Search Results (9)

Heavy fuel oil (HFO) is a widely used fuel in compression ignition engines, primarily in Brazilian thermoelectric plants, mainly due to its availability, low cost, and low operational expenses. However, heavy fuel oil is not compatible with most diesel engines and combustion systems in use and must be treated to maintain combustion process efficiency. The high viscosity of heavy fuel oil must be reduced before being introduced into the engine. To achieve this, appropriate heating devices are added to the fuel lines, with steam being the primary working fluid in these devices. Steam-generating boilers that burn fossil fuels, including HFO itself, are the most viable option from an economic standpoint and in terms of utilizing locally available fuels for this function. However, the need to mitigate the effects of environmental pollution has encouraged the adoption of other types of boilers, such as electric ones. In this work, a case study of a combustion steam generator installed in a Brazilian thermoelectric plant is developed. This study involves the thermodynamic and combustion modeling of the steam generator through the balancing of the respective thermodynamic and combustion equations. The models and the proposed chemical formula of HFO were validated, and through simulations using real data collected during the boiler’s operation throughout 2024, it was also possible to estimate the carbon dioxide emissions produced. Additionally, a hypothetical scenario was simulated in which the combustion boiler currently installed in the plant is replaced by two electric boilers. A simple economic analysis demonstrated that such a replacement would result in a total steam production cost of only 25% of the amount spent on the current combustion boiler, in addition to reducing $C{O}_2$ emissions to the atmosphere by 62.55 tons. Full article

This research makes a strong focus on improving fluid dynamics inside the reservoir after stimulation for enhancing oil and gas well performance, particularly in terms of increasing the Gas–oil ratio (GOR) and injectivity leading to a better productivity index (PI). Advanced stimulation operation using new formulated emulsified acid treatment greatly improves the reservoir permeability, allowing for better fluid movement and less formation damage. This, in turn, results in injectivity increases of at least 2.5 times and, in some situations, up to five times the original rate, which is critical for sustaining reservoir pressure and ensuring effective hydrocarbon recovery. The emulsified acid outperforms typical 15% HCl treatments in terms of dissolving and corrosion rates, as it is tuned for the reservoir’s pressure, temperature, permeability, and porosity. This dual-phase technology increases injectivity by five times while limiting the environmental and material consequences associated with spent and waste acid quantities. Field trials reveal significant improvements in injection pressure and a marked reduction in circulation pressure during stimulation, underscoring the treatment’s efficient penetration within the rock pores to enhance oil flow and sweep. This increase in performance is linked to the creation of the wormholing impact of the emulsified acid, resulting in improved fluid dynamics and optimized reservoir efficiency, as shown by the enhanced gas–oil ratio (GOR) in the four mentioned cases. A critical component of attaining such improvements is the capacity to effectively analyze and forecast reservoir behavior prior to executing the stimulation in real life. Engineers can accurately forecast injectivity gains and improve fluid injection tactics by constructing an advanced predictive model with low error margins, decreasing the need for time-consuming and costly trial-and-error approaches. Importantly, the research utilizes sophisticated neural network modeling to forecast stimulation results with minimal inaccuracies. This predictive ability not only diminishes the dependence on expensive and prolonged trial-and-error methods but also enables the proactive enhancement of treatment designs, thereby increasing efficiency and cost-effectiveness. This modeling approach based on several operational and reservoir factors, combines real-time field data, historical well performance records, and fluid flow simulations to verify that the expected results closely match the actual field outcomes. A well-calibrated prediction model not only reduces uncertainty but also improves decision making, allowing operators to create stimulation treatments based on unique reservoir features while minimizing unnecessary costs. Furthermore, enhancing fluid dynamics through precise modeling helps to improve GOR management by keeping gas output within appropriate limits while optimizing liquid hydrocarbon recovery. Finally, by employing data-driven modeling tools, oil and gas operators can considerably improve reservoir performance, streamline operational efficiency, and achieve long-term production growth through optimal resource usage. This paper highlights a new approach to optimizing reservoir productivity, aligning with global efforts to minimize environmental impacts in oil recovery processes. The use of real-time monitoring has boosted the study by enabling for exact measurement of post-injectivity performance and oil flow rates, hence proving the efficacy of these advanced stimulation approaches. The study offers unique insights into unconventional reservoir growth by combining numerical modeling, real-world data, and novel treatment methodologies. The aim is to investigate novel simulation methodology, advanced computational tools, and data-driven strategies for improving the predictability, reservoir performance, fluid behavior, and sustainability of heavy oil recovery operations. Full article

Biodiesel produced via oil transesterification often contains metallic impurities, such as copper, which affects its quality and engine performance. This study explores the use of activated carbon prepared from spent coffee grounds to remove copper from biodiesel. Activated carbon samples were prepared via biomass pyrolysis and chemical activation with KOH and HNO₃. The optimal conditions for copper adsorption were determined using a Taguchi L9 design. Maximum adsorption capacities were 13.4 and 17.3 mg/g at 30 and 40 °C, respectively, in batch adsorbers. In packed-bed columns, the axial dispersion reduced the adsorption efficiency obtaining bed adsorption capacities from 1.9 to 5.1 mg/g under tested experimental conditions. Adsorbent characterization and adsorption modeling indicated that copper removal was driven by multi-cationic interactions, where carboxylic groups from carbon surface acted as key active sites. The new adsorbent outperformed commercial bone char, making it a cost-effective alternative to improve biodiesel production contributing to the energy matrix diversification. Full article

The imperative of utilising alternative fuels for the operation of internal combustion engines stems from the requirements to reduce the emissions of greenhouse gases and other contaminants, the substantial demand for fuels, and the diminishing reserves of natural resources. The global inclination towards sustainable development necessitates the employment of biofuels as a substitute for fossil fuels. Nonetheless, the expenditures on raw materials for the manufacture of biodiesel remain substantial, thus underlining the importance of exploring solutions for reducing them. An instance of this could be the utilisation of plant and animal by-products, such as used frying oils and slaughterhouse waste, as feedstock for biodiesel production. Not only will this facilitate the creation of less costly biofuel, but it will also provide an effective solution for the management of post-production waste. The objective of the research delineated in this paper was to ascertain select physicochemical attributes of second-generation biodiesel, derived from spent frying oil, as well as mixtures of this biodiesel with diesel and biodiesel concentrations of 10, 20, and 30% (v/v). The biodiesel produced is the waste frying oil methyl esters WFOME. The proprietary GW-201 reactor was employed in the production of biodiesel. For WFOME biodiesel, DF diesel, and their blends—B10, B20, and B30—properties that influence the formation process of the combustible mixture, autoignition, and combustion of fuel–air mixtures in self-ignition engines were determined. The conducted research has established that “B” type fuels prepared from WFOME and DF present a viable alternative to fossil fuels. Pure biodiesel exhibited a marginally reduced lower heating value, however, in the case of fuel mixtures comprising up to 30% (v/v) biodiesel and diesel, the lower heating values approximated that of diesel. An elevated cetane number alongside an increased flash point of pure B100 biodiesel have been noted. The values of cetane number for WFOME and DF mixtures were found to be either comparable or marginally higher than those of pure DF diesel fuel. Full article

This article presents the results of research into the causes of the wear of the piston pin mounted in piston bosses by means of a hinge joint and in the connecting rod small end by means of the thermocompression bond. Changes in geometry and in the pin-top surface structure, which are caused by the mutual influence of the mating surfaces in variable lubrication conditions, are presented. The progress of scuffing as a result of insufficient lubrication of the mating elements or oil film breaking is demonstrated. The state of destruction was confirmed by the results of surface roughness measurements showing the formation of build-ups. The loss of the thermocompression bond surface, caused by the penetration of sintered engine oil fractions containing biofuel additive components and spent engine oil improver packages, was noted. The progressing forms of wear are the cause of engine failures due to the pin movement towards the cylinder wall, and due to boss breakage in the piston. Full article

Efforts to engineer high-productivity crops to accumulate oils in their vegetative tissue present the possibility of expanding biodiesel production. However, processing the new crops for lipid recovery and ethanol production from cell wall saccharides is challenging and expensive. In a previous study using corn germ meal as a model substrate, we reported that liquid hot water (LHW) pretreatment enriched the lipid concentration by 2.2 to 4.2 fold. This study investigated combining oil recovery with ethanol production by extracting oil following LHW and simultaneous saccharification and co-fermentation (SSCF) of the biomass. Corn germ meal was again used to model the oil-bearing energy crops. Pretreated germ meal hydrolysate or solids (160 and 180 °C for 10 min) were fermented, and lipids were extracted from both the spent fermentation whole broth and fermentation solids, which were recovered by centrifugation and convective drying. Lipid contents in spent fermentation solids increased 3.7 to 5.7 fold compared to the beginning germ meal. The highest lipid yield achieved after fermentation was 36.0 mg lipid g⁻¹ raw biomass; the maximum relative amount of triacylglycerol (TAG) was 50.9% of extracted oil. Although the fermentation step increased the lipid concentration of the recovered solids, it did not improve the lipid yields of pretreated biomass and detrimentally affected oil compositions by increasing the relative concentrations of free fatty acids. Full article

Impregnation is a common method of protecting wood from external influences. This study proposes the use of spent engine oil as an impregnating composition for modifying birch wood to make it resistant to biological degradation and water. The indicators of water resistance and dimensional stability of wood such as wetting contact angle, thermogravimetric analysis, Fourier transform infrared spectroscopy (FTIR), and biodegradation tests have been determined. It has been found that treatment with spent engine oil significantly increases the dimensional stability (56.8% and 45.7% in tangential and radial directions) and water-resistant indicators of wood. Thermogravimetric analysis has showed that the curves for the impregnated specimens were different from the control group and had two sharp peaks at 302 and 357 °C. However, FTIR indicated that no clear chemical reactions occur between spent engine oil and wood. A study on wood resistance to biological degradation has showed a significant increase in resistance against brown rot (Poria placenta fungi) in the treated specimens, in contrast to the control group. Thus, impregnation of wood with spent engine oil makes it possible to increase wood resistance to water and biological degradation. Full article

Concern for climate change is one of the drivers of new, transitional energy policies oriented towards economic growth and energy security, along with reduced greenhouse gas (GHG) emissions and preservation of biodiversity. Since 2010, the Climate Policy Initiative (CPI) has been publishing annual Global Landscape of Climate Finance reports. According to these reports, US$3660 billion has been spent on global climate change projects over the period 2011–2018. Fifty-five percent of this expenditure has gone to wind and solar energy. According to world energy reports, the contribution of wind and solar to world energy consumption has increased from 0.5% to 3% over this period. Meanwhile, coal, oil, and gas continue to supply 85% of the world’s energy consumption, with hydroelectricity and nuclear providing most of the remainder. With this in mind, we consider the potential engineering challenges and environmental and socioeconomic impacts of the main energy sources (old and new). We find that the literature raises many concerns about the engineering feasibility as well as environmental impacts of wind and solar. However, none of the current or proposed energy sources is a “panacea”. Rather, each technology has pros and cons, and policy-makers should be aware of the cons as well as the pros when making energy policy decisions. We urge policy-makers to identify which priorities are most important to them, and which priorities they are prepared to compromise on. Full article

Large-scale recycling of new industrial wastes or by-products in concrete has become a crucial issue for construction materials sustainability, with impact in the three pillars (environmental, social and economic), while still maintaining satisfactory, or improved, concrete performance. The main goal of the paper is to evaluate the technological feasibility of the partial, or total, replacement of fly-ashes (FA), widely used in ready-mixed concrete production, with spent equilibrium catalyst (ECat) from the oil-refinery industry. Three different concrete mixtures with binary binder blends of FA (33.3% by mass, used as reference) and of ECat (16.7% and 33.3%), as well as a concrete mixture with a ternary binder blend with FA and ECat (16.7%, of each) were tested regarding their mechanical properties and durability. Generically, in comparison with commercial concrete (i) 16.7% ECat binary blended concrete revealed improved mechanical strength and durability; (ii): ternary FA-ECat blended binder concrete presented similar properties; and (iii) 33% ECat binary blended concrete has a lower performance. The engineering performance of all ECat concretes meet both the international standards and the reference durability indicators available in the scientific literature. Thus, ECat can be a constant supply for ready-mixed eco-concretes production, promoting synergetic waste recycling across industries. Full article