Search Results (4,526)

This study developed a rapid, non-destructive method for the quantitative detection of protein in cottonseed by integrating near-infrared (NIR) fiber spectroscopy with chemometric machine learning. The establishment of this method holds significant importance for the rational and efficient utilization of cottonseed resources, advancing research on the genetic improvement of cottonseed nutritional quality, and promoting the development of equipment for raw cottonseed protein detection. Fuzzy cottonseed samples from three varieties were collected, and their NIR fiber-optic spectra were acquired. Reference protein contents were measured using the Kjeldahl method. Spectra were denoised through preprocessing, after which informative wavelengths were selected by combining Uninformative Variable Elimination (UVE) with Competitive Adaptive Reweighted Sampling (CARS) and the Random Frog (RF) algorithm. Partial least squares regression (PLSR), least-squares support vector machine (LSSVM), and support vector regression (SVR) models were then constructed to predict protein content. Model performance was assessed using the coefficient of determination (R²), root-mean-square error (RMSE), residual predictive deviation (RPD), and range error ratio (RER). The results indicate that the standard normal variate (SNV) is the most effective preprocessing step. The best performance was achieved by the LSSVM model coupled with UVE + CARS, yielding R² = 0.8571, RMSE = 0.0033, RPD = 2.7078, and RER = 10.72, outperforming the PLSR and SVR counterparts. These findings provide technical support for the rapid detection of fuzzy cottonseed protein and lay the groundwork for the development of related detection equipment. Full article

We demonstrate a dual-wavelength broad-area diode laser system with narrow linewidth and wide spectral tunability using a composite external cavity comprising a volume Bragg grating and a Littrow-type transmission grating. One wavelength is stabilized at 780.25 nm with a linewidth of ~0.13 nm, while the other achieves a continuous tuning range of 772.24–786.43 nm with a linewidth of ~0.17 nm. The system exhibits a side-mode suppression ratio exceeding 20 dB across the entire tuning range. At a dual-wavelength separation of 4.29 nm, the total output power reaches 2.62 W. Additionally, we successfully validate the system’s potential for nonlinear optical applications. Full article

The Volume Bragg Grating (VBG) imaging technique provides a novel approach to gaze-type hyperspectral imaging. However, collimation constraints of the incident beam during narrow-band filtering and high-spatial-resolution imaging introduce system complexity, hindering miniaturization and modularization of the optical system. To address these limitations, this paper proposes a convex transmissive VBG structure with tunable design parameters to enhance the field of view (FOV), relax collimation requirements, improve imaging quality, narrow filter spectral bandwidth, and simplify the optical system design. For the precise analysis and optimization of convex VBG performance, we established a physical model for filtered imaging using a convex transmissive VBG with polychromatic extended sources. An evaluation metric termed the “Maximal Splitting Angle (MSA)” was introduced to quantify the dispersion extent of image spots. This approach was employed to investigate the intrinsic correlations between structural parameters (such as the radius of curvature, vector tilt angle, grating period, and thickness) and key system performance indicators (spatial resolution and spectral resolution). The necessity of optimizing these parameters was rigorously demonstrated. Theoretical analysis confirms that convex transmissive VBG achieves superior spatial and spectral resolution over planar VBG under reduced collimation constraints. The experimental results show a 58.5% enhancement in spatial resolution and a 63.6% improvement in spectral bandwidth for the convex transmissive VBG system. Crucially, while planar transmissive VBG suffers from stray fringe interference during wavelength tuning, its convex counterpart remains unaffected. This study proposes a novel device structure, offering new perspectives for optimizing VBG-filtered spectral imaging systems. Full article

The immobilization of titanium dioxide (TiO₂) nanostructures on conductive supports offers a promising strategy to overcome the intrinsic limitations of a wide band gap, poor visible-light absorption, and rapid charge recombination in photocatalysis. Herein, a rutile TiO₂ nanorods (TiO₂NRs) array was directly grown on carbon cloth (CC) via a hydrothermal method by using titanium tetrachloride (TiCl₄) seed solutions of 0.1, 0.3, and 0.5 M, designated as TiO₂NR0.1/CC, TiO₂NR0.3/CC, and TiO₂NR0.5/CC, respectively. Structural analysis confirmed that the TiO₂ NRs array is vertically aligned, and phase=pure rutile NRs strongly adhered to CC. The optical characterization revealed broadened absorption in the visible wavelength region and progressive band gap narrowing with the increasing seeding concentration. Photoluminescence (PL) spectra showed pronounced quenching in the fabricated TiO₂NRs/CC samples, especially with TiO₂NR0.3/CC exhibiting the lowest PL intensity, indicating suppressed charge recombination. Electrochemical impedance spectroscopy further demonstrated reduced charge transfer resistance, and TiO₂NR0.3/CC achieved the most efficient electron transport kinetics. Photocatalytic tests at λ ≥ 400 nm irradiation confirmed the enhanced hydrogen evolution performance of TiO₂NR0.3/CC. The hydrogen yield of 2.66 mmol h⁻¹ g⁻¹ of TiO₂NR0.3/CC was 4.03-fold higher than that of TiO₂NRs (0.66 mmol h⁻¹ g⁻¹), along with excellent cyclic stability across three runs. Additionally, TiO₂NR0.3/CC achieved 90.2% degradation of methylene blue within 60 min, with a kinetic constant of 0.0332 min⁻¹ and minimal activity loss after three cycles. These results highlight the synergistic integration of TiO₂ NRs with CC in achieving a durable, recyclable, and efficient photocatalytic platform for sustainable hydrogen generation and wastewater remediation. Full article

Non-invasive glucose monitoring remains a persistent challenge in the scientific literature due to the complexity of biological samples and the limitations of traditional optical methods. Although advances have been made in the use of near-infrared (NIR) spectrophotometry, the direct application of the Lambert–Beer Law (LBL) to such systems has proven problematic, particularly due to the non-linear behavior observed in complex organic solutions. In this context, the objective of this work is to propose and validate a methodology for the determination of the extinction coefficient of glucose in blood, taking into account the limitations of the LBL and the specificities of molecular interactions. The method was optimized through an iterative process to provide consistent results over multiple replicates. Whole blood and plasma samples from two individuals were analyzed using spectrophotometry in the 700 nm to 1400 nm. The results showed that glucose has a high spectral sensitivity close to 975 nm.The extinction coefficients obtained for glucose (${\alpha }_g$) ranged from −0.0045 to −0.0053, and for insulin (${\alpha }_i$) from 0.000075 to 0.000078, with small inter-individual variations, indicating strong stability of these parameters. The non-linear behaviour observed in the relationship between absorbance, glucose and insulin concentrations might be explained by the changes imposed by both s and p orbitals of organic molecules. In order to make the LBL valid in this context, the extinction coefficients must be functions of the analyte concentrations, and the insulin concentration must also be a function of glucose. A regression model was found which allows to differentiate glucose from insulin concentration, by considering the cuvette thickness and sample absorbance at 965, 975, and 985 nm. It can also be concluded from experiments that wavelength of approximately 975 nm is more suitable for blood glucose calculation by using photometry. The final spectra are consistent with those reported in mid-infrared validation studies, suggesting that the proposed model encompasses the key aspects of glucose behavior in biological media. Full article

The growing need for efficient and safe high-energy lithium-ion batteries (LIBs) in electric vehicles and grid storage necessitates advanced internal monitoring solutions. This work presents a comprehensive simulation model of a novel integrated optical sensor based on ethylene carbonate-filled photonic crystal fiber (EC-PCF). The proposed design synergistically combines a chirped fiber Bragg grating (FBG) and an extrinsic Fabry–Pérot interferometer (EFPI) on a multiplexed platform for the multifunctional sensing of refractive index (RI), temperature, strain, and pressure (via strain coupling) within LIBs. By matching the RI of the PCF cladding to the battery electrolyte using ethylene carbonate, the design maximizes light–matter interaction for exceptional RI sensitivity, while the cascaded EFPI enhances mechanical deformation detection beyond conventional FBG arrays. The simulation framework employs the Transfer Matrix Method with Gaussian apodization to model FBG reflectivity and the Airy formula for high-fidelity EFPI spectra, incorporating critical effects like stress-induced birefringence, Transverse Electric (TE)/Transverse Magnetic (TM) polarization modes, and wavelength dispersion across the 1540–1560 nm range. Robustness against fabrication variations and environmental noise is rigorously quantified through Monte Carlo simulations with Sobol sequences, predicting temperature sensitivities of ∼12 pm/°C, strain sensitivities of ∼1.10 pm/$\mathsf{\mu }$$\mathsf{\epsilon }$, and a remarkable RI sensitivity of ∼1200 nm/RIU. Validated against independent experimental data from instrumented battery cells, this model establishes a robust computational foundation for real-time battery monitoring and provides a critical design blueprint for future experimental realization and integration into advanced battery management systems. Full article

Mode conversion effects in Fibre Bragg Gratings (FBGs) are widely exploited in applications such as sensing and fibre lasers. However, when FBGs are inscribed into Few-mode optical Fibres (FMFs), the mode interactions become highly complex due to the increased number of guided modes, rendering their practical use difficult. In this study, we investigate whether the addition of a spatial mode multiplexer, used to selectively excite specific fibre modes, can simplify the interpretation and utility of few-mode FBGs (FM-FBGs). We focus on point-by-point (PbP)-inscribed FBGs, localised with respect to the transverse cross-section of the fibre core, and study their interaction with a range of Hermitian Gauss input modes. We present a comprehensive numerical study supported by experimental validation, examining the mechanisms of mode coupling induced by localised FBGs and its implications, with a focus on sensing applications. Our results show that the introduction of a spatial mode multiplexer leads to slight simplification of the FBG transmission spectrum. Nevertheless, significant simplification of the reflection spectrum is achievable after modal filtering occurs as the reflected light re-traverses the spatial mode multiplexer, potentially enabling WDM monitoring of FM-FBGs. Notably, we report a novel approach to multiplexing FBGs based on their transverse location within the fibre core and the modal content initially coupled into the fibre. To the best of our knowledge, this multiplexing technique is yet to be reported. Full article

Optical transmission gratings with quasi-sinusoidal surface-relief profiles were inscribed in IOG and Pyrex glasses and in Bi₁₂GeO₂₀, Er: LiNbO_3, and Er: Fe: LiNbO₃ crystals by microbeams of carbon, nitrogen, and oxygen ions at ion energies of 5, 6, and 10.5 MeV. Grating constants were 4, 8, and 16 μm. Amplitudes of the surface-relief gratings were in the 10–2000 nm range. The diffraction efficiency of the gratings was measured at a wavelength of 640 nm. Maximum diffraction efficiencies were close to the theoretical maximum of 33% for thin gratings. Grating profiles were measured by optical microscopic profilometry. Measurement of the diffraction efficiencies at higher orders and Fourier analysis of the grating profiles revealed the dependence of the residual nonlinearity of the grating profiles on the implanted ion fluence. The ion microbeam-written gratings can be used as light coupling elements in integrated optics for sensors and telecommunication. Full article

Transmission and reflection spectra of single-crystal germanium plates were experimentally measured in the terahertz spectral range. The optical parameters of germanium were determined at various Sb-doping levels. Saturation of the absorption index was detected with increasing wavelength in the range of 1000–3000 μm. The optical parameters of germanium correspond to the Drude-Lorentz model. Full article

Diffractive sail components may be used in part or whole for in-space propulsion and attitude control. A sun-facing hybrid diffractive solar sail having reflective front facets and transmissive side facets is described. This hybrid design seeks to minimize the undesirable scattering from side facets. Predictions of radiation pressure are compared for analytical geometrical optics and numerical finite difference time domain approaches. Our calculations across a spectral irradiance band from 0.5 to 3 μm suggest the transverse force in a sun facing configuration reaches 48% when the refractive index of the sail material is 1.5. Diffraction measurements at a representative optical wavelength of 633 nm support our predictions. Full article

Multi-wavelength random lasers with switchable modes have advantages in the fields of novel light source and information security. Here, we propose a dual-wavelength phase transition random laser, which can modulate lasing modes arbitrarily assisted by the phase transition hydrogel. Once the phase transition occurs in hydrogel, the scattering properties of light in the random system changes, affecting the optical feedback mechanism and enabling reversible switching of the dual-wavelength random laser mode between incoherent and coherent states. More appealing, random lasing mixed incoherent mode and coherent mode have been obtained for the first time by controlling the local phase transition of the sample. Based on these properties, an information encryption system is constructed by encoding spectral fingerprints at different modes. This work provides an effective way to precisely control the output modes at different wavelengths in the multi-wavelength random laser, further expanding the application of random lasers in multifunctional light sources, color imaging, and information safety. Full article

Augmented reality (AR) displays are pivotal for delivering immersive experiences in the metaverse, thus driving significant research interest. Current AR systems, predominantly relying on diffraction principles, often suffer from low efficiency and face challenges in realizing monolithic full-color operation. Herein, we propose an AR system that integrates a broadband and highly efficient meta-grating in-coupler and an elliptical meta-grating out-coupler onto a single thin glass substrate. The meta-gratings, with unique nanostructures, enable coupling efficiency exceeding 60% for red (R), green (G), and blue (B) wavelengths across the entire field of view (FOV). Image-bearing light is first coupled into a single-layer optical waveguide via the meta-grating, then undergoes two-dimensional expansion through the elliptical meta-grating, and is ultimately coupled into the human eye to form a large AR FOV. Experimentally, we fabricated an optical waveguide prototype and validated the system’s high efficiency and color-enhanced imaging capabilities. This work advances the development of monolithic, trichromatic, highly efficient, and large FOV AR displays based on meta-grating technology. Full article

The present study investigates the luminescent behaviour of sol–gel derived Y₂SiO₅ powders doped with Eu³⁺ ions, subjected to spark plasma sintering. The sintering process induces the partial reduction of Eu³⁺ to Eu²⁺, and the phenomenon is strongly dependent on the holding time within the SPS chamber. The luminescent properties are tunable via the initial Eu concentration, holding time and excitation wavelength, resulting in a wide range of emission colours from red (Eu³⁺) at 220 nm excitation to blue (Eu²⁺) at 365 nm, and mixed colours at 257 nm. Moreover, the Eu³⁺/Eu²⁺ redox process is reversible. Overall, the results demonstrate that SPS conditions can be exploited to modulate the valence state of luminescent centres, which is reversible by oxidation under ambient conditions, enabling controlled modulation of the optical properties. Full article

Diabetes has become a global health challenge, driving the demand for innovative, non-invasive diagnostic technologies to improve glucose monitoring. Urinary glucose concentration, a reliable indicator of metabolic changes, provides a practical alternative for frequent monitoring without the discomfort of invasive methods. In this simulation-based study, we propose a novel asymmetric photonic structure that integrates Tamm plasmon polariton (TPP) modes and a cavity mode for high-precision refractive index sensing, with a conceptual focus on the potential detection of urinary glucose. The structure supports three distinct resonance modes, each with unique field localization. Both the TPP modes, confined at the metallic–dielectric interfaces, serve as stable references whose wavelengths are unaffected by refractive-index variations in human urine, whereas the cavity mode exhibits a redshift with increasing refractive index, enabling high responsiveness to analyte changes. The evaluation of sensing performance employs a sensitivity formulation that leverages either TPP mode as a reference and the cavity mode as a probe, thereby achieving dependable measurement and spectral stability. The optimized design achieves a sensitivity of 693 nm·RIU⁻¹ and a maximum figure of merit of 935 RIU⁻¹, indicating high detection resolution and spectral sharpness. The device allows both reflectance and transmittance measurements to ensure enhanced versatility. Moreover, the coupling between TPP and cavity modes demonstrates hybrid resonance, empowering applications such as polarization-sensitive or angle-dependent filtering. The figure of merit is analyzed further, considering resonance wavelength shifts and spectral sharpness, thus manifesting the structure’s robustness. Although this study does not provide experimental data such as calibration curves, recovery rates, or specificity validation, the proposed structure offers a promising conceptual framework for refractive index-based biosensing in human urine. The findings position the structure as a versatile platform for advanced photonic systems, offering precision, tunability, and multifunctionality beyond the demonstrated optical sensing capabilities. Full article

This study investigates the magneto-optical properties of a ferrofluid using an accessible Ferrocell device. Our findings demonstrate that the ferrofluid’s behavior is critically dependent on its concentration. At high concentrations, the medium is optically dense, with inter-particle scattering and absorption dominating, which prevents the formation of clear light patterns. However, with intermediate dilution, the system enters a “pattern formation zone” where the magnetic field effectively aligns the nanoparticles, creating complex, visible light patterns like horocycles. The appearance of these patterns provides evidence of field-induced ordering and structural coloration. The colors observed are not due to pigments, but result from the interaction of light with the periodic structures formed by the aligned nanoparticles. Our analysis, supported by the Mueller matrix framework, confirms that the ferrofluid acts as a retarder. The birefringence induced by the magnetic field varies across the film, leading to a chromatic dispersion that selectively suppresses certain wavelengths. This process explains how a specific color, such as blue, can be blocked at one location while others pass through, creating structural colors observed in the patterns. Full article