Search Results (273)

This study investigates the mechanisms behind strong water sensitivity in some low-clay-mineral-content tight conglomerate reservoirs in China’s Mahu Sag. Using core-scale water sensitivity tests, mineral analysis, in situ micro-CT scanning, and digital core techniques, we analyzed how water sensitivity alters pore structures across cores of varying permeability. Key findings include the following: (1) Water sensitivity damage increases as initial gas permeability decreases. (2) Despite low clay content, significant water sensitivity arises from the combined effect of water and velocity sensitivity, driven mainly by illite and kaolinite concentrated in gravel-edge fractures and key flow channels. (3) Water sensitivity causes non-uniform pore structure changes—some macropores and throats enlarge locally, reflecting heterogeneity. (4) Structural responses differ by permeability: medium–low permeability cores suffer from clay mineral swelling and particle migration, whereas high-permeability cores resist overall damage and may even have main flow paths enhanced by flushing. (5) Water sensitivity mainly degrades smaller pores but can improve larger ones, with the critical pore-size threshold between macro- and micro-pores inversely related to permeability. This work clarifies the pore-scale mechanisms of water sensitivity in some low-clay-mineral-content tight conglomerates, and can provide guidance for the optimization of water types injected into similar conglomerate reservoirs. Full article

The mineralogical, geochemical, and statistical characteristics of recent fluvial deposits from the Brahmaputra–Jamuna River, Bangladesh, were examined to determine their provenance, transport dynamics, and depositional environment. Sediments were analyzed using X-ray diffraction (XRD), wavelength dispersive X-ray fluorescence (WD-XRF), field emission scanning electron microscopy (FE-SEM), and electron probe microanalysis (EPMA). Grain size analysis revealed a predominance of medium-to-fine sand (mean grain size 1.77–3.43 ϕ), with moderately well-sorted textures (sorting: 0.33–0.77 ϕ), mesokurtic to leptokurtic distributions, and skewness values ranging from −0.21 to +0.30. Mineralogical results show a high quartz content with minor feldspar, mica, zircon, rutile, and iron-bearing minerals. Geochemical data indicates high SiO₂ (63.39%–70.94%) and Al₂O₃ (12.25%–14.20%) concentrations and calculated chemical index of alteration (CIA) values ranging from 60.90 to 66.82. The microstructural study revealed angular to sub-angular grains with conchoidal fractures and stepped microcracks, indicating brittle deformation under high-energy conditions, which is consistent with short transport distances, limited sedimentary recycling, and a derivation from mechanically weathered source rocks. Multivariate analyses (PCA and K-means clustering) of grain size parameters reveal two distinct sedimentary regimes, namely Cluster 1 as finer-grained (2.36 ϕ), poorly sorted sediments, and Cluster 2 as coarser (2.98 ϕ), well-sorted deposits. Discriminant function values (Y₂: 78.82–119.12; Y₃: −6.01 to −2.56; V₁: 1.457–2.442; V₂: 1.409–2.323) highlight shallow water, fluvial/deltaic aspects, and turbidite depositional environments. These findings advance the understanding of sedimentary dynamics within large, braided river basins and support future investigations into the sustainable management of fluvial depositional environments. Full article

The geochemical characteristics of reinjection fluids play a crucial role in controlling water–rock interactions and the long-term stability of geothermal reservoirs. This study aims to evaluate how different fluid chemistries affect mineral dissolution–precipitation behavior and ion migration during geothermal reinjection. Five types of reinjection water—including geothermal source water (i.e., formation water from the reservoir), primary and secondary treated waters, and their mixtures—were reacted with carbonate rocks from the Wumishan Formation of the Xiong’an New Area, North China Basin, under reservoir-like conditions (70 °C, 17 MPa). A combination of batch experiments, inverse modeling using PHREEQC, and one-dimensional reactive transport simulations was employed. Results show that fluid pH, ionic strength, and saturation state significantly influence reaction pathways. Alkaline-treated waters enhanced silicate dissolution, increasing Na⁺, K⁺, and Si concentrations, while source water and its mixtures promoted carbonate precipitation, increasing the risk of clogging. Simulations revealed that the early injection stage is the most reactive, with rapid ion front advancement and strong mineral transformations. Reaction-controlled ions such as Ca²⁺ and SO₄²⁻ formed enrichment zones, while conservative ions like Na⁺ and Cl⁻ propagated more uniformly. Moderate alkaline regulation was found to mitigate carbonate scaling and improve silicate reactivity, thereby reducing permeability loss. This integrated approach provides mechanistic understanding and practical guidance for reinjection fluid design in medium-to-deep geothermal systems. Full article

Multi-source hyperspectral data are increasingly applied in environmental monitoring, precision agriculture, and geological exploration, yet differences in sensor characteristics hinder interoperability. This study presents a systematic cross-validation of surface reflectance between the German EnMAP mission and the Chinese GF5-02 Advanced Hyperspectral Imager (AHSI) across four representative land cover types: minerals in the East Tianshan Mountains, tropical grasslands in Hainan Danzhou, desert in Dunhuang, and inland salt lakes in Qinghai. Using EnMAP Level-2A products as reference, we evaluated GF5-02 reflectance with spectral angle (SA), root mean squared error (RMSE), relative RMSE (RRMSE), and correlation coefficient (R). Results show strong consistency for high- and medium-reflectance surfaces (R > 0.96, SA < 0.08 rad), while water bodies exhibit larger discrepancies (R = 0.82, SA = 0.34 rad), likely due to atmospheric correction and sensor response differences. Additional ground validation in the East Tianshan region confirmed the reliability and stability of GF5-02 data. Overall, GF5-02 demonstrates high consistency with EnMAP across most land cover types, supporting quantitative applications, though further improvements are needed for low-reflectance environments. Full article

The Baijianshan deposit is the sole skarn Zn-Cu polymetallic deposit in the Xiaoshitouquan ore field, Xinjiang, China. Its ore genesis remains controversial, which hinders understanding of the relationship between skarn-type Zn-Cu and adjacent epithermal Ag-Cu-Pb-Zn mineralization and consequently impedes further regional exploration. LA-ICP-MS U-Pb dating on zircons from the granite and granite porphyry from the mining area yielded ages of 311 ± 1.7 Ma and 312 ± 1.6 Ma, respectively. The corresponding zircon ε_Hf(t) values and T_DM ages are 8.7–9.9 and 624–555 Ma for the granite, and 7.2–9.9 and 673–552 Ma for the granite porphyry. These granites are metaluminous, high-K calc-alkaline I-type granites, with high LREE/HREE ratios (4.92–9.03) and pronounced negative Eu anomalies. They are enriched in K, Th, U, Zr, and Hf, with significant depletions in Sr, P, and Ti. Combined geological and geochemical evidence indicate that these Late Carboniferous granites were derived from the juvenile crustal and formed in subduction-related back basin. Two-phase aqueous inclusions in the ore-bearing quartz and calcite have homogenization temperatures ranging from 117 to 207 °C and 112 to 160 °C, respectively, with the salinities in the ranges of 0.18~7.17 and 0.53~5.26 wt% NaCl eq. The S and Pb isotopic compositions of sulfides in the ores indicate that the ore-forming metals were sourced from the medium-acidic magmatite. The δ¹⁸O_H2O and δD_H2O values of hydrothermal fluids range from −6.97% to −5.84% and −106.8% to −99.6%, respectively, suggesting that the ore-forming fluids originated from the mixing of magmatic and meteoric water. Fluid mixing and corresponding conductive cooling were identified as the principal mechanism triggering the metallic mineral precipitation. The Baijianshan skarn Zn-Cu polymetallic deposit shares contemporaneous magmatic-mineralization ages and analogous material sources with the epithermal polymetallic deposits in the Xiaoshitouquan ore field, collectively constituting a unified skarn-epithermal metallogenic system. This hypothesis indicates that the deep parts of the epithermal deposits within the Yamansu volcanic rocks possess potential for exploring the porphyry-skarn-type deposits. Full article

Polyurethane foams (PUFs) utilised in the comfort industry generate substantial trim waste volumes requiring end-of-life management. Rebonding, one form of mechanical recycling, is a technique involving the mechanical breakdown and subsequent adhesion of PUF using polyurethane prepolymers yielding a recycled material. However, the limited investigation into the properties of rebond PUF constrains its potential for novel alternative uses, such as soilless plant-growing media. A laboratory-scale rebond production method has been developed, and a series of rebond PUFs produced to evaluate the influence of crumb size, density, prepolymer chemistry, and prepolymer loading on the properties of the rebond PUFs and their suitability as growing media. The results indicated that higher quality rebonds were obtained with larger crumb sizes (mixed or >7 mm), moderate amounts of prepolymer (4.5 to 7.5% by mass), and higher densities. Increasing density directly influenced plant growth-related properties, including reducing airflow, increasing water uptake through wicking, and increasing water retention through drainage alongside larger crumb sizes [>7 mm]. To demonstrate the method’s utility for rapid screening, a plant growth trial was conducted using density as the key variable. Eruca sativa plants grown in low-density rebonds exhibited comparable growth (leaf length, leaf width, and shoot fresh weight) to mineral wool, whereas medium- and high-density rebonds showed reduced growth. This study validates a lab-scale technique that enables the rapid optimisation of rebond PUFs for novel applications like soilless growing media. Full article

This study aimed to isolate and identify fungi capable of producing xylanases and cellulases. Thirty-eight fungal strains were isolated from decaying water hyacinth (WH), and two were selected based on their superior enzyme production under solid-state fermentation (SSF). The strains were identified through morphological, cultural, and molecular analyses as Aspergillus austwickii B6 and Trichoderma harzianum M7. Their ribosomal ITS sequences were deposited in GenBank under accession numbers PQ142799.1 for A. austwickii B6 and PQ007458.1 for T. harzianum M7. Enzyme production was evaluated under SSF using eight culture medium variants prepared with natural or pretreated biomasses of WH and sugarcane bagasse (SCB), combined with either NaNO₃ or (NH₄)₂SO₄ as nitrogen sources. The maximum xylanase and cellulase activities were 752 and 65 U/g dry matter (DM), respectively, for A. austwickii B6, and 1724 and 152 U/g DM for T. harzianum M7, when cultivated on a low-cost medium composed of pretreated WH, (NH₄)₂SO₄, and a simple mineral salt solution. These findings highlight the potential of locally isolated fungal strains and lignocellulosic residues as cost-effective substrates and inducers of xylanase and cellulase production under SSF and underscore the importance of WH pretreatment to enhance substrate availability and maximize enzyme yields. Full article

Red bell pepper (Capsicum annuum L.) is a valuable source of health-promoting phytochemicals and essential minerals. This study investigated the impact of using geothermal mineral water versus tap water as the fermentation medium on the nutritional, physicochemical, and sensory properties of two red bell peppers (cultivars ‘Yecla F₁’ and ‘Salomon F₁’). The results showed that fermentation caused a significant decrease in the content of L-ascorbic acid (by 30–50%), carotenoids (~30%) and polyphenols (by 25–30%), with lower nutrient losses observed in peppers fermented with geothermal water. In addition, fermentation with geothermal water increased the calcium, magnesium, and potassium contents of the peppers compared to tap water. Sensory analysis showed that the pepper cultivars had a greater impact on the overall sensory quality than the fermentation medium or the evaluation time, although geothermal water had a positive effect on the texture of the fermented peppers. These results suggest that geothermal water may be a beneficial alternative to traditional water sources in vegetable fermentation, improving both the nutritional and sensory properties of the final product. Full article

The transformation of smectite to illite documents multi-scale water–rock–hydrocarbon interaction dynamics. Current studies predominantly emphasize the influence of inorganic systems on this process, while overlooking the dynamic regulation by organic matter and the synergistic effects of multiple controlling factors under actual geological conditions. In this study, we conducted integrated semi-open pyrolysis experiments on natural samples from the Chang-7 Member and hydrothermal experiments using synthetic analogs. The illitization process of smectite was characterized through XRD analysis and SEM observations, while organic geochemical testing was employed to track the corresponding thermal evolution of organic matter. The semi-open pyrolysis results reveal that significant changes in illite–smectite (I/S) mixed layer minerals and illite content/morphology occur above 320 °C, which coincides with the critical threshold for extensive organic matter evolution. Thermal degradation of organic matter generates pore space, thereby enhancing water–rock interactions involving clay minerals. This demonstrates the co-evolution of organic matter and smectite, and indicates that temperature indirectly influences illitization by regulating organic matter thermal evolution. The hydrothermal simulation experiments demonstrate the early-stage characteristics of illitization. Unlike long-term geological evolution, K⁺ under experimental conditions primarily originates from the aqueous medium due to kinetic constraints on feldspar dissolution. Notably, organic matter regulates K⁺ partitioning dynamics—increased organic matter content hinders K⁺ incorporation into smectite interlayers, thereby suppressing the illitization process. Cross-system experimental analysis reveals that organic matter exhibits temporally dependent dual functionality, serving both mediating and modulating roles within inorganic diagenetic systems. This study delineates diagnostic-stage-dependent mechanisms governing smectite illitization through multifactorial synergistic interplay, establishing a predictive framework applicable to organic-rich systems exemplified by the Chang-7 Shale. Full article

The evolution of ore-forming fluids in gold precipitation is a key aspect in understanding the genesis of orogenic gold deposits. Traditional fluid inclusion analyses are often limited in revealing the fluid property changes during mineralization, leading to significant debates on the mineralization temperature and fluid sources. In this study, we selected the Liba gold deposit in the West Qinling orogen and employed scanning electron microscope–cathodoluminescence (SEM-CL) and laser ablation–inductively coupled plasma mass spectrometry (LA-ICPMS) to analyze the microstructure and trace element characteristics of quartz veins, revealing the multi-stage evolution of ore-forming fluids and the mineralization mechanisms. SEM-CL imaging identified five distinct quartz stages. The pre-mineralization (Qz0) and early-stage mineralization (Qz1) fluids were predominantly magmatic–metamorphic in origin, as indicated by relatively high δ¹⁸O and δD values. During the primary metallogenic (Qz2a, Qz2b) and late-stage mineralization (Qz3), temperatures progressively decreased, and the gradual mixing of meteoric water and formation water was observed, which promoted gold precipitation. And the content of trace elements in post-mineralization quartz (Qz4) is significantly lower and similar to that in the Qz0 stage. Through the analysis of quartz trace elements (e.g., Al/Ti, Ge/Al ratios) and isotope data (δ18O = 8.25‰ to 12.67‰, δD = −119.1‰ to −79.8‰), the results indicate that the Liba gold deposit is a medium- to low-temperature orogenic gold deposit. Furthermore, the gold enrichment process was primarily driven by a hydrothermal system, with variations in the fluid composition during mineralization contributing to the concentration of gold. Full article

The effects of wildfires and prescribed burnings on soil are highly variable. In order to evaluate the effects of different burning intensities on soil properties, a surface-controlled burn of undisturbed soil monoliths was carried out by combining temperatures (50 and 80 °C) and residence times (12 and 24 min). The effects of this burning gradient are evaluated at two soil depths (0–1 and 1–3 cm), with time (just after burning or immediate effects, T0, and five months later, T5), as well as the influence of ash (presence or absence). The results indicate that most soil properties were affected by the burning gradient applied only in the most superficial cm (0–1 cm), with few effects at greater depths. The most intense burn had the strongest immediate impact, reducing soil organic carbon, recalcitrant organic carbon, and microbial biomass carbon, as well as increasing the labile organic carbon and the microbial activity. On the other hand, this burning caused a strong decrease in soil water repellency at a 0–1 cm depth and increased it at 1–3 cm. In contrast, medium-intensity burning caused the opposite effect, increasing water repellency at the soil surface and reducing it at 1–3 cm. As a result of the mineralization of organic matter, the EC and pH increased significantly in all burning combinations and both soil depths studied. After five months (T5), several of these parameters tended to approach the values of unburned soil. Full article

To unravel the link between agate geochemistry, host volcanic rocks, and ore-forming processes, this study integrated elemental correlation analysis, interaction interpretation, and interpretable machine learning (LightGBM-SHAP framework with SMOTE and 5-fold cross-validation) using 203 in-situ element datasets from 16 global deposits. The framework achieved 99.01% test accuracy and 97.4% independent prediction accuracy in discriminating host volcanic rock types. Key findings reveal divergence between statistical elemental correlations and geological interactions. Synergies reflect co-migration/co-precipitation, while antagonisms stem from source competition or precipitation inhibition, unraveling processes like stepwise crystallization. Rhyolite-hosted agates form via a “crust-derived magmatic hydrothermal fluid—medium-low salinity complexation—multi-stage precipitation” model, driven by high-silica fluids enriching Sb/Zn. Andesite-hosted agates follow a “contaminated fluid—hydrothermal alteration—precipitation window differentiation” model, controlled by crustal contamination. Basalt-hosted agates form through a “low-temperature hydrothermal fluid—basic alteration—progressive mineral decomposition” model, with meteoric water regulating Na-Zn relationships. Zn acts as a cross-lithology indicator, tracing crust-derived fluid processes in rhyolites, feldspar alteration intensity in andesites, and alteration timing in basalts. This work advances volcanic-agate genetic studies via “correlation—interaction—mineralization model” coupling, with future directions focusing on large-scale micro-area elemental analysis. Full article

Ten ukiyo-e woodblock prints from the collection of the Museo delle Culture in Lugano (Switzerland) were analyzed to identify the materials used in their production. These Japanese artworks were traditionally created with colors derived from minerals and plants, mixed with diluted animal glue and applied to paper using wooden matrices. Due to their fragility, non-invasive external reflection infrared spectroscopy and imaging analysis were employed. Spectral data were compared with reference samples of Japanese pigments and existing literature, reflecting the growing interest in the characterization of ukiyo-e prints. Within the limits of the non-invasive approach, several colorants were identified, including akane (madder), suo (sappanwood), yamahaji (Japanese sumac), kariyasu (Eulalia), and kio (orpiment), along with a proteinaceous binding medium. The extensive use of bero-ai (Prussian blue), applied both as a pure pigment and in mixtures, was confirmed. Notably, mica was detected in the background of one print, providing the first analytical evidence of the kirazuri decorative technique, which produces a sparkling, silver-like effect. Ultraviolet-induced fluorescence imaging further contributed to the assessment of conservation status, revealing faded decorative motifs and signs of previous water damage. Full article

In the context of the current global transition toward low-carbon energy, the issue of $C{O}_2$ utilization has become increasingly important. One of the most promising natural targets for $C{O}_2$ sequestration is the terrigenous sedimentary formations found in oil, gas, and coal basins. It is generally assumed that $C{O}_2$ injected into such formations can be stored indefinitely in a stable form. However, the dissolution of $C{O}_2$ into subsurface water leads to a reduction in pH, which may cause partial dissolution of the host formation, altering the structure of the subsurface in the injection zone. This process is relatively slow, potentially unfolding over decades or even centuries, and its long-term consequences require careful investigation through mathematical modeling. The geological formation is treated as a partially soluble porous medium, where the dissolution rate is governed by surface chemical reactions occurring at the pore boundaries. In this study, we present an applied mathematical model that captures the coupled processes of mass transport, surface chemical reactions, and the resulting microscopic changes in the pore structure of the formation. To ensure the model remains grounded in realistic geological conditions, we based it on exploration data characterizing the composition and microstructure of the pore space typical of the Cenomanian suite in northern Western Siberia. The model incorporates the dominant geochemical reactions involving calcium carbonate (calcite, $CaC{O}_3$), characteristic of Cenomanian reservoir rocks. It describes the dissolution of $C{O}_2$ in the pore fluid and the associated evolution of ion concentrations, specifically $H^{+}$, $C{a}^{2+}$, and $HC{O}_3^{-}$. The input parameters are derived from experimental data. While the model focuses on calcite-based formations, the algorithm can be adapted to other mineralogies with appropriate modifications to the reaction terms. The simulation domain is defined as a cubic region with a side length of 1 $\mathsf{\mu }$m, representing a fragment of the geological formation with a porosity of 0.33. The pore space is initially filled with a mixture of liquid $C{O}_2$ and water at known saturation levels. The mathematical framework consists of a system of diffusion–reaction equations describing the dissolution of $C{O}_2$ in water and the subsequent mineral dissolution, coupled with a model for surface evolution of the solid phase. This model enables calculation of surface reaction rates within the porous medium and estimates the timescales over which significant changes in pore structure may occur, depending on the relative saturations of water and liquid $C{O}_2$. Full article

Currently, the partial substitution of mineral aggregates with rubber particles in the preparation of rubber concrete (RC) is an effective method for recycling waste rubber materials. However, the mechanism of interfacial interactions in RC at high temperatures is not well understood. This study aims to explore the effect of high temperature on intermolecular interactions at the RC interface and its relationship with macroscopic mechanical properties. Molecular dynamics (MD) simulation technology was employed to construct an RC interface model. The temperature is controlled at room temperature (300 K), medium low temperature (320 K, 340 K, 360 K), and high temperature (500 K, 700 K). The interface model was analyzed from multiple dimensions such as binding energy, turning radius, and interface structure. The results show that the higher the temperature, the more easily water molecules aggregate at the interface of the two phases. As the temperature increases, the proportion of water molecules at the interface increases from 6% to 16%. Since rubber and water molecules cannot form hydrogen bonds, the formation of chemical bonds at the interface between the two phases is affected, leading to a decrease in RC binding energy. The interface bonding energy decreases by 12.6% at a temperature of 700 K. In addition, the radius of gyration of rubber is proportional to temperature. As the temperature increases, the average radius of gyration increases from 5.8 Å to 6.15 Å, and the numerical fluctuation amplitude is greater, resulting in a relatively loose and unstable rubber structure. Furthermore, the bonding strength in RC mainly comes from non-hydrogen bond interactions, and high temperatures cause an increase in bond length while reducing the strength and stability of chemical bonds. Finally, high temperatures increase the atomic movement speed in natural rubber (NR). As the temperature increases, the diffusion coefficients of H_NR and C_NR increase from 0.08 and 0.04 to 1.835 and 1.473, respectively, preventing good connections between atoms at the interface. The study provides nanoscale insights for optimizing RC. Full article