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Search Results (169)

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Keywords = principles of water governance

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14 pages, 1709 KB  
Article
An Empirical–Analytical Model of Mine Water Level Rebound
by Dmytro Rudakov, Somayeh Sharifi and Sebastian Westermann
Mining 2025, 5(4), 59; https://doi.org/10.3390/mining5040059 - 23 Sep 2025
Viewed by 115
Abstract
This paper aims to develop a robust empirical–analytical model using the statistics of mine water level rebound in abandoned mines and the basic physical principles of underground hydraulics. The data collected and treated included the time series of the mine water level for [...] Read more.
This paper aims to develop a robust empirical–analytical model using the statistics of mine water level rebound in abandoned mines and the basic physical principles of underground hydraulics. The data collected and treated included the time series of the mine water level for 35 closed and flooded mines from four European countries. Within the developed model, mine water level evolution is governed by an ordinary differential equation with one fitting parameter that depends on the floodable cavity volume in a mine and water inflow before flooding begins. The model assumes that rock properties and residual void distribution are homogeneous, and the mines being flooded are almost isolated hydraulically from the neighboring ones. The exponential formula, as the governing equation solution, was found to be the most suitable for fitting the measurements. The calculated exponential curves allow for excellent or very good fitting of the measured water levels for 17 of 35 mines, and acceptable fitting for 11 mines in terms of minimizing mean-square-root deviation. The proposed approach can be applied to preliminary assessments of mine water level rebound in developing and calibrating sophisticated numerical flow models. Full article
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15 pages, 3772 KB  
Article
Coupled Vibration Response Analysis of Tension Leg Platform Tendon Under Irregular Ocean Wave Action
by Qiangqiang Wu, Yinguang Du, Xiaofeng Luo, Tao Sun and Heng Lin
J. Mar. Sci. Eng. 2025, 13(10), 1836; https://doi.org/10.3390/jmse13101836 - 23 Sep 2025
Viewed by 118
Abstract
To analyze the dynamic response of tension leg platform (TLP) tendons under irregular ocean wave action, the governing equations of coupled vibration between the platform and tendon under irregular wave action are established based on Hamilton’s principle and the Kirchhoff hypothesis. Using the [...] Read more.
To analyze the dynamic response of tension leg platform (TLP) tendons under irregular ocean wave action, the governing equations of coupled vibration between the platform and tendon under irregular wave action are established based on Hamilton’s principle and the Kirchhoff hypothesis. Using the spectrum representation–random function method, the power spectral density function of the irregular wave load is derived, and the lateral wave forces at different tendon locations are calculated. The coupled lateral and axial responses of the tendon system are obtained through the fourth-order Runge–Kutta method. Considering the parametric vibrations of both the platform and tendon, the extreme lateral deflection of the tendon is employed as the control index to derive the probability density curves of the tendon deflection under irregular wave load. The results show that the amplitude of the wave load increases gradually along the height of the tendon, with a faster growth rate at locations closer to the water surface. The tendon’s lateral deflection response changes more drastically due to coupled parametric vibration of the platform. Based on 628 complete samples of irregular wave loads, the probability density curve and cumulative distribution curve of the extreme lateral deflection of the tendon under irregular wave loads are obtained. Under typical sea state conditions generated from the P-M wave spectrum, the reliability of the tendon under irregular wave load increases with the initial tension force. Full article
(This article belongs to the Special Issue Advanced Studies in Marine Structures)
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29 pages, 9522 KB  
Article
Spatial Heterogeneity and Temporal Variation of Water Levels in Dongting Lake
by Shuai Yuan, Changbo Jiang, Yuan Ma and Shanshan Li
Sustainability 2025, 17(17), 8080; https://doi.org/10.3390/su17178080 - 8 Sep 2025
Viewed by 662
Abstract
To quantify the spatiotemporal patterns of the water-level variations in the study area, we conducted cluster analysis of the temporally varying measurements across multiple hydrological stations. The temporal trends and change points were analyzed, followed by IHA-RVA quantification of the water-level alterations before [...] Read more.
To quantify the spatiotemporal patterns of the water-level variations in the study area, we conducted cluster analysis of the temporally varying measurements across multiple hydrological stations. The temporal trends and change points were analyzed, followed by IHA-RVA quantification of the water-level alterations before and after change points. Cluster analysis demonstrated the following. (1) Hydrological stations segregate into two distinct groups at the Euclidean distance threshold d = 5, and into three clusters at d = 4, confirming the pronounced west–east heterogeneity in the lake. (2) The hydrological alteration degrees exhibit considerable variation across the lake’s sub-lakes (Qili, Muping, South Dongting, East Dongting), with marked heterogeneity persisting even among representative monitoring stations within individual sub-lakes. The water-level regimes in Qili Lake can be partitioned into two distinct periods, before and after the change point, exhibiting the highest hydrological alteration degree across the lake. Representative stations of the other sub-lakes fall into three periods. During the first phase of hydrological alteration, Zhouwenmiao, Jinshi, and Chenglingji exhibit moderate alteration. Throughout the second alteration phase, all the representative stations consistently exhibit moderate alteration, although significant heterogeneity emerges across hydrological indicators among the sub-lakes. (3) Downstream of Yangliutan station, the longitudinal profile exhibits terraced morphology, segmented into three distinct levels by two hydraulic knickpoints. This geomorphic configuration primarily controls both the localized stage reductions and the maintenance of elevated upstream water levels during dry seasons. Confronting the persistent dry-season stage declines at Yingtian Station, enhanced monitoring and conservation of terraced transition zones in South Dongting Lake must be prioritized, with implementation of the zoned control principle for water-level governance and lake management. This study establishes a scientific foundation for the protection and governance of Dongting Lake, thereby advancing sustainable utilization of its water resources. Full article
(This article belongs to the Section Sustainable Water Management)
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20 pages, 561 KB  
Review
Towards Zero-Waste Cities: An Integrated and Circular Approach to Sustainable Solid Waste Management
by Abdelhadi Makan, Youssef Salama, Fatima Zahrae Mamouni and Mustapha Makan
Sustainability 2025, 17(17), 7884; https://doi.org/10.3390/su17177884 - 2 Sep 2025
Viewed by 1381
Abstract
The exponential increase in global solid waste generation poses significant environmental, economic, and social challenges, particularly in rapidly urbanizing regions. Traditional waste management methods that focus on handling and disposal have proven unsustainable because of their negative impacts on air, soil, and water [...] Read more.
The exponential increase in global solid waste generation poses significant environmental, economic, and social challenges, particularly in rapidly urbanizing regions. Traditional waste management methods that focus on handling and disposal have proven unsustainable because of their negative impacts on air, soil, and water quality, and their contribution to greenhouse gas emissions. In response, the concept of zero-waste cities, rooted in circular economy principles, has gained increasing attention in recent years. This study proposes a comprehensive and integrated waste management system designed to optimize resource recovery across four distinct waste streams: household, healthcare, green/organic, and inert. The system integrates four specialized facilities: a Secondary Sorting Facility, Energy Recovery Facility, Composting Facility, and Inert Processing Facility, coordinated through a central Primary Sorting Hub. By enabling interconnectivity between these processing units, the system facilitates material cascading, maximizes the reuse and recycling of secondary raw materials, and supports energy recovery and circular nutrient flow. The anticipated benefits include enhanced operational efficiency, reduced environmental degradation, and generation of multiple revenue streams. However, the implementation of such a system faces challenges related to high capital investment, technological complexity, regulatory fragmentation, and low public acceptance. Overcoming these limitations will require strategic planning, stakeholder engagement, and adaptive governance. Full article
(This article belongs to the Special Issue Emerging Trends in Waste Management and Sustainable Practices)
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19 pages, 1561 KB  
Review
Inequalities in Drinking Water Access in Piura (Peru): Territorial Diagnosis and Governance Challenges
by Eduardo Alonso Sánchez Ruiz, Lázaro V. Cremades and Stephanie Villanueva Benites
Sustainability 2025, 17(16), 7542; https://doi.org/10.3390/su17167542 - 21 Aug 2025
Viewed by 1186
Abstract
Latin American countries continue to face critical challenges in ensuring safe and continuous access to drinking water, particularly in rural and peri-urban areas. This article presents a territorial and institutional diagnosis of drinking water access in the Piura region (Peru). It is a [...] Read more.
Latin American countries continue to face critical challenges in ensuring safe and continuous access to drinking water, particularly in rural and peri-urban areas. This article presents a territorial and institutional diagnosis of drinking water access in the Piura region (Peru). It is a coastal region with approximately 2 million inhabitants, characterized by environmental stress, governance fragmentation, and social inequality. The study adopts a structural documentary approach based on academic literature and validated institutional data to analyze spatial disparities in water coverage, continuity, and quality. It identifies structural and institutional barriers—such as overlapping mandates, limited local capacity, and the absence of monitoring systems—to universal access. The findings also highlight the limitations of isolated innovation efforts, such as pilot projects led by universities and private companies, which often lack mechanisms for institutional integration and policy scaling. The analysis is framed within international water governance frameworks, including the OECD Principles and the Integrated Water Resources Management paradigm, and aligns with Sustainable Development Goal 6. The study offers a multi-scalar perspective grounded in local realities and identifies governance research gaps in rural Peru. Results underscore the need for territorialized planning, strengthened coordination, and inclusive governance to achieve sustainable and equitable water access in fragile contexts. Full article
(This article belongs to the Section Sustainable Water Management)
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20 pages, 2993 KB  
Article
ABAQUS Subroutine-Based Implementation of a Fractional Consolidation Model for Saturated Soft Soils
by Tao Zeng, Tao Feng and Yansong Wang
Fractal Fract. 2025, 9(8), 542; https://doi.org/10.3390/fractalfract9080542 - 17 Aug 2025
Viewed by 508
Abstract
This paper presents a finite element implementation of a fractional rheological consolidation model in ABQUS, in which the fractional Merchant model governs the mechanical behavior of the soil skeleton, and the water flow is controlled by the fractional Darcy’s law. The implementation generally [...] Read more.
This paper presents a finite element implementation of a fractional rheological consolidation model in ABQUS, in which the fractional Merchant model governs the mechanical behavior of the soil skeleton, and the water flow is controlled by the fractional Darcy’s law. The implementation generally involves two main parts: subroutine-based fractional constitutive models’ development and their coupling. Considering the formal similarity between the energy equation and the mass equation, the fractional Darcy’s law was implemented using the UMATHT subroutine. The fractional Merchant model was then realized through the UMAT subroutine. Both subroutines were individually verified and then successfully coupled. The coupling was achieved by modifying the stress update scheme based on Biot’s poroelastic theory and the effective stress principle in UMAT, enabling a finite element analysis of the fractional consolidation model. Finally, the model was applied to simulate the consolidation behavior of a multi-layered foundation. The proposed approach may serve as a reference for the finite element implementation of consolidation models incorporating a fractional seepage model in ABAQUS. Full article
(This article belongs to the Special Issue Fractional Derivatives in Mathematical Modeling and Applications)
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14 pages, 262 KB  
Article
Comparative Study of ESG Practices Among Brazilian Sanitation Companies
by Estefânia Hetman de Almeida Caciato, Cândido Ferreira da Silva Filho, Samuel Carvalho De Benedicto, Vinícius Eduardo Ferrari, Duarcides Ferreira Mariosa, Diego de Melo Conti, Bruna Angela Branchi and Rubén Danilo Bourdon García
Sustainability 2025, 17(16), 7312; https://doi.org/10.3390/su17167312 - 13 Aug 2025
Viewed by 721
Abstract
Brazilian sanitation companies disclose their sustainable practices through sustainability reports as part of their commitment to Sustainable Development Goal (SDG) 6 of the 2030 Agenda, which aims to ensure universal access to water and sanitation. This study proposes a methodology to evaluate how [...] Read more.
Brazilian sanitation companies disclose their sustainable practices through sustainability reports as part of their commitment to Sustainable Development Goal (SDG) 6 of the 2030 Agenda, which aims to ensure universal access to water and sanitation. This study proposes a methodology to evaluate how these companies integrate Environmental, Social, and Governance (ESG) principles into their management and disclosure practices, rather than assessing service delivery or operational outputs directly. These indicators were applied to the sustainability reports of Brazil’s three largest sanitation companies: Sabesp (Companhia de Saneamento Básico do Estado de São Paulo), Copasa (Companhia de Saneamento de Minas Gerais), and Sanepar (Companhia de Saneamento do Paraná). The results indicate that all three companies have incorporated sustainability into their competitive strategies and corporate governance practices. Sabesp demonstrated a stronger adherence in the environmental and governance dimensions, Copasa excelled in social performance while also performing well in governance, and Sanepar exhibited the lowest adherence among the three. Hence, we present a methodological framework for monitoring corporate ESG performance and governance practices aligned with SDG 6, focusing on their management and disclosure practices, rather than directly assessing service delivery or operational results. Full article
37 pages, 4602 KB  
Review
Solar-Driven Atmospheric Water Harvesting Technologies Using Adsorption: Principles, Materials, Performance, and System Configurations
by Malek Mannai, Valeria Palomba, Andrea Frazzica and Elpida Piperopoulos
Energies 2025, 18(16), 4250; https://doi.org/10.3390/en18164250 - 9 Aug 2025
Viewed by 1083
Abstract
The global scarcity of freshwater, driven by population growth and the unequal distribution of water resources, has intensified the need for alternative water supply technologies. Among the most promising solutions, adsorption-based atmospheric water harvesting (AWH) systems offer the ability to extract water vapor [...] Read more.
The global scarcity of freshwater, driven by population growth and the unequal distribution of water resources, has intensified the need for alternative water supply technologies. Among the most promising solutions, adsorption-based atmospheric water harvesting (AWH) systems offer the ability to extract water vapor directly from ambient air, even under low-humidity conditions. This review presents a comprehensive overview of the thermodynamic principles and material characteristics governing these systems, with particular emphasis on adsorption isotherms and their role in predicting and optimizing system performance. A generalized theoretical framework is proposed to assess the energy efficiency of thermally driven AWH devices, based on key material parameters. Recent developments in sorbent materials, especially metal–organic frameworks (MOFs) and advanced zeolites, are examined for their high-water uptake, regeneration efficiency, and potential for operation under real climatic conditions. The Dubinin–Astakhov and modified Langmuir isotherm models are reviewed for their effectiveness in describing nonlinear sorption behaviors critical to performance modeling. In addition, component-level design strategies for adsorption-based AWH systems are discussed. The integration of solar energy is also discussed, highlighting recent prototypes and design strategies that have achieved water yields ranging from 0.1 to 2.5 L m−2/day and specific productivities up to 2.8 L kg−1 using MOF-801 at 20% RH. Despite notable progress, challenges remain, including limited productivity in non-optimized setups, thermal losses, long-term material stability, and scalability. This review concludes by identifying future directions for material development, system integration, and modeling approaches to advance the practical deployment of efficient and scalable AWH technologies. Full article
(This article belongs to the Section B: Energy and Environment)
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20 pages, 1090 KB  
Article
Reforming Water Governance: Nordic Lessons for Southern Europe
by Eleonora Santos
Sustainability 2025, 17(15), 7079; https://doi.org/10.3390/su17157079 - 5 Aug 2025
Cited by 1 | Viewed by 598
Abstract
Water governance in Europe faces mounting challenges from climate change, demographic pressures, and aging infrastructure—especially in Southern regions increasingly affected by drought and institutional fragmentation. In contrast, Nordic countries such as Denmark and Sweden exhibit coherent, integrated governance systems with strong regulatory oversight. [...] Read more.
Water governance in Europe faces mounting challenges from climate change, demographic pressures, and aging infrastructure—especially in Southern regions increasingly affected by drought and institutional fragmentation. In contrast, Nordic countries such as Denmark and Sweden exhibit coherent, integrated governance systems with strong regulatory oversight. This study introduces the Water Governance Maturity Index (WGMI), a document-based assessment tool designed to evaluate national water governance across five dimensions: institutional capacity, operational effectiveness, environmental ambition, equity, and climate adaptation. Applying the WGMI to eight EU countries—four Nordic and four Southern—reveals a persistent North–South divide in governance maturity. Nordic countries consistently score in the “advanced” or “model” range, while Southern countries face systemic gaps in implementation, climate integration, and territorial inclusion. Based on these findings, the study offers actionable policy recommendations, including the establishment of independent regulators, strengthening of river basin coordination, mainstreaming of climate-water strategies, and expansion of affordability and participation mechanisms. By translating complex governance principles into measurable indicators, the WGMI provides a practical tool for benchmarking reform progress and supporting the EU’s broader agenda for just resilience and climate adaptation. Unlike broader frameworks like SDG 6.5.1, the WGMI’s document-based, dimension-specific approach provides granular, actionable insights for governance reform, enhancing its utility for EU and global policymakers. Full article
(This article belongs to the Special Issue Sustainability in Urban Water Resource Management)
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27 pages, 2565 KB  
Review
The Role of ESG in Driving Sustainable Innovation in Water Sector: From Gaps to Governance
by Gabriel Minea, Elena Simina Lakatos, Roxana Maria Druta, Alina Moldovan, Lucian Marius Lupu and Lucian Ionel Cioca
Water 2025, 17(15), 2259; https://doi.org/10.3390/w17152259 - 29 Jul 2025
Cited by 1 | Viewed by 1278
Abstract
The water sector is facing a convergence of systemic challenges generated by climate change, increasing demand, and increasingly stringent regulations, which threaten its operational and strategic sustainability. In this context, the article examines how ESG (environmental, social, governance) principles are integrated into the [...] Read more.
The water sector is facing a convergence of systemic challenges generated by climate change, increasing demand, and increasingly stringent regulations, which threaten its operational and strategic sustainability. In this context, the article examines how ESG (environmental, social, governance) principles are integrated into the governance, financing, and management of water resources, with a comparative focus on Romania and the European Union. It aims to assess the extent to which ESG practices contribute to the sustainable transformation of the water sector in the face of growing environmental and socio-economic challenges. The methodology is based on a systematic analysis of policy documents, regulatory frameworks, and ESG standards applicable to the water sector at both national (Romania) and EU levels. This study also investigates investment strategies and their alignment with the EU Taxonomy for Sustainable Activities, enabling a comparative perspective on implementation, gaps and strengths. Findings reveal that while ESG principles are increasingly recognized across Europe, their implementation remains uneven (particularly in Romania) due to unclear standards, limited funding mechanisms, and fragmented policy coordination. ESG integration shows clear potential to foster innovation, improve governance transparency, and support long-term resilience in the water sector. These results underline the need for coherent, integrated policies and stronger institutional coordination to ensure consistent ESG adoption across Member States. Policymakers should prioritize the development of clear guidelines and supportive funding instruments to accelerate sustainable outcomes. The originality of our study lies in its comparative approach, offering an in-depth analysis of ESG integration in the water sector across different governance contexts. It provides valuable insights for advancing policy coherence, investment alignment, and sustainable water resource management at both national and European levels. Full article
(This article belongs to the Section Water Resources Management, Policy and Governance)
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20 pages, 2319 KB  
Article
Sustainability Synergies Between Water Governance and Agrotourism Development in the Semi-Arid Climate: A Case Study of Esmeraldas Province, Ecuador
by Eliana Ivanova Cuero Espinoza, Qudus Adeyi, Mirza Junaid Ahmad, Hwa-Seok Hwang and Kyung-Sook Choi
Water 2025, 17(15), 2215; https://doi.org/10.3390/w17152215 - 24 Jul 2025
Viewed by 651
Abstract
Effective water governance is essential for sustainable development amidst water scarcity challenges in semi-arid regions like Esmeraldas Province, which has substantial agrotourism potential. Yet, fragmented governance and chronic water shortages threaten its viability. Using a mixed-method approach, this study analyzed how sustainable water [...] Read more.
Effective water governance is essential for sustainable development amidst water scarcity challenges in semi-arid regions like Esmeraldas Province, which has substantial agrotourism potential. Yet, fragmented governance and chronic water shortages threaten its viability. Using a mixed-method approach, this study analyzed how sustainable water governance can support agrotourism development in Esmeraldas Province, Ecuador. This study combined policy gaps analysis, stakeholder surveys (policymakers, farmers, community leaders, and tourism operators), and water availability using the Standardized Precipitation Evapotranspiration Index (SPEI) from 1980 to 2022. The results revealed a lack of policy regulation and water infrastructure as the major governance gaps that need more intervention. The survey respondents indicated that water is mainly used for domestic and economic activities and the conservation of natural ecosystems. The SPEI revealed a significant drought trend falling below −3, with severe drought years coinciding with many crop losses and a fall in tourism. This study highlights the interconnection between water governance and agrotourism in Esmeraldas, Ecuador, proposing a strategic framework that incorporates adaptive governance principles and inclusive participation mechanisms, emphasizing targeted capacity building to strengthen water management practices and enhance the Sustainable Development Goals for agrotourism resilience. Full article
(This article belongs to the Special Issue Water: Economic, Social and Environmental Analysis)
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16 pages, 722 KB  
Article
From Desalination to Governance: A Comparative Study of Water Reuse Strategies in Southern European Hospitality
by Eleonora Santos
Sustainability 2025, 17(15), 6725; https://doi.org/10.3390/su17156725 - 24 Jul 2025
Viewed by 660
Abstract
As climate change intensified water scarcity in Southern Europe, tourism-dependent regions such as Portugal’s Algarve faced growing pressure to adapt their water management systems. This study investigated how hotel groups in the Algarve have adopted and communicated water reuse technologies—specifically desalination and greywater [...] Read more.
As climate change intensified water scarcity in Southern Europe, tourism-dependent regions such as Portugal’s Algarve faced growing pressure to adapt their water management systems. This study investigated how hotel groups in the Algarve have adopted and communicated water reuse technologies—specifically desalination and greywater recycling—under environmental, institutional, and reputational constraints. A comparative qualitative case study was conducted involving three hotel groups—Vila Vita Parc, Pestana Group, and Vila Galé—selected through purposive sampling based on organizational capacity and technology adoption stage. The analysis was supported by a supplementary mini-case from Mallorca, Spain. Publicly accessible documents, including sustainability reports, media coverage, and policy frameworks, were thematically coded using organizational environmental behavior theory and the OECD Principles on Water Governance. The results demonstrated that (1) higher organizational capacity was associated with greater maturity in water reuse implementation; (2) communication transparency increased alongside technological advancement; and (3) early-stage adopters encountered stronger financial, regulatory, and operational barriers. These findings culminated in the development of the Maturity–Communication–Governance (MCG) Framework, which elucidates how internal resources, stakeholder signaling, and institutional alignment influence sustainable infrastructure uptake. This research offered policy recommendations to scale water reuse in tourism through financial incentives, regulatory simplification, and public–private partnerships. The study contributed to the literature on sustainable tourism and decentralized climate adaptation, aligning with UN Sustainable Development Goals 6.4, 12.6, and 13. Full article
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16 pages, 4204 KB  
Article
Assessment of the Source and Dynamics of Water Inrush Based on Hydrochemical Mixing Model in Zhaxikang Mining Area, Tibet, China
by Hongyu Gu, Yujie Liu, Huizhong Liu, Xinyu Cen, Jinxian Zhong, Dewei Wang and Lei Yi
Water 2025, 17(15), 2201; https://doi.org/10.3390/w17152201 - 23 Jul 2025
Viewed by 379
Abstract
Water source identification and dynamic assessment are critical for mining safety, particularly in mines governed by complex geological structures. The hydrochemical mixing model demonstrates a natural advantage for early warning of water intrusion compared to geophysical monitoring techniques. This study discusses core issues [...] Read more.
Water source identification and dynamic assessment are critical for mining safety, particularly in mines governed by complex geological structures. The hydrochemical mixing model demonstrates a natural advantage for early warning of water intrusion compared to geophysical monitoring techniques. This study discusses core issues related to the mixing model, including the conceptual framework, selection of end-members, and choice of tracers, and formulates principles for general applicability. In this study, three sources were identified using the conceptual model and hydrochemical analysis: water in F7 (main fault), shallow fracture water, and river water. A correlation analysis and variability analysis were applied to determine the tracers, and the 18O, D, Cl, B, and Li were determined. The end-members of the three sources are time-dependent in July and September, especially the shallow fracture water’s end-members. The dynamics of the mixing ratios of the three sources suggest that river water contributes only to the inrush (1–4%), with this being especially low in September, as the increasing hydraulic gradient from south to north prevents recharge. The water in F7 accounts for at least 70% of the inrush water. Shallow fracture water accounts for the rest and increases slightly in September as the precipitation increases in mining-disturbed areas. Finally, this work makes the later water control work more targeted. Full article
(This article belongs to the Section Hydrogeology)
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15 pages, 2184 KB  
Article
First-Principles Study on Interfacial Triboelectrification Between Water and Halogen-Functionalized Polymer Surfaces
by Taili Tian, Bo Zhao, Yimin Wang, Shifan Huang, Xiangcheng Ju and Yuyan Fan
Lubricants 2025, 13(7), 303; https://doi.org/10.3390/lubricants13070303 - 11 Jul 2025
Viewed by 636
Abstract
Contact electrification (CE), or triboelectrification, is an electron transfer phenomenon occurring at the interface between dissimilar materials due to differences in polarity, holding significant research value in tribology. The microscopic mechanisms of CE remain unclear due to the complex coupling of multiple physical [...] Read more.
Contact electrification (CE), or triboelectrification, is an electron transfer phenomenon occurring at the interface between dissimilar materials due to differences in polarity, holding significant research value in tribology. The microscopic mechanisms of CE remain unclear due to the complex coupling of multiple physical processes. Recently, with the rise of triboelectric nanogenerator (TENG) technology, solid–liquid contact electrification has demonstrated vast application potential, sparking considerable interest in its underlying mechanisms. Emerging experimental evidence indicates that at water–polymer CE interfaces, the process involves not only traditional ion adsorption but also electron transfer. Halogen-containing functional groups in the solid material significantly enhance the CE effect. To elucidate the microscopic mechanism of water–polymer CE, this study employed first-principles density functional theory (DFT) calculations, simulating the interfacial electrification process using unit cell models of water contacting polymers. We systematically and quantitatively investigated the charge transfer characteristics at interfaces between water and three representative polymers with similar backbones but different halogen-functionalized (F, Cl) side chains: fluorinated ethylene propylene (FEP), polyvinyl chloride (PVC), and polytetrafluoroethylene (PTFE), focusing on evaluating halogen’s influence and mechanism on interfacial electron transfer. The results reveal that electron transfer is primarily governed by the energy levels of the polymer’s lowest unoccupied molecular orbital (LUMO) and highest occupied molecular orbital (HOMO). Halogen functional groups modulate the material’s electron-donating/accepting capabilities by altering these frontier orbital energy levels. Consequently, we propose that the critical strategy for polymer chemical modification resides in lowering the LUMO energy level of electron-accepting materials. This study provides a novel theoretical insight into the charge transfer mechanism at solid–liquid interfaces, offers guidance for designing high-performance TENG interfacial materials, and holds significant importance for both the fundamental theory and the development of advanced energy devices. Full article
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21 pages, 6342 KB  
Article
Enhancing Transboundary Water Governance Using African Earth Observation Data Cubes in the Nile River Basin: Insights from the Grand Ethiopian Renaissance Dam and Roseries Dam
by Baradin Adisu Arebu, Esubalew Adem, Fahad Alzahrani, Nassir Alamri and Mohamed Elhag
Water 2025, 17(13), 1956; https://doi.org/10.3390/w17131956 - 30 Jun 2025
Viewed by 1323
Abstract
The construction of the Grand Ethiopian Renaissance Dam (GERD) on the Blue Nile has heightened transboundary water tensions in the Nile River Basin, particularly affecting downstream Sudan and Egypt. This study leverages African Earth Observation Data Cubes, specifically Digital Earth Africa’s Water Observations [...] Read more.
The construction of the Grand Ethiopian Renaissance Dam (GERD) on the Blue Nile has heightened transboundary water tensions in the Nile River Basin, particularly affecting downstream Sudan and Egypt. This study leverages African Earth Observation Data Cubes, specifically Digital Earth Africa’s Water Observations from Space (WOfS) platform, to quantify the hydrological impacts of GERD’s three filling phases (2019–2022) on Sudan’s Roseires Dam. Using Sentinel-2 satellite data processed through the Open Data Cube framework, we analyzed water extent changes from 2018 to 2023, capturing pre- and post-filling dynamics. Results show that GERD’s water spread area increased from 80 km2 in 2019 to 528 km2 in 2022, while Roseires Dam’s water extent decreased by 9 km2 over the same period, with a notable 5 km2 loss prior to GERD’s operation (2018–2019). These changes, validated against PERSIANN-CDR rainfall data, correlate with GERD’s filling operations, alongside climatic factors like evapotranspiration and reduced rainfall. The study highlights the potential of Earth Observation (EO) technologies to support transparent, data-driven transboundary water governance. Despite the Cooperative Framework Agreement (CFA) ratified by six upstream states in 2024, mistrust persists due to Egypt and Sudan’s non-ratification. We propose enhancing the Nile Basin Initiative’s Decision Support System with EO data and AI-driven models to optimize water allocation and foster cooperative filling strategies. Benefit-sharing mechanisms, such as energy trade from GERD, could mitigate downstream losses, aligning with the CFA’s equitable utilization principles and the UN Watercourses Convention. This research underscores the critical role of EO-driven frameworks in resolving Nile Basin conflicts and achieving Sustainable Development Goal 6 for sustainable water management. Full article
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