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20 pages, 7865 KB  
Article
Study on Development of Hydrogen Peroxide Generation Reactor with Pin-to-Water Atmospheric Discharges
by Sung-Young Yoon, Eun Jeong Hong, Junghyun Lim, Seungil Park, Sangheum Eom, Seong Bong Kim and Seungmin Ryu
Plasma 2025, 8(4), 41; https://doi.org/10.3390/plasma8040041 (registering DOI) - 14 Oct 2025
Abstract
We present an experimentally validated, engineering-oriented framework for the design and operation of pin-to-water (PTW) atmospheric discharges to produce hydrogen peroxide (H2O2) on demand. Motivated by industrial needs for safe, point-of-use oxidant supply, we combine time-resolved diagnostics (FTIR, OES), [...] Read more.
We present an experimentally validated, engineering-oriented framework for the design and operation of pin-to-water (PTW) atmospheric discharges to produce hydrogen peroxide (H2O2) on demand. Motivated by industrial needs for safe, point-of-use oxidant supply, we combine time-resolved diagnostics (FTIR, OES), liquid-phase analysis (ion chromatography, pH, conductivity), and coupled plasma-chemistry/fluid simulations to link plasma state to aqueous H2O2 yield. Under the tested conditions (14.3 kHz, 0.2 kW; electrode to quartz wall distance 12–14 mm; coolant setpoints 0–40 °C), H2O2 concentration follows a reproducible non-monotonic trajectory: rapid accumulation during the early treatment (typical peak at ~15–25 min), followed by decline with continued operation. The decline coincides with a robust vibrational-temperature (Tvib) threshold near ~4900 K measured from N2 emission, and with concurrent NOX accumulation and bulk acidification. Global chemistry modeling and Fluent flow fields reproduce the observed trend and show that both vibrational excitation (kinetics) and convective transport (mass/heat transfer) determine the productive time window. Based on these results, we formulate practical design rules—electrode gap (power density), discharge current control, thermal/flow management, water quality, and OES-based Tvib monitoring with an automated stop rule—that maximize H2O2 yield while avoiding NOX-dominated suppression. The study provides a clear path for transforming mechanistic plasma insights into deployable, industrial H2O2 generator designs. Full article
(This article belongs to the Special Issue Feature Papers in Plasma Sciences 2025)
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17 pages, 8553 KB  
Article
High-Intensity Focused Pressure Wave Generation via Q-Switched Er:YAG Laser with a Water Layer Formed by the Coupled Lens for Optoacoustic Conversion
by Dominik Šavli, Aleš Babnik, Daniele Vella and Matija Jezeršek
Appl. Sci. 2025, 15(19), 10860; https://doi.org/10.3390/app151910860 - 9 Oct 2025
Viewed by 221
Abstract
We demonstrate coating-free optoacoustic generation and focusing of ultrasound using a mechanically Q-switched (MQS) erbium-doped yttrium aluminum garnet (Er:YAG) source (~100 ns, ≤20 mJ) combined with a concave water interface that simultaneously serves as converter and acoustic lens. Axial, lateral, and focal-point measurements [...] Read more.
We demonstrate coating-free optoacoustic generation and focusing of ultrasound using a mechanically Q-switched (MQS) erbium-doped yttrium aluminum garnet (Er:YAG) source (~100 ns, ≤20 mJ) combined with a concave water interface that simultaneously serves as converter and acoustic lens. Axial, lateral, and focal-point measurements mapped the pressure field while varying beam diameter (2w = 5–15 mm) and pulse energy (E = 10–20 mJ). The maximum focal positive pressure (Pmax = 7 MPa) occurs at an intermediate diameter (~10 mm), whereas the tightest lateral/axial confinement and strongest spectral enhancement arise at larger diameters (14–15 mm) with fc = ~5 MHz and −6 dB bandwidth up to 7 MHz. Pressure increases nearly monotonically with energy. For equal fluence, larger diameters yield higher focal pressures due to greater focusing gain. Small beams (2w ≈ 5–7 mm) show shorter apparent time-of-flight (TOF) and waveform broadening, consistent with early shock-like emission from locally vaporizing region. These results provide practical rules for tuning amplitude, spectrum, and confinement, enabling sub-millimeter focusing for contamination-sensitive and therapeutic applications. Full article
(This article belongs to the Section Optics and Lasers)
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26 pages, 2781 KB  
Article
Iterative Optimization of Structural Entropy for Enhanced Network Fragmentation Analysis
by Fatih Ozaydin, Vasily Lubashevskiy and Seval Yurtcicek Ozaydin
Information 2025, 16(10), 828; https://doi.org/10.3390/info16100828 - 24 Sep 2025
Viewed by 299
Abstract
Identifying and ranking influential nodes is central to tasks such as targeted immunization, misinformation containment, and resilient design. Structural entropy (SE) offers a principled, community-aware scoring rule, yet the one-shot (static) use of SE may become suboptimal after each intervention, as the residual [...] Read more.
Identifying and ranking influential nodes is central to tasks such as targeted immunization, misinformation containment, and resilient design. Structural entropy (SE) offers a principled, community-aware scoring rule, yet the one-shot (static) use of SE may become suboptimal after each intervention, as the residual topology and its modular structure change. We introduce iterative structural entropy (ISE), a simple yet powerful modification that recomputes SE on the residual graph before every removal, thus turning node targeting into a sequential, feedback-driven policy. We evaluate SE and ISE on seven benchmark networks using (i) cumulative structural entropy (CSE), (ii) cumulative sum of largest connected component sizes (LCCs), and (iii) dynamic panels that track average shortest-path length and diameter within the residual LCC together with a near-threshold percolation proxy (expected outbreak size). Across datasets, ISE consistently fragments earlier and more decisively than SE; on the Netscience network, ISE reduces the cumulative LCC size by 43% (RLCCs =0.567). In parallel, ISE achieves perfect discriminability (monotonicity M=1.0) among positively scored nodes on all benchmarks, while SE and degree-based baselines display method-dependent ties. These results support ISE as a practical, adaptive alternative to static SE when sequential decisions matter, delivering sharper rankings and faster structural degradation under identical measurement protocols. Full article
(This article belongs to the Special Issue Optimization Algorithms and Their Applications)
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25 pages, 1507 KB  
Article
DARN: Distributed Adaptive Regularized Optimization with Consensus for Non-Convex Non-Smooth Composite Problems
by Cunlin Li and Yinpu Ma
Symmetry 2025, 17(7), 1159; https://doi.org/10.3390/sym17071159 - 20 Jul 2025
Viewed by 397
Abstract
This paper proposes a Distributed Adaptive Regularization Algorithm (DARN) for solving composite non-convex and non-smooth optimization problems in multi-agent systems. The algorithm employs a three-phase iterative framework to achieve efficient collaborative optimization: (1) a local regularized optimization step, which utilizes proximal mappings to [...] Read more.
This paper proposes a Distributed Adaptive Regularization Algorithm (DARN) for solving composite non-convex and non-smooth optimization problems in multi-agent systems. The algorithm employs a three-phase iterative framework to achieve efficient collaborative optimization: (1) a local regularized optimization step, which utilizes proximal mappings to enforce strong convexity of weakly convex objectives and ensure subproblem well-posedness; (2) a consensus update based on doubly stochastic matrices, guaranteeing asymptotic convergence of agent states to a global consensus point; and (3) an innovative adaptive regularization mechanism that dynamically adjusts regularization strength using local function value variations to balance stability and convergence speed. Theoretical analysis demonstrates that the algorithm maintains strict monotonic descent under non-convex and non-smooth conditions by constructing a mixed time-scale Lyapunov function, achieving a sublinear convergence rate. Notably, we prove that the projection-based update rule for regularization parameters preserves lower-bound constraints, while spectral decay properties of consensus errors and perturbations from local updates are globally governed by the Lyapunov function. Numerical experiments validate the algorithm’s superiority in sparse principal component analysis and robust matrix completion tasks, showing a 6.6% improvement in convergence speed and a 51.7% reduction in consensus error compared to fixed-regularization methods. This work provides theoretical guarantees and an efficient framework for distributed non-convex optimization in heterogeneous networks. Full article
(This article belongs to the Section Mathematics)
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27 pages, 5014 KB  
Article
A Microbial Food Web Dynamics Under the Influence of Leachate Recirculation
by Fatema Ahmed Al Najim, Miled El Hajji and Bader Saad Alshammari
Mathematics 2025, 13(13), 2146; https://doi.org/10.3390/math13132146 - 30 Jun 2025
Viewed by 309
Abstract
The three-tiered microbial food chain without maintenance under leachate recirculation is the subject of a mathematical seven-dimensional dynamical system that is proposed in this work. This model captures the complex interactions between chlorophenol degraders, phenol degraders, and methanogens in the presence of hydrogen [...] Read more.
The three-tiered microbial food chain without maintenance under leachate recirculation is the subject of a mathematical seven-dimensional dynamical system that is proposed in this work. This model captures the complex interactions between chlorophenol degraders, phenol degraders, and methanogens in the presence of hydrogen inhibition. The implementation allows for investigation of how hydrogen levels affect the overall system dynamics and phenol production. There is a thorough qualitative analysis provided. A stability analysis of equilibrium points is performed. It is demonstrated that the persistence of the three bacteria is correlated with the existence of the positive equilibrium point, assuming some monotonicity properties on the growth rates. Asymptotic coexistence is satisfied, although periodic orbit possibilities are not ruled out. In order to decrease the amount of organic materials within the reactor, we suggest an optimal strategy on the rate of leachate recirculation in the second stage. Lastly, we offer a few numerical investigations that support and strengthen the theoretical conclusions. Full article
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20 pages, 579 KB  
Article
Optimal Energy-Aware Scheduling of Heterogeneous Jobs with Monotonically Increasing Slot Costs
by Lin Zhao, Hao Fu and Mu Su
Symmetry 2025, 17(7), 980; https://doi.org/10.3390/sym17070980 - 20 Jun 2025
Viewed by 869
Abstract
Energy-aware scheduling plays a critical role in modern computing and manufacturing systems, where energy consumption often increases with job execution order or resource usage intensity. This study investigates a scheduling problem in which a sequence of heterogeneous jobs—classified as either heavy or light—must [...] Read more.
Energy-aware scheduling plays a critical role in modern computing and manufacturing systems, where energy consumption often increases with job execution order or resource usage intensity. This study investigates a scheduling problem in which a sequence of heterogeneous jobs—classified as either heavy or light—must be assigned to multiple identical machines with monotonically increasing slot costs. While the machines are structurally symmetric, the fixed job order and cost asymmetry introduce significant challenges for optimal job allocation. We formulate the problem as an integer linear program and simplify the objective by isolating the cumulative cost of heavy jobs, thereby reducing the search for optimality to a position-based assignment problem. To address this challenge, we propose a structured assignment model termed monotonic machine assignment, which enforces index-based job distribution rules and restores a form of functional symmetry across machines. We prove that any feasible assignment can be transformed into a monotonic one without increasing the total energy cost, ensuring that the global optimum lies within this reduced search space. Building on this framework, we first present a general dynamic programming algorithm with complexity O(n2m2). More importantly, by introducing a structural correction scheme based on misaligned assignments, we design an iterative refinement algorithm that achieves global optimality in only O(nm2) time, offering significant scalability for large instances. Our results contribute both structural insight and practical methods for optimal, position-sensitive, energy-aware scheduling, with potential applications in embedded systems, pipelined computation, and real-time operations. Full article
(This article belongs to the Special Issue Symmetry in Computing Algorithms and Applications)
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17 pages, 4713 KB  
Article
Rapoport’s Rule, the Ecotone Concept, and Salinity Gradient Predict the Distribution of Benthic Foraminifera in a Southeastern Pacific Estuary
by Leonardo D. Fernández and Margarita Marchant
Ecologies 2025, 6(1), 11; https://doi.org/10.3390/ecologies6010011 - 2 Feb 2025
Cited by 1 | Viewed by 1075
Abstract
This study explores the biogeographic processes shaping the distribution of benthic foraminifera along a salinity gradient in the Contaco Estuary, southeastern Pacific, Chile. The primary aim was to evaluate the applicability of key ecological paradigms—Rapoport’s rule, the mid-domain effect, ecotones, and source–sink dynamics—to [...] Read more.
This study explores the biogeographic processes shaping the distribution of benthic foraminifera along a salinity gradient in the Contaco Estuary, southeastern Pacific, Chile. The primary aim was to evaluate the applicability of key ecological paradigms—Rapoport’s rule, the mid-domain effect, ecotones, and source–sink dynamics—to unicellular eukaryotes in estuarine environments. A 1550 m longitudinal transect, sampled at 50 m intervals, revealed a pronounced salinity-driven pattern in species richness and diversity, with calcareous taxa dominating euhaline zones and agglutinated taxa thriving in brackish and freshwater areas. Source–sink dynamics were not supported, as beta diversity analyses identified turnover as the dominant driver, highlighting species replacement along the salinity gradient. Evidence of a longitudinal Rapoport effect was observed, with broader distribution ranges in low-salinity environments, reflecting adaptations to suboptimal conditions. Contrary to predictions, the mid-domain effect was not supported, as foraminiferal richness showed a monotonic decline. These findings extend macroecological principles to microbial communities, emphasizing deterministic processes in shaping estuarine diversity. This research provides a robust framework for understanding biodiversity patterns in dynamic ecosystems, offering valuable insights for conservation and ecological monitoring. Full article
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11 pages, 271 KB  
Article
On Qi’s Normalized Remainder of Maclaurin Power Series Expansion of Logarithm of Secant Function
by Hong-Chao Zhang, Bai-Ni Guo and Wei-Shih Du
Axioms 2024, 13(12), 860; https://doi.org/10.3390/axioms13120860 - 8 Dec 2024
Cited by 6 | Viewed by 1115
Abstract
In the study, the authors introduce Qi’s normalized remainder of the Maclaurin power series expansion of the function lnsecx=lncosx; in view of a monotonicity rule for the ratio of two Maclaurin power series and by [...] Read more.
In the study, the authors introduce Qi’s normalized remainder of the Maclaurin power series expansion of the function lnsecx=lncosx; in view of a monotonicity rule for the ratio of two Maclaurin power series and by virtue of the logarithmic convexity of the function (2x1)ζ(x) on (1,), they prove the logarithmic convexity of Qi’s normalized remainder; with the aid of a monotonicity rule for the ratio of two Maclaurin power series, the authors present the monotonic property of the ratio between two Qi’s normalized remainders. Full article
15 pages, 315 KB  
Article
Modified Trapezoidal Product Cubature Rules: Definiteness, Monotonicity, and a Posteriori Error Estimates
by Geno Nikolov and Petar Nikolov
Mathematics 2024, 12(23), 3783; https://doi.org/10.3390/math12233783 - 29 Nov 2024
Viewed by 694
Abstract
We study two modifications of the trapezoidal product cubature formulae, approximating double integrals over the square domain [a,b]2=[a,b]×[a,b]. Our modified cubature formulae use mixed type [...] Read more.
We study two modifications of the trapezoidal product cubature formulae, approximating double integrals over the square domain [a,b]2=[a,b]×[a,b]. Our modified cubature formulae use mixed type data: except evaluations of the integrand on the points forming a uniform grid on [a,b]2, they involve two or four univariate integrals. A useful property of these cubature formulae is that they are definite of order (2,2), that is, they provide one-sided approximation to the double integral for real-valued integrands from the class C2,2[a,b]={f(x,y):4fx2y2continuousanddoesnotchangesignin(a,b)2}. For integrands from C2,2[a,b] we prove monotonicity of the remainders and derive a posteriori error estimates. Full article
(This article belongs to the Special Issue Approximation Theory and Applications)
24 pages, 3130 KB  
Article
Weighted Aggregated Sum Product Assessment Method Based on Aczel–Alsina T-Norm and T-Conorm Under Bipolar T-Spherical Fuzzy Information: Design Scheme Selection Application
by Zhifeng Zhao and Yunfeng Shu
Symmetry 2024, 16(11), 1473; https://doi.org/10.3390/sym16111473 - 5 Nov 2024
Cited by 1 | Viewed by 1245
Abstract
Selecting optimal design solutions is inherently complex due to multiple criteria encompassing users’ uncertain needs, experiences, and costs. This process must manage uncertainty and ambiguity, making developing a scientific, rational, and efficient guidance method imperative. Bipolar T-spherical fuzzy sets (BTSFS), a hybrid of [...] Read more.
Selecting optimal design solutions is inherently complex due to multiple criteria encompassing users’ uncertain needs, experiences, and costs. This process must manage uncertainty and ambiguity, making developing a scientific, rational, and efficient guidance method imperative. Bipolar T-spherical fuzzy sets (BTSFS), a hybrid of bipolar fuzzy sets and T-spherical fuzzy sets, effectively handle the bipolarity inherent in all elements. In this work, we propose a Weighted Aggregated Sum Product Assessment (WASPAS) method based on BTSFS and the Aczel–Alsina T-norm (AATN) and T-conorm (AATCN) to address the problem of selecting conceptual design solutions. We first establish operational rules for BTSFS using AATN and AATCN and introduce weighted aggregation operators (BTSFAAWA) and geometric aggregation operators (BTSFAAWG) while examining fundamental properties, such as idempotency, boundedness, and monotonicity. Subsequently, we propose a two-stage BTSFS-based WASPAS method; criterion weights are calculated using the BTSFAAWA operator, and final rankings are obtained through comprehensive calculations using both the weighted sum method (WSM) based on BTSFAAWA and the weighted product method (WPM) based on BTSFAAWG. Finally, we validate the effectiveness of our method through a case study of the selection of cultural and creative products. Sensitivity and comparative analyses are conducted to demonstrate the advantages of our approach. Full article
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13 pages, 278 KB  
Article
An Improved Non-Monotonic Adaptive Trust Region Algorithm for Unconstrained Optimization
by Mingming Xu, Quanxin Zhu and Hongying Xiao
Mathematics 2024, 12(21), 3398; https://doi.org/10.3390/math12213398 - 30 Oct 2024
Viewed by 1110
Abstract
The trust region method is an effective method for solving unconstrained optimization problems. Incorrectly updating the rules of the trust region radius will increase the number of iterations and affect the calculation efficiency. In order to obtain an effective radius for the trust [...] Read more.
The trust region method is an effective method for solving unconstrained optimization problems. Incorrectly updating the rules of the trust region radius will increase the number of iterations and affect the calculation efficiency. In order to obtain an effective radius for the trust region, an adaptive radius updating criterion is proposed based on the gradient of the current iteration point and the eigenvalue of the Hessian matrix which avoids calculating the inverse of the Hessian matrix during radius updating. This approach reduces the computation time and enhances the algorithm’s performance. On this basis, we apply adaptive radius and non-monotonic techniques to the trust region algorithm and propose an improved non-monotonic adaptive trust region algorithm. Under proper assumptions, the convergence of the algorithm is analyzed. Numerical experiments confirm that the suggested algorithm is effective. Full article
40 pages, 475 KB  
Article
Decision Analysis Algorithm Using Frank Aggregation in the SWARA Framework with p,qRung Orthopair Fuzzy Information
by Jawad Ali, Suhad Ali Osman Abdallah and N. S. Abd EL-Gawaad
Symmetry 2024, 16(10), 1352; https://doi.org/10.3390/sym16101352 - 12 Oct 2024
Cited by 9 | Viewed by 940
Abstract
The present study introduces an innovative approach to multi-criteria decision making (MCDM) aimed at handling decision analysis involving p,qrung orthopair fuzzy (p,qROF) data, where the criteria weights are completely unknown. To achieve this objective, we formulate [...] Read more.
The present study introduces an innovative approach to multi-criteria decision making (MCDM) aimed at handling decision analysis involving p,qrung orthopair fuzzy (p,qROF) data, where the criteria weights are completely unknown. To achieve this objective, we formulate generalized operational rules referred to as Frank operational rules, tailored for p,qROF numbers (p,qROFNs) utilizing the Frank t-norm and t-conorm. With these newly devised operations as a foundation, we create a variety of p,qROF aggregation operators (AOs) to effectively aggregate p,qROF information. Furthermore, we examine specific instances of these operators and rigorously establish their desirable properties, including idempotency, monotonicity, boundedness, and symmetry. Subsequently, we adapt the SWARA technique to the realm of p,qROF fuzzy data and this adapted technique becomes instrumental in determining criteria weights within the proposed MCDM framework centered around proposed AOs. We furnish a descriptive example to exemplify the practicality of the developed approach. Lastly, the effectiveness and soundness of our approach are underscored through both parameter analysis and a comparative evaluation. Full article
(This article belongs to the Section Engineering and Materials)
20 pages, 6109 KB  
Article
Dynamic Analysis and Approximate Solution of Transient Stability Targeting Fault Process in Power Systems
by Hao Wu and Jing Li
Mathematics 2024, 12(19), 3065; https://doi.org/10.3390/math12193065 - 30 Sep 2024
Viewed by 1369
Abstract
Modern power systems are high-dimensional, strongly coupled nonlinear systems with complex and diverse dynamic characteristics. The polynomial model of the power system is a key focus in stability research. Therefore, this paper presents a study on the approximate transient stability solution targeting the [...] Read more.
Modern power systems are high-dimensional, strongly coupled nonlinear systems with complex and diverse dynamic characteristics. The polynomial model of the power system is a key focus in stability research. Therefore, this paper presents a study on the approximate transient stability solution targeting the fault process in power systems. Firstly, based on the inherent sinusoidal coupling characteristics of the power system swing equations, a generalized polynomial matrix description in perturbation form is presented using the Taylor expansion formula. Secondly, considering the staged characteristics of the stability process in power systems, the approximate solutions of the polynomial model during and after the fault are provided using coordinate transformation and regular perturbation techniques. Then, the structural characteristics of the approximate solutions are analyzed, revealing the mathematical basis of the stable motion patterns of the power grid, and a monotonicity rule of the system’s power angle oscillation amplitude is discovered. Finally, the effectiveness of the proposed methods and analyses is further validated by numerical examples of the IEEE 3-machine 9-bus system and IEEE 10-machine 39-bus system. Full article
(This article belongs to the Special Issue Mathematical and Computational Methods for Mechanics and Engineering)
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11 pages, 260 KB  
Article
Absolute Monotonicity of Normalized Tail of Power Series Expansion of Exponential Function
by Feng Qi
Mathematics 2024, 12(18), 2859; https://doi.org/10.3390/math12182859 - 14 Sep 2024
Cited by 10 | Viewed by 1655
Abstract
In this work, the author reviews the origination of normalized tails of the Maclaurin power series expansions of infinitely differentiable functions, presents that the ratio between two normalized tails of the Maclaurin power series expansion of the exponential function is decreasing on the [...] Read more.
In this work, the author reviews the origination of normalized tails of the Maclaurin power series expansions of infinitely differentiable functions, presents that the ratio between two normalized tails of the Maclaurin power series expansion of the exponential function is decreasing on the positive axis, and proves that the normalized tail of the Maclaurin power series expansion of the exponential function is absolutely monotonic on the whole real axis. Full article
(This article belongs to the Special Issue Polynomials: Theory and Applications, 2nd Edition)
15 pages, 300 KB  
Article
Some Properties on Normalized Tails of Maclaurin Power Series Expansion of Exponential Function
by Zhi-Hua Bao, Ravi Prakash Agarwal, Feng Qi and Wei-Shih Du
Symmetry 2024, 16(8), 989; https://doi.org/10.3390/sym16080989 - 5 Aug 2024
Cited by 10 | Viewed by 1876
Abstract
In the paper, (1) in view of a general formula for any derivative of the quotient of two differentiable functions, (2) with the aid of a monotonicity rule for the quotient of two power series, (3) in light of the logarithmic convexity of [...] Read more.
In the paper, (1) in view of a general formula for any derivative of the quotient of two differentiable functions, (2) with the aid of a monotonicity rule for the quotient of two power series, (3) in light of the logarithmic convexity of an elementary function involving the exponential function, (4) with the help of an integral representation for the tail of the power series expansion of the exponential function, and (5) on account of Čebyšev’s integral inequality, the authors (i) expand the logarithm of the normalized tail of the power series expansion of the exponential function into a power series whose coefficients are expressed in terms of specific Hessenberg determinants whose elements are quotients of combinatorial numbers, (ii) prove the logarithmic convexity of the normalized tail of the power series expansion of the exponential function, (iii) derive a new determinantal expression of the Bernoulli numbers, deduce a determinantal expression for Howard’s numbers, (iv) confirm the increasing monotonicity of a function related to the logarithm of the normalized tail of the power series expansion of the exponential function, (v) present an inequality among three power series whose coefficients are reciprocals of combinatorial numbers, and (vi) generalize the logarithmic convexity of an extensively applied function involving the exponential function. Full article
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