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15 pages, 5060 KB  
Article
Tubular Wax Projections on Plant Epidermal Surfaces as Anti-Adhesive Coatings for Insects: A Numerical Modeling Approach
by Stanislav N. Gorb, Elena V. Gorb and Alexander E. Filippov
Surfaces 2026, 9(2), 37; https://doi.org/10.3390/surfaces9020037 (registering DOI) - 8 Apr 2026
Abstract
Three-dimensional (3D) epicuticular wax coverage on plant surfaces contributes to multifunctional surface properties, such as enhanced water repellence, reduced pathogen adherence, modified optical properties, and reduced insect adhesion. The diversity in wax projection morphology, size, abundance, and spatial arrangement among plant species results [...] Read more.
Three-dimensional (3D) epicuticular wax coverage on plant surfaces contributes to multifunctional surface properties, such as enhanced water repellence, reduced pathogen adherence, modified optical properties, and reduced insect adhesion. The diversity in wax projection morphology, size, abundance, and spatial arrangement among plant species results in a broad spectrum of anti-adhesive effects, reflecting both phylogenetic history and ecological function. This study presents a numerical model consisting of 3D tubular-shaped structures randomly deposited on a substrate and forming a highly porous layer. The simulations based on this model demonstrate a strong reduction in adhesion to the contacting insect adhesive pad. It is found that a structure formed by sufficiently long tubes, where the length is enough to support the tubes in space and build a porous 3D structure with a very low density, at relatively weak attraction to the underlying substrate, leads to the weakest adhesion. The model is constructed on the basis of our recent works combining discrete and continuous approaches in biological modeling. It mainly exploits the technique of the movable digital automata, allowing modeling of numerous numerically elastic cylinders that can be moved in 3D space, elastically collide with one another and with boundaries, and build self-consistent surface structures, which can be used to mimic nano- or microscale surface coverages of real plants. Full article
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17 pages, 2463 KB  
Article
Optimization of Parameters of Block-Shaped Support Tooth Structure Using Orthogonal Experimental Design in Laser Powder Bed Fusion
by Zhongli Li, Guosheng Fei, Daijian Wu, Xiaoci Chen, Yingyan Yu, Zuofa Liu, Jiansheng Zhang and Jie Zhou
Materials 2026, 19(8), 1480; https://doi.org/10.3390/ma19081480 (registering DOI) - 8 Apr 2026
Abstract
To address the challenges associated with laser powder bed fusion (LPBF) of overhanging structures—namely warping deformation, powder adhesion, and inadequate forming accuracy—this study investigates the optimization of the support–part contact interface using Inconel 625 alloy. The objective is to achieve high-quality part formation [...] Read more.
To address the challenges associated with laser powder bed fusion (LPBF) of overhanging structures—namely warping deformation, powder adhesion, and inadequate forming accuracy—this study investigates the optimization of the support–part contact interface using Inconel 625 alloy. The objective is to achieve high-quality part formation with minimal support structures. A Taguchi experimental design was employed to systematically evaluate the effects of key block support parameters—tooth height, tooth top length, tooth base length, and tooth base spacing—on the forming performance of overhanging structures, with forming accuracy and support removability as the optimization targets. The results reveal that tooth top length significantly influences both the forming accuracy of overhanging specimens and the ease of support removal. Specifically, an increase in tooth top length leads to a rapid reduction in specimen deformation, but simultaneously increases the difficulty of support removal. When the tooth top length was set to 0.1 mm, all overhanging specimens failed to form successfully. Tooth base length also plays a critical role in support removability, with removal difficulty initially decreasing and then stabilizing as the tooth base length increases. Based on the trade-off between forming quality and support removability, the optimal parameter combination was identified as: tooth height of 0.4 mm, tooth top length of 0.7 mm, tooth base length of 1.0 mm, and tooth base spacing of 0.3 mm. A validation experiment conducted using this optimized configuration demonstrated good forming accuracy in the support contact area, with a deformation value of −0.208 mm, confirming the effectiveness and reliability of the proposed parameters. This study not only provides a theoretical foundation for the optimal design of block supports in LPBF but also offers experimental data and practical guidance for selecting support parameters in the fabrication of overhanging structures. Full article
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26 pages, 7110 KB  
Article
Research on an Automatic Detection Method for Response Keypoints of Three-Dimensional Targets in Directional Borehole Radar Profiles
by Xiaosong Tang, Maoxuan Xu, Feng Yang, Jialin Liu, Suping Peng and Xu Qiao
Remote Sens. 2026, 18(7), 1102; https://doi.org/10.3390/rs18071102 - 7 Apr 2026
Abstract
During the interpretation of Borehole Radar (BHR) B-scan profiles, the accurate determination of the azimuth of geological targets in three-dimensional space is a critical issue for achieving precise anomaly localization and spatial structure inversion. However, existing directional BHR anomaly localization methods exhibit limited [...] Read more.
During the interpretation of Borehole Radar (BHR) B-scan profiles, the accurate determination of the azimuth of geological targets in three-dimensional space is a critical issue for achieving precise anomaly localization and spatial structure inversion. However, existing directional BHR anomaly localization methods exhibit limited intelligence, insufficient adaptability to multi-site data, and weak generalization capability, rendering them inadequate for engineering applications under complex geological conditions. To address these challenges, a robust deep learning model, termed BSS-Pose-BHR, is developed based on YOLOv11n-pose for keypoint detection in directional BHR profiles. The model incorporates three key optimizations: Bi-Level Routing Attention (BRA) replaces Multi-Head Self-Attention (MHSA) in the backbone to improve computational efficiency; Conv_SAMWS enhances keypoint-related feature weighting in the backbone and neck; and Spatial and Channel Reconstruction Convolution (SCConv) is integrated into the detection head to reduce redundancy and strengthen local feature extraction, thereby improving suitability for keypoint detection tasks. In addition, a three-dimensional electromagnetic model of limestone containing a certain density of clay particles is established to construct a simulation dataset. On the simulated test set, compared with current mainstream deep learning approaches and conventional directional borehole radar anomaly localization algorithms, BSS-Pose-BHR achieves superior performance, with an mAP50(B) of 0.9686, an mAP50–95(B) of 0.7712, an mAP50(P) of 0.9951, and an mAP50–95(P) of 0.9952. Ablation experiments demonstrate that each proposed module contributes significantly to performance improvement. Compared with the baseline, BSS-Pose-BHR improves mAP50(B) by 5.39% and mAP50(P) by 0.86%, while increasing model weight by only 1.05 MB, thereby achieving a reasonable trade-off between detection accuracy and complexity. Furthermore, indoor physical model experiments validate the effectiveness of the method on measured data. Robustness experiments under different Peak Signal-to-Noise Ratio (PSNR) conditions and varying missing-trace rates indicate that BSS-Pose-BHR maintains high detection accuracy under moderate noise and data loss, demonstrating strong engineering applicability and practical value. Full article
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26 pages, 4492 KB  
Article
Flood Risk Assessment Considering the Spatial and Temporal Characteristics of Disaster-Causing Factors
by Shichao Xu, Da Liu, Hui Chen, Guangling Huang, Changhong Hong and Lingfang Chen
Sustainability 2026, 18(7), 3646; https://doi.org/10.3390/su18073646 - 7 Apr 2026
Abstract
Refined urban flood risk assessment serves as a fundamental safeguard for urban sustainability. However, most studies based on scenario analysis method tend to rely on a single risk evaluation criterion, with limited consideration of applicability differences arising from underlying computational principles. Furthermore, as [...] Read more.
Refined urban flood risk assessment serves as a fundamental safeguard for urban sustainability. However, most studies based on scenario analysis method tend to rely on a single risk evaluation criterion, with limited consideration of applicability differences arising from underlying computational principles. Furthermore, as flood events are inherently dynamic spatial–temporal processes, most studies often overlook the three-dimensional characteristics of flood risk, particularly the connectivity of risk in physically adjacent spaces. To address these issues, this paper proposes a comprehensive flood risk assessment framework that integrates the spatial–temporal characteristics of disaster-causing factors. An improved analysis method for grid-scale flood assessment is proposed based on the comprehensive mechanical analysis method and the drowning factor. In addition, a quantitative approach for characterizing the spatial aggregation of urban flood risk is established using risk thresholds and aggregation area thresholds. These methods are then integrated through a combination weighting–cluster analysis framework for comprehensive flood risk assessment. The results show that the improved analysis method can better reflect the change in risk of flow velocity and water depth combined. Spatiotemporally, the Yinshan Road and western section of the Dongzhong Road, exhibiting high localized risk, moderate overall risk, high risk on the time scale and high spatial agglomeration status, are comprehensively assessed as extremely high-risk flooded zones. The proposed framework effectively characterizes the spatial–temporal distribution of disaster-causing factors, providing a scientific basis for disaster prevention and contributing to urban sustainability. Full article
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23 pages, 3097 KB  
Article
Preliminary Neutronic Design and Thermal-Hydraulic Feasibility Analysis for a Liquid-Solid Space Reactor Using Cross-Shaped Spiral Fuel
by Zhichao Qiu, Kun Zhuang, Xiaoyu Wang, Yong Gao, Yun Cao, Daping Liu, Jingen Chen and Sipeng Wang
Energies 2026, 19(7), 1811; https://doi.org/10.3390/en19071811 - 7 Apr 2026
Abstract
As the key technology of space exploration, space power has been a major area of international research focus. A lot of research work has been carried out around the world for the space nuclear reactor using the heat pipe, liquid metal and gas [...] Read more.
As the key technology of space exploration, space power has been a major area of international research focus. A lot of research work has been carried out around the world for the space nuclear reactor using the heat pipe, liquid metal and gas cooling methods. With the development of molten salt reactor in the Generation IV reactor system, molten salt dissolving fissile material and acting as a coolant at the same time has become a new cooling scheme, which provides new ideas for the design of space nuclear reactors. In this study, a novel reactor, the liquid-solid dual-fuel space nuclear reactor (LSSNR) was preliminarily proposed, combining the molten salt fuel and cross-shaped spiral solid fuel to achieve the design goals of 30-year lifetime and an active core weight of less than 200 kg. Monte Carlo neutron transport code OpenMC based on ENDF/B-VII.1 library was employed for neutronics design in the aspect of fuel type, cladding material, reflector material and the spectral shift absorber. Then, the thickness of the control drum absorber was optimized to meet the requirement of the sufficient shutdown margin, lower solid fuel enrichment, and 30-effective-full power-years (EFPY) operation lifetime. Finally, UC solid fuel with U-235 enrichment of 80.98 wt.% and B4C thickness of 0.75 cm were adopted in LSSNR, and BeO was adopted as the reflector and the matrix material of the control drum. A spectral shift absorber Gd2O3 was used to avoid the subcritical LSSNR returning to criticality in a launch accident. The keff with the control drum in the innermost position is 0.954949, and the keff reaches 1.00592 after 30 EFPY of operation. The total mass of the active core is 158.11 kg. In addition, the thermal-hydraulic feasibility of LSSNR using cross-shaped spiral fuel was analyzed based on a 4/61 reactor core model. The structure of cross-shaped spiral fuel achieves enhanced heat transfer by generating turbulence, which leads to a uniform temperature distribution of the coolant flow field and reduces local temperature peaks. Based on the LSSNR scheme, some neutronic characteristics were analyzed. Results demonstrate that the LSSNR has strongly negative reactivity coefficients due to the thermal expansion of liquid fuel, and the fission gas-induced pressure meets safety requirements. One hundred years after the end of core life, the total radioactivity of reactor core is reduced by 99% and is 7.1305 Ci. Full article
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13 pages, 2283 KB  
Article
Study on RF Parameter Extraction Method for Novel Heterogeneous Integrated GaN Schottky Rectifiers Based on Hierarchical Reinforcement Learning
by Yi Wei, Li Huang, Ce Wang, Xiong Yin and Ce Wang
Electronics 2026, 15(7), 1537; https://doi.org/10.3390/electronics15071537 - 7 Apr 2026
Abstract
This study presents a heterogeneous integration micro-assembly process and circuit board packaging solution for GaN Schottky Barrier Diode (SBD) rectifiers, and innovatively constructs a hierarchical reinforcement learning strategy for optimizing SBD RF parameters. By establishing an optimization framework with the goal of efficiency [...] Read more.
This study presents a heterogeneous integration micro-assembly process and circuit board packaging solution for GaN Schottky Barrier Diode (SBD) rectifiers, and innovatively constructs a hierarchical reinforcement learning strategy for optimizing SBD RF parameters. By establishing an optimization framework with the goal of efficiency in the load-input power two-dimensional space, a dual-layer optimization mechanism is employed: the high-level strategy dynamically selects optimization regions and parameter combinations, while the low-level strategy implements specific parameter adjustments. This approach effectively addresses the challenges of device parameter modeling and circuit design. Experimental data shows that the efficiency error for the SBD1 rectifier remains stable within 2%, and the average error for SBD2 is reduced to 1.5%. This method enables efficient and accurate optimization of RF parameters, providing a reliable technical pathway for the engineering application of Wireless Power Transmission systems. Full article
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30 pages, 2308 KB  
Article
Early Detection of Virtual Machine Failures in Cloud Computing Using Quantum-Enhanced Support Vector Machine
by Bhargavi Krishnamurthy, Saikat Das and Sajjan G. Shiva
Mathematics 2026, 14(7), 1229; https://doi.org/10.3390/math14071229 - 7 Apr 2026
Abstract
Cloud computing is one of the essential computing platforms for modern enterprises. A total of 84 percent of large businesses use cloud computing services in 2025 to enable remote working and higher flexibility of operation with reduction in the cost of operation. Cloud [...] Read more.
Cloud computing is one of the essential computing platforms for modern enterprises. A total of 84 percent of large businesses use cloud computing services in 2025 to enable remote working and higher flexibility of operation with reduction in the cost of operation. Cloud environments are dynamic and multitenant, often demanding high computational resources for real-time processing. However, the cloud system’s behavior is subjected to various kinds of anomalies in which patterns of data deviate from the normal traffic. The varieties of anomalies that exist are performance anomalies, security anomalies, resource anomalies, and network anomalies. These anomalies disrupt the normal operation of cloud systems by increasing the latency, reducing throughput, frequently violating service level agreements (SLAs), and experiencing the failure of virtual machines. Among all anomalies, virtual machine failures are one of the potential anomalies in which the normal operation of the virtual machine is interrupted, resulting in the degradation of services. Virtual machine failure happens because of resource exhaustion, malware access, packet loss, Distributed Denial of Service attacks, etc. Hence, there is a need to detect the chances of virtual machine failures and prevent it through proactive measures. Traditional machine learning techniques often struggle with high-dimensional data and nonlinear correlations, ending up with poor real-time adaptation. Hence, quantum machine learning is found to be a promising solution which effectively deals with combinatorially complex and high-dimensional data. In this paper, a novel quantum-enhanced support vector machine (QSVM) is designed as an optimized binary classifier which combines the principles of both quantum computing and support vector machine. It encodes the classical data into quantum states. Feature mapping is performed to transform the data into the high-dimensional form of Hilbert space. Quantum kernel evaluation is performed to evaluate similarities. Through effective optimization, optimal hyperplanes are designed to detect the anomalous behavior of virtual machines. This results in the exponential speed-up of operation and prevents the local minima through entanglement and superposition operation. The performance of the proposed QSVM is analyzed using the QuCloudSim 1.0 simulator and further validated using expected value analysis methodology. Full article
24 pages, 4332 KB  
Article
Depth-Aware Adversarial Domain Adaptation for Cross-Domain Remote Sensing Segmentation
by Lulu Niu, Xiaoxuan Liu, Enze Zhu, Yidan Zhang, Hanru Shi, Xiaohe Li, Hong Wang, Jie Jia and Lei Wang
Remote Sens. 2026, 18(7), 1099; https://doi.org/10.3390/rs18071099 - 7 Apr 2026
Abstract
As a key task in remote sensing analysis, semantic segmentation of remote sensing images (RSI) underpins many practical applications. Despite its importance, obtaining dense pixel-wise annotations remains labor-intensive and time-consuming. Unsupervised domain adaptation (UDA) offers a promising solution by utilizing knowledge from labeled [...] Read more.
As a key task in remote sensing analysis, semantic segmentation of remote sensing images (RSI) underpins many practical applications. Despite its importance, obtaining dense pixel-wise annotations remains labor-intensive and time-consuming. Unsupervised domain adaptation (UDA) offers a promising solution by utilizing knowledge from labeled source domains for unlabeled target domains, yet its effectiveness is often compromised by significant distribution shifts arising from variations in imaging conditions. To address this challenge, we propose a depth-aware adaptation network (DAAN), a novel two-branch network that explicitly leverages complementary depth information from a digital surface model (DSM) to enhance cross-domain remote sensing segmentation. Unlike conventional UDA methods that primarily focus on semantic features, DAAN incorporates depth data to build a more generalized feature space. This network introduces three key components: an adaptive feature aggregator (AFA) for progressive semantic-depth feature fusion, a gated prediction selection unit (GPSU) that selectively integrates predictions to mitigate the impact of noisy depth measurements, and misalignment-focused residual refinement (MFRR) module that emphasizes poorly aligned target regions during training. Experiments on the ISPRS and GAMUS datasets demonstrate the effectiveness of the proposed method. In particular, DAAN achieves an mIoU of 50.53% and an F1 score of 65.75% for cross-domain segmentation on ISPRS to GAMUS, outperforming models without depth information by 9.17% and 8.99%, respectively. These results demonstrate the advantage of integrating auxiliary geometric information to improve model generalization on unlabeled remote sensing datasets, contributing to higher mapping accuracy, more reliable automated analysis, and enhanced decision-making support. Full article
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14 pages, 364 KB  
Article
Low-Level Helicopter Flights: Safety and Operational Specificity
by Alex de Voogt, Teck Chen Koh and Yi Lu
Safety 2026, 12(2), 48; https://doi.org/10.3390/safety12020048 - 7 Apr 2026
Abstract
Low-level flight or maneuvering defines a flight phase that is particularly common and, in some cases, central to helicopter operations, but brings several safety concerns. At low altitude, helicopters are more susceptible to collisions with objects, while there is also limited time and [...] Read more.
Low-level flight or maneuvering defines a flight phase that is particularly common and, in some cases, central to helicopter operations, but brings several safety concerns. At low altitude, helicopters are more susceptible to collisions with objects, while there is also limited time and space in which to perform an emergency landing. A total of 403 helicopter accidents in the low-level flight phase that occurred between 1 January 2009 and 31 December 2022 in the US were analyzed for their most common causes and differentiated based on the type of flight operation to gain insight into low-level flight accidents. It is shown that, for low-level flights, the proportion of fatal accidents in flights conducted under Federal Aviation Regulations Part 91, General Aviation, is 30%, but in flights conducted under Part 137, aerial application or agricultural flights, only 12%. Logistic regression analysis shows that while controlling for other factors, the proportion of fatal accidents was significantly higher in Part 91 operations. Flight experience measured as total flight hours was not a significant factor for estimating fatality. It is recommended that low-level helicopter training includes low-altitude autorotations in simulators to optimize the mitigating effect of this emergency procedure in this flight phase with a specific focus on Part 91 operations. Full article
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34 pages, 1260 KB  
Article
Conformally Compactified Minkowski Space: A Re-Examination with Emphasis on the Double Cover and Conformal Infinity
by Arkadiusz Jadczyk
Mathematics 2026, 14(7), 1228; https://doi.org/10.3390/math14071228 (registering DOI) - 7 Apr 2026
Abstract
This paper presents a detailed re-examination of the conformalcompactification M¯ of Minkowski space M, constructed as the projective null cone of the six-dimensional space R4,2. We provide an explicit and basis-independent formulation, emphasizing geometric clarity. A central [...] Read more.
This paper presents a detailed re-examination of the conformalcompactification M¯ of Minkowski space M, constructed as the projective null cone of the six-dimensional space R4,2. We provide an explicit and basis-independent formulation, emphasizing geometric clarity. A central result is the explicit identification of M¯ with the unitary group U(2) via a diffeomorphism, offering a clear matrix representation for points in the compactified space. We then systematically construct and analyze the action of the full conformal group O(4,2) and its connected component SO0(4,2) on this manifold. A key contribution is the detailed study of the double cover, M˜, which is shown to be diffeomorphic to S3×S1. This construction resolves the non-effectiveness of the SO(4,2) action on M¯, yielding an effective group action on the covering space. A significant portion of our analysis is devoted to a precise and novel geometric characterization of the conformal infinity. Moving beyond the often-misrepresented “double cone” description, we demonstrate that the infinity of the double cover, M˜, is a squeezed torus (specifically, a horn cyclide), while the simple infinity, M¯, is a needle cyclide. We provide explicit parametrizations and graphical representations of these structures. Finally, we explore the embedding of five-dimensional constant-curvature spaces, whose boundary is the compactified Minkowski space. The paper aims to clarify long-standing misconceptions in the literature and provides a robust, coordinate-free geometric foundation for conformal compactification, with potential implications for cosmology and conformal field theory. Full article
(This article belongs to the Section E4: Mathematical Physics)
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19 pages, 329 KB  
Article
Using International Human Rights to Address Anti-Transgender and Anti-Gender-Affirming Care Laws in the United States
by Katherine M. Fobear
Soc. Sci. 2026, 15(4), 237; https://doi.org/10.3390/socsci15040237 - 7 Apr 2026
Abstract
Over the past five years, the number of new United States laws banning gender-affirming care, restricting public access to services and spaces for transgender and gender-diverse persons, and forcibly outing transgender youth in schools has increased dramatically. Much of the focus in the [...] Read more.
Over the past five years, the number of new United States laws banning gender-affirming care, restricting public access to services and spaces for transgender and gender-diverse persons, and forcibly outing transgender youth in schools has increased dramatically. Much of the focus in the media and research has been on the domestic political and social causes of these anti-transgender and anti-gender-affirming care laws and their devastating effects on vulnerable transgender and gender-diverse communities. This article argues that the current wave of anti-transgender and anti-gender-affirming care laws violates civil and human rights in the context of international human rights resolutions and principles on healthcare and displacement. I explore the implications of using international human rights to challenge anti-transgender and anti-gender-affirming care legislation and what coalitional possibilities exist when expanding the fight against these laws transnationally. Full article
(This article belongs to the Section Gender Studies)
16 pages, 1212 KB  
Article
Quad-Element Implantable MIMO Antenna for Wireless Capsule Endoscopy
by Amor Smida, Jun Jiat Tiang, Mohamed I. Waly and Surajo Muhammad
Sensors 2026, 26(7), 2276; https://doi.org/10.3390/s26072276 - 7 Apr 2026
Abstract
Compared to antennas bearing a single port, MIMO antennas with several ports enable higher data throughput by exploiting spatial diversity. This capability is essential for next-generation implantable medical devices, where high channel capacity is a key requirement. A quad-element implantable MIMO antenna is [...] Read more.
Compared to antennas bearing a single port, MIMO antennas with several ports enable higher data throughput by exploiting spatial diversity. This capability is essential for next-generation implantable medical devices, where high channel capacity is a key requirement. A quad-element implantable MIMO antenna is designed and practically validated at 1420 MHz in this paper. It occupies a compact volume of 7×8×0.1 mm3 (5.6 mm3). The compactness is realized by combining high-permittivity substrate (Rogers 3010 with relative permittivity of 10.2) with meandered radiator paths, which increase the effective current length while maintaining a small physical size. All antennas have very small mutual coupling with isolation of more than 31.78 dB, which is mainly due to the spacing of 1 mm between the elements and the substrate, which is thin. The peak realized gain for each antenna element is 27.3 dBi. The simulation is performed within a capsule-like structure, which is embedded in the stomach tissue model. The experimental verification is carried out by embedding antenna within minced meat. The ECC, channel capacity, and link margin are also evaluated and found to be satisfactory. The proposed antenna ensures reliable communication performance, with the transmission range being as high as 2.5 m, link margin being 15 dB, and the data rate being 120 Mb/s. The proposed antenna ensures a good level of ECC, which is less than 0.1. The SAR is 52.3 W/kg at 1420 MHz. This design is favorable for implants because of the small size, good impedance matching, high isolation, low correlation, good level of gain, and good link performance. Full article
(This article belongs to the Section Biomedical Sensors)
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19 pages, 2813 KB  
Article
Confined Sulfate Radicals in Layered Double Hydroxide Nanoreactors for Efficient Defluorination Reactions
by Zichao Lian, Yupeng Yang, Lihui Wang, Han Xiao, Di Luo, Xiaoru Huang, Jiangzhi Zi and Wei Wang
Catalysts 2026, 16(4), 336; https://doi.org/10.3390/catal16040336 - 7 Apr 2026
Abstract
Controlling radical selectivity within nanoreactors remains a formidable challenge due to the inherent high reactivity and short half-lives of reactive species. Herein, we report a novel size-matched nanoconfinement strategy using a cobalt-nickel-layered double hydroxide (CoNi-LDH) nanoreactor for the highly selective generation and stabilization [...] Read more.
Controlling radical selectivity within nanoreactors remains a formidable challenge due to the inherent high reactivity and short half-lives of reactive species. Herein, we report a novel size-matched nanoconfinement strategy using a cobalt-nickel-layered double hydroxide (CoNi-LDH) nanoreactor for the highly selective generation and stabilization of sulfate radicals (SO4∙−) via piezoelectric activation of peroxymonosulfate (PMS). By precisely tailoring the LDH interlayer spacing to 5.27 Å to match the kinetic diameter of SO4∙−, the nanoreactor effectively suppresses non-selective side reactions and radical quenching. Consequently, the CoNi-LDH achieves an unprecedented reaction rate (kobs = 0.40 min−1) and superior defluorination efficiency (78.9%) for fluoroquinolone antibiotics, significantly outperforming non-size-confined counterparts. Mechanistic insights reveal a synergistic pathway where piezo-generated hot electrons, mediated by Ni sites, accelerate the Co2+/Co3+ redox cycle to ensure long-term catalytic stability. The robustness of this nanoconfined system is further demonstrated by its exceptional tolerance to complex water matrices and its practical operability in a continuous-flow reactor. This study provides a pioneering approach for spatial radical control at the nanoscale to achieve efficient and targeted environmental remediation. Full article
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27 pages, 6807 KB  
Article
Unlocking the Restorative Power of Urban Green Spaces in Summer: The Interplay of Vegetation Structure, Activity Modality, and Human Well-Being
by Yifan Duan, Hua Bai, Le Yang and Shuhua Li
Sustainability 2026, 18(7), 3619; https://doi.org/10.3390/su18073619 - 7 Apr 2026
Abstract
Amidst global urbanization and rising psychological stress, urban green spaces are increasingly recognized as critical infrastructure for sustainable urban development and public health. However, the mechanisms by which summer vegetation structure mediates both physiological and psychological restoration, and the interplay between these two [...] Read more.
Amidst global urbanization and rising psychological stress, urban green spaces are increasingly recognized as critical infrastructure for sustainable urban development and public health. However, the mechanisms by which summer vegetation structure mediates both physiological and psychological restoration, and the interplay between these two dimensions, remain poorly understood. Understanding these mechanisms is essential for designing sustainable, health-promoting urban environments that can support growing urban populations in a warming climate. This study employed a controlled field experiment in Xi’an during summer to examine the effects of five vegetation structure types (Single-Layer Grassland, single-layer woodland, tree–shrub–grass composite woodland, tree–grass composite woodland, and a non-vegetated square) on university students’ physiological (heart rate variability) and psychological (perceived restorativeness and affective states) restoration. Following stress induction, 300 participants engaged with the green spaces through both quiet sitting and walking. The results revealed three key findings: (1) the tree–shrub–grass composite woodland consistently showed the most favorable trends other vegetation types across all psychological restoration dimensions, while also showing favorable trends in physiological recovery, underscoring the importance of structural complexity for restorative quality; (2) walking significantly enhanced physiological recovery compared to seated observation across all settings, confirming the role of physical activity as a critical activator of green space benefits; (3) correlation analysis identified a specific cross-system association: the R-R interval recovery value showed a weak but significant correlation with positive affect (PA) scores, suggesting that physiological calmness and positive emotional experience are linked, yet their weak coupling under short-term exposure indicates they may operate as parallel processes with distinct temporal dynamics. These findings indicate that the restorative potential of summer green spaces emerges from an integrated framework combining vegetation complexity and activity support. We propose that future sustainable landscape design should prioritize multi-layered vegetation structures as nature-based solutions that simultaneously enhance human well-being and urban resilience. These findings provide empirical evidence for integrating health-promoting green infrastructure into sustainable urban planning frameworks, supporting multiple Sustainable Development Goals (SDGs), including SDG 3 (Good Health and Well-being), SDG 11 (Sustainable Cities and Communities), and SDG 13 (Climate Action). Full article
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14 pages, 2611 KB  
Article
Brillouin Zone Folding-Induced Magnetic Toroidal Dipole Metasurfaces for Tunable Mid-Infrared Upconversion
by Wanghao Zhu, Congfu Zhang, Wenjuan Shi, Di Ma and Hongjun Liu
Photonics 2026, 13(4), 350; https://doi.org/10.3390/photonics13040350 - 7 Apr 2026
Abstract
High quality factor (Q factor) resonant metasurfaces enable efficient mid-infrared (MIR) upconversion, yet their narrow operating bandwidths severely limit practical broadband detection and imaging applications. Although high Q magnetic toroidal dipole (MTD) modes exhibit outstanding momentum space (k-space) stability in linear [...] Read more.
High quality factor (Q factor) resonant metasurfaces enable efficient mid-infrared (MIR) upconversion, yet their narrow operating bandwidths severely limit practical broadband detection and imaging applications. Although high Q magnetic toroidal dipole (MTD) modes exhibit outstanding momentum space (k-space) stability in linear optics, their application in nonlinear processes has primarily been confined to degenerate second-harmonic generation (SHG), leaving complex non-degenerate processes such as sum-frequency generation (SFG) largely unexplored. Here, we propose a tunable MIR upconversion platform based on an all-dielectric gallium phosphide (GaP) dimer metasurface. Breaking the in-plane symmetry to trigger Brillouin zone folding excites robust MTD quasi-guided modes (MTD-QGM), tightly confining the locally enhanced optical fields within the highly nonlinear GaP nanostructure. Synchronizing this high Q resonance with a spatially overlapping pump mode yields an exceptional SFG conversion efficiency of 7.9×104, successfully translating a 3101.8 nm MIR signal to the 903 nm near-infrared band. Crucially, the intrinsic k-space stability of the MTD-QGM enables continuous, broadband upconversion through simple angle tuning. This mechanism effectively overcomes the narrow-band limitations characteristic of typical symmetry-protected resonators, establishing a robust paradigm for room-temperature MIR detection. Full article
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