Search Results (470)

Forward osmosis (FO) membranes face challenges in balancing high water permeability, low reverse salt flux (RSF), and mechanical durability. Although nanopores in graphene have great theoretical potential, the existing methods make it difficult to independently optimize the nanopores of the graphene layer and the microstructure of the substrate without damaging each other. Here, we propose a defect engineering strategy based on oxygen plasma etching to address this collaborative optimization challenge. Monolayer porous graphene (PG) was integrated with polysulfone (Psf) substrates, followed by oxygen plasma etching to introduce nanopores and oxygen-containing functional groups (e.g., carboxyl, hydroxyl). By controlling the etching time to 10 s, the resulting membrane (S-PG10) exhibited a water flux of 0.24 LMH in 0.5 M NaCl, representing an order-of-magnitude increase compared to the pristine graphene membrane (S-G). Remarkably, S-PG10 maintained a high salt rejection (>96%) and a low J_s/J_w (<0.35 g·L⁻¹). Substrate modification via short-term plasma etching (5 min) further doubled the water flux of S*5-PG10 (0.47 LMH in 0.5 M NaCl) by increasing porosity (81.8%→85.6%) and hydrophilicity. However, prolonged etching (>15 min) degraded mechanical strength and increased RSF due to pore structure disruption. To enhance robustness, Poly(D,L-lactic acid) (PDLLA)-doped substrates (S^#-PG) were engineered, with 0.1 wt.% PDLLA optimizing mechanical properties while maintaining low RSF and high flux. Excessive PDLLA (10 wt.%) induced hydrophobicity and crystalline structures, reducing permeability. The study demonstrates that synergistic optimization of plasma etching duration on the graphene selective layer (5~10 s) and substrates (5 min) as well as PDLLA doping (0.1 wt.%) balances pore architecture, surface chemistry, and substrate integrity, achieving FO membranes with superior water-salt selectivity and mechanical stability. These findings provide critical insights into designing high-performance graphene-based membranes for sustainable desalination and water purification. Full article

A reconfigurable THz metasurface (MS) capable of independent reflection amplitude and phase modulation is designed and analyzed. The tunability is achieved in a simple few-layer structure by control over the chemical potential of a graphene monolayer patterned in square patches and over the bulk conductivity of an overlying vanadium dioxide (VO₂) patch array; these impart control over the reflection phase and magnitude, respectively. To design and analyze the MS unit cell, we employ intuitive equivalent circuit and transmission line modeling, which is validated against full-wave simulations, showing good agreement in the regime of interest, i.e., on the first resonance for normal plane wave incidence. The simulated phase modulation approaches $250°$, enabling binary-encoded digital metasurface designs, while the magnitude modulation spans more than 20 dB, from $-3$ dB almost down to perfect absorption. The flexibility of dynamic phase and amplitude control can unlock the full potential of such THz MS hybrid designs for future wireless communications (6G and beyond) and for sensing applications. Finally, the analytical modeling can be extended to polarization-dependent, anisotropic, or non-local EM responses and/or to include aspects of the multiphysical control mechanisms. Full article

The representation of electronic wavefunctions in real space grids, which are directly related to molecular orbitals and electronic densities either in molecular or crystalline systems, is a fundamental part of many studies at ab initio levels, since it contributes to the understanding of complex physical and chemical phenomena at the nanoscale. This work proposes the use of a deep convolutional neural network for the prediction of electronic wavefunctions at arbitrary positions along high-symmetry points within the reciprocal space (first Brillouin zone), which can be represented as isosurfaces in the real space. The proposed neural network algorithm is trained with data from density functional theory (DFT) calculations of monolayer 2D crystalline systems (i.e., pristine, B- and N-doped graphene, and MoS₂) and was able to produce predictions of data for wavefunction representation on the real space, with accuracies in between 62% and 92%, from calculated determination coefficients. Moreover, the optimized method for generating spatial representations of electronic wavefunctions, based on Machine Learning, is at least 25× faster than the conventional DFT-based methodology, enabling an efficient way for a quick assessment of 2D material properties related to the spatial distribution of electronic wavefunctions in the real space, such as local charge density and molecular orbital visualization in crystalline systems, and including their dependence on the position within the reciprocal space. Full article

We investigate time-resolved wave-packet transport in monolayer graphene patterned with asymmetric arrays of circular electrostatic scatterers. Using the Dirac continuum model with a split-operator scheme, we track how transmission evolves with scatterer radius and polarity sequence. To this end, we consider three potential configurations (Samples 1–3). The results reveal a geometry-controlled crossover from near-ballistic propagation at small radii to interference-dominated backscattering at large radii. Sample 1, where the potential exhibit two parallel lines of circles, each line sharing the same potential sign, preserves the highest transmission. Conversely, in Sample 3, where potential signs are intercalated between circles of the same line, the dwell time increases, which produces stronger confinement. As the radius increases, pronounced temporal oscillations emerge due to repeated internal reflections (similar to Fabry–Pérot interferometer), and the radius dependence of the saturated transmission probability exhibits anti-resonant dips that are tunable by geometry and potential magnitude. These behaviors establish simple design rules for graphene nanodevices: small-radius Sample 1 for high-throughput transport, Sample 2 (with inverted potential signs as compared to Sample 1) for broadband suppression, and Sample 3 for finely tunable, interference-based confinement. Full article

This work proposes new architecture, supported by analytical modelling and computer-aided design (CAD) simulations, for a highly sensitive monolayer graphene-gated AlGaN/GaN HEMT terahertz (THz) detector operating at room temperature (RT). The monolayer graphene gate acts as a surface plasmon absorber for the incident THz radiation. The carrier density perturbation caused by incident THz energy on the monolayer graphene surface is then capacitively coupled to the two-dimensional electron gas (2DEG) channel of the HEMT structure underneath. The channel is partially depleted for increased mobility and nonlinearity with potential asymmetry across the channel for consistent photogeneration. The Drude absorption of THz radiation initiates intraband transitions in monolayer graphene, thereby reducing phonon losses. These reduced phonon losses enable RT THz detection. Based on our simulations, the proposed detector architecture can generate a responsivity of 2.12 × 10⁶ V/W at 1 THz with a broadband bandwidth of 2 THz. Full article

The structure of self-assembled monolayers (SAMs) greatly influences electrochemical interface behavior. This study systematically examines how positional isomers of aromatic diamines (ADMs) assemble on a glassy carbon (GC) electrode and how such ordering affects the attachment and performance of electrochemically reduced graphene oxide (ERGO). SAMs of ortho-, meta-, and para-phenylenediamine (o-PDA, m-PDA, and p-PDA) were fabricated on GC and characterized using atomic force microscopy (AFM) and Raman spectroscopy. Among them, GC/p-PDA exhibited the most compact and homogeneous interfacial structure. ERGO was subsequently immobilized through the free amine functionalities of the SAM, as confirmed by attenuated total reflectance–Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV). Strong covalent coupling and electrostatic interactions between the positively charged ERGO and terminal amines enabled stable attachment. Under optimized conditions, the modified GC/p-PDA/ERGO electrode demonstrated exceptional electrocatalytic activity toward nitrobenzene (NBz) reduction, achieving a high sensitivity of 1410 μA mM⁻¹ cm⁻² and a low detection limit of 0.040 μM. In addition, this sensor displayed outstanding anti-interference capability, stability, and recovery in a water sample. These results establish GC/p-PDA/ERGO sensor as a robust and efficient electrocatalytically active interface for nitroaromatic pollutants detection and sustainable environmental monitoring. Full article

Wide-bandgap diamond photodetectors face a fundamental trade-off between dark current suppression and photocurrent collection due to high Schottky barriers. Here, a photo-modulation strategy is demonstrated by integrating monolayer graphene as transparent electrodes on oxygen-terminated single-crystal diamond. The atomically thin graphene (87.3% UV transmittance at 220 nm) allows photons to penetrate and dynamically reduce Schottky barriers through photoinduced electric fields, while maintaining high barriers (~2.3 eV) under dark conditions for ultralow leakage current. Compared with conventional 100 nm Au electrodes, graphene-based devices exhibit a 4.9-fold responsivity improvement (0.158 A/W at 220 nm) and a 5.2-fold detectivity increase (8.35 × 10¹³ cm·Hz^1/2/W), while preserving ultralow dark current (~10⁻¹² A at ±100 V). XPS measurements confirm a minimal Fermi level shift (0.06 eV) upon graphene integration, demonstrating robust surface state pinning by oxygen termination. Transient photoresponse reveals a 27% faster rise time (30 ns vs. 41 ns) with bi-exponential decay governed by band-to-band recombination (τ1 ≈ 75 ns) and trap-assisted recombination (τ2 ≈ 411 ns). The devices maintain stable performance after one month of ambient exposure and successfully demonstrate UV optical communication capability. This transparent electrode approach offers a versatile strategy for enhancing wide-bandgap semiconductor photodetectors for secure communications, environmental monitoring, and industrial sensing applications. Full article

Cancer poses a global challenge, affecting millions of people and placing a significant burden on families and healthcare systems. Chemotherapy, radiotherapy, hormone therapy, and immunotherapy are commonly used for cancer treatment; their side effects can be severe. Photothermal therapy (PTT) has emerged as a promising alternative due to its minimal invasiveness and high efficiency. In this study, graphene oxide (GO) was synthesized and functionalized to obtain nitrogen-doped graphene oxide (NGO) and boron-doped graphene oxide (BGO) via a hydrothermal process, aiming to use them as photoactive agents (PAs) in PTT. Atomic force microscopy (AFM) analysis revealed that GO, BGO, and NGO exhibit monolayer atomic structures. Spectroscopic analyses confirmed the presence of oxygen and carbon in all samples, along with successful boron and nitrogen doping in BGO and NGO, respectively. Cytotoxicity assays yielded half-maximal inhibitory concentrations (IC₅₀) of 1025.26 μg/mL for GO, 2695.03 μg/mL for BGO, and 1319.81 μg/mL for NGO. Photothermal experiments were conducted using a 635 nm light source with an intensity of 65.5 mW/cm², resulting in temperature thresholds of 44.87 °C for GO, 48.36 °C for NGO, and 55.91 °C for BGO. Anticancer assays were performed using the T-47D breast cancer cell line, demonstrating tumor cell elimination rates of 97.93% for GO, 98.54% for BGO, and 97.98% for NGO, underscoring their efficacy as PAs. Density functional theory (DFT) simulations were carried out to determine the absorbance coefficient as a function of doping percentage. The results revealed that increased doping enhances light absorbance and, consequently, the photothermal response, as higher absorbance at the irradiation wavelength leads to greater energy absorption and temperature elevation. Full article

Graphene nanoplatelets (GNPs) represent a promising class of carbon nanomaterials bridging the gap between graphite and monolayer graphene. Their unique combination of high electrical conductivity, large specific surface area, mechanical strength, and chemical stability makes them attractive for advanced energy storage applications. This review summarizes recent developments in the synthesis, functionalization, characterization, and application of GNPs in supercapacitors, batteries, and hybrid systems. The influence of key structural parameters—such as flake thickness, lateral size, surface chemistry, and defect density—on electrochemical performance is discussed, highlighting structure–property correlations. Particular emphasis is placed on scalable production methods, including mechanical, liquid-phase, and electrochemical exfoliation, as well as edge functionalization and heteroatom doping strategies. Comparative analyses show that GNP-based electrodes can significantly improve specific capacitance, conductivity, and cycling stability, especially when used in composites with polymers or metal oxides. The review also addresses current challenges related to aggregation, dispersion, standardization, and environmental impact. Finally, prospects for the development of sustainable, low-emission GNP production and its integration into next-generation energy storage systems are outlined. Full article

For growth control of graphene, observation techniques, particularly those allowing in situ imaging during synthesis, are essential. Scanning electron microscopy (SEM) is a conventional surface observation method capable of in situ imaging of graphene segregation or growth in chemical vapor deposition, as well as ex situ imaging of synthesized materials. However, secondary electron (SE) emission from graphene is not fully understood, and the contrast formation mechanism of the monolayer material remains unclear. This review summarizes the SEM imaging of graphene, with a focus on SE contrast mechanisms under different conditions. The monolayer graphene layer does not greatly affect SE emission. Its SE contrast is brought from the charging effect, oxidation effect, or attenuation effect of backscattered electron (BSE) from the substrate. Characteristics of SE detectors, such as energy window, acceptance angle, and detected SE/BSE ratio, also contribute to the graphene contrast formation. Full article

We theoretically study plasmon dispersion within the random-phase approximation in two-dimensional systems, including undoped and doped monolayer graphene at zero and finite temperatures, and hole- and electron-doped monolayer $X\mathrm{Se}$ ($X=\mathrm{In},\mathrm{Ga}$) and disordered two-dimensional electron gas at zero temperature, in the presence of a non-Coulomb interaction of the form $\sim r^{-\eta }$. Our findings show that the parameter $\eta$, which characterizes the non-Coulombic nature of the interaction, strongly affects the dependence of the plasmon frequency on the wave vector in the long-wavelength limit. Furthermore, the carrier density dependence of the plasmon frequency is unaffected by the parameter $\eta$ in this regime. For $\eta =1$, corresponding to the Coulomb case, the well-known results are fully recovered for all systems studied here. Full article

Graphene oxide (GO) was prepared by a waterless synthesis route to generate GO sheets, which were then applied to coat calcined oyster shell with fertilizer (OSF) pellets, resulting in the creation of an OSF-GO particle. The GO sheets (ID/IG = 0.86) were characterized by Raman spectroscopy, which showed that the GO-coated OSF pellet features a compact coating approximately 13.68 μm thick. SEM and AFM analyses revealed that the GO sheets displayed a monolayer configuration with a crinkled topography (about 0.91 nm). The EDS analysis confirmed that the core was primarily composed of Ca, K, P, O, N, and C elements. The hydroponic experiment results showed that a GO concentration of 80 mg/L significantly enhanced plant height, stem thickness, and root length in loose-leaf lettuce, while higher concentrations induced oxidative stress. In pot experiments, the OSF-GO composite effectively raised the soil pH from 5.38 to 6.41 and improved nutrient availability. OSF-GO composite functions effectively as both a soil conditioner and slow-release fertilizer (SRF), simultaneously remediating degraded soils and optimizing nutrient delivery. Full article

Graphene, owing to its exceptional mechanical properties and interfacial modulation capability, is considered an ideal material for enhancing the interfacial strength and damage resistance during the fabrication of ultra-thin lithium foils. Although previous studies have demonstrated the reinforcing effects of graphene on lithium metal interfaces, most analyses have been restricted to single-temperature or idealized substrate conditions, lacking systematic investigations under practical, multi-temperature environments. Consequently, the influence of graphene coatings on lithium-ion conductivity and mechanical stability under real thermal conditions remains unclear. To address this gap, we employ LAMMPS-based molecular dynamics simulations to construct atomic-scale models of pristine lithium and graphene-coated lithium (C/Li) interfaces at three representative temperatures. Through comprehensive analyses of dislocation evolution, root-mean-square displacement, frictional response, and lithium-ion diffusion, we find that graphene coatings synergistically alleviate interfacial stress, suppress crack initiation, reduce friction, and enhance ionic conductivity, with these effects being particularly pronounced at elevated temperatures. These findings reveal the coupled mechanical and electrochemical regulation imparted by graphene, providing a theoretical basis for optimizing the structure of next-generation high-performance lithium metal anodes and laying the foundation for advanced interfacial engineering in battery technologies. Full article

Direct growth of high-quality, Bernal-stacked bilayer graphene (BLG) on dielectric substrates is crucial for electronic and optoelectronic devices, yet it remains hindered by poor film quality, uncontrollable thickness, and high-density grain boundaries. In this work, a facile, catalyst-assisted method to grow high-quality, single-crystalline BLG directly on dielectric substrates (SiO₂/Si, sapphire, and quartz) was demonstrated. A single-crystal monolayer graphene template was first employed as a seed layer to facilitate the homoepitaxial synthesis of single-crystalline BLG directly on insulating substrates. Nanostructure Cu powders were used as the remote catalysis to provide long-lasting catalytic activity during the graphene growth. Transmission electron microscopy confirms the single-crystalline nature of the resulting BLG domains, which validates the superiority of the homoepitaxial growth technique. Raman spectroscopy and electrical measurement results indicate that the quality of the as-grown BLG is comparable to that on metal substrate surfaces. Field-effect transistors fabricated directly on the as-grown BLG/SiO₂/Si showed a room temperature carrier mobility as high as 2297 ± 3 cm² V⁻¹ s⁻¹, which is comparable to BLG grown on Cu and much higher than that reported on in-sulators. Full article

Recent theoretical studies have shown that gapped Dirac materials (such as gapped monolayer graphene) optically pumped with circularly polarized light can host edge-localized plasmon modes with nonreciprocal dispersions driven by valley population imbalance. Here, we extend this framework to Bernal-stacked bilayer graphene. Using the Wiener–Hopf method, we compute the exact edge plasmon dispersion, confinement length, and electric potential. Our results show that bilayer graphene exhibits stronger nonreciprocity in edge plasmons, requiring approximately one order of magnitude lower pump amplitude to achieve splitting compared with monolayer Dirac systems. Furthermore, the gate-tunable energy gap of bilayer graphene provides an additional degree of control, positioning optically pumped bilayer graphene as a versatile platform for magnet-free nonreciprocal plasmonics. Full article