Search Results (816)

The West Qinling Orogenic Belt (WQOB) contains a sedimentary succession that is approximately 15 km thick, spanning from the Carboniferous to the Jurassic period. This succession offers critical insights into the tectonic evolution of the Paleo-Tethys Ocean. While previous models have suggested various depositional environments, the late Paleozoic to Mesozoic tectonic evolution of the WQOB is still not fully understood. In this study, we incorporate new detrital zircon U-Pb age data and whole-rock geochemical analyses from six stratigraphic units, dating back to the Carboniferous to Triassic periods in the Xiahe–Hezuo region, alongside existing datasets. The detrital zircon age spectra from the WQOB reveal three distinct groups: Devonian–Carboniferous strata exhibit dominant Neoproterozoic (~800–900 Ma) zircon populations, whereas Permian–Triassic rock samples show prominent Paleoproterozoic (1840–1880 Ma) and Archean (2450–2500 Ma) peaks. A minor Neoproterozoic component in Permian spectra disappears by the Triassic, while Jurassic–Cretaceous assemblages lack Precambrian grains. These trends reflect evolving source terranes linked to Paleo-Tethyan subduction dynamics. Furthermore, the geochemical signatures of the Devonian–Triassic clastic rocks align with the composition of upper continental crust, indicating a tectonic relationship with continental island arcs and active continental margins. By synthesizing these findings with established detrital zircon ages, magmatic records, and geophysical data, we propose that the WQOB underwent pre-Triassic tectonic evolution that was marked by pre-Triassic subduction and localized extension during the process of continental underthrusting. Full article

Machine learning (ML) algorithms have promoted the development of predictive modeling of mineral prospectivity, enabling data-driven decision-making processes by integrating multi-source geological information, leading to efficient and accurate prediction of mineral exploration targets. However, it is challenging to conduct ML-based mineral prospectivity mapping (MPM) in under-explored areas where scarce data are available. In this study, the Narigongma district of the Qiangtang block in the Himalayan–Tibetan orogen was chosen as a case study. Five typical alterations related to porphyry mineralization in the study area, namely pyritization, sericitization, silicification, chloritization and propylitization, were extracted by remote sensing interpretation to enrich the data source for MPM. The extracted alteration evidences, combined with geological, geophysical and geochemical multi-source information, were employed to train the ML models. Four machine learning models, including artificial neural network (ANN), random forest (RF), support vector machine and logistic regression, were employed to map the Cu-polymetallic prospectivity in the study area. The predictive performances of the models were evaluated through confusion matrix-based indices and success-rate curves. The results show that the classification accuracy of the four models all exceed 85%, among which the ANN model achieves the highest accuracy of 96.43% and a leading Kappa value of 92.86%. In terms of predictive efficiency, the RF model outperforms the other models, which captures 75% of the mineralization sites within only 3.5% of the predicted area. A total of eight exploration targets were delineated upon a comprehensive assessment of all ML models, and these targets were further ranked based on the verification of high-resolution geochemical anomalies and evaluation of the transportation condition. The interpretability analyses emphasize the key roles of spatial proxies of porphyry intrusions and geochemical exploration in model prediction as well as significant influences everted by pyritization and chloritization, which accords well with the established knowledge about porphyry mineral systems in the study area. The findings of this study provide a robust ML-based framework for the exploration targeting in greenfield areas with good outcrops but low exploration extent, where fusion of a remote sensing technique and multi-source geo-information serve as an effective exploration strategy. Full article

To further investigate the collision process and tectonic regime transition between the North China (NCB) and South China Block (SCB), two magnetotelluric profiles were arranged across the Dabie Orogeny Belt (DOB) and eastern SCB. We then obtain the lithospheric resistivity models. The prominent feature revealed by our new model is an extensive conductive arc from the lower crust to the upper mantle, across the Jiangnan orogenic belt (JNOB) and the eastern Cathaysia Block (CAB). In addition, a huge resistor beneath the conductive arc is revealed, which is separated by a conductive wedge. Combining the heat flow and seismic tomographic imaging results, the conductors are to contain a large amount of hot material that present as the detachment layers (belts) controlled by the two subduction slabs. Considering multi-phase magmatism in the study area, new models suggest an intracontinental tectonic event in eastern CAB. Therefore, we propose a reliable tectonic process that occurred in the study area, including five stages: (1) an eastward intracontinental subduction and orogen carried out in CAB before the collision between SCB and NCB; (2) an extensional structural developed in CAB, following the subduction slab wrecking/sinking; (3) after the collision with NCB, the SCB crust/lithosphere thickened following the westward subduction of the Paleo-Pacific plate; (4) following the westward Yangtze slab sinking, the regional extension developed with the asthenosphere upwelling beneath SCB; (5) afterwards, the SCB was welded into one continent in a setting of westward compression. Full article

The provenance of the Middle-Upper Permian in the Lintan and Jiangligou areas, remnants of rift basin sedimentation within the West Qinling, remains controversial, hindering understanding of the basin-range coupling evolution of the Qinling Orogenic Belt and its periphery. Heavy minerals, major and trace elements, rare earth elements, detrital zircon U-Pb dating, and in situ Lu-Hf isotopes were analyzed to determine the provenance of the Middle-Upper Permian sandstones. Results were integrated with previous studies to investigate basin-range coupling processes. The results reveal the following: (1) The Upper Member of the Shilidun Formation in the Lintan area was deposited during the Late Permian. Heavy minerals are dominated by moderately to highly stable species. Source rocks were derived from intermediate-acidic magmatic rocks and low- to medium-grade metamorphic terrains. The provenance was primarily situated in a continental island arc tectonic setting. Diverse source rock types were identified, including materials from felsic igneous, quartzose recycled, and mafic igneous provenances. Detrital zircon U–Pb age spectra display two major peak ages at 285 Ma and 442 Ma, along with five subordinate peaks at 818 Ma, 970 Ma, 1734 Ma, 1956 Ma, and 2500 Ma. The ε_Hf(t) values range from –44.95 to 42.67, and T_DM2 ages vary from 367 Ma to 4106 Ma. It is concluded that the sedimentary materials were mainly derived from the North Qinling Orogenic Belt, with minor contributions from the basement of the North China Craton. (2) In the Jiangligou area, the Shiguan Formation is characterized by highly and stable heavy minerals. The provenance is dominated by intermediate-acidic magmatic rocks, within an oceanic island arc tectonic setting. Detrital zircon U–Pb age spectrum displays a prominent peak at 442 Ma. The ε_Hf(t) values range from –0.5 to 10.55, with T_DM2 ages ranging from 744 Ma to 897 Ma. These results indicate that the sedimentary materials were derived from the North Qilian Orogenic Belt. (3) The Permian in the Western Qinling exhibit multi-provenance supply, dominated by the North Qinling Orogenic Belt and the North China Craton basement, with local contributions from the North Qilian Orogenic Belt. Significant regional variations in provenance contributions were identified. This study further constrains the closure of the Shangdan Ocean to pre-Late Permian. It reveals that the Western Qinling was situated in a back-arc rift basin setting during the Late Paleozoic. Key sedimentary evidence is provided for understanding the tectonic evolution of the Paleo-Tethys Ocean and the collision between the North China and Yangtze cratons. Full article

Strategic lithium resources are critical to national security and have attained heightened importance in contemporary geopolitical, economic, and military contexts. Persistent geochemical anomalies of lithium were first identified in coal-bearing claystones of the Middle Jurassic Xishanyao Formation at the Liuhuanggou Coal Mine in the southern Junggar Basin, Xinjiang. In this study, a suite of analytical techniques, including X-ray fluorescence spectrometry, inductively coupled plasma mass spectrometry, X-ray diffraction, scanning electron microscopy-energy dispersive spectroscopy, time-of-flight secondary ion mass spectrometry, and sequential chemical extraction, was employed to investigate the provenance, depositional environment, and modes of lithium occurrence in the claystone. Results indicated that the claystone at the Liuhuanggou Coal Mine was dominated by moderately felsic rocks. The notable enrichment of lithium in the Liuhuanggou coal mine claystone indicates favorable metallogenic potential. Lithium was primarily hosted in the aluminosilicate-bound fraction with inorganic affinity and was structurally incorporated within clay minerals, such as kaolinite, illite, and Fe-rich chlorite (chamosite). Lithium-rich claystone was deposited under intense chemical weathering conditions in a transitional, slightly brackish environment characterized by elevated temperatures and low oxygen levels. These findings advance our understanding of sedimentary lithium mineralization mechanisms and offer direct practical guidance for lithium resource exploration and metallogenic prediction in the Xinjiang region, thereby supporting the development of efficient extraction technologies. Full article

Tight sandstone reservoirs generally exhibit poor physical properties and characterization of microscopic pore structure is crucial for evaluating reservoir quality and fluid flow behavior. Fractal dimension provides an effective means to quantify the complexity and heterogeneity of pore structures in such reservoirs. This study investigates tight sandstone reservoirs of the Kongdian Formation in the Nanpi Slope, Cangdong Sag, using cast thin sections, scanning electron microscopy (SEM), high-pressure mercury injection (HPMI), and constant-rate mercury injection (CRMI) experiments. We establish a full-range fractal model to characterize pore-throat distributions and elucidate the correlation between fractal dimensions and reservoir properties, alongside factors influencing pore-structure heterogeneity. Key findings include that (1) pore types are predominantly residual intergranular pores, intergranular dissolution pores, and clay mineral intercrystalline pores, with throats primarily consisting of sheet-like and curved sheet-like types, exhibiting strong pore-structure heterogeneity; (2) full-range fractal dimensions D₁, D₂ and D₄ effectively characterize the heterogeneity of pore structure, where higher D₁ and D₂ values correlate with increased macro–mega pore and micro-fine throat abundance, respectively, indicating enhanced pore connectivity and superior flow capacity, while elevated D₄ reflects greater nano throat complexity, degrading reservoir properties and impeding hydrocarbon flow; (3) compared to conventional methods splicing HPMI and CRMI data at 0.12 μm, the fractal-derived integration point more accurately resolves full-range pore-throat distributions, revealing significant disparities in pore-throat size populations; (4) the fractal dimensions D₁, D₂, and D₄ are collectively governed by clay mineral content, average throat radius, displacement pressure, and tortuosity. Full article

The Xifanping Cu–(Au) deposit, a small-scale porphyry system in the central Jinshajiang–Red River tectonic belt (JSRR), formed in a Cenozoic collisional setting. This study integrates zircon U–Pb geochronology, Lu–Hf isotopes, whole-rock geochemistry, and zircon trace element analyses of ore-bearing and barren porphyries, combined with regional comparisons, to constrain magma sources, metallogenic controls, and genetic processes. Ore-bearing biotite quartz monzonite porphyries were emplaced at 32.15 ± 0.43 Ma and 32.49 ± 0.57 Ma, post-dating barren quartz monzonite porphyry (33.15 ± 0.51 Ma). These ages are consistent with molybdenite Re–Os ages (32.1 ± 1.6 Ma), indicating near-synchronous magmatism and mineralization. Both porphyry types belong to the shoshonitic, peraluminous series, enriched in LILE, depleted in HFSE, enriched in LREE, and lacking significant Eu anomalies. Their εHf (t) values (–2.94 to +3.68) and crustal model ages (TDM2 = 0.88–1.30 Ga) indicate derivation from Neoproterozoic subduction-modified lower crust. Ore-bearing porphyries, however, exhibit higher zircon Ce⁴⁺/Ce³⁺ ratios (average = 584 vs. 228 for barren porphyries) and elevated hydrous mineral contents (>10 vol.% amphibole + biotite), indicating more oxidized and water-rich parental magmas. Compared with large-scale porphyry systems (e.g., Dexing, northern Chile), the absence of adakitic signatures and only moderate oxidation limited the scale of mineralization. Overall, the Xifanping deposit formed through partial melting of Neoproterozoic subduction-modified lower crust in a post-collisional extensional regime: at ~33.2 Ma, melting of metasomatized ancient lower crust generated barren porphyries; at ~32 Ma, further evolution and differentiation of this lower crust magmas led to the extraction and enrichment of ore-forming materials from the thicken lower crust, producing hydrated, oxidized, ore-bearing magmas that intruded at shallow levels to form base and precious metal mineralizations. These results underscore the distinctive metallogenic characteristics of small-scale porphyry systems in collisional settings and provide new insights into how source composition and magma oxidation state constrain mineralization potential. Full article

The transformation of smectite to illite documents multi-scale water–rock–hydrocarbon interaction dynamics. Current studies predominantly emphasize the influence of inorganic systems on this process, while overlooking the dynamic regulation by organic matter and the synergistic effects of multiple controlling factors under actual geological conditions. In this study, we conducted integrated semi-open pyrolysis experiments on natural samples from the Chang-7 Member and hydrothermal experiments using synthetic analogs. The illitization process of smectite was characterized through XRD analysis and SEM observations, while organic geochemical testing was employed to track the corresponding thermal evolution of organic matter. The semi-open pyrolysis results reveal that significant changes in illite–smectite (I/S) mixed layer minerals and illite content/morphology occur above 320 °C, which coincides with the critical threshold for extensive organic matter evolution. Thermal degradation of organic matter generates pore space, thereby enhancing water–rock interactions involving clay minerals. This demonstrates the co-evolution of organic matter and smectite, and indicates that temperature indirectly influences illitization by regulating organic matter thermal evolution. The hydrothermal simulation experiments demonstrate the early-stage characteristics of illitization. Unlike long-term geological evolution, K⁺ under experimental conditions primarily originates from the aqueous medium due to kinetic constraints on feldspar dissolution. Notably, organic matter regulates K⁺ partitioning dynamics—increased organic matter content hinders K⁺ incorporation into smectite interlayers, thereby suppressing the illitization process. Cross-system experimental analysis reveals that organic matter exhibits temporally dependent dual functionality, serving both mediating and modulating roles within inorganic diagenetic systems. This study delineates diagnostic-stage-dependent mechanisms governing smectite illitization through multifactorial synergistic interplay, establishing a predictive framework applicable to organic-rich systems exemplified by the Chang-7 Shale. Full article

We present the chemical composition and the U-Pb chemical age of the recently discovered uranium mineralisation occurrence in the crystalline Shkhara Massif in the Greater Caucasus. The mineralisation consists of hydrothermal uraninites from veins that intersect into the Late Variscan biotite–plagioclase-rich granite and migmatites. The chemical composition and the Th–U total Pb chemical age of the uraninites were determined. Results show thorium-rich, (∑LREE/∑HREE)_N unfractionated uraninites that had been formed under higher temperatures above 450 ± 50 °C. Fifty-eight measurements on 14 grains revealed homogeneous and unaltered uraninites. Th–U–total Pb ages of the uraninite were calculated from 55 chemical analyses, among which 37 plot between 275 and 305 Ma. The weighted median age of the 55 data points corresponds to 291 ± 14 Ma: the boundary between the Carboniferous and Permian periods. These dates suggest that uraninite mineralisation is related to the late orogenic extensional process of the Great Caucasus structure. During this process, hydrothermal fluids permeated the biotite-+ and plagioclase-rich magmatic rocks of the Main Range zone and formed U- and Th-rich veins and uraninite mineralisation. This study shows that the Shkhara uranium occurrence correlates with most of the late Variscan uranium deposits in Central and Western Europe in terms of geodynamic setting, composition, age and type of mineralisation. Full article

The evolution of ore-forming fluids in gold precipitation is a key aspect in understanding the genesis of orogenic gold deposits. Traditional fluid inclusion analyses are often limited in revealing the fluid property changes during mineralization, leading to significant debates on the mineralization temperature and fluid sources. In this study, we selected the Liba gold deposit in the West Qinling orogen and employed scanning electron microscope–cathodoluminescence (SEM-CL) and laser ablation–inductively coupled plasma mass spectrometry (LA-ICPMS) to analyze the microstructure and trace element characteristics of quartz veins, revealing the multi-stage evolution of ore-forming fluids and the mineralization mechanisms. SEM-CL imaging identified five distinct quartz stages. The pre-mineralization (Qz0) and early-stage mineralization (Qz1) fluids were predominantly magmatic–metamorphic in origin, as indicated by relatively high δ¹⁸O and δD values. During the primary metallogenic (Qz2a, Qz2b) and late-stage mineralization (Qz3), temperatures progressively decreased, and the gradual mixing of meteoric water and formation water was observed, which promoted gold precipitation. And the content of trace elements in post-mineralization quartz (Qz4) is significantly lower and similar to that in the Qz0 stage. Through the analysis of quartz trace elements (e.g., Al/Ti, Ge/Al ratios) and isotope data (δ18O = 8.25‰ to 12.67‰, δD = −119.1‰ to −79.8‰), the results indicate that the Liba gold deposit is a medium- to low-temperature orogenic gold deposit. Furthermore, the gold enrichment process was primarily driven by a hydrothermal system, with variations in the fluid composition during mineralization contributing to the concentration of gold. Full article

The Gutaishan Au–Sb deposit is situated in the southern segment of the Jiangnan Orogenic Belt, a region characterized by a concentration of Au–Sb–W deposits. Previous research has predominantly concentrated on Au mineralization, whereas studies addressing the equally important Sb mineralization are relatively scarce. To investigate key scientific questions regarding the source of ore-forming materials, the physicochemical conditions, and mineralization mechanisms of Sb in the Gutaishan deposit, we conducted systematic analyses of trace elements in hydrothermal quartz and sulfur isotopes in stibnite. Li, Al, Sb, B, Na, K, Ti, Ge, and As are the dominant trace elements in hydrothermal quartz from the Gutaishan deposit. The dominant substitution mechanism is (Al³⁺, Sb³⁺) + (Li⁺, Na⁺, K⁺, H⁺) ↔ Si⁴⁺. The relatively low but variable Al concentrations indicate that quartz precipitated from fluids with fluctuating pH and weakly acidic conditions, while variations in Ti and Ge reflect significant temperature changes. These features suggest that fluid mixing was the primary mineralization mechanism in the Gutaishan deposit. Hydrothermal quartz contains anomalously high B concentrations (14.36–30.64 ppm), far exceeding typical hydrothermal levels, while stibnite displays consistent magmatic sulfur isotope signatures (−3.50‰ to −4.2‰, with an average of −3.99 ± 0.2‰), which are markedly different from the in situ δ³⁴S values of sedimentary sulfides (+7.0‰ to +23.3‰) in the host rocks. This combination of evidence indicates a magmatic–hydrothermal origin for Sb mineralization. Integrating previous geochronological and isotopic constraints with our new observations, we interpret that the Gutaishan deposit represents an intrusion-related Au–Sb deposit formed in a post-collisional extensional setting, where Sb was precipitated after Au mineralization as a result of fluid mixing. Full article

As critical components in continental shale systems, the composition and evolution of clay minerals are fundamental to their diagenetic processes and petrophysical properties. The Chang-7 shales in the Ordos Basin exhibit abundant clay mineral content, offering a valuable case study for clay mineral research under moderate diagenetic conditions. This study employed XRD analysis to determine the whole-rock mineralogy, clay mineral composition, and the evolution characteristics of illite-smectite mixed-layer minerals (I/S). Comprehensive clay mineral datasets compiled from 13 newly analyzed wells and existing literature revealed distinct lateral distribution patterns. Total Organic Carbon (TOC) analysis and vitrinite reflectance (R_o) measurements provided systematic quantification of organic matter abundance and thermal maturation parameters in the studied samples. The results reveal that the Chang-7 shale exhibits a characteristic clay mineral assemblage, with I/S (average 44.2%) predominating over illite (34.7%), followed by chlorite (15.6%) and limited kaolinite (5.4%). Frequent volcanic activities provided substantial precursor materials for smectite formation, which actively participated in subsequent illitization processes, while chlorite and kaolinite distributions were predominantly controlled by provenance inputs and sedimentary facies, respectively. Inconsistencies exist between diagenetic stages inferred from I/S mixed-layer ratios and R_o values, particularly in low-maturity samples exhibiting accelerated illitization. The observed negative correlation between TOC content and mixed-layer ratios in Well YY1 and YSC Section samples demonstrates the catalytic role of organic matter in facilitating smectite-to-illite transformation. These results systematically clarify the coupled effects of sedimentary-diagenetic processes, offering new insights into the mutual interactions between inorganic and organic phases during illitization under natural geological conditions. The findings advance the understanding of Chang-7 shale oil and gas systems and offer practical guidance for future exploration. Full article

The Variscan and Mesozoic basement are covered by Neogene and Quaternary sediments belonging to the Guadalquivir foreland Basin (southern Spain). This study explores the subsurface of the northern margin of its westernmost sector using the HVSR method, recording seismic noise at 334 stations between the mouths of the Guadiana and the Guadalquivir rivers, near Doñana National Park. Fundamental frequency and basement measurements enabled the estimation of an empirical formula for basement depth: h = 80.16·f₀^−1.48. Five distinct HVSR responses were obtained: (a) low-frequency peaks, indicating deep substratum; (b) high-frequency peaks, shallow bedrock; (c) broad peaks, potential critical zones (3D-2D effects, suggesting faults); (d) double peaks (marshlands); and (e) no peaks, near-outcropping bedrock. The soil fundamental frequencies range from 0.23 to 18 Hz, with bedrock depth ranges from 1 to 5 m in the northwest to over 600 m in the southeast. Borehole data correlate strongly with HVSR-derived results, with typical discrepancies of only a few tens of meters, likely due to the presence of non-geological basement acting as a mechanical basement. Although the possibility of ancient fluvial terraces of the Guadalquivir River contributing to abrupt slope changes is considered, H/V spectra with broad peaks suggest tectonic origins. This study presents the first regional three-dimensional model of the basin basement over an area exceeding 2300 km², revealing a horst-and-graben system formed by foreland deformation linked to the westward advance of the Rif-Betic orogenic front. Full article

The integration of petrological and geochemical analyses serves as an effective methodology for reconstructing depositional environments and constraining sediment provenance within distinct tectonic frameworks. This study investigates the provenance characteristics of the Silurian Kepingtag Formation in the northwestern Tarim Basin through an integrated approach combining field outcrop observations and laboratory analyses. Fieldwork covers the Sishichang, Dawangou, and Tongguzibulong sections, while laboratory analyses include clastic component identification, whole-rock major and trace element geochemical analysis, and rare earth element (REE) profiling. These efforts enable a systematic evaluation of sediment sources and their tectonic linkages. The research provides a theoretical basis for understanding the tectono-sedimentary framework of the northwestern Tarim Basin during the Early Silurian and offers significant guidance for reconstructing the lithofacies paleogeographic pattern of the basin during this period. Petrographic analyses reveal a lithological assemblage dominated by lithic quartz sandstones and lithic sandstones, with subordinate feldspathic lithic sandstones. Quartz exhibits secondary overgrowths. In a relatively stable tectonic environment, sediments undergo a gentle burial rate, which favors the formation of this phenomenon. Lithic fragments are dominated by magmatic lithics, indicating that the source contains magmatic rocks. Detrital component analysis reveals that the provenance of Kepingtag Formation sandstones in the study area is predominantly characterized by stable craton and recycled orogenic belt tectonic settings. Integrated geochemical datasets from major element compositions and trace element signatures constrain the provenance characteristics of the Kepingtag Formation sandstones. Major element ratios demonstrate predominant contributions from felsic igneous source rocks, while trace element ratios are diagnostic of sediment derivation from passive continental margin settings, consistent with prolonged tectonic quiescence along the northern Tarim cratonic margin during Silurian deposition The CIA index indicates that the Silurian Kepingtag Formation in the study area exhibits weak to moderate weathering. Integrating the above analyses, the Tabei Uplift—ancient craton setting—is interpreted as the likely provenance source for the sandstones of the Kepingtag Formation in the northwestern Tarim Basin. Full article

This study presents a novel methodology for mapping Fault- and Thrust-based Structural Lineaments (FT-SL) in the rugged and inaccessible Oued-Laou watershed of the Rif Belt, Morocco. Combining optical (Landsat-8 OLI, Sentinel-2 MSI) and radar (Sentinel-1 SAR) remote sensing data, the research employs manual, semi-automatic, and automatic extraction methods enhanced by spatial filtering (Sobel, Laplacian, Kuan). A Knowledge-Based System (KBS) integrated with Multi-Criteria Decision Analysis (MCDA) evaluates the effectiveness of these methods, focusing on lineament statistics, orientation, density distribution, and correlation with existing geological maps. The results highlight Sentinel-1 SAR’s superior performance in detecting subsurface structures, while manual extraction yields the highest accuracy. This study also demonstrates the potential for generalizing this approach to other Alpine orogenic regions, such as the Alps, due to shared geological characteristics. The findings provide a robust framework for structural lineament mapping in mountainous terrains, addressing challenges of accessibility and data scarcity. Full article