Search Results (110)

The compressor in automotive air-conditioning systems consumes a significant fraction of the vehicle’s energy, thereby reducing driving range. Consequently, developing more efficient compressor operation is essential for improving overall thermal management. Nano-enhanced lubricants have emerged as a promising passive strategy to reduce compressor power consumption, enhance thermodynamic performance, and improve tribological behavior by minimizing friction and wear. This review critically examines existing nano-lubricant research with a focus on automotive compressor and system-level performance, friction and wear reduction mechanisms, and the influence of nanoparticle type and concentration on lubricant thermo-physical properties. The analysis reveals that nano-lubricants consistently enhance compressor operation by lowering discharge temperature and reducing power consumption, while improving coefficient of performance and cooling capacity. However, these benefits have been validated primarily under cooling-mode conditions and predominantly for reciprocating-piston compressors. Tribological studies further demonstrate substantial reductions in coefficient of friction and surface roughness, with improved anti-wear characteristics compared to virgin lubricants. Four principal mechanisms—rolling, polishing, protective-film formation, and self-repairing—have been identified as contributors to these enhancements. Nevertheless, most tribological investigations rely on simplified test rigs that do not fully represent the complex contact, loading, and thermal environments inside actual automotive compressors. This review underscores the need for system-level, mechanism-driven, and compressor-architecture-specific investigations covering both cooling and heating modes of automotive air-conditioning operation. The insights presented aim to guide future development of reliable, durable, and refrigerant-compatible nano-lubricant technologies for next-generation automotive air-conditioning systems. Full article

Surface and interface science play an important role in the tribological properties of materials. Recently, research in this field has extended from the macroscopic scale to the molecular level to elucidate energy dissipation and structural evolution mechanisms at sliding interfaces. In this work, we propose a nanolubricant strategy based on carbon nanocages (CNCs). Three types of lubricating molecules—oleylamine (amine), oleic acid (carboxyl), and stearyl alcohol (hydroxyl)—were encapsulated into a polytetrafluoroethylene (PTFE) matrix to construct a composite tribological interface model. Molecular dynamics simulations were employed to investigate the interfacial enrichment, diffusion, and interaction mechanisms of these molecules with PTFE chains and the Fe counterface. Particular emphasis was placed on how different functional groups regulate energy transfer and dissipation pathways. This study deepens the molecular–level understanding of structure–lubrication relationships and provides theoretical guidance for designing high–performance polymer–based tribological materials. Full article

ZnMgAl layered double hydroxides (LDHs) were synthesised via coprecipitation, and oleic acid and stearic acid were grafted onto their surfaces via dehydration condensation to obtain two nano-lubricant additives, OA-ZnMgAl LDH and SA-ZnMgAl LDH. These surface modifications significantly improved the dispersion stability of ZnMgAl LDH in lubricating oil. Tribological tests showed that, at their respective optimal concentrations for friction reduction or wear resistance, ZnMgAl LDH, OA-ZnMgAl LDH, and SA-ZnMgAl LDH reduced the coefficient of friction by 3%, 20%, and 16%, and decreased the wear scar diameter by 7%, 9%, and 14%, respectively, compared with the base oil (XMP-Mobil 320). To clarify the lubrication mechanism, the wear morphology and chemical composition were analysed using 3D optical profilometry, X-ray photoelectron spectroscopy, scanning electron microscopy, and FIB-SEM. The results indicate that LDHs react with the steel surface under load and shear to form a multilayer protective film consisting of an inner oxide layer and an outer graphite layer, preventing direct contact between friction pairs. In addition, the rolling and filling effects of partially unreacted LDHs further reduce friction and wear. Full article

Recent innovations with the aid of nanotechnology are more frequently seen in the industrial sectors. Lubricants are a high-end commodity resource used in many manufacturing processes; unfortunately, most of these lubricants are petroleum-based, which come with certain drawbacks, such as environmental aspects, handling issues and high costs. With the incorporation of nanostructures within fluids and lubricants, novel material alternatives are replacing conventional lubrication systems, maintaining the required thermophysical and tribological characteristics. This research provides an analysis of vegetable lubricant, castor oil (CO), and the effects of the incorporation of WS₂ nanofiller at diverse filler fractions. A TEMPOS thermal analyzer device and a four-ball tribotester are used for the analysis of thermal conductivity and tribological assessments, respectively. Results showed the enhancement of thermal conductivity as the filler concentration and the evaluation temperature of the nanolubricants increased. The best thermal conductivity improvement was 27%, at 60 °C with merely 0.20 wt.% of nanofillers. For tribological performance, a decrease of 6% in the coefficient of friction (COF) and 31% in the wear scar diameter (WSD) was observed at 0.10 wt.% and 0.20 wt.%, respectively. Adhesion of the nanostructures to the steel surfaces creates a protective layer, preventing direct contact of the friction pairs. These results are an outcome of applied theoretical concepts such as Brownian motion and nano-layering of the lubricant–nanostructure interface. Full article

This study tests TiO₂ and SiO₂ nanolubricants in PAG oil using a Mini Traction Machine and an Ultra Shear Viscometer. The loads were 20 N and 40 N. The entrainment speeds ranged from 2.5 to 500 mm/s. The slide-to-roll ratio (SRR) ranged from 25 to 150%. The nanoparticle concentrations were 0.01, 0.03, and 0.05%. The ball size was 19.05 mm, and the disc was 46 mm. All tests were run at 40 °C. Only the 0.05% concentration lowered traction compared with PAG at a fixed SRR. TiO₂ at 0.05% showed the largest drop, up to 4.89% at 20 N and 2.99% at 40 N. However, lower concentrations increased traction. All the nanolubricants reduced wear. TiO₂ at 0.03% gave the lowest wear, with a reduction of about 35 µm at 40 N. Nanolubricant samples stayed between 40.2 and 40.5 °C, while PAG reached about 41.0 °C. TiO₂ produced slightly lower temperatures than SiO₂. Ultra-shear tests from 40 to 100 °C showed shear thinning. In most conditions, TiO₂ at 0.05% kept the highest viscosity at 40 and 60 °C, up to 12% above PAG. SiO₂ showed smaller changes. TiO₂ delivered better friction, wear, temperature, and viscosity performance. Overall, both nanolubricants at 0.03% are suitable when wear reduction and thermal stability are prioritised over traction reduction, such as in refrigeration applications, while the 0.05% suits high-load or high-shear use. Full article

An experiment examined the impact of 0.2% to 1.0% w/w graphite nanoparticles in 15W40 lubricating oil on tribological and rheological behaviour. Analysis, conducted with a pin-on-disc machine and four-ball tester, revealed improved tribological properties and a 30% reduction in friction coefficient compared to fresh 15W40. Wear was negligible, and extreme-pressure performance increased by approximately 20%. SEM morphology confirmed the presence of graphite nanoparticles on the tribo-pair surface, indicating enhanced lubricant performance. Full article

The stability of nanolubricants is critical for ensuring effective performance under extreme pressure (EP) conditions, where severe boundary lubrication governs friction and wear behaviour. This study examines palm kernel oil (PKO)-based nanolubricants enhanced with carbon graphene (CG), hexagonal boron nitride (hBN), and molybdenum disulfide (MoS₂), with and without oleic acid (OA) as a surfactant. OA incorporation improved CG dispersion stability, reducing agglomerate size by 30.4% (17.61 μm to 12.23 μm) and increasing the viscosity index from ~176 to 188, compared to 152 for the commercial hydrogen engine oil baseline. Under EP conditions, PKO + CG + OA achieved a 51.7% reduction in the coefficient of friction (0.58 to 0.28) and 18.2% improvement in weld load resistance, while wear scar diameter decreased by 13.4%. Surface and elemental analyses indicated the formation of a composite tribofilm containing oxide species, graphene platelets, and carboxylate-derived compounds from OA, consistent with iron–oleate-like chemistry that enhances load-carrying capacity and wear protection. These findings demonstrate the potential of OA-assisted PKO nanolubricants as sustainable, high-performance formulations for extreme pressure boundary lubrication, contributing to the advancement of green tribology. Full article

This study employs molecular dynamics simulations to investigate the frictional behavior of fullerene nano-additives on Fe-C alloy surfaces under varying loads and temperatures, focusing on boundary lubrication conditions. The results show that the x-direction friction force exhibits minimal sensitivity to normal pressure due to the high rigidity of fullerene molecules, which limits variations in real contact area and atomic interactions. In contrast, temperature has a significant effect: as it rises, enhanced atomic vibrations and thermal activation lower energy barriers for sliding. The coefficient of friction (COF) consistently decreases with both increasing load and temperature, driven by the mechanism of thermally activated motion. Although partial rotational motion from sliding to rolling friction was not explicitly observed in the simulations, the study remains within the sliding-dominated regime, highlighting the importance of temperature over load in controlling friction. A linear relationship between $\ln COF$ and $1/k_{B}T$ yields an average activation energy of ~0.03 eV, supporting a thermally activated friction mechanism. By introducing a composite parameter that combines load and temperature effects, the study provides a predictive framework for modeling friction behavior under thermo-mechanical coupling. These findings enhance the understanding of the friction-reducing capabilities of fullerene additives and offer a foundation for designing advanced nano-lubricants in boundary lubrication systems. Full article

This study examines the rheological and tribological behavior of bio-based nano-lubricants enhanced with cerium oxide (CeO₂) and multi-walled carbon nanotubes (MWCNTs), alongside the application of artificial intelligence (AI) models for performance prediction. Rheological results confirmed non-Newtonian, shear-thinning behavior across all formulations. CeO₂-based lubricants exhibited significantly higher viscosities at 40 °C (up to ~3700 mPa·s at low shear), which decreased sharply with shear, indicating strong particle interactions. In contrast, MWCNT-based lubricants maintained moderate viscosities (90–365 mPa·s at 40 °C) with improved flowability due to nanotube alignment. At 100 °C, both systems showed viscosity reduction, stabilizing between 8 and 18 mPa·s, which favors pumpability in high-temperature applications. Tribological testing revealed distinct performance characteristics. CeO₂ lubricants showed slightly higher coefficients of friction (0.144–0.169) but excellent wear resistance, achieving the lowest wear rate of 1.66 × 10⁻⁶ mm³/N-m. MWCNT-based lubricants offered stable and lower CoF values (0.116–0.148) while also providing very low wear rates, with MCO6 achieving 1.62 × 10⁻⁶ mm³/N-m. However, ternary blends (C20T80 and M20T80) displayed moderate CoF but significantly higher wear rates (up to 2.92 × 10⁻⁵ mm³/N-m), suggesting that blending improves dispersion but weakens tribo-film stability. To complement the experimental findings, support vector regression (SVR), artificial neural networks (ANN), and AdaBoost algorithms were employed to predict key performance parameters based on compositional and thermal input data. The models demonstrated high prediction accuracy, validating the feasibility of AI-driven formulation screening. These results highlight the complementary potential of CeO₂ and MWCNT additives for high-performance bio-lubricant development and emphasize the role of machine learning in accelerating material optimization for sustainable lubrication systems. Full article

This study systematically investigates the effect and mechanism of a TiO₂ nano-lubricant on edge cracking and surface quality during the rolling of Mg/Al composite foils. Initial friction and wear tests identified an optimal nano-lubricant concentration of 3.0 wt.%, at which the system achieved a minimum average coefficient of friction of 0.067. Subsequent rolling tests using this concentration showed that the nano-lubricant reduced rolling force by 5.39–7.54% compared to dry conditions. It also significantly suppressed the initiation and propagation of edge cracks. Furthermore, the surface roughness parameters Ra and Rz were reduced by 16.5% to 24.0%, and the height profile fluctuation range was reduced by 33% to 45%, resulting in a smoother and more uniform surface morphology. The analysis of the underlying mechanism indicates that the superior performance originates from the synergistic effects of the rolling effect, the mending effect, the polishing effect, and the protective film effect. This work establishes that the use of a 3.0 wt.% TiO₂ nano-lubricant is a viable strategy for fabricating high-quality Mg/Al composite foils with minimal defects. It thereby offers both theoretical and practical guidance for the advanced rolling of bimetallic composites. Full article

The automotive industry is undergoing a transformative shift toward sustainability, driven by stringent environmental regulations, rising energy demands, and the pursuit of enhanced performance and efficiency. Lubricating materials play a pivotal role in reducing friction, wear, and energy losses in automotive systems, yet conventional lubricants, primarily petroleum-based, pose significant ecological and operational challenges. This review examines the development and performance of sustainable and advanced lubricant including bio-based oils, synthetic esters, nanolubricants, and ionic/solid lubricants for automotive applications. Drawing on tribological principles and recent advances in materials science, the article categorizes these lubricants based on source, chemical structure, and tribological behavior. A comparative framework is introduced to evaluate key performance indicators such as viscosity index, thermal stability, oxidation resistance, biodegradability, and compatibility with modern engine designs. The review also highlights emerging trends, including nanotechnology-based additives, green synthesis techniques, and novel antioxidant systems that enhance lubricant functionality and lifespan. Furthermore, a strategic research roadmap is proposed, outlining short-, medium-, and long-term priorities that integrate technical, environmental, and economic dimensions. By bridging foundational science with practical innovation, this article aims to guide researchers, manufacturers, and policymakers toward the adoption of high-performance, eco-compatible lubricants that support the transition to cleaner and more efficient mobility systems. Future directions and challenges in scaling, cost-effectiveness, and lifecycle assessment are discussed to guide innovation in this critical domain. Full article

The development of stable and efficient nanolubricants remains one of the main challenges in tribology due to particle agglomeration, poor long-term stability, and inconsistent frictional behavior under boundary lubrication. This study investigates the tribological performance of SAE 10W-40 engine oil enhanced with titanium dioxide (TiO₂) nanoparticles subjected to thermal treatments. TiO₂ powders (Degussa P25, ~30 nm) were calcined at 450 °C, 550 °C, 650 °C, and 750 °C, and incorporated into the base oil at a constant concentration of 0.05 wt%. Tribological tests were conducted using a four-ball tribometer under ASTM D4172 conditions (396 N, 1200 rpm, 30 min) at both ambient (23 °C) and elevated (75 °C) temperatures. The coefficient of friction (COF) and wear scar area (WSA) were measured, while the surface morphology was analyzed via 3D optical profilometry, SEM, and EDS. The results indicate that TiO₂ nanoparticles thermally treated at 550 °C offered the best tribological behavior, exhibiting the lowest COF and smallest WSA at both test temperatures. The improved performance is attributed to optimized crystalline structure and enhanced dispersion stability after calcination. Although no Ti-based tribofilm was detected, smoother wear scars suggest physical surface protection mechanisms, such as rolling and asperity smoothing. These findings highlight the critical influence of thermal treatment on nanoparticle effectiveness and demonstrate the potential of optimized nanoadditized lubricants for advanced friction and wear reduction under boundary lubrication conditions, providing practical guidance for developing next generation nanolubricants with improved durability and efficiency under boundary lubrication conditions. Full article

Magnesium alloys are widely used in automotive and aerospace applications due to their light weight but suffer from poor tribological performance. This study investigates the effects of base oil (SAE 5W-30) with 100% hBN, 100% ZnO, and various ratios of hBN/ZnO hybrid nanoparticles on the tribological performance of AZ91D magnesium alloy. Pin-on-disk tribometer tests were conducted on AZ91D magnesium alloy under loads of 10–60 N and a sliding distance of 1000 m. Dry sliding produced the highest coefficient of friction (COF, ~0.30) and the greatest wear. Base oil lubrication reduced COF to ~0.14 and improved wear resistance by more than 50%. The 100% hBN nanolubricant provided the lowest wear and a COF of ~0.114, while the 75hBN/25ZnO hybrid achieved the lowest COF (~0.110) with wear values close to hBN. Surface analyses confirmed that hBN formed a lamellar tribofilm that minimized metal-to-metal contact, and ZnO contributed to the formation of load-bearing oxide layers that enhanced surface stability. Overall, the results demonstrate that hBN and ZnO, in single or hybrid form, can significantly reduce friction and wear, showing strong potential for applications in automotive, aerospace, defense, and industrial systems. Full article

This research investigates the multi-objective optimization of micro-milling processes for the titanium alloy Ti-3Al-2.5V (grade 9) through the application of grey relational analysis. The incorporation of nanometer-sized particles in hybrid machining lubricants plays a crucial role in improving heat transfer during machining. The approach aims to increase the efficiency and effectiveness of micro-milling by addressing various performance metrics simultaneously, leading to better machining results for this titanium alloy. Additionally, the integration of nanoparticles into the machining lubricant significantly improves the lubrication properties, reducing friction during the machining process. The study analyzed four machining parameters: machining speed, rate of feed, axial depth of cut, and the weight percentage concentration of hybrid machining lubricants Multi-wall Carbon Nano Tube and Alumina Oxide (MWCNT and Al₂O₃). The machining nanolubricant was formulated by adding 1% and 2% volume concentrations of MWCNT and Al₂O₃ nanoparticles to the industrial machining fluid. In this machining context, the friction between the machining tool and the Ti-3Al-2.5V work piece is a vital factor influencing the output quality. The results demonstrate that the chosen machining parameters and machining lubricants have a direct impact on the coefficient of friction and surface roughness. The study concludes that utilizing machining nanolubrication for machining Ti-3Al-2.5V (grade 9) significantly enhances the quality compared with traditional machining lubricants. Full article

To address the challenges of friction and wear in mechanical systems, two functionalized montmorillonite (MMT) nanolubricants were developed through mechanochemistry, namely 3-sulfotetradecyldimethyl betaine-modified MMT (BS-MMT) and coconut amide propyl betaine-modified MMT (CAB-MMT) lubricants. The modification significantly expanded MMT’s interlayer spacing, with CAB-MMT exhibiting superior delamination and dispersion stability due to its coconut fatty amide groups. Tribological tests demonstrated that 0.5% CAB-MMT reduced the friction coefficient by 71.4% (to 0.08) and wear scar diameter by 58.8%, while maintaining stable performance under high loads (392 N) and speeds (1450 rpm). The exceptional performance stems from a synergistic mechanism involving the physical adsorption of MMT nanosheets, chemical adhesion via Fe-N/C-N⁺ bonds, and dynamic repair by friction-induced oxides. This work presents an eco-friendly, high-performance water-based nano-lubricant with broad industrial application potential. Full article