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14 pages, 4679 KB  
Article
Rapid Dynamic Separation of Radial and Azimuthal Polarization Components in Circular Airy Vortex Beams via Linear Electro-Optic Effect in Uniaxial Crystals
by Guoliang Zheng, Tiefeng He, Zikun Xu, Jiawen Li, Xuhui Zhang, Lili Wan and Qingyang Wu
Photonics 2025, 12(9), 894; https://doi.org/10.3390/photonics12090894 - 5 Sep 2025
Abstract
This paper presents a rapid approach for the dynamic separation of radial polarization (R-pol) and azimuthal polarization (A-pol) components in circular Airy vortex beams (CAVBs) by utilizing the linear electro-optic (EO) effect in uniaxial crystals. By applying an external electric field along the [...] Read more.
This paper presents a rapid approach for the dynamic separation of radial polarization (R-pol) and azimuthal polarization (A-pol) components in circular Airy vortex beams (CAVBs) by utilizing the linear electro-optic (EO) effect in uniaxial crystals. By applying an external electric field along the z-axis of a strontium barium niobate (SBN) crystal, tunable spatial separation of the R-pol and A-pol components is achieved. Under positive electric fields, the crystal maintains negative uniaxial properties with increased birefringence, extending the focal separation distance. Conversely, negative electric fields initially reduce the birefringence of the crystal; further increases in negative field strength will transition the crystal to a positive uniaxial state, subsequently enhancing birefringence and restoring focal separation. Experimental simulations demonstrate a focal separation of 1.4 mm at ±15 kV/mm, with R-pol focusing first at +15 kV/mm and A-pol preceding at −15 kV/mm. The polarization distributions at the foci confirm the successful separation of the two components. This approach overcomes the static limitation of conventional polarization splitters in separating R-pol and A-pol components, showing significant potential for optical manipulation, high-resolution imaging, and quantum information processing. Full article
(This article belongs to the Section Optical Interaction Science)
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12 pages, 4113 KB  
Communication
Optical Communication Performance of Cylindrical Vector Partially Coherent Laguerre–Gaussian Beams in Atmospheric Turbulence
by Meng Liu, Linxuan Yao, Yaru Gao, Hui Zhang, Yangsheng Yuan, Bohan Guo and Huimin Shi
Photonics 2025, 12(9), 883; https://doi.org/10.3390/photonics12090883 - 2 Sep 2025
Viewed by 163
Abstract
The optical communication performance of cylindrical vector partially coherent Laguerre–Gaussian (PCLG) beams in different atmospheric turbulence models are investigated. Based on the unified theory of coherence and polarization and turbulence theory, analytical formulas for the signal-to-noise ratio (SNR), crosstalk equivalent intensity and bit [...] Read more.
The optical communication performance of cylindrical vector partially coherent Laguerre–Gaussian (PCLG) beams in different atmospheric turbulence models are investigated. Based on the unified theory of coherence and polarization and turbulence theory, analytical formulas for the signal-to-noise ratio (SNR), crosstalk equivalent intensity and bit error rate (BER) of cylindrical vector PCLG beams are derived in Kolmogorov turbulence, non-Kolmogorov turbulence and strong turbulence, respectively. Numerical analyses indicate that selecting a smaller azimuthal index l0 or a larger radial index p0 of beams can effectively enhance the SNR. In addition, selecting appropriate beam width, coherence length, wavelength of the beam, propagation distance and receiving aperture diameter enables the acquisition of the optimal signal detection position. Our results are conducive to the application of cylindrical vector PCLG beams in FSO communication. Full article
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12 pages, 3358 KB  
Article
Self-Powered Au/ReS2 Polarization Photodetector with Multi-Channel Summation and Polarization-Domain Convolutional Processing
by Ruoxuan Sun, Guowei Li and Zhibo Liu
Sensors 2025, 25(17), 5375; https://doi.org/10.3390/s25175375 - 1 Sep 2025
Viewed by 217
Abstract
Polarization information is essential for material identification, stress mapping, biological imaging, and robust vision under strong illumination, yet conventional approaches rely on external polarization optics and active biasing, which are bulky, alignment-sensitive, and power-hungry. A more desirable route is to encode polarization at [...] Read more.
Polarization information is essential for material identification, stress mapping, biological imaging, and robust vision under strong illumination, yet conventional approaches rely on external polarization optics and active biasing, which are bulky, alignment-sensitive, and power-hungry. A more desirable route is to encode polarization at the pixel level and read it out at zero bias, enabling compact, low-noise, and polarization imaging. Low-symmetry layered semiconductors provide persistent in-plane anisotropy as a materials basis for polarization selectivity. Here, we construct an eight-terminal radial ‘star-shaped’ Au/ReS2 metal-semiconductor junction array pixel that operates in a genuine photovoltaic mode under zero external bias based on the photothermoelectric effect. Based on this, electrical summation of phase-matched multi-junction channels increases the signal amplitude approximately linearly without sacrificing the two-lobed modulation depth, achieving ‘gain by stacking’ without external amplification. The device exhibits millisecond-scale transient response and robust cycling stability and, as a minimal pixel unit, realizes polarization-resolved imaging and pattern recognition. Treating linear combinations of channels as operators in the polarization domain, these results provide a general pixel-level foundation for compact, zero-bias, and scalable polarization cameras and on-pixel computational sensing. Full article
(This article belongs to the Special Issue Recent Advances in Optoelectronic Materials and Device Engineering)
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16 pages, 5482 KB  
Article
Non-Precipitation Echo Identification in X-Band Dual-Polarization Weather Radar
by Zihang Zhao, Hao Wen, Lei Wu, Ruiyi Li, Ting Zhuang and Yang Zhang
Remote Sens. 2025, 17(17), 3023; https://doi.org/10.3390/rs17173023 - 31 Aug 2025
Viewed by 246
Abstract
This study proposes a novel quality control method combining fuzzy logic and threshold discrimination for processing X-band dual-polarization radar data from Beijing. The method effectively eliminates non-precipitation echoes, including electromagnetic interference, clear-air echoes, and ground clutter through five key steps: (1) Identifying electromagnetic [...] Read more.
This study proposes a novel quality control method combining fuzzy logic and threshold discrimination for processing X-band dual-polarization radar data from Beijing. The method effectively eliminates non-precipitation echoes, including electromagnetic interference, clear-air echoes, and ground clutter through five key steps: (1) Identifying electromagnetic interference using continuity of reflectivity across adjacent elevation angles, radial mean correlation coefficient, and differential reflectivity; (2) Preserving precipitation data in ground clutter-mixed regions by jointly utilizing the difference in reflectivity before and after clutter suppression by the signal processor, and characteristic value proportions; (3) Developing a fuzzy logic algorithm with six parameters (e.g., reflectivity texture, depolarization ratio) for ground clutter and clear-air echoes removal; (4) Filtering echoes with missing dual-polarization variables using cross-elevation mean reflectivity, mean correlation coefficient, and valid range bin proportion; (5) Removing residual noise via radial/azimuthal reflectivity continuity analysis. Validation with 635 PPI scans demonstrates high identification accuracy across echo types: 93.5% for electromagnetic interference, 98.4% for ground clutter, 97.7% for clear-air echoes, and 98.2% for precipitation echoes. Full article
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22 pages, 11408 KB  
Article
The Influence of Beryllium Incorporation into an Al-5wt.%Cu-1wt.%Si Alloy on the Solidification Cooling Rate, Microstructural Length Scale, and Corrosion Resistance
by Joyce Ranay Santos, Milena Poletto Araújo, Talita Vida, Fabio Faria Conde, Noé Cheung, Amauri Garcia and Crystopher Brito
Metals 2025, 15(7), 736; https://doi.org/10.3390/met15070736 - 30 Jun 2025
Viewed by 399
Abstract
The addition of beryllium (Be) to Al–Cu alloys enhances their mechanical properties and corrosion resistance. This study aims to investigate the effects of solidification cooling rates and the addition of Be on the microstructural refinement and corrosion behavior of an Al–5wt.%Cu–1wt.%Si–0.5wt.%Be alloy. Radial [...] Read more.
The addition of beryllium (Be) to Al–Cu alloys enhances their mechanical properties and corrosion resistance. This study aims to investigate the effects of solidification cooling rates and the addition of Be on the microstructural refinement and corrosion behavior of an Al–5wt.%Cu–1wt.%Si–0.5wt.%Be alloy. Radial solidification under unsteady-state conditions was performed using a stepped brass mold, producing four distinct cooling rates. An experimental growth law, λ2 = 26T˙1/3, was established, confirming the influence of Be and the cooling rate on dendritic size reduction. The final microstructure was characterized by an α-Al dendritic matrix with eutectic compounds (α-Al + θ-Al2Cu + Si + Fe-rich phase) confined to the interdendritic regions. No Be-containing intermetallic phases were detected, and beryllium remained homogeneously distributed within the eutectic. Notably, Be addition promoted a morphological transformation of the Fe-rich phases from angular or acicular forms into a Chinese-script-like structure, which is associated with reduced local stress concentrations. Tensile tests revealed an ultimate tensile strength of 248.8 ± 11.2 MPa and elongation of approximately 6.4 ± 0.5%, indicating a favorable balance between strength and ductility. Corrosion resistance assessment by EIS and polarization tests in a 0.06 M NaCl solution showed a corrosion rate of 28.9 µm·year−1 and an Epit of −645 mV for the Be-containing alloy, which are lower than those measured for the reference Al–Cu and Al–Cu–Si alloys. Full article
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20 pages, 6122 KB  
Article
Surface Charge and Electric Field Distribution of Direct-Current Gas-Insulated Transmission Lines’ Basin-Type Insulators Under Multi-Field Coupling
by Junran Jia, Xin Lin, Zhenxin Geng and Jianyuan Xu
Appl. Sci. 2025, 15(13), 7061; https://doi.org/10.3390/app15137061 - 23 Jun 2025
Viewed by 471
Abstract
In direct-current gas-insulated transmission lines (DC GIL), complex heat transfer processes accelerate surface charge accumulation on insulators, causing local electric field distortion and elevating the risk of surface flashover. This study develops a three-dimensional multi-physics coupled mathematical model for ±200 kV DC GIL [...] Read more.
In direct-current gas-insulated transmission lines (DC GIL), complex heat transfer processes accelerate surface charge accumulation on insulators, causing local electric field distortion and elevating the risk of surface flashover. This study develops a three-dimensional multi-physics coupled mathematical model for ±200 kV DC GIL basin-type insulators. The bulk and surface conductivity of insulator materials were experimentally measured under varying temperature and electric field conditions, with fitting equations derived to describe their behavior. The model investigates surface charge accumulation and electric field distribution under DC voltage and polarity-reversal conditions, incorporating multi-field coupling effects. Results show that, at a 3150 A current in a horizontally arranged DC GIL, insulator temperatures reach approximately 62.8 °C near the conductor and 32 °C near the enclosure, with the convex surface exhibiting higher temperatures than the concave surface and distinct radial variations. Under DC voltage, surface charge accumulates faster in high-temperature regions, with both charge and electric field distributions stabilizing after approximately 300 h, following significant changes within the first 40 h. Following stabilization, the distribution of surface charge and electric field varies across different radial directions. During polarity reversal, residual surface charges cause electric field distortion, increasing maximum field strength by 13.6% and 47.2% on the convex and concave surfaces, respectively, with greater distortion on the concave surface, as calculated from finite element simulations with a numerical accuracy of ±0.5% based on mesh convergence and solver tolerance. These findings offer valuable insights for enhancing DC GIL insulation performance. Full article
(This article belongs to the Special Issue Advances in Electrical Insulation Systems)
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15 pages, 3143 KB  
Article
Molecular Dynamics Simulation of Plasticizing Effect of Mixed Dioctyl Phthalate and Isosorbide Diheptanoate on Polyvinyl Chloride Material
by Qin Lei, Xijian Yi, Wenxi Yu, Juan Cheng, Siyu Ou, Qiong Xue and Haiyun Jiang
Polymers 2025, 17(12), 1655; https://doi.org/10.3390/polym17121655 - 14 Jun 2025
Viewed by 867
Abstract
A molecular dynamics simulation was adopted to investigate the plasticizing effect of polyvinyl chloride (PVC) and its mechanism by blending isosorbide heptylate (SDH) with the traditional plasticizer dioctyl phthalate (DOP) and to explore the feasibility of SDH partially replacing DOP in PVC film. [...] Read more.
A molecular dynamics simulation was adopted to investigate the plasticizing effect of polyvinyl chloride (PVC) and its mechanism by blending isosorbide heptylate (SDH) with the traditional plasticizer dioctyl phthalate (DOP) and to explore the feasibility of SDH partially replacing DOP in PVC film. The results demonstrated that the difference in the solubility parameter between SDH and PVC was smaller than that between DOP and PVC, indicating the superior compatibility of SDH with PVC. This enhanced compatibility was further supported by the significantly higher interaction energy between SDH and PVC compared to that between DOP and PVC, primarily attributed to the stronger interactions formed between the polar functional groups in the SDH molecules and the PVC’s molecular chains. The analysis of the glass transition temperature demonstrated that the plasticizing effect of the SDH/DOP mixed plasticizer on the PVC exhibited intermediate behavior between that of pure SDH and DOP systems, showing a decreasing trend with an increasing proportion of SDH. An analysis of the radial distribution function further confirmed that the probability of hydrogen bond formation between the SDH and PVC molecules was significantly higher than that between DOP and PVC, contributing to the strong interaction between the SDH and PVC. From the analysis of the plasticizer’s diffusion, it was clearly concluded that the migration resistance of SDH was superior to that of DOP. These research findings can provide fundamental data and guidance for the strategy of partially replacing DOP with SDH. Full article
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15 pages, 2654 KB  
Article
Comprehensive Assessment of Ocean Surface Current Retrievals Using SAR Doppler Shift and Drifting Buoy Observations
by Shengren Fan, Biao Zhang and Vladimir Kudryavtsev
Remote Sens. 2025, 17(12), 2007; https://doi.org/10.3390/rs17122007 - 10 Jun 2025
Viewed by 603
Abstract
Ocean surface radial current velocities can be derived from synthetic aperture radar (SAR) Doppler shift observations using the Doppler centroid technique and a recently developed Doppler velocity model. However, comprehensive evaluations of the accuracy and reliability of these retrievals remain limited. To address [...] Read more.
Ocean surface radial current velocities can be derived from synthetic aperture radar (SAR) Doppler shift observations using the Doppler centroid technique and a recently developed Doppler velocity model. However, comprehensive evaluations of the accuracy and reliability of these retrievals remain limited. To address this gap, we analyzed 6341 Sentinel-1 SAR scenes acquired over the South China Sea (SCS) between December 2017 and October 2023, in conjunction with drifting buoy observations, to systematically validate the retrieved radial current velocities. A linear fitting method and the dual co-polarization Doppler velocity (DPDop) model were applied to correct for the influence of non-geophysical factors and sea state effects. The validation against the drifter data yielded a bias of 0.01 m/s, a root mean square error (RMSE) of 0.18 m/s, and a mean absolute error (MAE) of 0.16 m/s. Further comparisons with the Surface and Merged Ocean Currents (SMOC) dataset revealed bias, RMSE, and MAE values of 0.07 m/s, 0.14 m/s, and 0.12 m/s in the Beibu Gulf, and −0.06 m/s, 0.23 m/s, and 0.19 m/s in the Kuroshio intrusion area. These results demonstrate that SAR Doppler measurements have a strong potential to complement existing ocean observations in the SCS by providing high-resolution (1 km) ocean surface current maps. Full article
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17 pages, 1899 KB  
Article
Structural Mechanics of the Flight Feather Rachis: The Role of Cortical Keratin Asymmetry
by Hao Wu, Ju-Cheng Hsiao, Wan-Chi Liao, You-Sian Wang, Xiang-Ning Xie and Wen-Tau Juan
Symmetry 2025, 17(6), 880; https://doi.org/10.3390/sym17060880 - 5 Jun 2025
Viewed by 578
Abstract
The flight feather rachis is a lightweight, anisotropic structure that must withstand asymmetric aerodynamic loads generated during flapping flight—particularly under unidirectional compression during the wing downstroke. To accommodate this spatiotemporal loading regime, the rachis exhibits refined internal organization, especially along the dorsoventral axis. [...] Read more.
The flight feather rachis is a lightweight, anisotropic structure that must withstand asymmetric aerodynamic loads generated during flapping flight—particularly under unidirectional compression during the wing downstroke. To accommodate this spatiotemporal loading regime, the rachis exhibits refined internal organization, especially along the dorsoventral axis. In this study, we used finite element modeling (FEM) to investigate how dorsoventral polarization in cortical keratin allocation modulates the mechanical performance of shaft-like structures under bending. All models were constructed with conserved second moments of area and identical material properties to isolate the effects of spatial material placement. We found that dorsal-biased reinforcement delays yield onset, enhances strain dispersion, and promotes elastic recovery, while ventral polarization leads to premature strain localization and plastic deformation. These outcomes align with the dorsally thickened rachises observed in flight-specialized birds and reflect their adaptation to asymmetric aerodynamic forces. In addition, we conducted a conceptual exploration of radial (cortex–medulla) redistribution, suggesting that even inner–outer asymmetry may contribute to directional stiffness tuning. Together, our findings highlight how the flight feather rachis integrates cortical material asymmetry to meet directional mechanical demands, offering a symmetry-informed framework for understanding biological shaft performance. Full article
(This article belongs to the Section Life Sciences)
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20 pages, 1866 KB  
Article
Biosynthesis of Fe3O4 Nanoparticles Using Egg Albumin: Antifungal, Dielectric Analysis and Photocatalytic Activity
by Azam Raza, Sally Mostafa Khadrawy, Irfan Ahmad, Mohd Imran, Gulrana Khuwaja, Humaira Parveen, Sayeed Mukhtar, Bhagyashree R. Patil, Ahmed A. Allam, Hassan A. Rudayni, Syed Kashif Ali and Absar Ahmad
Catalysts 2025, 15(6), 505; https://doi.org/10.3390/catal15060505 - 22 May 2025
Viewed by 782
Abstract
The use of chemical pesticides has led to adverse effects on human health and the environment, prompting the exploration of alternative solutions. This study successfully biosynthesized iron oxide nanoparticles (Fe3O4 NPs) using chicken egg albumin, which served as reducing and [...] Read more.
The use of chemical pesticides has led to adverse effects on human health and the environment, prompting the exploration of alternative solutions. This study successfully biosynthesized iron oxide nanoparticles (Fe3O4 NPs) using chicken egg albumin, which served as reducing and capping agents, and evaluated their antifungal efficacy against Macrophomina phaseolina. The fungicidal potential of Fe3O4 NPs was assessed in vitro, demonstrating enhanced inhibition of M. phaseolina’s radial growth with increasing concentrations from 100 ppm to 300 ppm. Dielectric properties were also studied, revealing advantageous current conduction processes and conductive network development with temperature variation, which is particularly beneficial in the low-frequency range. At a fixed pH, dielectric studies showed increased mobile carrier movement and polarization with rising temperature at a fixed frequency. The photocatalytic activity of Fe3O4 NPs was assessed for the degradation of methylene blue (MB), an organic dye, under solar irradiation. In this study, Fe3O4 NPs photocatalysts achieved 89% (MB) degradation within 75 min. This research underscores the potential of using chicken egg albumin for the biosynthesis of Fe3O4 NPs. It offers a promising alternative for plant disease control and highlights their suitability for integration into eco-friendly plant protection strategies. Full article
(This article belongs to the Special Issue Catalytic Materials for Hazardous Wastewater Treatment)
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8 pages, 3282 KB  
Proceeding Paper
Design and Development of 35–4.4 GHz Inset-Fed 2 × 2 Phased Array Microstrip Patch Antenna for Intentional Electromagnetic Interference Testing
by John Joshua O. Gutierrez, Jervin D. Louis and Jennifer C. Dela Cruz
Eng. Proc. 2025, 92(1), 63; https://doi.org/10.3390/engproc2025092063 - 12 May 2025
Viewed by 433
Abstract
Communication devices are frequency-operating electronics equipment that utilizes analog modulation, frequency modulation, shortwave frequency, and even higher frequencies in telecommunications. We designed an antenna to transmit interfering frequencies for testing equipment and components based on the effects and conditions of achieving electromagnetic interference. [...] Read more.
Communication devices are frequency-operating electronics equipment that utilizes analog modulation, frequency modulation, shortwave frequency, and even higher frequencies in telecommunications. We designed an antenna to transmit interfering frequencies for testing equipment and components based on the effects and conditions of achieving electromagnetic interference. Ansys 2024 was used to design the 35 to 4.4 GHz 2 × 2 patch antennas and simulate the response using a sample frequency of 35 MHz to determine the antenna’s polarization. The polarization was circular, in contrast to the results of the phases Phi and Theta observed in the radial field 3D polar plot, which are completely out of phase and different in magnitude by 5.4 in Phi and 5402.01 in Theta. The measurements from Ansys were congruent to the 2D model dimensions in AutoCAD 2024. The antenna was fabricated under a double-layered photosensitive FR-4 copper board. The antenna connected to the signal generator ADF 4351 effectively was interfered with by a frequency near the actual frequency with a maximum distance of 7.5 m in a room. The frequencies that interfered were from 91.5 to 102.7 MHz. Strong electromagnetic waves for interference disrupted frequency-operating devices due to high signal power achieving destructive interference. Full article
(This article belongs to the Proceedings of 2024 IEEE 6th Eurasia Conference on IoT, Communication and Engineering)
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21 pages, 4739 KB  
Article
Photoacoustic Imaging with a Finite-Size Circular Integrating Detector
by Shan Gao, Xili Jing, Mengyu Fang, Jingru Zhao and Tianrun Zhang
Appl. Sci. 2025, 15(9), 4922; https://doi.org/10.3390/app15094922 - 29 Apr 2025
Viewed by 362
Abstract
Photoacoustic imaging (PAI) has rapidly developed in biomedical imaging. The point spread function (PSF) is critical for addressing image blurring in PAI. However, in circular integrating detection systems, the PSF exhibits spatial variations. This makes PSF extraction challenging. The existing studies typically assume [...] Read more.
Photoacoustic imaging (PAI) has rapidly developed in biomedical imaging. The point spread function (PSF) is critical for addressing image blurring in PAI. However, in circular integrating detection systems, the PSF exhibits spatial variations. This makes PSF extraction challenging. The existing studies typically assume that the PSF is known or obtained through experiments. This study proposes a method for extracting the PSF based on the polar coordinate system. By transforming the image from the Cartesian coordinate system to the polar coordinate system, the “spin blur” problem is decomposed into multiple independent subproblems. With the separation of the radial and angular directions, the blurring kernel remains invariant at each radius, thereby simplifying the estimation of the PSF. To estimate the blurring kernel, we use polynomial algebraic common factor extraction techniques. The numerical simulation results validate the effectiveness of the method, and the impact of sample size on computational efficiency and accuracy is discussed. Full article
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6 pages, 228 KB  
Article
Stellar Wind Parameters of Massive Stars in Accretion-Powered High-Mass X-Ray Binary Pulsars
by Nina Beskrovnaya, Nazar Ikhsanov and Vitaliy Kim
Galaxies 2025, 13(2), 37; https://doi.org/10.3390/galaxies13020037 - 5 Apr 2025
Viewed by 581
Abstract
The process of mass exchange between the components of High-Mass X-ray Binary (HMXB) systems with neutron stars undergoing wind-fed accretion is discussed. The X-ray luminosity of these systems allows us to evaluate the mass capture rate by the neutron star from the stellar [...] Read more.
The process of mass exchange between the components of High-Mass X-ray Binary (HMXB) systems with neutron stars undergoing wind-fed accretion is discussed. The X-ray luminosity of these systems allows us to evaluate the mass capture rate by the neutron star from the stellar wind of its massive companion and set limits on the relative velocity between the neutron star and the wind. We found that the upper limit to the wind velocity in the orbital plane during the high state of the X-ray source is in the range of 120–1000 kms1, which is by a factor of 2–4 lower than both the terminal wind velocity and the speed of the wind flowing out from the polar regions of massive stars for all the objects under investigation. This finding is valid not only for the systems with Be stars, but also for the systems in which the optical components do not exhibit the Be phenomenon. We also show that the lower limit to the radial wind velocity in these systems can unlikely be smaller than a few percent of the orbital velocity of the neutron star. This provides us with a new constraint on the mass transfer process in the outflowing disks of Be-type stars. Full article
(This article belongs to the Special Issue Circumstellar Matter in Hot Star Systems)
17 pages, 1042 KB  
Article
Experimental and Theoretical Study of the Synthesis of a Deep Eutectic Solvent Based on Protonated Caffeine, Ethylene Glycol, and ZnCl2
by Laura Sofía Benavides-Maya, Manuel Felipe Torres-Perdomo, Luz M. Ocampo-Carmona and Luver Echeverry-Vargas
Molecules 2025, 30(7), 1557; https://doi.org/10.3390/molecules30071557 - 31 Mar 2025
Cited by 1 | Viewed by 1223
Abstract
In this study, a deep eutectic solvent (DES) incorporating protonated caffeine (CafCl), ethylene glycol (EG), and zinc chloride (ZnCl2) was synthesized and characterized for the first time. Caffeine was protonated using an optimized procedure in an anhydrous medium to enhance [...] Read more.
In this study, a deep eutectic solvent (DES) incorporating protonated caffeine (CafCl), ethylene glycol (EG), and zinc chloride (ZnCl2) was synthesized and characterized for the first time. Caffeine was protonated using an optimized procedure in an anhydrous medium to enhance its interaction with the system, and its structure was confirmed by FTIR spectroscopy, NMR, and thermogravimetric analysis (TGA), evidencing the formation of the N-H bond in the imidazole ring. A eutectic mixture with a molar ratio of ETG:ZnCl2:CafCl of 1:2:0.1 was synthesized, and its characterization confirmed the formation of hydrogen bonds and the coordinative interaction between the components. Additionally, computational simulations based on COSMO-RS and ab initio molecular dynamics (AIMD) were conducted to analyze the charge distribution and the stability of the hydrogen bond network in the eutectic mixture. Sigma profiles revealed that protonated caffeine possesses highly polar regions capable of establishing strong interactions with EG and ZnCl2, enhancing the system’s stability. Furthermore, radial distribution functions (RDFs) showed a decrease in the interaction distance between key atoms after incorporating protonated caffeine. The results suggest that this novel DES has promising potential for industrial applications, especially in the extraction of sulfur compounds from fossil fuels due to the activation of the imidazole ring of caffeine. However, further studies are needed to optimize its operating conditions and evaluate its performance on an industrial scale. Full article
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26 pages, 8557 KB  
Article
A Novel Earth-System Spatial Grid Model: ISEA4H-ESSG for Multi-Layer Geoscience Data Integration and Analysis
by Yue Ma, Guoqing Li, Long Zhao and Xiaochuang Yao
Appl. Sci. 2025, 15(7), 3703; https://doi.org/10.3390/app15073703 - 27 Mar 2025
Viewed by 739
Abstract
This paper presents a novel Earth-System Stratified Grid (ISEA4H-ESSG) model, designed to address the challenges in multi-layer geoscience data management and analysis. In the realm of geosciences, which encompasses the solid earth, atmosphere, hydrosphere, and biosphere, as well as planetary and space sciences, [...] Read more.
This paper presents a novel Earth-System Stratified Grid (ISEA4H-ESSG) model, designed to address the challenges in multi-layer geoscience data management and analysis. In the realm of geosciences, which encompasses the solid earth, atmosphere, hydrosphere, and biosphere, as well as planetary and space sciences, the effective integration of diverse data sources is crucial. Traditional grids have limitations in three-dimensional spatial modeling, cross-layer data fusion, and dynamic multi-scale analysis. The ISEA4H-ESSG model overcomes these drawbacks by integrating the Icosahedral Snyder Equal-Area Aperture 4 Hexagon Discrete Global Grid System (ISEA4H DGGS) with a degenerative subdivision mechanism. It adheres to six core principles, including stratified spherical coverage, geographic consistency, multi-scale dynamic adaptability, global seamless partitioning, encoding uniqueness and efficiency, and multi-source data compatibility. Through the independent subdivision of spherical and radial layers, this model balances resolution differences and resolves polar-grid distortion and cross-layer data heterogeneity issues. The introduction of a four-dimensional spatiotemporal encoding framework enhances the storage and parallel computing capabilities of massive datasets. Case studies on ionosphere three-dimensional modeling and global atmospheric temperature field formatting demonstrate the high precision and adaptability of the ISEA4H-ESSG model. This research provides a unified spatial data infrastructure for geosciences, facilitating in-depth studies on natural hazards, climate change, and planetary evolution, and offering new perspectives for international partnerships and future Earth-related research. Full article
(This article belongs to the Section Earth Sciences)
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