Search Results (114)

The stochastic and intermittent characteristics of renewable energy pose significant challenges to energy utilization and power system stability. The reversible solid oxide cell (RSOC), as an emerging multi-energy conversion technology, exhibits high efficiency in both electrolysis and power generation modes, offering a promising solution to renewable energy integration and energy supply issues. However, RSOC performance degrades over time, and its average efficiency decay rate directly influences capacity investment decisions and day-ahead scheduling strategies. To address this, a comprehensive energy system model considering RSOC capacity is developed, with a detailed representation of each subsystem. A bi-level optimization framework is then proposed, where the upper level minimizes system investment and operation costs, and the lower level optimizes day-ahead scheduling costs. The model explicitly accounts for RSOC efficiency degradation and lifetime attenuation. Particle swarm optimization is applied to determine the optimal capacity configuration. Case studies demonstrate that the proposed model enhances system economics, promotes multi-energy complementarity, and prolongs RSOC lifetime, providing theoretical and technical support for the planning and operation of integrated energy systems with RSOC. Full article

In this study, commercial Ospray-2507 super-duplex stainless steel powder was investigated for the first time as a potential metal support material for solid oxide cells. Initially, metal supports were fabricated and processed in air using various sintering profiles, followed by comprehensive mechanical, structural and electrochemical characterization. The optimal sintering condition was identified as 900 °C for 5 h. Subsequently, sintering under a H₂ atmosphere was explored, and its effects on the microstructural and functional properties of the metal supports were systematically to assessed to evaluate the influence of the sintering atmosphere on material performance. Although X-ray diffraction patterns showed no phase changes between the two sintering atmospheres, notable improvements were observed in mechanical, electrochemical, and microstructural properties under H₂ sintering. XPS spectra reveal that both air- and hydrogen-treated surfaces remain rich in chromium (Cr) and Manganese (Mn), which together dominate the surface and consequently attenuate the signal from the underlying iron. The thickness of the Cr- and Mn-based oxide layer decreases when sintering MS in H₂ atmosphere. Specifically, mechanical strength, as measured by three-point bending tests, increased by a factor of 12.5, and hardness rose from 500.3 to 523.5 HV. Furthermore, electrical conductivity also improved significantly, exhibiting an approximately 2.3–2.4 fold increase under H₂-sintered conditions. Full article

Water electrolysis is a key technology for sustainable hydrogen production and a cornerstone of future low-carbon energy systems. However, large-scale deployment is constrained not only by efficiency and cost, but increasingly by the sustainability and availability of materials used in electrocatalysts and membranes. This review provides a materials-centric assessment of state-of-the-art and emerging electrocatalysts for alkaline (AEL), proton exchange membrane (PEM), and solid oxide electrolysis (SOEC) technologies, emphasizing the interdependence of performance, durability, cost, and sustainability. Electrocatalyst activity and stability are linked to cell- and stack-level efficiency, energy demand, and the levelized cost of hydrogen. Life cycle assessment (LCA) and resource criticality analyses are integrated to quantify environmental impacts, supply risks, and recycling potential of key materials, including platinum group metals, nickel, rare earth elements, and ceramic oxides. Particular attention is given to recycling and circularity strategies, which are essential for mitigating material scarcity and reducing upstream emissions, especially in PEM electrolyzers. Emerging catalyst concepts such as single-atom catalysts, high-entropy alloys, and noble-metal-free systems are discussed as promising pathways to reduce critical material dependence. The review concludes by highlighting the need for integrated material–technology–system approaches to enable efficient, scalable, and truly sustainable hydrogen production. Full article

This study examines the impact of photovoltaic (PV) modeling fidelity utilizing single-diode (SDM), double-diode (DDM), and triple-diode (TDM) representations on the precision of hydrogen production (H₂P) estimates when integrated with various electrolyzer technologies, specifically proton exchange membrane (PEM), alkaline (AEL), and solid oxide electrolysis cells (SOECs). Precise evaluation of solar-powered green hydrogen (H₂) systems necessitated a dependable estimate of PV power under authentic working circumstances. Hourly site-specific irradiance and ambient temperature (T_a) data for Riyadh, Saudi Arabia, were used to calculate PV power outputs, which were then sent to physically based electrolyzer models regulated by electrochemical voltage relationships and Faraday’s law. The findings indicate that while all PV models display the same seasonal patterns, SDM somewhat overestimates yearly PV energy in comparison to DDM and TDM, with relative errors around 0.03%. These discrepancies somewhat affect H₂ yield estimations but do not change the relative ranking of electrolyzer technology. Among the assessed options, SOEC consistently produced the highest H₂ output, generating approximately 21.8% more H₂ than PEM and 9.1% more than AEL, with annual yields of 62.46–62.47 g for PEM, 69.70–69.71 g for AEL, and 76.04–76.05 g for SOEC across the SDM, DDM, and TDM frameworks under equivalent solar power inputs. The findings indicate that the selection of electrolyzer technology significantly impacts H₂P more than the choice of a PV model, while high-fidelity PV modeling is crucial for a physically realistic and precise system-level assessment of integrated PV-H₂ energy systems. Full article

This work presents the development and validation of a 1D finite-volume model for the simulation of planar solid oxide cells (SOCs), developed for integration in more complex systems and process simulations. The model allows to investigate the temperature, composition, and current density profiles along the channel. In this work, the Fick’s equations typically used to calculate the concentration overpotential due to H₂ and H₂O diffusion in the electrode are improved compared to 1D SOC models available in the literature. In particular, the approximate analytical solution of the dusty gas model (DGM) equations allows for a better definition of H₂ and H₂O mixture diffusion coefficients, which are relevant, for instance, in the case of solid oxide fuel cells (SOFCs) fed with reformate gas mixtures. Differently from other 1D models available in the literature, the model developed is validated using experimental SOFC polarization curves covering a wide range of operating conditions in terms of molar fraction of H₂ (21–93%) and H₂O (7–50%) in the fuel, temperature (550–750 °C), and fuel utilization factor (exceeding 90%), demonstrating that 1D SOC models retain a good description of the physical processes occurring within the cell. While this work focuses on a co-flow SOFC configuration, the model can simulate a counter-flow configuration and electrolysis operation without modifying the model equations. Full article

ABO₃ perovskite oxides are a versatile class of materials whose surfaces and interfaces play essential roles in sustainable energy technologies, including catalysis, solid oxide fuel and electrolysis cells, thermoelectrics, and energy-relevant oxide electronics. The interplay between point defects and surface reconstructions strongly affects interfacial stability, charge transport, and catalytic activity under operating conditions. This review summarizes recent progress in understanding how oxygen vacancies, cation nonstoichiometry, and electronic defects couple to atomic-scale surface rearrangements in representative perovskite systems. We first revisit Tasker’s classification of ionic surfaces and clarify how defect chemistry provides compensation mechanisms that stabilize otherwise polar or metastable terminations. We then discuss experimental and theoretical insights into defect-mediated reconstructions on perovskite surfaces and how they influence the performance of energy conversion devices. Finally, we conclude with a perspective on design strategies that leverage defect engineering and surface control to enhance functionality in energy applications, aiming to connect fundamental surface science with practical materials solutions for the transition to sustainable energy. Full article

The growing necessity to decarbonize the global energy system has positioned green hydrogen as a central enabler of a secure and sustainable future. Among various production paths, water electrolysis has emerged as the most developed route for generating high purity hydrogen from renewable power. The paper includes a broad and comparative overview of four leading electrolyzer technologies: Alkaline Water Electrolyzers (AWE), Proton Exchange Membrane Electrolyzers (PEM), Solid Oxide Electrolyzer Cells (SOEC), and new Anion Exchange Membrane Electrolyzers (AEM). Key technical parameters, operating principles, system level properties, and innovation trends are discussed, with a particular emphasis on their deployment and application in different regions of Canada. The study also highlights Canada’s growing role in the global hydrogen economy, supported by vast renewable resources, a favorable policy environment, and a dense network of research facilities and technology hubs. By combining comparative insights and tying them to national energy strategy, this survey establishes the agenda for driving adoption and innovation in electrolyzers in Canada’s clean energy shift. Full article

This scoping review evaluates the literature on options for planar solid oxide cell (SOC) performance optimization, with a focus on applied fabrication methods and design enhancements. Literature identification, selection, and charting followed PRISMA-ScR guidelines to ensure transparency, reproducibility, and comprehensive coverage, while also enabling the identification of research gaps beyond the scope of narrative reviews. We analyze the influence of fabrication methods on cell and component characteristics and evaluate optimization approaches identified in the literature. Subsequent discussion explores how design innovations intersect with fabrication choices. The surveyed literature reveals a broad spectrum of manufacturing methods, including conventional processes, thin-film deposition, infiltration, and additive manufacturing. Our critical assessment of scalability revealed that reduction in operating temperature, improving robustness, and electrochemical performance are the main optimization objectives for SOC designs. Regarding production cost, production scale-up, and process control, inkjet, electrophoretic deposition, and solution aerosol thermolysis appeared to be promising manufacturing methods for design enhancements. By combining the PRISMA-ScR evidence map with a synthesis focused on scalability and process control, this review provides practical insights and a strong foundation for future SOC research and scale-up, also for evolving the field of proton-conducting cells. Full article

This study presents a novel solid oxide electrolysis cell (SOEC) design with variable channel widths to optimize thermal management and electrochemical performance for enhanced hydrogen production. Using high-fidelity computational modeling in COMSOL Multiphysics 6.1, five distinct channel width configurations were analyzed, with a baseline model validated against experimental data. The simulations showed that modifying the channel geometry, particularly in Scenario 2, significantly improved hydrogen production rates by 6.8% to 29% compared to a uniform channel design, with the effect becoming more pronounced at higher voltages. The performance enhancement was found to be primarily due to improved fluid velocity regulation, which increased reactant residence time and enhanced mass transport, rather than a significant thermal effect, as temperature distribution remained largely uniform across the cell. Additionally, the inclusion of a dedicated heat transfer channel was shown to improve current density and overall efficiency, particularly at lower voltages. While a small increase in voltage raised internal cell pressure, the variable-width designs, especially those with widening channels, led to greater hydrogen output, albeit with a corresponding increase in system energy consumption due to higher pressure. Overall, the findings demonstrate that strategically designed variable-width channels offer a promising approach to optimizing SOEC performance for industrial-scale hydrogen production. Full article

The article presents experimental data on the electrochemical oxidation of vanadium-bearing ore with the aim of increasing the efficiency of vanadium extraction during subsequent hydrometallurgical processing. Three different charge compositions were studied during the preliminary oxidative roasting stage, differing in the type of oxidizers used: calcined soda, sodium chloride, and their mixture in a mass ratio of 9:1. Electrochemical oxidation was carried out in a sulfuric acid medium using a membrane electrolysis cell equipped with an MK-40 type diaphragm. Experimental studies were conducted by varying key technological parameters: H₂SO₄ concentration (5–15%), solid-to-liquid phase ratio (1:2–1:5), temperature (25–85 °C), process duration (0.5–3 h), and current density (100–1000 A/m²). It was found that preliminary roasting promotes the conversion of vanadium into higher oxidation states, predominantly V⁵⁺, which significantly increases its solubility during subsequent electrochemical treatment. For the first time, the kinetic patterns of electrochemical vanadium leaching were identified, as well as the limiting mechanism of the process, associated with the formation of poorly soluble oxide films on the ore surface. Optimization of the electrochemical oxidation parameters allowed us to achieve vanadium extraction into solution up to 92%. Full article

Solid oxide electrolysis cells (SOEC) system has potential to offer an efficient green hydrogen production technology. However, the significant cost of this technology is related to the high operating temperatures, materials and thermal management including the waste heat. Recovering the waste heat can be conducted through techniques to reduce the overall energy consumption. This approach aims to improve accuracy and efficiency by recovering and reusing the heat that would otherwise be lost. In this paper, thermal energy models are proposed based on waste heat recovery methodologies to utilize the heat from outlet fluids within the SOEC system. The mathematical methods for calculating thermal energy and energy transfer in SOEC systems have involved the principles of heat transfer. To address this, different simplified thermal models are developed in Simulink Matlab R2025b. The obtained results for estimating proper thermal energy for heating incoming fluids and recycled heat are discussed and compared to determine the efficient and potential thermal model for improvement the waste heat recovery. Full article

Solid oxide electrolysis cells (SOECs) have emerged as a promising technology for efficient energy storage and CO₂ utilization via H₂O–CO₂ co-electrolysis. While most previous studies focused on planar or tubular configurations, this work investigated a novel flat, tubular SOEC design using a comprehensive 3D multi-physics model developed in COMSOL Multiphysics 5.6. This model integrates charge transfer, gas flow, heat transfer, chemical/electrochemical reactions, and structural mechanics to analyze operational behavior and thermo-mechanical stress under different voltages and pressures. Simulation results indicate that increasing operating voltage leads to significant temperature and current density inhomogeneity. Furthermore, elevated pressure improves electrochemical performance, possibly due to increased reactant concentrations and reduced mass transfer limitations; however, it also increases temperature gradients and the maximum first principal stress. These findings underscore that the design and optimization of flat tubular SOECs in H₂O–CO₂ co-electrolysis should take the trade-off between performance and durability into consideration. Full article

Solid oxide electrolysis cells (SOECs) are emerging as a promising technology for high-efficiency and environmentally friendly hydrogen production. While laboratory-scale experiments and physics-based simulations have significantly advanced SOEC research, there remains a need for faster, scalable, and cost-effective methods to predict electrochemical performance. This study explores the feasibility of using machine learning (ML) techniques to model the performance of SOECs with the material configuration LSM-YSZ/YSZ/Ni-YSZ. A dataset of 593 records (from 31 IV curves) was compiled from 12 peer-reviewed sources and used to train and evaluate four ML algorithms: SVR, ANN, XGBoost, and Random Forest. Among these, XGBoost achieved the highest accuracy, with an R² of 98.39% for cell voltage prediction and 98.10% for IV curve interpolation test under typical conditions. Extrapolation tests revealed the model’s limitations in generalizing beyond the bounds of the training data, emphasizing the importance of comprehensive data coverage. Overall, the results confirm that ML models, particularly XGBoost, can serve as accurate and efficient tools for predicting SOEC electrochemical behavior when applied with appropriate data coverage and guided by materials science concepts. Full article

The production of hydrogen through water electrolysis has emerged as a promising alternative to decarbonizing the energy sector, especially when integrated with renewable energy sources. Among the key operational parameters that affect electrolysis performance, temperature and current density play a critical role in determining the energy efficiency, hydrogen yield and durability of the system. The study presents a Systematic Literature Review (SLR) that includes peer-reviewed publications from 2018 to 2025, focusing on the effects of temperature and current density across a variety of electrolysis technologies, including alkaline (AEL), proton exchange membrane (PEMEL), and solid oxide electrolysis cells (SOEC). A total of seven high-quality studies were selected following the PRISMA 2020 framework. The results show that high temperatures improve electrochemical kinetics and reduce excess potential, especially in PEM and SOEC systems, but can also accelerate component degradation. Higher current densities increase hydrogen production rates but lead to lower Faradaic efficiency and increased material stress. The optimal operating range was identified for each type of electrolysis, with PEMEL performing best at 60–80 °C and 500–1000 mA/cm², and SOEC at >750 °C. In addition, system-level studies emphasize the importance of integrating hydrogen production with flexible generation and storage infrastructure. The review highlights several research gaps, including the need for dynamic modeling, multi-parameter control strategies, and techno-economic assessments. These findings provide a basic understanding for optimizing hydrogen electrolysis systems in low-carbon energy architectures. Full article

Solid oxide electrolysis (SOEL) has emerged as a promising technology for efficient hydrogen production. Its main advantages lie in the high operating temperatures, which enhance thermodynamic efficiency, and in the ability to supply part of the required energy in the form of heat. Nevertheless, improving the long-term durability of stack materials remains a key challenge. Thermal energy can be supplied by dedicated integration with different industrial processes, where the main challenge lies in the elevated stack operating temperature (700–900 °C). This review provides a comprehensive analysis of the integration of solid oxide electrolysis cells (SOECs) into different industrial applications. Main processes cover methanol production, methane production, Power-to-Hydrogen systems, or the use of reversible solid oxide electrolysis cell (rSOEC) stacks that can operate in both electrolysis and fuel cell mode. The potential of co-electrolysis to increase process flexibility and broaden application areas is also analyzed. The aim is to provide a comprehensive analysis of the integration strategies, identify the main technical and economic challenges, and highlight recent developments and future trends in the field. A detailed comparison assessment of the different processes is being discussed in terms of electrical and thermal efficiencies and operating parameters, as well as Key Performance Indicators (KPIs) for each process. Technical-economic challenges that are currently a barrier to their implementation in industry are also analyzed. Full article