18:0) or oleic acid (C18:1), [...] Read more.
This study investigates the effects of microwave post-treatment and fatty acid type on the physicochemical properties of starch–lipid complexes derived from water caltrop (Trapa taiwanensis Nakai) starch. Complexes were prepared using stearic acid (C18:0) or oleic acid (C18:1), followed by microwave post-treatment at varying durations. Morphological analysis revealed that the starch–stearic acid complex exhibited more plate-like structures and birefringent spots compared to the starch–oleic acid complex. The complexing index increased with extended microwave exposure, indicating enhanced complex formation. Fourier-transform infrared spectroscopy showed no significant variation in the 1047/1022 cm−1 absorption ratio, suggesting that the short-range molecular order remained unaffected. However, X-ray diffraction analysis indicated increased relative crystallinity, particularly in the stearic acid complex (10.4%) compared to the oleic acid complex (4.8%), likely due to the higher linearity and saturation of stearic acid. Differential scanning calorimetry confirmed the presence of both type I and type II crystallization in all samples. The starch–stearic acid complex exhibited greater thermal stability, promoted type II crystallization, and enhanced the ordered structure of type I crystallization. In contrast, microwave treatment had limited influence on the thermal properties of the starch–oleic acid complex. These findings demonstrate that microwave post-treatment facilitates starch–lipid complex formation and improves structural organization, particularly when saturated fatty acids are employed. Full article
(This article belongs to the Special Issue Research on the Structure and Physicochemical Properties of Starch)
Show Figures

Figure 1

19 pages, 5431 KB  
Article
Polarization-Insensitive Silicon Grating Couplers via Subwavelength Metamaterials and Metaheuristic Optimization
by Jorge Parra
Photonics 2025, 12(5), 428; https://doi.org/10.3390/photonics12050428 - 29 Apr 2025
Cited by 1 | Viewed by 997
Abstract
Silicon photonics is the leading platform in photonic integrated circuits (PICs), enabling dense integration and low-cost manufacturing for applications such as data communications, artificial intelligence, and quantum processing, to name a few. However, efficient and polarization-insensitive fiber-to-PIC coupling for multipoint wafer characterization remains [...] Read more.
Silicon photonics is the leading platform in photonic integrated circuits (PICs), enabling dense integration and low-cost manufacturing for applications such as data communications, artificial intelligence, and quantum processing, to name a few. However, efficient and polarization-insensitive fiber-to-PIC coupling for multipoint wafer characterization remains a challenge due to the birefringence of silicon waveguides. Here, we address this issue by proposing polarization-insensitive grating couplers based on subwavelength dielectric metamaterials and metaheuristic optimization. Subwavelength periodic structures were engineered to act as uniaxial homogeneous linear (UHL) materials, enabling tailored anisotropy. On the other hand, particle swarm optimization (PSO) was employed to optimize the coupling efficiency, bandwidth, and polarization-dependent loss (PDL). Numerical simulations demonstrated that a pitch of 100 nm ensures UHL behavior while minimizing leaky waves. Optimized grating couplers achieved coupling efficiencies higher than −3 dB and a PDL of below 1 dB across the telecom C-band (1530–1565 nm). Three optimization strategies were explored, balancing efficiency, the bandwidth, and the PDL while considering the Pareto front. This work establishes a robust framework combining metamaterial engineering with computational optimization, paving the way for high-performance polarization-insensitive grating couplers with potential uses in advanced photonic applications. Full article
(This article belongs to the Special Issue Photonics Metamaterials: Processing and Applications)
Show Figures

Figure 1

30 pages, 8461 KB  
Article
Layer-by-Layer Multifractal Scanning of Optically Anisotropic Architectonics of Blood Plasma Films: Fundamental and Applied Aspects
by Alexander Ushenko, Natalia Pavlyukovich, Oksana Khukhlina, Olexander Pavlyukovich, Mykhaylo Gorsky, Iryna Soltys, Alexander Dubolazov, Yurii Ushenko, Olexander Salega, Ivan Mikirin, Jun Zheng, Zhebo Chen and Lin Bin
Photonics 2025, 12(3), 215; https://doi.org/10.3390/photonics12030215 - 28 Feb 2025
Viewed by 558
Abstract
This study focuses on the topographic structure of optical anisotropy maps (theziograms) of dehydrated blood plasma films (facies) to identify and utilize markers for diagnosing self-similarity (multifractality) in the birefringence parameters of supramolecular protein networks. The research is based on the Jones-matrix analytical [...] Read more.
This study focuses on the topographic structure of optical anisotropy maps (theziograms) of dehydrated blood plasma films (facies) to identify and utilize markers for diagnosing self-similarity (multifractality) in the birefringence parameters of supramolecular protein networks. The research is based on the Jones-matrix analytical framework, which describes the formation of polarization-structural speckle fields in polycrystalline blood plasma facies. In the proposed model, algorithms were developed to relate the real and imaginary parts of the complex elements of the Jones matrix to the theziograms of linear and circular birefringence. To experimentally implement these algorithms, a novel optical technology was introduced for polarization-interference registration and phase scanning of the laser speckle field of blood plasma facies. The laser-based Jones-matrix layer-by-layer theziography relies on polarization filtration and the digital recording of interference patterns from microscopic images of blood plasma facies. This process includes digital 2D Fourier reconstruction and phase-by-phase scanning of the object field of complex amplitudes, enabling the acquisition of phase sections of laser polarization-structural speckle field components scattered with varying multiplicities. Jones-matrix images of supramolecular networks, along with their corresponding theziograms of linear and circular birefringence, were obtained for each phase plane. The experimental data derived from laser layer-by-layer Jones-matrix theziography were quantitatively analyzed using two complementary approaches: statistical analysis (central moments of the 1st to 4th orders) and multifractal analysis (spectra of fractal dimension distributions). As a result, the most sensitive markers—namely asymmetry and kurtosis—were identified, highlighting changes in the statistical and scale self-similar structures of the theziograms of linear and circular birefringence in blood plasma facies. The practical aspect of this work is to evaluate the diagnostic potential of the Jones-matrix theziography method for identifying and differentiating changes in the birefringence of supramolecular networks in blood plasma facies caused by the long-term effects of COVID-19. For this purpose, a control group (healthy donors) and three experimental groups of patients, confirmed to have had COVID-19 one-to-three years prior, were formed. Within the framework of evidence-based medicine, the operational characteristics of the method—sensitivity, specificity, and accuracy—were assessed. The method demonstrated excellent accuracy in the differential diagnosis of the long-term effects of COVID-19. This was achieved by statistically analyzing the spectra of fractal dimensions of Jones-matrix theziograms reconstructed in the phase plane of single scattering within the volume of blood plasma facies. Full article
(This article belongs to the Special Issue Emerging Trends in Polarization Optics for Biomedical Applications)
Show Figures

Figure 1

12 pages, 3533 KB  
Article
Bessel Beams in Gyroanisotropic Crystals with Optical Activity
by Yuriy Egorov, Bogdan Sokolenko, Aziz Aliev, Ruslan Dzhemalyadinov, Ervin Umerov and Alexander Rubass
Physics 2025, 7(1), 6; https://doi.org/10.3390/physics7010006 - 10 Feb 2025
Viewed by 1352
Abstract
Using a Bessel beam as an example, it is shown that such a beam with the initial circular polarization, propagating through an optically active medium devoid of linear birefringence, generates an optical vortex in the orthogonally polarized component. It is shown that a [...] Read more.
Using a Bessel beam as an example, it is shown that such a beam with the initial circular polarization, propagating through an optically active medium devoid of linear birefringence, generates an optical vortex in the orthogonally polarized component. It is shown that a medium with genuine optical activity allows the mutual conversion of beams with radial and azimuthal polarization distributions. It is also shown that a considerably weak perturbation of a medium with genuine optical activity by linear birefringence leads to the destruction of an isotropic point. In the vicinity of this point, the optical activity is suppressed by linear birefringence, so that a medium with a combined type of anisotropy responds as a medium with genuine linear birefringence. The structure of the fields of the eigenmodes of Bessel beams in a birefringent uniaxial crystal with optical activity is similar to the structure of the modes of a medium with genuine optical activity. The findings of the current study are believed to expand the understanding of physical processes in the developing field of polarization and the phase profilometry of materials. Full article
(This article belongs to the Section Classical Physics)
Show Figures

Figure 1

13 pages, 2932 KB  
Article
Encapsulation of Fatty Acids Using Linear Dextrin from Waxy Potato Starch: Effect of Debranching Time and Degree of Unsaturation
by Huifang Xie, Qingfei Duan, Guohua Hu, Xinyi Dong, Litao Ma, Jun Fu, Yiwen Yang, Huaran Zhang, Jiahui Song, Qunyu Gao and Long Yu
Gels 2025, 11(2), 91; https://doi.org/10.3390/gels11020091 - 24 Jan 2025
Viewed by 1140
Abstract
This study investigates the effects of the debranching time of waxy potato starch using pullulanase and recrystallization on particle morphology, debranching degree, and crystal structure. The results demonstrated that after gelatinization and debranching, the surface of the starch crystals became rough and uneven [...] Read more.
This study investigates the effects of the debranching time of waxy potato starch using pullulanase and recrystallization on particle morphology, debranching degree, and crystal structure. The results demonstrated that after gelatinization and debranching, the surface of the starch crystals became rough and uneven due to hydrolysis, with most particles showing a fragmented surface. The crystalline state was not significantly changed with debranching time. X-ray diffraction analysis revealed no significant differences in the patterns of recrystallized linear dextrin (LD) after various debranching times. Notably, the short-range ordered structure of LD after debranching and recrystallization was more organized than that of the original or gelatinized starch. Additionally, polarized light microscopy showed that the birefringent pattern disappeared as a result of debranching and recrystallization, indicating the breakdown of particle structure, although the overall particle morphology did not change significantly with varying debranching times. Furthermore, linear dextrin derived from starch debranched for 6 h (with pullulanase at 15 μg/g) successfully embedded stearic acid, oleic acid, and linoleic acid, forming a VI-type starch–fatty acid complex. Full article
(This article belongs to the Special Issue Recent Advances in Food Gels (2nd Edition))
Show Figures

Figure 1

11 pages, 2649 KB  
Communication
Applications of Isosceles Triangular Coupling Structure in Optical Switching and Sensing
by Lili Zeng, Xingjiao Zhang, Qinghua Guo, Yang Fan, Yuanwen Deng, Zhengchao Ma and Boxun Li
Sensors 2024, 24(24), 8221; https://doi.org/10.3390/s24248221 - 23 Dec 2024
Cited by 1 | Viewed by 841
Abstract
In the case of waveguide-based devices, once they are fabricated, their optical properties are already determined and cannot be dynamically controlled, which limits their applications in practice. In this paper, an isosceles triangular-coupling structure which consists of an isosceles triangle coupled with a [...] Read more.
In the case of waveguide-based devices, once they are fabricated, their optical properties are already determined and cannot be dynamically controlled, which limits their applications in practice. In this paper, an isosceles triangular-coupling structure which consists of an isosceles triangle coupled with a two-bus waveguide is proposed and researched numerically and theoretically. The coupled mode theory (CMT) is introduced to verify the correctness of the simulation results, which are based on the finite difference time domain (FDTD). Due to the existence of the side mode and angular mode, the transmission spectrum presents two high transmittance peaks and two low transmittance peaks. In addition, the four transmission peaks exhibit different variation trends when the dimensions of the isosceles triangle are changed. The liquid crystal (LC) materials comprise anisotropic uniaxial crystal and exhibit a remarkable birefringence effect under the action of the external field. When the isosceles triangle coupling structure is filled with LC, the refractive index of the liquid crystal can be changed by changing the applied voltage, thereby achieving the function of an optical switch. Within a certain range, a linear relationship between refractive index and applied voltage can be obtained. Moreover, the proposed structure can be applied to biochemical sensing to detect glucose concentrations, and the sensitivity reaches as high as 0.283 nm·L/g, which is significantly higher than other values reported in the literature. The triangular coupling structure has advantages such as simple structure and ease of manufacturing, making it an ideal choice for the design of high-performance integrated plasmonic devices. Full article
Show Figures

Figure 1

15 pages, 4107 KB  
Article
A Spectral Method for Rapidly Determining the Linear Birefringence of Thin Polymer Films
by Dana Ortansa Dorohoi and Dan Gheorghe Dimitriu
Molecules 2024, 29(24), 6007; https://doi.org/10.3390/molecules29246007 - 20 Dec 2024
Viewed by 830
Abstract
A rapid and simple spectral method for determining the linear birefringence of thin anisotropic films, using the channeled spectra, is proposed in this article. Two channeled spectra must be recorded for a transparent system containing a thick anisotropic layer and a thin stretched [...] Read more.
A rapid and simple spectral method for determining the linear birefringence of thin anisotropic films, using the channeled spectra, is proposed in this article. Two channeled spectra must be recorded for a transparent system containing a thick anisotropic layer and a thin stretched polymer film, when the two anisotropic uniaxial layers have parallel and perpendicular optical axes, respectively. The sum and difference of the two channeled spectra indicate (by the positions of the maxima and minima in the resulting channeled spectra) the phase difference introduced by the thin polymer film. One must measure with precision only the thickness of the polymer film in order to compute the linear birefringence of the thin polymer film, using the position of the maxima and minima of the sum and difference. The experimental data obtained for poly (vinyl alcohol)—PVA—and poly (ethylene terephthalate)—PET—films attest to the applicability of the proposed method to the uniaxial transparent polymeric thin films. Full article
(This article belongs to the Special Issue Macromolecular Chemistry in Europe)
Show Figures

Figure 1

13 pages, 874 KB  
Article
Electro-Optic Kerr Response in Optically Isotropic Liquid Crystal Phases
by Tetiana Yevchenko, Dorota Dardas, Natalia Bielejewska and Arkadiusz C. Brańka
Materials 2024, 17(19), 4926; https://doi.org/10.3390/ma17194926 - 9 Oct 2024
Viewed by 1195
Abstract
The results of an experimental investigation of the temperature and wavelength dependence of the Kerr constant (K) of mixtures with an increasing amount of chiral dopant in an isotropic liquid crystal phase are reported. The material was composed of a nematic [...] Read more.
The results of an experimental investigation of the temperature and wavelength dependence of the Kerr constant (K) of mixtures with an increasing amount of chiral dopant in an isotropic liquid crystal phase are reported. The material was composed of a nematic liquid crystal (5CB) and a chiral dopant (CE2), which formed non-polymer-stabilized liquid crystalline blue phases with an exceptionally large value of K∼2 × 10−9 mV−2. The measurements were performed on liquid and blue phases at several concentrations covering a range of temperatures and using three wavelengths: 532 nm, 589 nm and 633 nm. The work focused on changes caused by concentration and their impact on the increase in the value of K, and it was found that in the case of the 5CB/CE2 mixture these changes were significant and quite systematic with temperature and wavelength. It is shown that the dispersion relation based on the single-band birefringence model described K well in isotropic liquid crystal phases at all of the measured concentrations. In an isotropic fluid, both temperature-dependent parameters in the dispersion relation had a simple linear form and, therefore, the K-surface could be described by only four constants. In the blue phase, the expression reproducing the temperature variation of K depended on concentration, which could vary from being almost linear to quasi-linear and could be represented well by an inverse exponential analytic expression. Full article
(This article belongs to the Section Optical and Photonic Materials)
Show Figures

Figure 1

12 pages, 4684 KB  
Article
Polarimeters for the Detection of Anisotropy from Reflectance
by Shuji Kamegaki, Zahra Khajehsaeidimahabadi, Meguya Ryu, Nguyen Hoai An Le, Soon Hock Ng, Ričardas Buividas, Gediminas Seniutinas, Vijayakumar Anand, Saulius Juodkazis and Junko Morikawa
Micromachines 2024, 15(6), 794; https://doi.org/10.3390/mi15060794 - 17 Jun 2024
Viewed by 1609
Abstract
Polarimetry is used to determine the Stokes parameters of a laser beam. Once all four S0,1,2,3 parameters are determined, the state of polarisation is established. Upon reflection of a laser beam with the defined S polarisation [...] Read more.
Polarimetry is used to determine the Stokes parameters of a laser beam. Once all four S0,1,2,3 parameters are determined, the state of polarisation is established. Upon reflection of a laser beam with the defined S polarisation state, the directly measured S parameters can be used to determine the optical properties of the surface, which modify the S-state upon reflection. Here, we use polarimetry for the determination of surface anisotropies related to the birefringence and dichroism of different materials, which have a common feature of linear patterns with different alignments and scales. It is shown that polarimetry in the back-reflected light is complementary to ellipsometry and four-polarisation camera imaging; experiments were carried out using a microscope. Full article
Show Figures

Figure 1

16 pages, 3149 KB  
Article
New Insights on Solvent-Induced Changes in Refractivity and Specific Rotation of Poly(propylene oxide) Systems Extracted from Channeled Spectra
by Alexandru Zara, Raluca Marinica Albu, Iuliana Stoica, Andreea Irina Barzic, Dan Gheorghe Dimitriu and Dana Ortansa Dorohoi
Int. J. Mol. Sci. 2024, 25(9), 4682; https://doi.org/10.3390/ijms25094682 - 25 Apr 2024
Viewed by 1421
Abstract
Investigation of chiroptical polymers in the solution phase is paramount for designing supramolecular architectures for photonic or biomedical devices. This work is devoted to the case study of poly(propylene oxide) (PPO) optical activity in several solvents: benzonitrile, carbon disulfide, chloroform, ethyl acetate, and [...] Read more.
Investigation of chiroptical polymers in the solution phase is paramount for designing supramolecular architectures for photonic or biomedical devices. This work is devoted to the case study of poly(propylene oxide) (PPO) optical activity in several solvents: benzonitrile, carbon disulfide, chloroform, ethyl acetate, and p-dioxane. To attain information on the interactions in these systems, rheological testing was undertaken, showing distinct variations of the rheological parameters as a function of the solvent type. These aspects are also reflected in the refractive index dispersive behavior, from which linear and non-linear optical properties are extracted. To determine the circular birefringence and specific rotation of the PPO solutions, the alternative method of the channeled spectra was employed. The spectral data were correlated with the molecular modeling of the PPO structural unit in the selected solvents. Density functional theory (DFT) computational data indicated that the torsional potential energy—related to the O1-C2-C3-O4 dihedral angle from the polymer repeating unit—was hindered in solvation environments characterized by high polarity and the ability to interact via hydrogen bonding. This was in agreement with the optical characterization of the samples, which indicated a lower circular birefringence and specific rotation for the solutions of PPO in ethyl acetate and p-dioxane. Also, the shape of optical rotatory dispersion curves was slightly modified for PPO in these solvents compared with the other ones. Full article
(This article belongs to the Special Issue Recent Research in Supramolecular Chemistry)
Show Figures

Figure 1

24 pages, 10468 KB  
Article
Optical Anisotropy of Polyethylene Terephthalate Films Characterized by Spectral Means
by Mihaela Iuliana Avadanei, Dan Gheorghe Dimitriu and Dana Ortansa Dorohoi
Polymers 2024, 16(6), 850; https://doi.org/10.3390/polym16060850 - 20 Mar 2024
Cited by 8 | Viewed by 2838
Abstract
Polyethylene terephthalate (PET) films are the subject of intensive research because of great interest in using them in applications, especially in medicine. From an optical point of view, PET films with a low degree of stretching can be considered uniaxial materials, for which [...] Read more.
Polyethylene terephthalate (PET) films are the subject of intensive research because of great interest in using them in applications, especially in medicine. From an optical point of view, PET films with a low degree of stretching can be considered uniaxial materials, for which the determination of the linear birefringence and its dispersion is very important. Two methods were applied here for the estimation of these parameters: the ellipsometric method and the channeled spectra method. The ellipsometric method uses monochromatic radiation; therefore, the linear birefringence of the PET films is determined for a given value of the radiation wavelength. The channeled spectra method allows for the estimation of the linear birefringence and its dispersion for a large range of wavelengths in the visible spectrum. A decrease in both parameters with the increase in the wavelength was recorded. To evidence the microstructure of PET films and the conformational changes induced by elongation and to evaluate the degree of orientation, a polarized infrared spectral study in attenuated total reflection (ATR-FTIR) mode was performed. The dichroic ratio (between the absorbance measured with linearly polarized radiation parallel and orthogonal relative to the stretching direction, respectively) and the ATR absorbance ratio for the machine direction (MD) and transversal direction (TD) configurations both for the stretched and unstretched PET samples were measured. Full article
(This article belongs to the Special Issue Advanced Polymeric Films II)
Show Figures

Figure 1

13 pages, 3022 KB  
Article
Structure-Function Correlation of Retinal Fibrosis in Eyes with Neovascular Age-Related Macular Degeneration
by Markus Schranz, Stefan Sacu, Gregor S. Reiter, Magdalena Baratsits, Silvia Desissaire, Michael Pircher, Georgios Mylonas, Christoph Hitzenberger, Ursula Schmidt-Erfurth and Philipp Ken Roberts
J. Clin. Med. 2024, 13(4), 1074; https://doi.org/10.3390/jcm13041074 - 14 Feb 2024
Cited by 3 | Viewed by 1894
Abstract
Purpose: To assess retinal function in areas of presumed fibrosis due to neovascular age-related macular degeneration (nAMD), using multimodal imaging and structure-function correlation. Design: Cross-sectional observational study. Methods: 30 eyes of 30 consecutive patients with nAMD with a minimum history of one year [...] Read more.
Purpose: To assess retinal function in areas of presumed fibrosis due to neovascular age-related macular degeneration (nAMD), using multimodal imaging and structure-function correlation. Design: Cross-sectional observational study. Methods: 30 eyes of 30 consecutive patients with nAMD with a minimum history of one year of anti-vascular endothelial growth factor therapy were included. Each patient underwent microperimetry (MP), color fundus photography (CFP), standard spectral-domain-based OCT (SD-OCT), and polarization sensitive-OCT (PS-OCT) imaging. PS-OCT technology can depict retinal fibrosis based on its birefringence. CFP, SD-OCT, and PS-OCT were evaluated independently for the presence of fibrosis at the corresponding MP stimuli locations. MP results and morphologic findings in CFP, SD-OCT, and PS-OCT were co-registered and analyzed using mixed linear models. Results: In total, 1350 MP locations were evaluated to assess the functional impact of fibrosis according to a standardized protocol. The estimated means of retinal areas with signs of fibrosis were 12.60 db (95% confidence interval: 10.44–14.76) in CFP, 11.60 db (95% COI: 8.84–14.36) in OCT, and 11.02 db (95% COI 8.10–13.94) in PS-OCT. Areas evaluated as subretinal fibrosis in three (7.2 db) or two (10.1 db) modalities were significantly correlated with a lower retinal sensitivity than a subretinal fibrosis observed in only one (15.3 db) or none (23.3 db) modality (p < 0.001). Conclusions: CFP, SD-OCT and PS-OCT are all suited to detect areas of reduced retinal sensitivity related to fibrosis, however, a multimodal imaging approach provides higher accuracy in the identification of areas with low sensitivity in MP (i.e., impaired retinal function), and thereby improves the detection rate of subretinal fibrosis in nAMD. Full article
Show Figures

Figure 1

Back to TopTop