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21 pages, 11378 KB  
Article
Identifying High-Potential Zones for Iron Mineralization in Bahia, Brazil, Using a Spectral Angle Mapper–Random Forest Integrated Framework
by Rafael Franca-Rocha, Carlos M. Souza, Rodrigo N. Vasconcelos, Pedro Walfir Martins Souza-Filho, Tati de Almeida and Washington J. S. Franca-Rocha
Minerals 2025, 15(11), 1119; https://doi.org/10.3390/min15111119 (registering DOI) - 27 Oct 2025
Abstract
The state of Bahia in Brazil possesses significant, yet underexploited, iron ore reserves. To support the initial stages of mineral exploration in this vast region, cost-effective and rapid large-scale mapping methods are essential. This paper presents a workflow based on publicly available remote [...] Read more.
The state of Bahia in Brazil possesses significant, yet underexploited, iron ore reserves. To support the initial stages of mineral exploration in this vast region, cost-effective and rapid large-scale mapping methods are essential. This paper presents a workflow based on publicly available remote sensing data for a state mineral prospectivity mapping (MPM) for iron. The methodology employs a Random Forest (RF) classification model on Sentinel-2 multispectral images, trained with a randomly selected dataset in the image at varying distances defined from the location of known iron mines in the state. The Spectral Angle Mapper (SAM) algorithm was used to categorize the samples according to spectral similarity features with laboratory-confirmed ore signatures from samples collected in the mine pit area. The resulting MPM successfully delineated known iron districts and highlighted new, unexplored areas with potential. A quantitative evaluation of the model yielded an overall accuracy of 69.8%, a macro-average F1-score of 0.697, and a Cohen’s Kappa coefficient of 0.623, indicating a reasonable agreement beyond random chance. This work demonstrates a validated, low-cost, and simple approach for regional-scale MPM, offering a valuable reconnaissance tool for preliminary exploration, particularly in extensive and data-scarce regions. Full article
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13 pages, 1139 KB  
Article
Analysis of Agronomic and Genetic Components of Conilon Clones in an Irrigated Production System in the Central Cerrado
by Thiago Paulo da Silva, Adriano Delly Veiga, Renato Fernando Amabile, Juaci Malaquias, Michelle Souza Vilela, Sônia Maria Costa Celestino, Arlini Rodrigues Fialho, João Victor Pinheiro Melo and Gustavo Barbosa Cobalchini Santos
Agronomy 2025, 15(11), 2491; https://doi.org/10.3390/agronomy15112491 (registering DOI) - 27 Oct 2025
Abstract
Canephora coffee genotypes developed in other growing regions, with traits of interest such as drought tolerance and high coffee bean yield, need to be introduced and characterized in other locations to check adaptability. The aim of this study was to check the agronomic [...] Read more.
Canephora coffee genotypes developed in other growing regions, with traits of interest such as drought tolerance and high coffee bean yield, need to be introduced and characterized in other locations to check adaptability. The aim of this study was to check the agronomic performance and determine the genetic parameters of the clonal canephora coffee cultivar Marilândia ES 8143, composed by twelve genotypes, developed by the Capixaba Institute of Research, Technical Assistance and Rural Extension (Instituto Capixaba de Pesquisa, Assistência Técnica e Extensão Rural—Incaper), in an irrigated system of the Central Cerrado region of Brazil. The study was conducted in the experimental areas of Embrapa Cerrados at 1050 m altitude in a center pivot irrigation system using a management system with water stress controlled for around 65 days. A randomized block experimental design was used with three replications, and each plot consisted of eight plants. The clones were planted in February 2019 and in 2021 and 2022. Phenotyping was carried out to evaluate the following traits: coffee bean yields, sieve retention percentages, plant height, canopy projection, number of pairs of plagiotropic branches, and frost damage using a scoring scale. Clone 5 stood out in mean value in the two years evaluated for bean yield. Clones 5, 6, 7, 8, and 9 had higher mean values for flat-type coffee beans in both years. Clones 1 and 5 exhibited mean values indicating good vegetative development. Clones 5 and 12 showed no visible symptoms for low air temperatures and frost effects. Highly significant differences were observed among the genotypes for all the morphoagronomic traits evaluated, and high values of heritability, genetic coefficients of variation, and selective accuracy showed conditions favorable to the selection of clones for the agronomic traits analyzed. Clones 1, 2 and 6 have values in lower groups for chlorogenic acids and caffeine, and in higher groups for protein and soluble solids, thus showing greater potential for obtaining quality beverages. Full article
(This article belongs to the Section Horticultural and Floricultural Crops)
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21 pages, 1414 KB  
Systematic Review
Effectiveness of Occupational Therapy-Based Intervention on Gross Motor Function and Independence in Activities of Daily Living in Children with Cerebral Palsy: A Systematic Review with Meta-Analysis
by Diego Fernandez-Cardenas, Celia Sánchez-Gomez, Edgar Vásquez-Carrasco, Jordan Hernandez-Martinez, Joaquín Pérez-Cárcamo, Cristian Sandoval, Pablo Valdés-Badilla, Eduardo Carmine-Peña, Constanza Lorca and Eduardo Fernández-Rodríguez
J. Clin. Med. 2025, 14(21), 7624; https://doi.org/10.3390/jcm14217624 (registering DOI) - 27 Oct 2025
Abstract
Background/Objectives: Children with cerebral palsy (CP) commonly present impairments in gross motor function and limitations in activities of daily living (ADLs), which negatively impact independence and quality of life. Identifying effective rehabilitation strategies is essential to promote functional development. To evaluate the effectiveness [...] Read more.
Background/Objectives: Children with cerebral palsy (CP) commonly present impairments in gross motor function and limitations in activities of daily living (ADLs), which negatively impact independence and quality of life. Identifying effective rehabilitation strategies is essential to promote functional development. To evaluate the effectiveness of occupational therapy (OT) interventions on gross motor function and independence in ADLs among children with CP. Methods: Seven electronic databases were searched through August 2025. The review protocol was registered in PROSPERO (CRD42025634706) and conducted in accordance with PRISMA guidelines. Methodological quality and certainty of evidence were assessed using the Oxford Centre for Evidence-Based Medicine scale, the Risk of Bias 2 (RoB 2) tool, and GRADEpro. Randomized controlled trials reporting OT interventions targeting gross motor and ADL outcomes were included. Results: Of 594 identified records, 14 studies met the inclusion criteria. Meta-analysis indicated that OT interventions significantly improved gross motor function (GMFM-66; ES = 0.32 [0.01–0.63], p = 0.04), mobility (PEDI-Mobility; ES = 0.46 [0.05–0.87], p = 0.02), and occupational performance (COPM-Performance; ES = 2.63 [1.14–4.11], p = 0.001) and satisfaction (COPM-Satisfaction; ES = 2.17 [0.82–3.51], p = 0.002). No significant changes were observed in self-care (PEDI-Self-Care; ES = 0.19 [–0.14–0.53], p = 0.26). Conclusions: Evidence suggests that OT interventions effectively enhance gross motor function, mobility, and occupational performance in children with CP. These results support the integration of OT within pediatric rehabilitation programs to optimize functional outcomes. Full article
(This article belongs to the Special Issue Cerebral Palsy: Clinical Rehabilitation and Treatment)
23 pages, 1730 KB  
Article
Automated Modeling Method and Strength Analysis of Irregular Deformation of Floating Roof Caused by Welding—Taking Double-Layer Floating Roof Storage Tanks as an Example
by Chunyang Li, Yuanyuan Jiang, Luyang Zhang, Wei Guan and Yan Zhou
Appl. Sci. 2025, 15(21), 11473; https://doi.org/10.3390/app152111473 (registering DOI) - 27 Oct 2025
Abstract
The external floating roof of a large storage tank directly covers the liquid surface as the liquid level rises and falls, enhancing the tank’s safety and environmental performance. It is fabricated from thin SA516 Gr.70 steel plates, with a carbon equivalent of 0.37% [...] Read more.
The external floating roof of a large storage tank directly covers the liquid surface as the liquid level rises and falls, enhancing the tank’s safety and environmental performance. It is fabricated from thin SA516 Gr.70 steel plates, with a carbon equivalent of 0.37% calculated according to AWS standards, using single-sided butt welding. Such plates are susceptible to welding-induced deformations, resulting in irregular warping of the bottom plate. Current research on floating roofs for storage tanks mostly relies on idealized models that assume no deformation, thereby neglecting the actual deformation characteristics of the floating roof structure. To address this, the present study develops an automated modeling approach that reconstructs a three-dimensional floating roof model based on measured deformation data, accurately capturing the initial irregular geometry of the bottom plate. This method employs parametric numerical reconstruction and automatic finite element model generation techniques, enabling efficient creation of the irregular initial deformation caused by welding of the floating roof bottom plate and its automatic integration into the finite element analysis process. It overcomes the inefficiencies, inconsistent accuracy, and challenges associated with traditional manual modeling when conducting large-scale strength analyses under in-service conditions. Based on this research, a strength analysis of the deformed floating roof structure was conducted under in-service conditions, including normal floating, extreme rainfall, and outrigger contact scenarios. An idealized geometric model was also established for comparative analysis. The results indicate that under the normal floating condition, the initial irregular deformation increases the local stress peak of the floating roof bottom plate by 19%, while the maximum positive and negative displacements increase by 22% and 83%, respectively. Under extreme uniform rainfall conditions, it raises the stress peak of the bottom plate by 24%, with maximum positive and negative displacements increasing by 21% and 28%, respectively. Under the extreme non-uniform rainfall condition, it significantly elevates the stress peak of the bottom plate by 227%, and the maximum positive and negative displacements increase by 45% and 47%, respectively. Under the outrigger bottoming condition, it increases the local stress peak of the bottom plate by 25%, with maximum positive and negative displacements remaining similar. The initial irregular deformation not only significantly amplifies the stress and displacement responses of the floating roof bottom plate but also intensifies the deformation response of the top plate through structural stiffness weakening and deformation coupling, thereby reducing the safety margin of the floating roof structure. This study fills the knowledge gap regarding the effect of welding-induced irregular deformation on floating roof performance and provides a validated workflow for automated modeling and mechanical assessment of large-scale welded steel structures. Full article
(This article belongs to the Section Applied Industrial Technologies)
21 pages, 3273 KB  
Article
The Depression Effect of Micromolecular Depressant Containing Amino and Phosphonic Acid Group on Serpentine in the Flotation of Low-Grade Nickel Sulphide Ore
by Chenxu Zhang, Wei Sun, Zhiyong Gao, Bingang Lu, Xiaohui Su, Chunhua Luo, Xiangan Peng and Jian Cao
Minerals 2025, 15(11), 1116; https://doi.org/10.3390/min15111116 (registering DOI) - 27 Oct 2025
Abstract
Selective depression of serpentine remains a major challenge in the flotation of low-grade nickel sulphide ores because serpentine slimes impair concentrate grade and recovery. In this study, four structurally related micromolecular depressants bearing amino and phosphonic functionalities were designed, synthesized and systematically evaluated. [...] Read more.
Selective depression of serpentine remains a major challenge in the flotation of low-grade nickel sulphide ores because serpentine slimes impair concentrate grade and recovery. In this study, four structurally related micromolecular depressants bearing amino and phosphonic functionalities were designed, synthesized and systematically evaluated. Micro-flotation screening (depressant range: 0–20 mg·L−1) and bench-scale tests identified an operational optimum near pH 9 and a reagent dosage of ≈18 mg·L−1; potassium butyl xanthate (PBX) was used as a collector and methyl isobutyl carbinol (MIBC) as a frother. Phosphonate-containing molecules (PMIDA and GLY) delivered the largest gains in pentlandite recovery and concentrate selectivity compared with carboxylate analogues and a benchmark depressant. Mechanistic studies (zeta potential, adsorption isotherms, FT-IR, and XPS) indicated that selective adsorption of amino and phosphonate groups on serpentine occurs via coordination with surface Mg sites and by altering the electrical double layer. The DLVO modelling showed that these reagents generate an increased repulsive barrier, mitigating slime coating and entrainment. Contact-angle measurements confirmed selective hydrophilization of serpentine while pentlandite remained hydrophobic. These findings demonstrate that incorporating targeted phosphonate chelation into small-molecule depressants is an effective strategy to control serpentine interference and to enhance flotation performance. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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26 pages, 3155 KB  
Article
Symmetry and Asymmetry in Pre-Trained Transformer Models: A Comparative Study of TinyBERT, BERT, and RoBERTa for Chinese Educational Text Classification
by Munire Muhetaer, Xiaoyan Meng, Jing Zhu, Aixiding Aikebaier, Liyaer Zu and Yawen Bai
Symmetry 2025, 17(11), 1812; https://doi.org/10.3390/sym17111812 (registering DOI) - 27 Oct 2025
Abstract
With the advancement of educational informatization, vast amounts of Chinese text are generated across online platforms and digital textbooks. Effectively classifying such text is essential for intelligent education systems. This study conducts a systematic comparative evaluation of three Transformer-based models—TinyBERT-4L, BERT-base-Chinese, and RoBERTa-wwm-ext—for [...] Read more.
With the advancement of educational informatization, vast amounts of Chinese text are generated across online platforms and digital textbooks. Effectively classifying such text is essential for intelligent education systems. This study conducts a systematic comparative evaluation of three Transformer-based models—TinyBERT-4L, BERT-base-Chinese, and RoBERTa-wwm-ext—for Chinese educational text classification. Using a balanced four-category subset of the THUCNews corpus (Education, Technology, Finance, and Stock), the research investigates the trade-off between classification effectiveness and computational efficiency under a unified experimental framework. The experimental results show that RoBERTa-wwm-ext achieves the highest effectiveness (93.12% Accuracy, 93.08% weighted F1), validating the benefits of whole-word masking and extended pre-training. BERT-base-Chinese maintains a balanced performance (91.74% Accuracy, 91.66% F1) with moderate computational demand. These findings reveal a clear symmetry–asymmetry dynamic: structural symmetry arises from the shared Transformer encoder and identical fine-tuning setup, while asymmetry emerges from differences in model scale and pre-training strategy. This interplay leads to distinct accuracy–latency trade-offs, providing practical guidance for deploying pre-trained language models in resource-constrained intelligent education systems. Full article
(This article belongs to the Section Computer)
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29 pages, 2947 KB  
Review
A Comparative Review of Vertical Axis Wind Turbine Designs: Savonius Rotor vs. Darrieus Rotor
by Alina Fazylova, Kuanysh Alipbayev, Alisher Aden, Fariza Oraz, Teodor Iliev and Ivaylo Stoyanov
Inventions 2025, 10(6), 95; https://doi.org/10.3390/inventions10060095 (registering DOI) - 27 Oct 2025
Abstract
This paper reviews and analyzes three types of vertical-axis wind rotors: the classic Savonius, spiral Savonius, and Darrieus designs. Using numerical modeling methods, including computational fluid dynamics (CFD), their aerodynamic characteristics, power output, and efficiency under different operating conditions are examined. Key parameters [...] Read more.
This paper reviews and analyzes three types of vertical-axis wind rotors: the classic Savonius, spiral Savonius, and Darrieus designs. Using numerical modeling methods, including computational fluid dynamics (CFD), their aerodynamic characteristics, power output, and efficiency under different operating conditions are examined. Key parameters such as lift, drag, torque, and power coefficient are compared to identify the strengths and weaknesses of each rotor. Results highlight that the Darrieus rotor demonstrates the highest efficiency at higher wind speeds due to lift-based operation, while the spiral Savonius offers improved stability, smoother torque characteristics, and adaptability in turbulent or low-wind environments. The classic Savonius, though less efficient, remains simple, cost-effective, and suitable for small-scale urban applications where reliability is prioritized over high performance. In addition, the study outlines the importance of blade geometry, tip speed ratio, and advanced materials in enhancing rotor durability and efficiency. The integration of modern optimization approaches, such as CFD-based design improvements and machine learning techniques, is emphasized as a promising pathway for developing more reliable and sustainable vertical-axis wind turbines. Although the primary analysis relies on numerical simulations, the observed performance trends are consistent with findings reported in experimental studies, indicating that the results are practically meaningful for design screening, technology selection, and siting decisions. Unlike prior studies that analyze Savonius and Darrieus rotors in isolation or under heterogeneous setups, this work (i) establishes a harmonized, fully specified CFD configuration (common domain, BCs, turbulence/near-wall treatment, time-stepping) enabling like-for-like comparison; (ii) couples the transient aerodynamic loads p(θ,t) into a dynamic FEA + fatigue pipeline (rainflow + Miner with mean-stress correction), going beyond static loading proxies; (iii) quantifies a prototype-stage materials choice rationale (aluminum) with a validated migration path to orthotropic composites; and (iv) reports reproducible wake/torque metrics that are cross-checked against mature models (DMST/actuator-cylinder), providing design-ready envelopes for small/medium VAWTs. Overall, the work provides recommendations for selecting rotor types under different wind conditions and operational scenarios to maximize energy conversion performance and long-term reliability. Full article
23 pages, 8508 KB  
Article
Diversity, Pattern, and Environmental Drivers of Climbing Plants in China
by Haoran Wang and Guangfu Zhang
Plants 2025, 14(21), 3281; https://doi.org/10.3390/plants14213281 (registering DOI) - 27 Oct 2025
Abstract
As a distinct plant functional group, climbers critically sustain ecosystem structure and function globally. However, little is known about those in China. Here, we examine the diversity and distribution of Chinese climbers at a regional scale. First, climbing species data were collected. Then, [...] Read more.
As a distinct plant functional group, climbers critically sustain ecosystem structure and function globally. However, little is known about those in China. Here, we examine the diversity and distribution of Chinese climbers at a regional scale. First, climbing species data were collected. Then, Pearson correlations were conducted to assess relationships between environmental variables and climber species richness. Also, variation partitioning was used to reveal the pure and shared effects of four explanatory variable groups on species richness. A total of 3485 climber species (551 genera, 105 families) were recorded in China. Woody lianas dominated the climbing flora (64.73% of species) relative to herbaceous vines; twining represented the predominant mechanism (1829 species, 52.48%) relative to the others. Chinese climbers largely presented a pattern of species richness that decreased from south to north in China. Moreover, endemic and threatened climbers exhibited strong distributional congruence with all climbers. Additionally, four predictor groups (temperature, precipitation, geography, human impact) were found to jointly account for over 70% of species density variance across different climber types through variation partitioning, with precipitation’s pure effect dominating. Thus, Chinese climbers exhibit high diversity and an uneven distribution, primarily driven by precipitation. This study also provides a valuable reference on climbers at the regional scale for future studies. Full article
(This article belongs to the Section Plant Ecology)
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24 pages, 16055 KB  
Article
Unified Open-Set Recognition and Novel Class Discovery via Prototype-Guided Representation
by Jiuqing Dong, Sicheng Wang, Jianxin Xue, Siwen Zhang, Zixin Li and Heng Zhou
Appl. Sci. 2025, 15(21), 11468; https://doi.org/10.3390/app152111468 (registering DOI) - 27 Oct 2025
Abstract
The existing research on open-set recognition (OSR) and novel class discovery (NCD) has largely treated these tasks as independent fields. OSR aims to identify samples that do not belong to the training set classes, while NCD seeks to further classify such unseen, unlabeled [...] Read more.
The existing research on open-set recognition (OSR) and novel class discovery (NCD) has largely treated these tasks as independent fields. OSR aims to identify samples that do not belong to the training set classes, while NCD seeks to further classify such unseen, unlabeled samples into novel classes. However, there is a lack of a unified framework to automate both tasks systematically. In this paper, we propose a unified training framework to identify and categorize unseen samples. Specifically, we conduct a comprehensive evaluation of existing post hoc OSR methods and observe that their performance is highly sensitive to the temperature scaling factor. To address this, we introduce a distance-based evaluation method for OSR, which not only outperforms existing post hoc approaches but also integrates seamlessly with them to deliver enhanced performance. Furthermore, we developed a prototype-based classification head leveraging this distance metric, which facilitates compact feature representations for known classes and guides the clustering of unknown classes, thereby significantly enhancing the classification accuracy for novel classes. On the CUB-200-2011 dataset, our unified framework achieves a 0.95–6.12% improvement in AUROC scores on OSR benchmarks and a 3.19% increase in classification accuracy for novel classes. Extensive experiments and visualizations validate the effectiveness of the proposed approach. We believe that this unified framework will pave the way for automating the integration of OSR and NCD, offering a more efficient and systematic approach to addressing these tasks. Full article
(This article belongs to the Section Computing and Artificial Intelligence)
20 pages, 1002 KB  
Review
Diet, Exercise, and Lifestyle in Glaucoma: Current Evidence and Future Perspectives
by Akiko Hanyuda, Satoru Tsuda, Noriko Himori, Kota Sato, Naoki Takahashi and Toru Nakazawa
Nutrients 2025, 17(21), 3369; https://doi.org/10.3390/nu17213369 (registering DOI) - 27 Oct 2025
Abstract
Glaucoma is a major ocular neurodegenerative disease and a leading cause of irreversible blindness worldwide, with prevalence projected to exceed 110 million by 2040. Although lowering intraocular pressure (IOP) remains the only proven treatment, glaucoma arises from a complex interplay of genetic, local, [...] Read more.
Glaucoma is a major ocular neurodegenerative disease and a leading cause of irreversible blindness worldwide, with prevalence projected to exceed 110 million by 2040. Although lowering intraocular pressure (IOP) remains the only proven treatment, glaucoma arises from a complex interplay of genetic, local, and systemic factors—including oxidative stress, vascular dysregulation, mitochondrial dysfunction, and neuroinflammation. Emerging evidence suggests that modifiable lifestyle factors may influence these pathogenic pathways. In this review, higher dietary nitrate from leafy greens is consistently associated with lower primary open-angle glaucoma risk, aligning with nitric-oxide-mediated endothelial support and more stable ocular perfusion pressure. Flavonoids (anthocyanins and flavanols), carotenoids (lutein/zeaxanthin), and B vitamins have strong biological rationale for glaucoma prevention but have limited support from long-term, large population-based studies. The effect of polyunsaturated fats on glaucoma remains inconsistent and warrants source-(plant vs. animal) and substitution-based analyses. Consistent protective effects of aerobic exercise and high-quality sleep may be associated with favorable metabolic profiles and ocular perfusion, potentially mitigating retinal ganglion cell loss. Conversely, smoking and alcohol use are frequently coupled with poorer diet quality (e.g., lower vegetable intake) and heightened oxidative stress, which may exacerbate glaucomatous neurodegeneration. However, much of the current literature is constrained by cross-sectional designs, reliance on self-reported food frequency questionnaires, and insufficient use of structural endpoints such as retinal nerve fiber layer imaging. This review focuses on the potential of lifestyle modification and future directions in prevention and treatment strategies for glaucoma, highlighting the need for large-scale, multi-ethnic, genotype-stratified longitudinal studies and randomized controlled trials to establish causality and define optimal intervention strategies. Full article
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20 pages, 2679 KB  
Article
Dynamic Characteristics and Parametric Sensitivity Analysis of Underground Powerhouse in Pumped Storage Power Stations
by Junhao Gao, Zhenzhong Shen, Yiqing Sun, Lei Gan, Liqun Xu, Hongwei Zhang, Yaxin Feng, Yong Ni, Yanhe Zhang and Yang Xiang
Appl. Sci. 2025, 15(21), 11464; https://doi.org/10.3390/app152111464 (registering DOI) - 27 Oct 2025
Abstract
China has witnessed extensive construction of underground powerhouses for pumped storage power stations. With the continuous increase in unit capacity, vibration problems have become particularly pronounced. Intense vibrations may not only disrupt the normal operation of hydropower units but also compromise the overall [...] Read more.
China has witnessed extensive construction of underground powerhouses for pumped storage power stations. With the continuous increase in unit capacity, vibration problems have become particularly pronounced. Intense vibrations may not only disrupt the normal operation of hydropower units but also compromise the overall structural safety of the powerhouse. Moreover, in dynamic analyses of powerhouse structures, different parameters exert varying degrees of influence on the results, making it essential to systematically examine their impacts. This study focuses on a large-scale underground powerhouse, establishing a three-dimensional finite element model of Unit #1 to investigate its dynamic characteristics and parametric sensitivity. Through modal and harmonic response analyses, the effects of key parameters—including the zone of surrounding rock, elastic modulus of surrounding rock, dynamic elastic modulus of concrete, and damping ratio—were systematically evaluated. Results indicate that an expanded surrounding rock zone reduces natural frequency and increases dynamic displacement, with a zone twice the span length offering an optimal balance between accuracy and computational efficiency. Increasing the elastic modulus of the surrounding rock raises the natural frequency and slightly reduces displacement, while having a limited impact on dynamic stress. The dynamic elastic modulus of concrete shows a square-root relationship with natural frequency and an inverse correlation with dynamic displacement. The damping ratio has negligible influence on natural frequency, dynamic displacement, and dynamic stress. These findings provide a theoretical basis and practical guidance for parameter selection in the dynamic analysis of underground powerhouse structures, enhancing the reliability of numerical simulations. Full article
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20 pages, 577 KB  
Review
Threats and Challenges Associated with Ammonia Transport via Pipeline Systems
by Tomasz Kuchta, Anna Wróblewska, Jadwiga Holewa-Rataj and Anna Król
Appl. Sci. 2025, 15(21), 11465; https://doi.org/10.3390/app152111465 (registering DOI) - 27 Oct 2025
Abstract
Ammonia, due to its favorable physicochemical properties, is considered an effective hydrogen carrier, enabling the storage of surplus energy generated from renewable sources. Large-scale implementation of this concept requires the safe transport of ammonia over long distances, commonly achieved through pipeline systems—a practice [...] Read more.
Ammonia, due to its favorable physicochemical properties, is considered an effective hydrogen carrier, enabling the storage of surplus energy generated from renewable sources. Large-scale implementation of this concept requires the safe transport of ammonia over long distances, commonly achieved through pipeline systems—a practice with global experience dating back to the 1960s. However, operational history demonstrates that failures in such infrastructures remain inevitable, often leading to severe environmental consequences. This article reviews both passive and active methods for preventing and mitigating incidents in ammonia pipeline systems. Passive measures include the assessment of material compatibility with ammonia and the designation of adequate buffer zones. Active methods focus on leak detection techniques, such as balance-based systems, acoustic monitoring, and ammonia-specific sensors. Additionally, the article highlights the potential environmental risks associated with ammonia release, emphasizing its contribution to the greenhouse effect, as well as its adverse impacts on soil, surface and groundwater, and human health. By integrating historical lessons with modern safety technologies, the article contributes to the development of reliable ammonia transport infrastructure for the hydrogen economy. Full article
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25 pages, 8861 KB  
Article
Best Practice in PCB Design with Experimental Validation of a 50 A-120 V Converter for Low-Voltage Propulsion and Energy Applications
by Matteo Villa, Simone Cosso, Alessandro Benevieri, Luis Vaccaro, Massimiliano Passalacqua, Simon Kissling, Mauro Carpita and Mario Marchesoni
Electronics 2025, 14(21), 4195; https://doi.org/10.3390/electronics14214195 (registering DOI) - 27 Oct 2025
Abstract
Low-voltage power converters in the 25–200 V range are increasingly employed in emerging applications such as hybrid electric vehicles (HEVs), photovoltaic systems with battery storage, and electric propulsion systems for recreational boats. In these contexts, 48 V battery systems have become standard, due [...] Read more.
Low-voltage power converters in the 25–200 V range are increasingly employed in emerging applications such as hybrid electric vehicles (HEVs), photovoltaic systems with battery storage, and electric propulsion systems for recreational boats. In these contexts, 48 V battery systems have become standard, due to safety considerations. Among various converter topologies, H-bridge configurations operating around 100 V DC are widely used in laboratory-scale prototyping. While MOSFETs are the preferred switching devices in this voltage range, due to their high efficiency and fast switching characteristics, they also introduce design challenges related to high current slew rates and associated overvoltage spikes caused by parasitic inductances in the PCB layout. These overvoltages, though modest in absolute terms, can be critical in low-voltage systems, due to the lower device ratings. This paper presents design strategies and layout best practice for a 120 V, 50 A H-bridge converter using 200 V rated MOSFETs. The effectiveness of various mitigation techniques—including the use of ceramic capacitors in parallel with film and electrolytic types, Schottky diodes across MOSFETs, and snubber circuits—is evaluated and experimentally validated on a dedicated prototype. The results highlight the critical role of PCB design in ensuring switching reliability and device protection in low-voltage converter systems. In addition, with the design solutions shown in this study, it was possible to obtain a voltage overshoot during switching of just 165 V with a 120 V DC-link voltage, which guarantees a sufficient safety margin for the MOSFET rated voltage. Full article
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38 pages, 36010 KB  
Review
Cobalt-Rich Fe-Mn Crusts in the Western Pacific Magellan Seamount Trail: Geochemistry and Chronostratigraphy
by Igor S. Peretyazhko, Elena A. Savina and Irina A. Pulyaeva
Geosciences 2025, 15(11), 411; https://doi.org/10.3390/geosciences15110411 (registering DOI) - 27 Oct 2025
Abstract
Synthesis of published and new data from the Govorov and Kocebu guyots provide geochemical and chronostratigraphic constraints on hydrogenetic cobalt-rich Fe-Mn crusts from the Western Pacific Magellan Seamount Trail (MST). The history of the crusts began about 65–60 Ma, when the relict layer [...] Read more.
Synthesis of published and new data from the Govorov and Kocebu guyots provide geochemical and chronostratigraphic constraints on hydrogenetic cobalt-rich Fe-Mn crusts from the Western Pacific Magellan Seamount Trail (MST). The history of the crusts began about 65–60 Ma, when the relict layer R was deposited in the Campanian—Maastrichtian and Late Paleocene along the shores of guyots. The growth of the old-generation crusts continued in the Late Paleocene—Early Eocene (Layer I-1) and in the Middle—Late Eocene (Layer I-2) in a shallow-water shelf environment. The younger layers formed in the Late Oligocene—Early Miocene (Layer I-2b), Miocene (Layer II), and Pliocene—Pleistocene (Layer III) at depths about the present sea level. The precipitation of Fe and Mn oxyhydroxides from seawater was interrupted by several times, with the longest gap from 38 to 26.5 Ma between the old (R, I-1, and I-2) and young (I-2b, II, and III) layers. Fe and Mn oxyhydroxides in the crusts were affected by two global events of phosphogenesis in the Pacific: Late Eocene—Early Oligocene, from 43 to 39 Ma (Layers R, I-1, I-2) and Late Oligocene—Early Miocene, from 27 to 21 Ma (Layer I-2b). The trace element patterns in different layers of the Co-rich Fe-Mn crusts are grouped using factor analysis of principal components (varimax raw) into four factors: (1) +(all REEs except Ce and La); (2) +(Ce, La, Ba, Mo, Sr, Pb); (3) +(Zr, Hf, Nb, Rb, As)/-Pb; (4) +(U, Th, Co, As, Sb, W)/-Y. The factor score diagrams highlight fields which are especially contrasting for Layers I-1, I-2, and II + III according to factors 2 and 4. Consistent REE and Y variations in Layers I-2b → II → III of the crust from Pallada Guyot correlate with gradual ocean deepening between the Late Oligocene—Early Miocene and Present when the MST guyots were submerging. Large variations in the trace element contents across coeval layers may be due to the hydrodynamics of currents on the guyot surfaces. Furthermore, the geochemistry of the crusts bears effects from repeated episodes of Cenozoic volcanism in the MST region of the Pacific Plate. Higher contents of Nb, Zr, As, Sb, and W in the younger layers II and III may result from large-scale volcanism, including Miocene eruptions of petit-spot volcanoes. Full article
(This article belongs to the Section Geochemistry)
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Article
Peer-Delivered Hepatitis C Testing and Health Screening Provided in a Community Pharmacy Setting: Proof of Concept
by Neha Sankla, Ray Cottington, Chris Cowie, Paul Huggett, Leila Reid, Stuart Smith, Sorcha Daly, Danny Morris, James Spear, Amanda Marsden, David Richards, Rachel Halford, Scott Walter and Jenny Scott
Pharmacy 2025, 13(6), 154; https://doi.org/10.3390/pharmacy13060154 (registering DOI) - 27 Oct 2025
Abstract
In order to reach and maintain hepatitis C virus (HCV) elimination goals, it is imperative to reach marginalized people who do not engage with traditional testing and treatment. Peer-led interventions are effective in engaging such individuals. Studies have demonstrated community pharmacy as a [...] Read more.
In order to reach and maintain hepatitis C virus (HCV) elimination goals, it is imperative to reach marginalized people who do not engage with traditional testing and treatment. Peer-led interventions are effective in engaging such individuals. Studies have demonstrated community pharmacy as a low-threshold setting for HCV testing, but pharmacy teams’ competing demands are a barrier to maximizing potential. This pilot project aimed to assess whether a pharmacy-based peer-led model of HCV testing was implementable, deliverable, able to engage marginalized people, and overcome pharmacy staff constraints. We implemented a peer-led HCV testing service in one community pharmacy in the Midlands, England, providing four focused phases of testing, totalling 198 h, over two years. In total, 591 tests for antibodies or RNA were undertaken, identifying 24 active infections. Subsequent phases retested 20%, 16%, and 11% of those tested in combined preceding phases. In response to feedback, phases 3 and 4 included health screening (blood pressure, cholesterol, diabetes, and nurse-performed Fibroscans®). We demonstrate engagement and the ability to identify and refer those with abnormal results to appropriate healthcare. This pilot shows that peer-led testing in the pharmacy setting can be implemented and warrants further scale up and evaluation. Full article
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