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Keywords = linen yellowing

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22 pages, 9241 KB  
Article
Identification of Shellfish Blue on an Ancient Egyptian (Dynasty XVIII) Painted Votive Textile
by Jennifer Poulin, Margaret-Ashley Veall and Chris Paulocik
Heritage 2025, 8(7), 257; https://doi.org/10.3390/heritage8070257 - 1 Jul 2025
Cited by 1 | Viewed by 2371
Abstract
In 1906, Charles T. Currelly participated in excavations at Deir el-Bahri, Egypt, recovering votive offerings from the Temple of Hathor (Dynasty XVIII, reign of Hatshepsut, 1479–1458 BCE). These objects became part of the founding collection of the Royal Ontario Museum, where Currelly served [...] Read more.
In 1906, Charles T. Currelly participated in excavations at Deir el-Bahri, Egypt, recovering votive offerings from the Temple of Hathor (Dynasty XVIII, reign of Hatshepsut, 1479–1458 BCE). These objects became part of the founding collection of the Royal Ontario Museum, where Currelly served as the first director. Among the offerings are several paintings on linen cloth. During examination of one painted textile, a border fringe with cream (suspected undyed), yellow and blue looped threads was sampled and analysed for dyes using gas chromatography–mass spectrometry. The yellow threads were found to contain a tannin-rich dyestuff, likely derived from Rhus spp., a common dye in ancient Egypt. Unexpectedly, the blue threads yielded brominated-indigoid marker compounds, indicating the use of a Murex-derived dye. While purple shellfish dye is rare due to the high cost of its complex production, blue shellfish dye is even more exceptional and has only been identified a handful of times on archaeological textiles. Calculated values of di-brominated to mono-brominated indigoid compounds suggests the dye originated from an indigotin-rich type of Hexaplex trunculus snail, a Mediterranean species. This finding represents a rare example of blue shellfish dye use in ancient Egypt and provides new insights into the dyeing technologies of Dynasty XVIII and the importance of this sky-blue colour in the worship of the goddess Hathor. Full article
(This article belongs to the Special Issue Dyes in History and Archaeology 43)
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44 pages, 14796 KB  
Article
Painting Materials and Technique for the Expression of Chinese Inheritance in Liu Kang’s Huangshan and Guilin Landscapes (1977–1996)
by Damian Lizun, Teresa Kurkiewicz, Bogusław Szczupak and Jarosław Rogóż
Materials 2022, 15(21), 7481; https://doi.org/10.3390/ma15217481 - 25 Oct 2022
Cited by 3 | Viewed by 3861
Abstract
Liu Kang (1911–2004) was a Chinese artist who settled in Singapore in 1945 and eventually became a leading modern artist in Singapore. He received academic training in Shanghai (1926–1928) and Paris (1929–1932). Liu Kang’s frequent visits to China from the 1970s to the [...] Read more.
Liu Kang (1911–2004) was a Chinese artist who settled in Singapore in 1945 and eventually became a leading modern artist in Singapore. He received academic training in Shanghai (1926–1928) and Paris (1929–1932). Liu Kang’s frequent visits to China from the 1970s to the 1990s contributed to a special artistic subject—the Huangshan and Guilin mountains. This subject matter triggered an uncommon painting approach for his oeuvre. In this context, this study elucidates the artist’s choice of materials and methods for the execution of 11 paintings, dating between 1977 and 1996, depicting Huangshan and Guilin landscapes. The paintings belong to the collection of the National Gallery Singapore. They were investigated with a combination of non- and micro-invasive techniques, supplemented by a wealth of documentary sources and art history research. The obtained results highlight the predominant use of hardboards resembling Masonite® Presdwood® without the application of an intermediate ground layer. Commercially prepared cotton and linen painting supports were used less frequently, and their structure and ground composition were variable. This study revealed the use of a conventional colour base for the execution of the paintings—a consistent colour scheme favouring ultramarine, yellow and red iron-containing earths, viridian and titanium white. Less commonly used pigments include Prussian blue, cobalt blue, phthalocyanine blue, phthalocyanine green, naphthol red AS-D, umber, Cr-containing yellow(s), cadmium yellow or its variant(s), Hansa yellow G, lithopone and/or barium white and zinc white and bone black. The documentary sources indirectly pointed to the use of Royal Talens, Rowney and Winsor & Newton, brands of oil paints. Moreover, technical and archival findings indicated the artist’s tendency to recycle rejected compositions, thereby strongly suggesting that the paintings were executed in the studio. Although this study focuses on the Singapore artist and his series of paintings relating to China, it contributes to existing international studies of modern artists’ materials. Full article
(This article belongs to the Special Issue Pigments between Antiquity and Modernity)
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20 pages, 3012 KB  
Article
Long-Term Temperature Effects on the Natural Linen Aging of the Turin Shroud
by Liberato De Caro, César Barta, Giulio Fanti, Emilio Matricciani, Teresa Sibillano and Cinzia Giannini
Information 2022, 13(10), 458; https://doi.org/10.3390/info13100458 - 28 Sep 2022
Cited by 3 | Viewed by 11567
Abstract
In 2021, Wide-angle X-ray Scattering (WAXS) was applied to a sample of the Turin Shroud as a new method for dating ancient linen threads by inspecting their structural degradation. The major result of the research was to estimate the natural aging of the [...] Read more.
In 2021, Wide-angle X-ray Scattering (WAXS) was applied to a sample of the Turin Shroud as a new method for dating ancient linen threads by inspecting their structural degradation. The major result of the research was to estimate the natural aging of the linen of the Shroud, through which it was found to be compatible with the hypothesis of a 2000-year-old relic, and not a medieval fabric. The present work regards the theoretical natural aging of the linen versus different alleged historical–geographical paths of the Shroud through cities where the presence of icons of Jesus Christ is attested. The theoretical results of the natural aging of the Shroud, calculated for the year 2021, agree extremely well with the experimental results for at least one alleged path. The results also show that if the Shroud were medieval and kept in Europe for 7 centuries, natural aging that is one order of magnitude less than that measured by WAXS would have resulted. Today, the Shroud is kept in a reliquary with a controlled atmosphere, at 19~20 °C temperature, and 50% relative humidity. These values are shown to be unsuitable for maintaining the depolymerization of the cellulose at a level that is sufficiently low enough to preserve the image visible on the Shroud for a long time. Full article
(This article belongs to the Special Issue Techniques and Data Analysis in Cultural Heritage)
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11 pages, 3906 KB  
Article
X-ray Dating of a Turin Shroud’s Linen Sample
by Liberato De Caro, Teresa Sibillano, Rocco Lassandro, Cinzia Giannini and Giulio Fanti
Heritage 2022, 5(2), 860-870; https://doi.org/10.3390/heritage5020047 - 11 Apr 2022
Cited by 9 | Viewed by 155750
Abstract
On a sample of the Turin Shroud (TS), we applied a new method for dating ancient linen threads by inspecting their structural degradation by means of Wide-Angle X-ray Scattering (WAXS). The X-ray dating method was applied to a sample of the TS consisting [...] Read more.
On a sample of the Turin Shroud (TS), we applied a new method for dating ancient linen threads by inspecting their structural degradation by means of Wide-Angle X-ray Scattering (WAXS). The X-ray dating method was applied to a sample of the TS consisting of a thread taken in proximity of the 1988/radiocarbon area (corner of the TS corresponding to the feet area of the frontal image, near the so-called Raes sample). The size of the linen sample was about 0.5 mm × 1 mm. We obtained one-dimensional integrated WAXS data profiles for the TS sample, which were fully compatible with the analogous measurements obtained on a linen sample whose dating, according to historical records, is 55–74 AD, Siege of Masada (Israel). The degree of natural aging of the cellulose that constitutes the linen of the investigated sample, obtained by X-ray analysis, showed that the TS fabric is much older than the seven centuries proposed by the 1988 radiocarbon dating. The experimental results are compatible with the hypothesis that the TS is a 2000-year-old relic, as supposed by Christian tradition, under the condition that it was kept at suitable levels of average secular temperature—20.0–22.5 °C—and correlated relative humidity—75–55%—for 13 centuries of unknown history, in addition to the seven centuries of known history in Europe. To make the present result compatible with that of the 1988 radiocarbon test, the TS should have been conserved during its hypothetical seven centuries of life at a secular room temperature very close to the maximum values registered on the earth. Full article
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18 pages, 8712 KB  
Article
Yellowing of Ancient Linen and Its Effects on the Colours of the Holy Face of Manoppello
by Liberato De Caro, Emilio Matricciani and Giulio Fanti
Heritage 2020, 3(1), 1-18; https://doi.org/10.3390/heritage3010001 - 23 Dec 2019
Cited by 3 | Viewed by 7779
Abstract
On both sides of the Veil of Manoppello, made with very thin linen, translucent linen threads, probably starched, a Holy Face of Jesus Christ is visible. During the centuries, the yellowing of the linen threads has changed the aspect of the original face, [...] Read more.
On both sides of the Veil of Manoppello, made with very thin linen, translucent linen threads, probably starched, a Holy Face of Jesus Christ is visible. During the centuries, the yellowing of the linen threads has changed the aspect of the original face, in particular producing unnatural colours of the eyes. Indeed, as inferred by some experimental evidences, both on a microscopic and a macroscopic scale, the eyes were probably originally blue. Blue was the colour mainly affected by the yellowing of the linen threads, leading to greenish shades not compatible with human irises’ colours. Thus, we think that this finding compelled an artist to retouch the eyes’ irises with brown colour. The theoretical analysis of degradation times of the cellulose contained in starched linen indicates that, at ambient temperature, the yellowing takes about ten centuries to reach 95% of its maximum. Due to its peculiar optical characteristics and historical vicissitudes, the Veil of Manoppello likely coincides with the Veronica’s Veil, the alleged relic of the face of Christ impressed during his Passion, just before his crucifixion. If the Manoppello and Veronica’s Veils are the same object, any hypothesized colour retouch was done just before its first known public procession and exhibition in Rome, i.e., before the year 1200, after ten centuries of yellowing. Therefore, the Veil of Manoppello could be very ancient, even of the Roman epoch. Full article
(This article belongs to the Section Artistic Heritage)
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5 pages, 499 KB  
Letter
Describing, Step by Step, the Shroud Body Image Formation
by Giovanni Fazio, Giuseppe Mandaglio and Antonio Anastasi
Heritage 2019, 2(1), 34-38; https://doi.org/10.3390/heritage2010003 - 22 Dec 2018
Cited by 6 | Viewed by 6913
Abstract
In the recent past, we introduced a natural mechanism (stochastic) in the literature to explain the image formation on the Linen of Turin by taking into account the yellowed linen fibrils distribution of the Shroud. In our opinion, a weak energy source like [...] Read more.
In the recent past, we introduced a natural mechanism (stochastic) in the literature to explain the image formation on the Linen of Turin by taking into account the yellowed linen fibrils distribution of the Shroud. In our opinion, a weak energy source like the thermal radiation produced by the enveloped corpse yielded on the linen a latent image, ruled by a stochastic process, and made by small bundles of yellowed fibrils. The image on the Shroud is unique and it appeared later than the blood image with its 2D and 3D characteristics. Moreover, a correlation between the density of yellowed fibrils and the cloth-body distance is present, again proving the action of a stochastic process. In this paper, we would like to discuss, step by step, the whole natural process that occurred in the formation of the Shroud body image. In every case, to confirm our hypothesis of Shroud body image formation, it is necessary to perform experimental investigations in the Forensic Medicine area. Full article
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