Search Results (13)

Steel is an important product in many engineering sectors; however, steelmaking remains one of the largest ${\mathrm{CO}}_2$ emitters. Therefore, new governmental policies drive the steelmaking industry toward a cleaner and more sustainable operation such as the gas-based direct reduction–electric arc furnace process. To become carbon neutral, utilizing more scrap is one of the feasible solutions to achieve this goal. Addressing knowledge gaps regarding scrap heterogeneity (size, shape, and composition) is essential to evaluate the effects of increased scrap ratios in basic oxygen furnace (BOF) operations. This review systematically examines heat and mass transfer correlations relevant to scrap melting in BOF steelmaking, with a focus on low Prandtl number fluids (thick thermal boundary layer) and dense particulate systems. Notably, a majority of these correlations are designed for fluids with high Prandtl numbers. Even for the ones tailored for low Prandtl, they lack the introduction of the porosity effect which alters the melting behavior in such high temperature systems. The review is divided into two parts. First, it surveys heat transfer correlations for single elements (rods, spheres, and prisms) under natural and forced convection, emphasizing their role in predicting melting rates and estimating maximum shell size. Second, it introduces three numerical modeling approaches, highlighting that the computational fluid dynamics–discrete element method (CFD–DEM) offers flexibility in modeling diverse scrap geometries and contact interactions while being computationally less demanding than particle-resolved direct numerical simulation (PR-DNS). Nevertheless, the review identifies a critical gap: no current CFD–DEM framework simultaneously captures shell formation (particle growth) and non-isotropic scrap melting (particle shrinkage), underscoring the need for improved multiphase models to enhance BOF operation. Full article

To address the deployment accuracy issues of multi-frequency band reflector antennas, this study takes a hexagonal prism modular deployable antenna as an example and proposes an accuracy design method. This paper proposes a screw-theory-based sub-chain precision analysis method. This method constructs a virtual screw model of rod length errors and hinge gap errors. Based on geometric relationships, a multi-loop point position error model is established, and accuracy surfaces considering rod length errors and hinge gap are output using MATLAB R2024b. By outputting the relationship curves of single-rod errors relative to point errors, the linearized influence law of individual rods on precision is further elucidated. Simulation results demonstrate the reliability of the error modeling theory. Based on the established cost-effective precision model and the minimum point error, which is obtained by using the numerical iterative method, the optimal solution for error parameters is obtained. Full article

This study evaluated binocular visual function using automatic dual rotational Risley prisms (ADRRPs) to measure phoria and vergence ranges. Thirty-nine (mean age: 21.82 ± 1.10 years; age range: 20–24 years) healthy adults with normal binocular vision participated. Each underwent baseline refraction exams followed by phoria and vergence tests conducted using both a phoropter with Maddox rods and the ADRRPs. The results revealed a strong positive correlation between the two instruments for distance phoria (r = 0.959, p < 0.001) and near-phoria measurements (r = 0.968, p < 0.001). For vergence testing, positive fusional vergence (PFV) at distance showed a moderate-to-strong correlation for break points (r = 0.758, p < 0.001) and a moderate correlation for recovery points (r = 0.452, p < 0.001). Negative fusional vergence (NFV) at distance demonstrated a strong correlation for break points (r = 0.863, p < 0.001) and a moderate correlation for recovery points (r = 0.458, p < 0.01). Near-vergence testing showed moderate-to-strong correlations for break points (r = 0.777, p < 0.001) and recovery points (r = 0.623, p < 0.001). The inclusion of Bland–Altman analysis provides a more comprehensive evaluation of agreement between ADRRPs and the phoropter. While strong correlations were observed, systematic bias and LoA indicate that these methods are not perfectly interchangeable. The ADRRPs demonstrated potential for binocular vision assessment but require further validation for clinical application. Full article

Changing the morphology is an excellent option for altering the textural parameters of SBA-15 materials. This study provides a guide on how the properties of mesoporous structures behave according to their morphology and their contribution to thermal stability. The objective of this work was to synthesize different morphologies (spherical, hexagonal prisms, rice-like grains, rods, and fibers) of SBA-15 materials and evaluate the existing textural changes. The materials were synthesized by varying the temperature of the synthesis gel from 25 °C to 55 °C, with stirring at 300 or 500 rpm. The results of X-ray diffraction, Fourier transform infrared spectroscopy, N₂ adsorption and desorption, and scanning electron microscopy were evaluated. Thermal stability tests were also conducted in an inert atmosphere. The materials were successfully synthesized, and it was observed that they all exhibited different characteristics, such as their ordering, interplanar distance, mesoporous parameter, specific surface area, micropore and mesopore volumes, external mesoporous area, and wall thickness. They also presented different thermal stabilities. The rice grain morphology had the highest specific surface area (908.8 cm²/g) and the best thermal stability, while the rod morphology had the best pore diameter (7.7 nm) and microporous volume (0.078 cm³/g). Full article

In this work, the TiC and Ti₅Si₃-reinforced Cu matrix composites with different contents were successfully prepared through Ti–SiC reaction in Cu melts; accordingly, the microstructures of them were studied, and the hardness of the composites was tested. It is found that the synthesized TiC are granular, with a size ranging from 0.5 μm to 3 μm, while the Ti₅Si₃ are rod-like hexagonal prisms with a diameter of about 1 μm and a length-to-diameter ratio of about 5~25. In addition, it is noticed that many Ti₅Si₃ rods are actually Cu@Ti₅Si₃ core–shell structure rods. TiC and Ti₅Si₃ alternately distribute in the Cu matrix to form the hybrid reinforcement system. With the increase in Ti–SiC content, the TiC particles, Ti₅Si₃ rods and Cu@Ti₅Si₃ increased obviously, and the solid skeleton structure of TiC–Ti₅Si₃ was formed. The hardness of the composites was 2.2 to 2.74 times greater than that of the as-cast pure copper. It is deduced that, compared to the composites reinforced by either TiC or Ti₅Si₃, the formation of the TiC–Ti₅Si₃ hybrid system is more helpful for improving the properties of the composites due to the different morphologies of TiC and Ti₅Si₃. Full article

The Keratinocyte differentiation factor 1 (KDF1) is reported to take part in tooth formation in humans, but the dental phenotype of Kdf1 mutant mice has not been understood. Additionally, the role of the KDF1 gene in dental hard tissue development is rarely known. In this study, we constructed a Kdf1 missense mutation knock-in mouse model through CRISPR/Cas9 gene-editing technology. Enamel samples from wildtypes (WT) and Kdf1 homozygous mutants (HO) were examined using micro-computed tomography (micro-CT), scanning electron microscopy (SEM), an atomic force microscope (AFM) and Raman microspectroscopy. The results showed that a novel Kdf1 missense mutation (c. 908G>C, p.R303P) knock-in mice model was constructed successfully. The enamel of HO mice incisors appeared chalky and defective, exposing the rough interior of the inner enamel and dentin. Micro-CT showed that HO mice had lower volume and mineral density in their tooth enamel. In addition, declined thickness was found in the unerupted enamel layer of incisors in the HO mice. Using SEM and AFM, it was found that enamel prisms in HO mice enamel were abnormally and variously shaped with loose decussating crystal arrangement, meanwhile the enamel rods were partially fused and collapsed, accompanied by large gaps. Furthermore, misshapen nanofibrous apatites were disorderly combined with each other. Raman microspectroscopy revealed a compromised degree of order within the crystals in the enamel after the Kdf1 mutation. To conclude, we identified enamel structure defects in the Kdf1 missense mutation knock-in mice, which displayed fragmentary appearance, abnormally shaped prism structure, decreased mineral density, altered crystal ordering degree and chemical composition of the enamel layer. This may support the potential role of the KDF1 gene in the natural development of enamel. Full article

In this paper, a novel optical measurement principle for deformation, especially torsion, is presented. A laser beam is guided via total internal reflection (TIR) in a prism rod. Every single reflection causes an increasing change in the beam path, which can be measured by its effect on the outcoupling position of the laser. With a diameter of the prism rod of $10 \mathrm{mm}$ and a length of $120 \mathrm{mm}$, the system achieves torsion sensitivities between $350 \mu \mathrm{m}/°$ and more than $7000 \mu \mathrm{m}/°$, depending on the actual torsion angle $\phi$. A decency level of sensitivity is defined for comparison, which is exceeded by a factor of $~55$ at $\phi =0$. The presented principle of TIR prism rods can be adapted to measure different load cases. Using two laser beams, bending and torsion can be distinguished and combined load cases analyzed. The resulting system can be integrated into machine elements, such as screws, to perform condition monitoring on mechanically loaded components. Full article

The design and synthesis of sol-gel silica-based hybrid materials and composites offer significant benefits to obtain innovative biomaterials with controlled porosity at the nanostructure level for applications in bone tissue engineering. In this work, the combination of robocasting with sol-gel ink of suitable viscosity prepared by mixing tetraethoxysilane (TEOS), gelatin and β-tricalcium phosphate (β-TCP) allowed for the manufacture of 3D scaffolds consisting of a 3D square mesh of interpenetrating rods, with macropore size of 354.0 ± 17.0 μm, without the use of chemical additives at room temperature. The silica/gelatin/β-TCP system underwent irreversible gelation, and the resulting gels were also used to fabricate different 3D structures by means of an alternative scaffolding method, involving high-resolution laser micromachining by laser ablation. By this way, 3D scaffolds made of 2 mm thick rectangular prisms presenting a parallel macropore system drilled through the whole thickness and consisting of laser micromachined holes of 350.8 ± 16.6-micrometer diameter, whose centers were spaced 1312.0 ± 23.0 μm, were created. Both sol-gel based 3D scaffold configurations combined compressive strength in the range of 2–3 MPa and the biocompatibility of the hybrid material. In addition, the observed Si, Ca and P biodegradation provided a suitable microenvironment with significant focal adhesion development, maturation and also enhanced in vitro cell growth. In conclusion, this work successfully confirmed the feasibility of both strategies for the fabrication of new sol-gel-based hybrid scaffolds with osteoconductive properties. Full article

Diabetes affects the developing enamel by altering the mineralization process, which can have a detrimental effect on oral health. The objectives of this study were to examine the ultrastructure and composition of surface enamel in primary teeth of diabetic children and its clinical implications. Hundred extracted primary teeth from diabetic children (Test group: n = 50) and healthy children (Control group: n = 50), between 6 and 12 years of age, were subjected to scanning electron microscopy to qualitatively examine the enamel surface. Energy dispersive X-ray (EDX) analysis was performed to investigate the mass percentage of calcium (Ca) and phosphorous (P) in the surface enamel. Ultrastructural aberrations of surface enamel were observed in the test group teeth. Additionally, prism perforations were seen at the junction of rod and inter-rod enamel and the prisms were loosely packed. An even aprismatic layer of surface enamel was evident in the control group teeth. There was a statistically significant difference (p < 0.05) of Ca and P mass percentage between the test and control group teeth. The mean mass percentage rates of Ca and P were 33.75% and 16.76%, respectively. A poor surface characteristic and elemental composition of the enamel surface of primary teeth is observed in diabetic children. Therefore, appropriate caries preventive measures are mandatory to maintain the structural integrity of the tooth in these patients. Full article

In this study the catalytic activity of different gold and bimetallic nanoparticle solutions towards the reduction of methylene blue by sodium borohydride as a model reaction is investigated. By utilizing differently shaped gold nanoparticles, i.e., spheres, cubes, prisms and rods as well as bimetallic gold–palladium and gold–platinum core-shell nanorods, we evaluate the effect of the catalyst surface area as available gold surface area, the shape of the nanoparticles and the impact of added secondary metals in case of bimetallic nanorods. We track the reaction by UV/Vis measurements in the range of 190–850 nm every 60 s. It is assumed that the gold nanoparticles do not only act as a unit transferring electrons from sodium borohydride towards methylene blue but can promote the electron transfer upon plasmonic excitation. By testing different particle shapes, we could indeed demonstrate an effect of the particle shape by excluding the impact of surface area and/or surface ligands. All nanoparticle solutions showed a higher methylene blue turnover than their reference, whereby gold nanoprisms exhibited 100% turnover as no further methylene blue absorption peak was detected. The reaction rate constant k was also determined and revealed overall quicker reactions when gold or bimetallic nanoparticles were added as a catalyst, and again these were highest for nanoprisms. Furthermore, when comparing gold and bimetallic nanorods, it could be shown that through the addition of the catalytically active second metal platinum or palladium, the dye turnover was accelerated and degradation rate constants were higher compared to those of pure gold nanorods. The results explore the catalytic activity of nanoparticles, and assist in exploring further catalytic applications. Full article

Eu(OH)₃ with various shape-controlled morphologies and size, such as plate, rod, tube, prism and nanoparticles was successfully synthesized through simple hydrothermal reactions. The products were characterized by XRD (X-Ray Powder Diffraction), FE-SEM (Field Emission- Scanning Electron Microscopy) and TG (Thermogravimetry). The influence of the initial pH value of the starting solution and reaction temperature on the crystalline phase and morphology of the hydrothermal products was investigated. A possible formation process to control morphologies and size of europium products by changing the hydrothermal temperature and initial pH value of the starting solution was proposed. Full article

In this contribution, the synthesis of the metal−organic framework (MOF) based on lanthanum that exhibits trigonal prism shape is presented. The length of a single side of this structure ranges from 2 to 10 μm. The carbonized lanthanum-based organic framework (CMOF–La) maintained the original shape. However, the lanthanum oxide was reshaped in the form of rods during the carbonization. It resulted in the creation of parallel arranged channels. The unique structure of the carbonized structure motivated us to reveal its adsorption performance. Therefore, the adsorption kinetics of acid red 18 onto a carbonized metal−organic framework were conducted. Various physicochemical parameters such as initial dye concentration and pH of dye solution were investigated in an adsorption process. The adsorption was found to decrease with an increase in initial dye concentration. In addition, the increase in adsorption capacity was noticed when the solution was changed to basic. Optimal conditions were obtained at a low pH. Kinetic adsorption data were analyzed using the pseudo-first-order kinetic model, the pseudo-second-order kinetic model and the intraparticle diffusion model. The adsorption kinetics were well fitted using a pseudo-second-order kinetic model. It was found that the adsorption of anionic dye onto CMOF–La occurs by hydrophobic interactions between carbonized metal-organic framework and acid red 18. Full article

Oblique ceramic armor structure composed of an oblique part and a backing part was designed to resist the ballistic impact of long rod penetrators. The front part consisted of an oblique silicon carbide ceramic and a triangular titanium alloy prism. The backing part contained layered silicon carbide and armor steel designed to absorb the residual energy of penetrators. The structure’s response to penetration was examined experimentally by considering different impact locations on oblique targets. Numerical simulations of the experiments were performed to reproduce the penetration and failure processes that occurred in the armor modules. In addition, a simple layer structure with the identical line-of-sight thickness of each material used in the oblique impact was simulated under a normal impact. The rod and target performances with the oblique impact and normal impact were compared and analyzed in detail. The results showed that the oblique structure had a better ballistic performance as a result of an extra short dwell period before penetrating the ceramic in comparison with the normal layer case. The ability of the oblique targets to defeat long rod projectiles differed with the impact location on the ceramic. The present study paves the way for ceramic armor obliquity applications. Full article