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22 pages, 9503 KB  
Article
Analysis of Annual Maximum Ice-Influenced and Open-Water Levels at Select Hydrometric Stations on Canadian Rivers
by Yonas Dibike, Laurent de Rham, Spyros Beltaos, Daniel L. Peters and Barrie Bonsal
Water 2025, 17(20), 2930; https://doi.org/10.3390/w17202930 - 10 Oct 2025
Abstract
River ice is a common feature in most Canadian rivers and streams during the cold season. River channel hydraulics under ice conditions may cause higher water levels at a relatively lower discharge compared to the open-water flood events. Elevated water levels resulting from [...] Read more.
River ice is a common feature in most Canadian rivers and streams during the cold season. River channel hydraulics under ice conditions may cause higher water levels at a relatively lower discharge compared to the open-water flood events. Elevated water levels resulting from river ice processes throughout fall freeze-over, mid-winter, and spring break-up are important hydrologic events with diverse morphological, ecological, and socio-economic impacts. This study analyzes the timing of maximum water levels (occurring during freeze-over, spring break-up, and open-water periods) and the typology of maximum ice-related events (at freeze-over, mid-winter, and spring break-up) using data from the Canadian River Ice Database. The study also compares annual maximum water levels during the river ice and open-water periods at selected hydrometric stations from 1966 to 2015, divided into two 25-year windows: 1966–1990 and 1991–2015. A return period classification method was applied to define ice-influenced, open-water, and mixed-regime conditions. The results indicate that the majority of ice-influenced maximum water levels occurred during spring break-up (~79% in 1966–1990 and ~69% in 1991–2015), followed by fall freeze-up (~13% and ~23%) and mid-winter break-up (~8% and ~7%) for the two periods, respectively. Among 15 stations analyzed for 1966–1990 and 42 stations for 1991–2015, the proportion of annual maximum water levels dominated by open-water conditions increased from 47% to 55%, while ice-dominated events decreased from 13% to 12%, and mixed-regime events dropped from 40% to 33%. However, a focused comparison of eight common stations revealed minimal change in the distribution of water level-generating events between the two periods. The findings offer valuable insights into the spatial distribution of maximum water level-generating mechanisms across Canada. Full article
(This article belongs to the Special Issue Hydroclimatic Changes in the Cold Regions)
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19 pages, 2721 KB  
Article
Effect of Vibration Timing on Mechanical and Durability Properties of Early-Strength Cement-Based Composites for Bridge Wet Joints
by Xiaodong Li, Jianxin Li, Xiang Tian, Yafeng Pang, Bing Fu and Shuangxi Zhou
Materials 2025, 18(20), 4645; https://doi.org/10.3390/ma18204645 - 10 Oct 2025
Abstract
This study explores the influence of vibration timing on the performance of high early-strength cement-based composites used in bridge wet joints. A series of experimental techniques, including SEM, MIP, and RCM tests, were employed to evaluate microstructural evolution, mechanical properties, and durability. The [...] Read more.
This study explores the influence of vibration timing on the performance of high early-strength cement-based composites used in bridge wet joints. A series of experimental techniques, including SEM, MIP, and RCM tests, were employed to evaluate microstructural evolution, mechanical properties, and durability. The results indicate that vibration applied between the initial and final setting phases has a critical impact, significantly reducing early-age compressive, flexural, and bond strengths. This deterioration is mainly attributed to micro-crack formation and enhanced pore connectivity, as confirmed by SEM and MIP analyses. Moreover, vibration markedly increases the chloride diffusion coefficient, particularly in mixtures with higher water-to-binder ratios, thereby raising long-term durability concerns. These findings underscore the necessity of optimizing mix proportions and strictly controlling vibration timing to ensure both the mechanical performance and service life of high early-strength cement composites in bridge construction. The study provides practical insights for the design and application of durable, resilient bridge wet joints. Full article
(This article belongs to the Section Construction and Building Materials)
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17 pages, 1757 KB  
Article
Analysis on Carbon Sink Benefits of Comprehensive Soil and Water Conservation in the Red Soil Erosion Areas of Southern China
by Yong Wu, Jiechen Wu, Shennan Kuang and Xiaojian Zhong
Forests 2025, 16(10), 1551; https://doi.org/10.3390/f16101551 - 8 Oct 2025
Viewed by 142
Abstract
Soil erosion is an increasingly severe problem and a global focus. As one of the countries facing relatively serious soil erosion, China encounters significant ecological challenges. This study focuses on the carbon sink benefits of comprehensive soil and water conservation management in the [...] Read more.
Soil erosion is an increasingly severe problem and a global focus. As one of the countries facing relatively serious soil erosion, China encounters significant ecological challenges. This study focuses on the carbon sink benefits of comprehensive soil and water conservation management in the red soil erosion area of southern China, conducting an in-depth analysis using the Ziyang small watershed in Shangyou County, Jiangxi Province, as a typical case. Research methods involved constructing an integrated monitoring approach combining basic data, measured data, and remote sensing data. Changes in soil and vegetation carbon storage in the Ziyang small watershed across different years were determined by establishing a baseline scenario and applying inverse distance spatial interpolation, quadrat calculation, feature extraction, and screening. The results indicate that from 2002 to 2023, after 21 years of continuous implementation of various soil and water conservation measures under comprehensive watershed management, the carbon storage of the Ziyang small watershed increased significantly, yielding a net carbon sink of 54,537.28 tC. Tending and Management of Coniferous and Broad-leaved Mixed Forest, Low-efficiency Forest Improvement, and Thinning and Tending contributed substantially to the carbon sink, accounting for 72.72% collectively. Furthermore, the carbon sink capacity of the small watershed exhibited spatial variation influenced by management measures: areas with high carbon density were primarily concentrated within zones of Tending and Management of Coniferous and Broad-leaved Mixed Forest, while areas with low carbon density were mainly found within zones of Bamboo Forest Tending and Reclamation. The increase in watershed carbon storage was attributed to contributions from both vegetation and soil carbon pools. Comprehensive management of soil erosion demonstrates a significant carbon accumulation effect. The annual growth rate of vegetation carbon storage was higher than that of soil carbon storage, yet the proportion of soil carbon storage increased yearly. This study provides a theoretical basis and data foundation for the comprehensive management of soil and water conservation in small watersheds in the southern red soil erosion region of China and can offer technical and methodological support for other soil and water conservation carbon sink projects in this area. Full article
(This article belongs to the Section Forest Ecology and Management)
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25 pages, 1616 KB  
Article
Performance Evaluation of Economic, Environmental, and Social Sustainability and GRI-Based SDG Disclosures in Turkey’s Automotive Sector
by Efsun Dindar
Sustainability 2025, 17(19), 8905; https://doi.org/10.3390/su17198905 - 7 Oct 2025
Viewed by 315
Abstract
Sustainability reporting has emerged as a pivotal tool for corporate accountability, integrating environmental, social, and economic performance into transparent disclosures that align with global frameworks such as the Global Reporting Initiative (GRI) Standards and the United Nations Sustainable Development Goals (SDGs). This study [...] Read more.
Sustainability reporting has emerged as a pivotal tool for corporate accountability, integrating environmental, social, and economic performance into transparent disclosures that align with global frameworks such as the Global Reporting Initiative (GRI) Standards and the United Nations Sustainable Development Goals (SDGs). This study evaluates the environmental sustainability performance of Turkey’s automotive manufacturing sector by analyzing the extent and depth of GRI-based disclosures and their alignment with SDG targets. A mixed-method approach, combining quantitative Key Performance Indicator (KPI) coverage analysis with qualitative content assessment, was applied to sustainability reports from 12 major manufacturers. By identifying the most frequently reported indicators, assessing their coverage of economic, environmental, and social dimensions, and evaluating their direct relevance to specific SDGs, this research fills a critical gap and provides actionable insights for policymakers, industry leaders, and sustainability practitioners. The results indicate that while social indicators achieve the highest average disclosure rate (77.3%), environmental themes dominate narrative emphasis, reflecting sectoral materiality and regulatory pressures rather than proportional (KPI) coverage. Key gaps include underreporting of governance-related SDGs (e.g., SDG 5, SDG 8, SDG 16), limited target-level mapping, and a lack of measurable, outcome-based indicators. The study proposes a structured methodology for linking GRI metrics to SDG targets, enabling more consistent benchmarking and highlighting opportunities for balanced integration across all sustainability pillars. The findings contribute to both academic discourse and industry practice by demonstrating the need to bridge the gap between quantitative breadth and qualitative depth in sustainability reporting, ensuring more robust alignment with the 2030 Agenda. Full article
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26 pages, 4484 KB  
Article
Banana (Musa sapientum) Waste-Derived Biochar–Magnetite Magnetic Composites for Acetaminophen Removal via Photochemical Fenton Oxidation
by Manasik M. Nour, Maha A. Tony, Mai Kamal Fouad and Hossam A. Nabwey
Catalysts 2025, 15(10), 955; https://doi.org/10.3390/catal15100955 - 5 Oct 2025
Viewed by 231
Abstract
Recently, researchers have been focused on the recycling as well as transforming of bio-waste streams into a valuable resource. Banana peels are promising for such application, due to their wide availability. In this context, the integration of banana peel-derived biochar with environmentally benign [...] Read more.
Recently, researchers have been focused on the recycling as well as transforming of bio-waste streams into a valuable resource. Banana peels are promising for such application, due to their wide availability. In this context, the integration of banana peel-derived biochar with environmentally benign magnetite has significantly broadened its potential applications as a solar photocatalyst compared to the conventional photocatalysts. The materials are mixed in varied proportions of Ban-Char500-Mag@-(0:1), Ban-Char500@Mag-(1:1) and Ban-Char500@Mag-(2:1) and characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM) augmented with dispersive X-ray spectroscopy (EDX). Such modification is leading to an improvement in its application as a solar photocatalyst using the photochemical solar collector facility. The study discusses the factors controlling acetaminophen removal from aqueous effluent within 30 min of solar illumination time. Furthermore, the highlighted optimum parameters are pH 3.0, using 10 mg/L of the Ban-Char500@Mag-(1:1) catalyst and 100 mg/L of the hydrogen peroxide as a Fenton combination system for removing a complete acetaminophen from wastewater (100% oxidation). Also, the temperature influence in the oxidation system is studied and the high temperature is unfavorable, which verifies that the reaction is exothermic in nature. The catalyst is signified as a sustainable (recoverable, recyclable and reusable) substance, and showed a 72% removal even though it was in the six cyclic uses. Further, the kinetic study is assessed, and the experimental results revealed the oxidation process is following the first-order kinetic reaction. Also, the kinetic–thermodynamic parameters of activation are investigated and it is confirmed that the oxidation is exothermic and non-spontaneous in nature. Full article
(This article belongs to the Special Issue Environmentally Friendly Catalysis for Green Future)
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18 pages, 9463 KB  
Article
DIC-Based Crack Mode Identification and Constitutive Modeling of Magnesium-Based Wood-like Materials Under Uniaxial Compression
by Chunjie Li, Kaicong Kuang, Huaxiang Yang, Hongniao Chen, Jun Cai and Johnny F. I. Lam
Forests 2025, 16(10), 1542; https://doi.org/10.3390/f16101542 - 4 Oct 2025
Viewed by 244
Abstract
This study investigates the uniaxial compression failure of magnesium-based wood-like material (MWM) prisms (100 × 100 × 300 mm3) using digital image correlation (DIC). The results revealed an average compressive strength of 8.76 MPa and a dominant failure mode with Y-shaped [...] Read more.
This study investigates the uniaxial compression failure of magnesium-based wood-like material (MWM) prisms (100 × 100 × 300 mm3) using digital image correlation (DIC). The results revealed an average compressive strength of 8.76 MPa and a dominant failure mode with Y-shaped or inclined penetrating cracks. A novel piecewise constitutive model was established, combining a quartic polynomial and a rational fraction, demonstrating high fitting accuracy. Critically, the proportional limit was identified to be very low (20–35% of peak stress), attributed to early-stage damage from fiber–matrix interfacial defects. DIC analysis quantitatively distinguished dual crack initiation modes, pure mode I (occurring at ≈100% peak load) and mixed mode I/II (initiating earlier at 90.02% peak load), demonstrating that tensile shear coupling accelerates failure. These findings provide critical mechanistic insights and a reliable model for optimizing MWM in sustainable construction. Future work will explore the material’s behavior under multiaxial loading. Full article
(This article belongs to the Special Issue Advanced Numerical and Experimental Methods for Timber Structures)
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11 pages, 1669 KB  
Article
From Filamentous Bulking to Utilization: Formation Mechanisms of Filamentous Biofilms and Construction of Stabilized Systems
by Tao Song, Ji Li and Xiaolei Zhang
Water 2025, 17(19), 2885; https://doi.org/10.3390/w17192885 - 3 Oct 2025
Viewed by 301
Abstract
Sludge bulking in wastewater treatment is often caused by massive filamentous bacteria. This study aimed to turn such bacteria into a stable system dominated by filamentous biofilms (FBs) by using a continuous flow reactor (CFR) fed with simulated domestic wastewater; to address FBs’ [...] Read more.
Sludge bulking in wastewater treatment is often caused by massive filamentous bacteria. This study aimed to turn such bacteria into a stable system dominated by filamentous biofilms (FBs) by using a continuous flow reactor (CFR) fed with simulated domestic wastewater; to address FBs’ poor solid–liquid separation and uncontrollable sludge retention time (SRT), string carriers were added, SRT was controlled at 30 days, and parameters like mixed liquid suspended solids (MLSS) and sludge volume index (SVI) were monitored. Results showed filamentous Sphaerotilus (68–93% of FBs) self-aggregated as FBs’ reticular skeleton (loose, porous, stable, max 8 cm) with non-filamentous bacteria anchoring; FBs achieved >80% COD/NH4+-N removal despite low MLSS (<1000 mg/L) and SVI > 350 mL/g. The application of carriers increased the proportion of non-filamentous microorganisms to over 80%, reduced SVI to 150–400 mL/g, and increased MLSS to over 2700 mg/L, enabling stable operation. This study challenges the traditional negative perception of filamentous bacteria and opens new prospects for wastewater treatment technology. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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25 pages, 8960 KB  
Article
Analysis on Durability of Bentonite Slurry–Steel Slag Foam Concrete Under Wet–Dry Cycles
by Guosheng Xiang, Feiyang Shao, Hongri Zhang, Yunze Bai, Yuan Fang, Youjun Li, Ling Li and Yang Ming
Buildings 2025, 15(19), 3550; https://doi.org/10.3390/buildings15193550 - 2 Oct 2025
Viewed by 313
Abstract
Wet–dry cycles are a key factor aggravating the durability degradation of foam concrete. To address this issue, this study prepared bentonite slurry–steel slag foam concrete (with steel slag and cement as main raw materials, and bentonite slurry as admixture) using the physical foaming [...] Read more.
Wet–dry cycles are a key factor aggravating the durability degradation of foam concrete. To address this issue, this study prepared bentonite slurry–steel slag foam concrete (with steel slag and cement as main raw materials, and bentonite slurry as admixture) using the physical foaming method. Based on 7-day unconfined compressive strength tests with different mix proportions, the optimal mix proportion was determined as follows: mass ratio of bentonite to water 1:15, steel slag content 10%, and mass fraction of bentonite slurry 5%. Based on this optimal mix proportion, dry–wet cycle tests were carried out in both water and salt solution environments to systematically analyze the improvement effect of steel slag and bentonite slurry on the durability of foam concrete. The results show the following: steel slag can act as fine aggregate to play a skeleton role; after fully mixing with cement paste, it wraps the outer wall of foam, which not only reduces foam breakage but also inhibits the formation of large pores inside the specimen; bentonite slurry can densify the interface transition zone, improve the toughness of foam concrete, and inhibit the initiation and propagation of matrix cracks during the dry–wet cycle process; the composite addition of the two can significantly enhance the water erosion resistance and salt solution erosion resistance of foam concrete. The dry–wet cycle in the salt solution environment causes more severe erosion damage to foam concrete. The main reason is that, after chloride ions invade the cement matrix, they erode hydration products and generate expansive substances, thereby aggravating the matrix damage. Scanning Electron Microscopy (SEM) analysis shows that, whether in water environment or salt solution environment, the fractal dimension of foam concrete decreased slightly with an increasing number of wet–dry cycle times. Based on fractal theory, this study established a compressive strength–porosity prediction model and a dense concrete compressive strength–dry–wet cycle times prediction model, and both models were validated against experimental data from other researchers. The research results can provide technical support for the development of durable foam concrete in harsh environments and the high-value utilization of steel slag solid waste, and are applicable to civil engineering lightweight porous material application scenarios requiring resistance to dry–wet cycle erosion, such as wall bodies and subgrade filling. Full article
(This article belongs to the Section Building Structures)
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24 pages, 4277 KB  
Article
Effect of Gellan Gum on the Properties of Collagen-HPMC Freeze-Dried Hydrogels for Mucosal Administration
by Ioana Luca, Mădălina Georgiana Albu Kaya, Raluca Țuțuianu, Cristina Elena Dinu-Pîrvu, Maria Minodora Marin, Lăcrămioara Popa, Irina Titorencu, Valentina Anuța and Mihaela Violeta Ghica
Gels 2025, 11(10), 793; https://doi.org/10.3390/gels11100793 - 2 Oct 2025
Viewed by 206
Abstract
Mucosal drug delivery is gaining attention for its ability to provide localized treatment with reduced systemic side effects. The vaginal route has been proven effective for managing gynecological conditions, though it poses certain limitations. Biopolymers can help overcome these challenges by enhancing therapeutic [...] Read more.
Mucosal drug delivery is gaining attention for its ability to provide localized treatment with reduced systemic side effects. The vaginal route has been proven effective for managing gynecological conditions, though it poses certain limitations. Biopolymers can help overcome these challenges by enhancing therapeutic efficiency and offering beneficial properties. This study aimed to develop and evaluate hydrogels and their freeze-dried forms (wafers) based on collagen, hydroxypropyl methylcellulose, and gellan gum. Initially, a collagen gel was obtained by extraction from calfskin, which was brought to a concentration of 1% and a physiological pH with 1 M sodium hydroxide solution. This gel was combined with either 2% hydroxypropyl methylcellulose gel, 1.2% gellan gum gel, or both, in different proportions. Thus, five mixed hydrogels were obtained, which, along with the three individual gels (controls), were lyophilized to obtain wafers. Furthermore, the hydrogels were assessed for rheological behavior, while the collagen structural integrity in the presence of the other biopolymers was evaluated using circular dichroism and FT-IR spectroscopy. The wafers were characterized for morphology, wettability, swelling capacity, enzymatic degradation resistance, and in vitro biocompatibility. All hydrogels exhibited non-Newtonian, pseudoplastic behavior and showed collagen structure preservation. The wafers’ characterization showed that gellan gum enhanced the hydrophilicity and enzymatic stability of the samples. In addition, the extracts from the tested samples maintained cell viability and did not affect actin cytoskeleton morphology, indicating a lack of cytotoxic effects. This study emphasizes the importance of evaluating both the physicochemical properties and biocompatibility of biopolymeric supports as a key preliminary step in the development of vaginal drug delivery platforms with biomedical applications in the management of gynecological conditions. Full article
(This article belongs to the Special Issue Advances in Functional Hydrogels and Their Applications)
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17 pages, 845 KB  
Article
Effects of Indoor Temperature, Relative Humidity, and Carbon Dioxide Conditions on Wean-to-Finish Swine Survivability
by Olivia J. Kittle, Mark T. Knauer, Glen W. Almond, Apostolos Stamenos, Laura Kushner, Simon Weisenhorn and Suzanne M. Leonard
Agriculture 2025, 15(19), 2050; https://doi.org/10.3390/agriculture15192050 - 30 Sep 2025
Viewed by 222
Abstract
In swine production, it is broadly recognized that ventilation rates and indoor environmental conditions influence pig productivity. However, sparse scientific data are available on the combined effects and potential interactions of these factors in commercial production systems. This study investigated indoor environmental and [...] Read more.
In swine production, it is broadly recognized that ventilation rates and indoor environmental conditions influence pig productivity. However, sparse scientific data are available on the combined effects and potential interactions of these factors in commercial production systems. This study investigated indoor environmental and management factors influencing wean-to-finish pig mortality in a commercial system. Temperature, relative humidity (RH), and carbon dioxide (CO2) were recorded every 10 min in the front and back of 16 barns across five grow-finish sites in eastern North Carolina for two turns (four barns) or three turns (12 barns) for a total of 44 pig groups. Proportional weekly mortality was modeled using a generalized linear mixed model. Results showed that pigs in environments warmer than the desired room temperature had lower mortality (p < 0.001), suggesting cold stress was more detrimental than heat stress. Elevated RH and CO2 at the back of the barn were linked to increased mortality (p < 0.001), highlighting air exchange rates as a key indicator. Mortality was greatest in pig groups placed during Spring and lowest in Summer (p < 0.05), and mortality declined as pigs aged (p = 0.0134). Surprisingly, greater barn occupancy correlated with lower mortality (p = 0.0012), potentially related to piglet quality at placement. The predictive power of the model varied with the turn of pigs, with R2 averaging 0.24 (ranging from 0.001 to 0.61) and an average RMSE of 0.36% (ranging from 0.17% to 0.77%). Ammonia (NH3) was recorded at the back of six barns, and concentrations were modeled. Greater NH3 concentrations were associated with increased pig age, RH, and CO2, as well as lower deviation from desired room temperature and lower barn occupancy. Collectively, these findings highlight the importance of proper ventilation and management on swine productivity. Full article
(This article belongs to the Section Farm Animal Production)
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15 pages, 694 KB  
Article
Mechanical Performance and Durability of Concretes with Partial Replacement of Natural Aggregates by Construction and Demolition Waste
by Thamires Alves da Silveira, Rafaella dos Passos Nörnberg, Marcelo Subtil Santi, Renata Rabassa Morales, Alessandra Buss Tessaro, Hebert Luis Rosseto, Rafael de Avila Delucis and Guilherme Hoehr Trindade
Waste 2025, 3(4), 32; https://doi.org/10.3390/waste3040032 - 30 Sep 2025
Viewed by 206
Abstract
This study investigated the mechanical performance and durability of concretes produced with varying proportions of recycled coarse aggregate from construction and demolition waste (CDW), ranging from 0% to 100% replacement of natural coarse aggregate, using recycled aggregates derived from crushed concrete and mortar [...] Read more.
This study investigated the mechanical performance and durability of concretes produced with varying proportions of recycled coarse aggregate from construction and demolition waste (CDW), ranging from 0% to 100% replacement of natural coarse aggregate, using recycled aggregates derived from crushed concrete and mortar debris, characterized by lower density and high water absorption (~9%) compared to natural aggregates. A key contribution of this research lies in the inclusion of intermediate replacement levels (20%, 25%, 45%, 50%, and 65%), which are less explored in the literature and allow a more refined identification of performance thresholds. Fresh-state parameters (slump), axial compressive strength (7 and 28 days), total immersion water absorption, sorptivity, and chloride ion penetration depth (after 90 days of immersion in a 3.5% NaCl solution) were evaluated. The results indicate that, up to 50% CDW content, the concrete maintains slump (≥94 mm), characteristic strength (≥37.2 MPa at 28 days), and chloride penetration (≤14.1 mm) within the limits for moderate exposure conditions, in accordance with ABNT: NBR 6118. Water absorption doubled from 4.5% (0% CDW) to 9.5% (100% CDW), reflecting the higher porosity and adhered mortar on the recycled aggregate, which necessitates adjustments to the water–cement ratio and SSD pre-conditioning to preserve workability and minimize sorptivity. Concretes with more than 65% CDW exhibited chloride penetration depths exceeding 15 mm, potentially compromising durability without additional mitigation. The judicious incorporation of CDW, combined with optimized mix design practices and the use of supplementary cementitious materials (SCMs), demonstrates technical viability for reducing environmental impacts without significantly impairing the structural performance or service life of the concrete. Full article
(This article belongs to the Special Issue Use of Waste Materials in Construction Industry)
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15 pages, 1213 KB  
Article
Valorization of Mixed Lignocellulosic Biomass for Bioethanol Production Using Thermotolerant Yeast Saccharomyces cerevisiae SC90
by Malaika Amjad, Muhammad Abbas, Abdullah Langou, Imrana Niaz Sultan and Afrasiab Khan Tareen
Fermentation 2025, 11(10), 565; https://doi.org/10.3390/fermentation11100565 - 30 Sep 2025
Viewed by 516
Abstract
Bioethanol manifests an extraordinary potential to overcome the severe energy crises and reliance on fossil fuels, yet it supports the sustainable and cost-effective production of fuels for automobile engines and contributes to the reduction of greenhouse gas (GHG) emissions and other global climate-related [...] Read more.
Bioethanol manifests an extraordinary potential to overcome the severe energy crises and reliance on fossil fuels, yet it supports the sustainable and cost-effective production of fuels for automobile engines and contributes to the reduction of greenhouse gas (GHG) emissions and other global climate-related challenges. The present study examines the potential of Mixed Lignocellulosic Biomass (MLB) as a sustainable feedstock for the consistent year-round production of bioethanol. The primary MLB sources considered in this research to underscore the significance of this heterogeneous strategy include sweet sorghum bagasse (SSB), sugarcane bagasse (SCB), and date palm trunk (DPT). Each of the three feedstocks, i.e., SSB, SCB, and DPT, were individually subjected to alkaline pretreatment, a step aimed at breaking down structural barriers and facilitating greater release of fermentable sugars during fermentation. Likewise, the alkaline-pretreated biomasses were subjected to simultaneous saccharification and fermentation (SSF) for 96 h, both individually as well as in various combined proportions. Individually, pretreated sweet sorghum bagasse (SSB) fibers produced the highest ethanol concentration, of 30.79 ± 0.44 g/L; an ethanol yield of 0.40 ± 0.62 g/g; an ethanol productivity of 0.42 ± 0.87 g/L/h; and a theoretical ethanol yield of 79.81% at 72 h. In contrast, the combination of MLB (50% of pretreated SSB and 50% of DPT fibers) produced a significantly higher ethanol concentration of 31.47 ± 0.57 g/L and an ethanol productivity of 0.653 ± 0.24 g/L/h in much less time, i.e., 48 h of SSF fermentation. The empirical data confirms that MLB offers a sustainable paradigm for ethanol biosynthesis by curtailing fermentation time and optimizing economic and operational efficacy. Full article
(This article belongs to the Special Issue Lignocellulosic Biomass Valorisation, 2nd Edition)
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26 pages, 10152 KB  
Article
Linking Acoustic Indices to Vegetation and Microclimate in a Historical Urban Garden: Setting the Stage for a Restorative Soundscape
by Alessia Portaccio, Francesco Chianucci, Francesco Pirotti, Marco Piragnolo, Marco Sozzi, Andrea Zangrossi, Miriam Celli, Marta Mazzella di Bosco, Monica Bolognesi, Enrico Sella, Maurizio Corbetta, Francesca Pazzaglia and Raffaele Cavalli
Land 2025, 14(10), 1970; https://doi.org/10.3390/land14101970 - 30 Sep 2025
Viewed by 350
Abstract
Urban soundscapes are increasingly recognized as fundamental for both ecological integrity and human well-being, yet the complex interplay between the vegetation structure, seasonal dynamics, and microclimatic factors in shaping these soundscapes remains poorly understood. This study tests the hypothesis that vegetation structure and [...] Read more.
Urban soundscapes are increasingly recognized as fundamental for both ecological integrity and human well-being, yet the complex interplay between the vegetation structure, seasonal dynamics, and microclimatic factors in shaping these soundscapes remains poorly understood. This study tests the hypothesis that vegetation structure and seasonally driven biological activity mediate the balance and the quality of the urban acoustic environment. We investigated seasonal and spatial variations in five acoustic indices (NDSI, ACI, AEI, ADI, and BI) within a historical urban garden in Castelfranco Veneto, Italy. Using linear mixed-effects models, we analyzed the effects of season, microclimatic variables, and vegetation characteristics on soundscape composition. Non-parametric tests were used to assess spatial differences in vegetation metrics. Results revealed strong seasonal patterns, with spring showing increased NDSI (+0.17), ADI (+0.22), and BI (+1.15) values relative to winter, likely reflecting bird breeding phenology and enhanced biological productivity. Among microclimatic predictors, temperature (p < 0.001), humidity (p = 0.014), and solar radiation (p = 0.002) showed significant relationships with acoustic indices, confirming their influence on both animal behaviour and sound propagation. Spatial analyses showed significant differences in acoustic patterns across points (Kruskal–Wallis p < 0.01), with vegetation metrics such as tree density and evergreen proportion correlating with elevated biophonic activity. Although the canopy height model did not emerge as a significant predictor in the models, the observed spatial heterogeneity supports the role of vegetation in shaping urban sound environments. By integrating ecoacoustic indices, LiDAR-derived vegetation data, and microclimatic parameters, this study offers novel insights into how vegetational components should be considered to manage urban green areas to support biodiversity and foster acoustically restorative environments, advancing the evidence base for sound-informed urban planning. Full article
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23 pages, 3485 KB  
Article
A Capacity Expansion Model of Hydrogen Energy Storage for Urban-Scale Power Systems: A Case Study in Shanghai
by Chen Fu, Ruihong Suo, Lan Li, Mingxing Guo, Jiyuan Liu and Chuanbo Xu
Energies 2025, 18(19), 5183; https://doi.org/10.3390/en18195183 - 29 Sep 2025
Viewed by 211
Abstract
With the increasing maturity of renewable energy technologies and the pressing need to address climate change, urban power systems are striving to integrate a higher proportion of low-carbon renewable energy sources. However, the inherent variability and intermittency of wind and solar power pose [...] Read more.
With the increasing maturity of renewable energy technologies and the pressing need to address climate change, urban power systems are striving to integrate a higher proportion of low-carbon renewable energy sources. However, the inherent variability and intermittency of wind and solar power pose significant challenges to the stability and reliability of urban power grids. Existing research has primarily focused on short-term energy storage solutions or small-scale integrated energy systems, which are insufficient to address the long-term, large-scale energy storage needs of urban areas with high renewable energy penetration. This paper proposes a mid-to-long-term capacity expansion model for hydrogen energy storage in urban-scale power systems, using Shanghai as a case study. The model employs mixed-integer linear programming (MILP) to optimize the generation portfolios from the present to 2060 under two scenarios: with and without hydrogen storage. The results demonstrate that by 2060, the installed capacity of hydrogen electrolyzers could reach 21.5 GW, and the installed capacity of hydrogen power generators could reach 27.5 GW, accounting for 30% of the total installed capacity excluding their own. Compared to the base scenario, the electricity–hydrogen collaborative energy supply system increases renewable penetration by 11.6% and utilization by 12.9% while reducing the levelized cost of urban comprehensive electricity (LCOUCE) by 2.514 cents/kWh. These findings highlight the technical feasibility and economic advantages of deploying long-term hydrogen storage in urban grids, providing a scalable solution to enhance the stability and efficiency of high-renewable urban power systems. Full article
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Article
Long-Term Changes in the Structural and Functional Composition of Spruce Forests in the Center of the East European Plain
by Tatiana Chernenkova, Nadezhda Belyaeva, Alexander Maslov, Anastasia Titovets, Alexander Novikov, Ivan Kotlov, Maria Arkhipova and Mikhail Popchenko
Forests 2025, 16(10), 1526; https://doi.org/10.3390/f16101526 - 29 Sep 2025
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Abstract
Norway spruce (Picea abies (L.) H. Karst.) is a primary forest-forming species in the European part of Russia, both in terms of its distribution and economic importance. A number of studies indicate that one of the reasons for the disturbance of spruce [...] Read more.
Norway spruce (Picea abies (L.) H. Karst.) is a primary forest-forming species in the European part of Russia, both in terms of its distribution and economic importance. A number of studies indicate that one of the reasons for the disturbance of spruce forests is linked to rising temperatures, particularly the detrimental effects of extreme droughts. The aim of our research is to identify changes in the structural and functional organization of mature spruce forests at the center of the East European Plain. The study was conducted in intact spruce forests using resurveyed vegetation relevés within the Smolensk–Moscow Upland, with relevés repeated after 40 years (in 1985 and 2025). Changes in structural and functional parameters of spruce communities were analyzed. The results showed that significant disturbances of the tree layer led to changes in the vegetation of subordinate layers, as well as the successional dynamics of spruce forests. It was found that following the collapse of old-growth spruce stands, two types of secondary succession developed: (1) with the renewal of spruce and (2) with active development of shrubs (hazel and rowan) and undergrowth of broadleaved species. It was also demonstrated that the typological diversity of the studied communities changed over 40 years not only due to the loss of the tree layer and the formation of new “non-forest” types but also because several mixed spruce-broadleaved communities transitioned into broadleaved ones, and pine–spruce communities of boreal origin shifted to nemoral types. An analysis of the complete species composition of spruce forests based on Ellenberg’s scales scoring revealed changes in habitat conditions over the 40-year period. A noticeable trend was an increase in the proportion of thermophilic and alkaliphilic species, indicating a shift toward a nemoral vegetation spectrum. It is expected that under the current forest management regime, the next 40 to 60 years will see a decline in the proportion of spruce within mixed stands, potentially culminating in the complete collapse of monospecific spruce forests in the center of the East European Plain. Full article
(This article belongs to the Special Issue Features of Forest Stand Structure Under Changing Conditions)
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