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Keywords = monatomic fluids

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19 pages, 785 KB  
Entry
Static Structures in Monatomic Fluids
by Luis M. Sesé
Encyclopedia 2025, 5(3), 141; https://doi.org/10.3390/encyclopedia5030141 - 5 Sep 2025
Cited by 1 | Viewed by 2055
Definition
The basic structural concepts in the study of monatomic fluids at equilibrium are presented in this entry. The scope encompasses both the classical and the quantum domains, the latter concentrating on the diffraction and the zero-spin boson regimes. The main mathematical objects for [...] Read more.
The basic structural concepts in the study of monatomic fluids at equilibrium are presented in this entry. The scope encompasses both the classical and the quantum domains, the latter concentrating on the diffraction and the zero-spin boson regimes. The main mathematical objects for describing the fluid structures are the following n-body functions: the correlation functions in real space and their associated structure factors in Fourier space. In these studies, the theory of linear response to external weak fields, involving functional calculus, and Feynman’s path integral formalism are the key conceptual ingredients. Emphasis is placed on the physical implications when going from the classical domain (limit of high temperatures) to the abovementioned quantum regimes (low temperatures). In the classical domain, there is only one class of n-body structures, which at every n level consists of one correlation function plus one structure factor. However, the quantum effects bring about the splitting of the foregoing class into three path integral classes, namely instantaneous, total thermalized-continuous linear response, and centroids; each of them is associated with the action of a distinct external weak field and keeps the above n-level structures. Special attention is given to the structural pair level n=2, and future directions towards the complete study of the quantum triplet level n=3 are suggested. Full article
(This article belongs to the Section Physical Sciences)
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63 pages, 3738 KB  
Article
Contribution to the Statistical Mechanics of Static Triplet Correlations and Structures in Fluids with Quantum Spinless Behavior
by Luis M. Sesé
Quantum Rep. 2024, 6(4), 564-626; https://doi.org/10.3390/quantum6040038 - 3 Nov 2024
Cited by 2 | Viewed by 2299
Abstract
The current developments in the theory of quantum static triplet correlations and their associated structures (real r-space and Fourier k-space) in monatomic fluids are reviewed. The main framework utilized is Feynman’s path integral formalism (PI), and the issues addressed cover quantum [...] Read more.
The current developments in the theory of quantum static triplet correlations and their associated structures (real r-space and Fourier k-space) in monatomic fluids are reviewed. The main framework utilized is Feynman’s path integral formalism (PI), and the issues addressed cover quantum diffraction effects and zero-spin bosonic exchange. The structures are associated with the external weak fields that reveal their nature, and due attention is paid to the underlying pair-level structures. Without the pair, level one cannot fully grasp the triplet extensions in the hierarchical ladder of structures, as both the pair and the triplet structures are essential ingredients in the triplet response functions. Three general classes of PI structures do arise: centroid, total continuous linear response, and instantaneous. Use of functional differentiation techniques is widely made, and, as a bonus, this leads to the identification of an exact extension of the “classical isomorphism” when the centroid structures are considered. In this connection, the direct correlation functions, as borrowed from classical statistical mechanics, play a key role (either exact or approximate) in the corresponding quantum applications. Additionally, as an auxiliary framework, the traditional closure schemes for triplets are also discussed, owing to their potential usefulness for rationalizing PI triplet results. To illustrate some basic concepts, new numerical calculations (path integral Monte Carlo PIMC and closures) are reported. They are focused on the purely diffraction regime and deal with supercritical helium-3 and the quantum hard-sphere fluid. Full article
(This article belongs to the Special Issue Exclusive Feature Papers of Quantum Reports in 2024–2025)
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25 pages, 824 KB  
Technical Note
On the Dynamical Instability of Monatomic Fluid Spheres in (N + 1)-Dimensional Spacetime
by Wei-Xiang Feng
Astronomy 2023, 2(1), 22-46; https://doi.org/10.3390/astronomy2010004 - 2 Mar 2023
Cited by 4 | Viewed by 4327
Abstract
In this note, I derive the Chandrasekhar instability of a fluid sphere in (N + 1)-dimensional Schwarzschild–Tangherlini spacetime and take the homogeneous (uniform energy density) solution for illustration. Qualitatively, the effect of a positive (negative) cosmological constant tends to destabilize (stabilize) the [...] Read more.
In this note, I derive the Chandrasekhar instability of a fluid sphere in (N + 1)-dimensional Schwarzschild–Tangherlini spacetime and take the homogeneous (uniform energy density) solution for illustration. Qualitatively, the effect of a positive (negative) cosmological constant tends to destabilize (stabilize) the sphere. In the absence of a cosmological constant, the privileged position of (3 + 1)-dimensional spacetime is manifest in its own right. As it is, the marginal dimensionality in which a monatomic ideal fluid sphere is stable but not too stable to trigger the onset of gravitational collapse. Furthermore, it is the unique dimensionality that can accommodate stable hydrostatic equilibrium with a positive cosmological constant. However, given the current cosmological constant observed, no stable configuration can be larger than 1021M. On the other hand, in (2 + 1) dimensions, it is too stable either in the context of Newtonian Gravity (NG) or Einstein’s General Relativity (GR). In GR, the role of negative cosmological constant is crucial not only to guarantee fluid equilibrium (decreasing monotonicity of pressure) but also to have the Bañados–Teitelboim–Zanelli (BTZ) black hole solution. Owing to the negativeness of the cosmological constant, there is no unstable configuration for a homogeneous fluid disk with mass 0<M0.5 to collapse into a naked singularity, which supports the Cosmic Censorship Conjecture. However, the relativistic instability can be triggered for a homogeneous disk with mass 0.5<M0.518 under causal limit, which implies that BTZ holes of mass MBTZ>0 could emerge from collapsing fluid disks under proper conditions. The implicit assumptions and implications are also discussed. Full article
(This article belongs to the Special Issue Feature Papers in the Astronomical Sciences)
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