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30 pages, 3118 KB  
Article
Prediction of Combustion Parameters and Pollutant Emissions of a Dual-Fuel Engine Based on Recurrent Neural Networks
by Joel Freidy Ebolembang, Fabrice Parfait Nang Nkol, Lionel Merveil Anague Tabejieu, Fernand Toukap Nono and Claude Valery Ngayihi Abbe
Appl. Sci. 2025, 15(18), 9868; https://doi.org/10.3390/app15189868 (registering DOI) - 9 Sep 2025
Abstract
A critical challenge in engine research lies in minimizing harmful emissions while optimizing the efficiency of internal combustion engines. Dual-fuel engines, operating with methanol and diesel, offer a promising alternative, but their combustion modeling remains complex due to the intricate thermochemical interactions involved. [...] Read more.
A critical challenge in engine research lies in minimizing harmful emissions while optimizing the efficiency of internal combustion engines. Dual-fuel engines, operating with methanol and diesel, offer a promising alternative, but their combustion modeling remains complex due to the intricate thermochemical interactions involved. This study proposes a predictive framework that combines validated CFD simulations with deep learning techniques to estimate key combustion and emission parameters in a methanol–diesel dual-fuel engine. A three-dimensional CFD model was developed to simulate turbulent combustion, methanol injection, and pollutant formation, using the RNG k-ε turbulence model. A temporal dataset consisting of 1370 samples was generated, covering the compression, combustion, and early expansion phases—critical regions influencing both emissions and in-cylinder pressure dynamics. The optimal configuration identified involved a 63° spray injection angle and a 25% methanol proportion. A Gated Recurrent Unit (GRU) neural network, consisting of 256 neurons, a Tanh activation function, and a dropout rate of 0.2, was trained on this dataset. The model accurately predicted in-cylinder pressure, temperature, NOx emissions, and impact-related parameters, achieving a Pearson correlation coefficient of ρ = 0.997. This approach highlights the potential of combining CFD and deep learning for rapid and reliable prediction of engine behavior. It contributes to the development of more efficient, cleaner, and robust design strategies for future dual-fuel combustion systems. Full article
(This article belongs to the Special Issue Diesel Engine Combustion and Emissions Control)
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17 pages, 2298 KB  
Article
Influence of the Process-Related Surface Structure of L-PBF Manufactured Components on Residual Stress Measurement Using the Incremental Hole Drilling Method
by Sebastian Gersch, Ulf Noster, Carsten Schulz and Jörg Bagdahn
Appl. Sci. 2025, 15(18), 9861; https://doi.org/10.3390/app15189861 (registering DOI) - 9 Sep 2025
Abstract
Laser Powder Bed Fusion (L-PBF) parts combine geometric freedom with process-induced rough surfaces that challenge residual-stress metrology. We evaluated the accuracy of the incremental hole-drilling (IHD) method with electronic speckle pattern interferometry (ESPI) by applying defined stresses via four-point bending to stress-relieved AlSi10Mg [...] Read more.
Laser Powder Bed Fusion (L-PBF) parts combine geometric freedom with process-induced rough surfaces that challenge residual-stress metrology. We evaluated the accuracy of the incremental hole-drilling (IHD) method with electronic speckle pattern interferometry (ESPI) by applying defined stresses via four-point bending to stress-relieved AlSi10Mg coupons, rather than measuring unknown process stresses. Flat specimens (2 mm, thin per ASTM E837) were analyzed on up-skin, side-skin, and CNC-milled surfaces; thin-specimen calibration coefficients were used. After a preliminary inter-specimen check (three specimens per surface; spread < 8 MPa), one representative specimen per surface was tested with three drill sites to assess intra-specimen uniformity. Measured IHD–ESPI stresses agreed best at 70 MPa: deviations were ~4.1% (up-skin), 6.0% (side-skin), and 6.24% (CNC-milled). At 10 MPa the relative errors increased (23.6%, 18.4%, and 1.40%), consistent with reduced ESPI signal-to-noise and fixture compliance in the low-stress regime. At 140 MPa, deviations rose again (21.1%, 14.3%, and 13.1%), reflecting operation near the ~60% Rp0.2 elastic limit of hole-drilling and potential local plasticity. Surface-dependent artifacts also mattered as follows: the side-skin required no coating and performed comparably to CNC-milled, whereas the up-skin’s roughness plus matting spray introduced fringe distortions and chip/coating debris near the hole. This controlled study indicates that IHD–ESPI can provide reliable results on L-PBF AlSi10Mg in the mid-stress range when surface preparation, coating, and rig compliance are carefully managed. Limitations include excluding down-skin surfaces and testing only one specimen per condition; thus, results should be generalized cautiously. Full article
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16 pages, 1358 KB  
Article
Preharvest Application of 1-Methylcyclopropene (1-MCP) to Schedule the Harvest and Maintain the Storage Quality of ‘Maxi Gala’ Apples
by Cassandro Vidal Talamini do Amarante, Luiz Carlos Argenta, Sergio Tonetto de Freitas and Cristiano André Steffens
Agronomy 2025, 15(9), 2151; https://doi.org/10.3390/agronomy15092151 (registering DOI) - 9 Sep 2025
Abstract
This three-year study in southern Brazil assessed the effectiveness of the preharvest spraying of 1-methylcyclopropene (1-MCP; Harvista™ 1.3 SC) in reducing the fruit drop, delaying the maturity, and maintaining the postharvest quality of ‘Maxi Gala’ apples. 1-MCP was sprayed at 0, 75, 125, [...] Read more.
This three-year study in southern Brazil assessed the effectiveness of the preharvest spraying of 1-methylcyclopropene (1-MCP; Harvista™ 1.3 SC) in reducing the fruit drop, delaying the maturity, and maintaining the postharvest quality of ‘Maxi Gala’ apples. 1-MCP was sprayed at 0, 75, 125, 175, and 225 mg a.i. L−1 seven days before the anticipated harvest time (DBAH). Aminoethoxyvinylglycine (AVG; Retain®), a commercial control, was applied at 124 mg a.i. L−1 28 DBAH. After harvest, the fruit were stored for seven months under a controlled atmosphere (CA; 1.5 kPa O2 and 2.5 kPa CO2 at 0.8 ± 0.6 °C/RH of 94–95%), followed by seven days of shelf life (23 ± 1 °C/RH of 70–80%). Increasing 1-MCP concentrations significantly reduced preharvest fruit drop, and 1-MCP at 175 and 225 mg L−1 was more effective over time than AVG. While 1-MCP, like AVG, delayed red color development, fruit treated with 175 and 225 mg L−1 still achieved over 44.5 N firmness after CA storage, even when harvested 28 days after spraying, allowing for red color development and an average 12 g fruit weight increase. 1-MCP at ≥75 mg L−1 was more efficient than AVG in maintaining flesh firmness, while at 225 mg L−1, it also preserved higher titratable acidity and a lower soluble solid content after CA storage. Thus, the preharvest spraying of 1-MCP is a valuable tool for growers to schedule the harvest and maintain the postharvest quality of ‘Maxi Gala’ apples. Full article
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1836 KB  
Article
Accelerated Corrosion and Multimodal Characterization of Steel Pins in High-Voltage AC Insulators Under Multi-Stress Conditions
by Cong Zhang, Heng Zhong, Zikui Shen, Hongyan Zheng, Yibo Yang, Junbin Su and Xiaotao Fu
Materials 2025, 18(17), 4218; https://doi.org/10.3390/ma18174218 (registering DOI) - 8 Sep 2025
Abstract
Ensuring the long-term electro-mechanical reliability of high-voltage alternating current (HVAC) insulator strings requires a detailed understanding of how multiple environmental and electrical stressors influence the corrosion behavior of hot-dip galvanized steel fittings. In this study, a three-factor, three-level L9(33) orthogonal accelerated [...] Read more.
Ensuring the long-term electro-mechanical reliability of high-voltage alternating current (HVAC) insulator strings requires a detailed understanding of how multiple environmental and electrical stressors influence the corrosion behavior of hot-dip galvanized steel fittings. In this study, a three-factor, three-level L9(33) orthogonal accelerated corrosion test was conducted to systematically evaluate the individual and interactive effects of marine salt deposition (0–10 g m−2 day−1), acetic acid pollution (0–8 µg m−3), and 50 Hz AC leakage current (0–10 mA) on miniature pin-type assemblies. A comprehensive post-corrosion characterization approach was employed. The results revealed that chloride loading from salt deposition was the dominant contributor to corrosion. However, the synergistic interaction between salt and leakage current led to an acceleration in zinc depletion compared to the additive effect of the individual factors. A quadratic regression model with a high correlation coefficient was developed to predict corrosion volume per unit area. The findings offer a mechanistic explanation for field-reported failures in coastal power grids and provide actionable guidance for optimizing corrosion-resistant coatings and implementing electrical mitigation strategies. Full article
(This article belongs to the Section Corrosion)
32 pages, 10218 KB  
Article
A Study of the Collision Characteristics of Colloidal Particles in Fuel Servo Valves
by Jin Zhang, Ranheng Du, Jie Ni, Wenlong Yin, Geng Cao, Ying Li and Huan Wang
Aerospace 2025, 12(9), 812; https://doi.org/10.3390/aerospace12090812 (registering DOI) - 8 Sep 2025
Abstract
The fuel electro-hydraulic servo valve is a core component of the aero-engine fuel control system, playing a crucial role in engine performance. Due to the operational characteristics of the aviation fuel supply and injection system, fuel is directly sprayed through the nozzle for [...] Read more.
The fuel electro-hydraulic servo valve is a core component of the aero-engine fuel control system, playing a crucial role in engine performance. Due to the operational characteristics of the aviation fuel supply and injection system, fuel is directly sprayed through the nozzle for combustion after passing through the pipeline. The working environment and medium are subject to a wide temperature range, and the medium lacks a circulating filtration process, making it difficult to effectively remove impurities. As a result, the fuel contains a high concentration of contaminant particles. Under high-temperature conditions, colloidal particles precipitated from the fuel medium collide and adhere to metallic and other contaminant particles carried by the fuel, subsequently attaching to the internal surfaces of the fuel servo valve, causing valve sticking. This study aims to establish an adhesion criterion suitable for colloidal particles in fuel systems based on a traditional particle collision model. The adhesion criterion incorporates the viscoelastic and surface energy characteristics of colloidal particles, providing a more accurate description of their deposition behavior under the conditions studied. A particle–particle and particle–wall collision test apparatus was designed, and experiments were conducted. A comparison between experimental results and theoretical calculations shows that the overall error for collisions between colloidal particles and walls is controlled within 10%, validating the feasibility of the adhesion criterion. The Young’s modulus, Poisson’s ratio, and surface free energy of the colloidal particles were measured as 688 MPa, 0.39, and 77 mJ/m2, respectively. These results provide theoretical and experimental foundations for particle migration and deposition processes in fuel systems. The analytical method clarifies the key mechanism of adhesion caused by colloidal particles, providing guidance for improving the reliability, safety, and maintenance of fuel servo valves in aero-engine applications. Full article
(This article belongs to the Section Aeronautics)
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16 pages, 3001 KB  
Article
Experimental and Simulation Investigation of Octadecyltriethoxysilane-Decorated Diatomaceous Earth Coatings with Enhanced Superhydrophobic and Self-Cleaning Properties
by Aijia Zhang, Nan Xiao, Kunjie Yuan and Wenbin Cao
Materials 2025, 18(17), 4209; https://doi.org/10.3390/ma18174209 - 8 Sep 2025
Abstract
In this study, an effective diatomaceous earth (Dia)/octadecyltriethoxysilane (OTS)/epoxy resin (EP) with enhanced superhydrophobic and self-cleaning coating was prepared by spraying method, and the effect of OTS modification on the hydrophobicity of Dia materials was investigated through molecular dynamics computational simulation. The results [...] Read more.
In this study, an effective diatomaceous earth (Dia)/octadecyltriethoxysilane (OTS)/epoxy resin (EP) with enhanced superhydrophobic and self-cleaning coating was prepared by spraying method, and the effect of OTS modification on the hydrophobicity of Dia materials was investigated through molecular dynamics computational simulation. The results showed that the number of hydrogen bonds and electrostatic interaction energy between diatomite and water molecules were significantly reduced after OTS modification, which significantly enhanced the hydrophobicity of diatomite. The coating exhibits excellent superhydrophobic properties, with a contact angle of up to 152.3°, and has a wide range of applicability, being able to uniformly cover a wide range of substrate surfaces such as glass, wood, and aluminium panels. In addition, it demonstrates excellent self-cleaning capabilities, effectively removing surface contaminants. The mechanical and chemical stability of the coating has also been thoroughly investigated, and it remains superhydrophobic even after abrasion tests and shows excellent stability in acidic or alkaline corrosive environments. Molecular dynamics calculations further elucidated the reason for the change in hydrophobicity of the coatings in acidic and alkaline environments, revealing that the diffusion of water molecules slows down in alkaline environments and solid–liquid interactions are enhanced, resulting in a slight decrease in hydrophobicity. The results of this study not only provide new ideas for the low-cost and environmentally friendly preparation of superhydrophobic materials but also provide a solid theoretical basis and practical guidance for further optimising the material properties. Full article
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14 pages, 609 KB  
Article
Moroccan Ulva rigida Extracts: A Promising Biostimulant for Improving Growth and Photosynthetic Performance in Salt-Stressed Bean Plants
by Salma Latique
Crops 2025, 5(5), 61; https://doi.org/10.3390/crops5050061 - 8 Sep 2025
Abstract
Soil salinity is a crucial factor that limits agricultural production, negatively impacting the growth and physiological functions of salt-sensitive crops, such as beans. The present study examined the efficiency of Ulva rigida seaweed extracts (URE) as biostimulants to enhance the growth and photosynthetic [...] Read more.
Soil salinity is a crucial factor that limits agricultural production, negatively impacting the growth and physiological functions of salt-sensitive crops, such as beans. The present study examined the efficiency of Ulva rigida seaweed extracts (URE) as biostimulants to enhance the growth and photosynthetic ability of bean plants (Phaseolus vulgaris L.) under saline conditions (51.33 mM NaCl). Seaweed extracts were obtained by maceration and ultrasonic assistance at two concentrations, 25% and 50% (v/v), and applied as a foliar spray or irrigation. The most significant improvement was observed following foliar sprays of 50% ultrasonic extract (UP-50), with an increase of 96% in CCI compared to salt-stressed controls and by 71% compared to non-stressed controls. Stomatal conductance (SC) was also significantly improved with UP-50, reaching levels that were 146% higher than those of salt-stressed plants and 53% higher than those of non-stressed plants. The OJIP transients under salinity were significantly improved by both ultrasonic-assisted and maceration extracts; especially, 50% maceration extracts (MP-50) restored PSII quantum efficiency (ΦPo) and total performance index (PItotal) of salinity-stressed seedlings to 107% and 255% of non-stressed control and 122% and 314% of salt-stressed control, respectively. Root length and indole acetic acid (IAA) levels in treated plants were also enhanced, particularly in response to higher concentrations of the extract, suggesting improved root growth as well as hormonal homeostasis in the presence of salt stress. According to these findings, U. rigida extracts, specifically those applied at high concentrations as a foliar spray, serve as biostimulants that mitigate the adverse effects of salt stress on beans by preventing chlorophyll degradation and enhancing photosynthesis, root development, and hormonal balance. Full article
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18 pages, 3901 KB  
Article
Experimental Investigation of Wetting Materials for Indirect Evaporative Cooling Applications
by Lanbo Lai, Xiaolin Wang, Gholamreza Kefayati, Eric Hu and Kim Choon Ng
Appl. Sci. 2025, 15(17), 9818; https://doi.org/10.3390/app15179818 (registering DOI) - 7 Sep 2025
Abstract
The indirect evaporative cooling system, which exploits the water evaporation process to generate cooling loads without introducing additional moisture, has been recognised as a viable alternative to conventional air-conditioning systems. This acknowledgment is due to its attributes of energy efficiency and environmental friendliness. [...] Read more.
The indirect evaporative cooling system, which exploits the water evaporation process to generate cooling loads without introducing additional moisture, has been recognised as a viable alternative to conventional air-conditioning systems. This acknowledgment is due to its attributes of energy efficiency and environmental friendliness. The meticulous selection of wetting materials for an indirect evaporative cooler is of paramount importance as it significantly influences the heat and mass transfer performance of the system. Therefore, this paper experimentally examined a novel material produced by laser-resurfaced technology, and this material was compared with four other distinct materials (kraft paper, cotton fibre, polyester fibre, and polypropylene + nylon fibre) while considering the wicking ability, water-holding capacity, and thermal response performance. The results revealed that the fabric materials, specifically cotton fibre and polyester fibre, exhibited outstanding water-wicking ability, with a vertical wicking distance exceeding 16 cm. Cotton fibre also demonstrated an exceptional water-holding ability, registering a value of 0.0754 g/cm2. In terms of thermal response performance, polypropylene + nylon fibre and the laser-resurfaced polymer achieved stable conditions within one minute, which could be attributed to the absence of a mechanical support plate and adhesive layer. All five materials attained stability after 4.2 min. Cotton and polyester fibres exhibited advantages in the duration of the evaporation process, maintaining stable conditions for 24 and 90 min, respectively. Based on the experimental results, appropriate water-spray strategies are proposed for each material. Full article
(This article belongs to the Section Applied Thermal Engineering)
16 pages, 5140 KB  
Article
Microwave–Assisted OSA–Faba Bean Starch Production for Probiotic Microencapsulation
by Mayra Esthela González-Mendoza, Fernando Martínez-Bustos, Eduardo Castaño-Tostado, María del Carmen Cortez-Trejo and Silvia Lorena Amaya-Llano
Polysaccharides 2025, 6(3), 81; https://doi.org/10.3390/polysaccharides6030081 (registering DOI) - 7 Sep 2025
Viewed by 74
Abstract
Probiotics offer significant health benefits; however, their efficacy is often compromised by low survival rates in stressful conditions. Microencapsulation using modified starches presents a promising strategy to enhance probiotic viability. This study aimed to evaluate microwave-assisted octenyl succinic anhydride (OSA) modification of faba [...] Read more.
Probiotics offer significant health benefits; however, their efficacy is often compromised by low survival rates in stressful conditions. Microencapsulation using modified starches presents a promising strategy to enhance probiotic viability. This study aimed to evaluate microwave-assisted octenyl succinic anhydride (OSA) modification of faba bean starch to provide a protective matrix for the microencapsulation of Lactobacillus rhamnosus GG (LGG) through spray drying. Starch was extracted from faba beans and hydrolyzed, and a factorial design was employed for OSA esterification (3% w/w) using a conventional microwave (30 or 60 s at power levels of 2 or 10). The starches were characterized, and the most effective treatment was selected for the microencapsulation of LGG, varying the inlet temperature (120 and 140 °C) and flow rate (7 and 12 mL/min) at 30% solids content. Microwaves significantly reduced the processing time for starch esterification. Microwave-assisted OSA modification produced starches with low viscosity (<0.015 Pa·s), high amylose and resistant starch content, and good solubility, making them suitable for probiotic encapsulation. The microencapsulation of LGG resulted in a powder yield of 41–55%, with particle sizes ranging from 5 to 20 µm and survival rates of 81–90%. This study presents an effective method of producing OSA-modified starch from faba beans using microwave energy, demonstrating strong potential for probiotic delivery applications. Full article
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31 pages, 18432 KB  
Article
Elderberry-Based Multifunctional Prebiotic Systems Prepared via Spray Drying
by Anna Gościniak, Lidia Tajber, Piotr Szulc, Andrzej Miklaszewski, Tomasz M. Karpiński and Judyta Cielecka-Piontek
Biomolecules 2025, 15(9), 1289; https://doi.org/10.3390/biom15091289 - 7 Sep 2025
Viewed by 59
Abstract
Elderberry (Sambucus nigra L.) is recognized as a rich source of anthocyanins and other bioactives with antioxidant and antidiabetic potential, and is increasingly explored as a functional ingredient in nutraceuticals. However, cultivar-dependent variability can strongly influence chemical composition and bioactivity, underscoring the [...] Read more.
Elderberry (Sambucus nigra L.) is recognized as a rich source of anthocyanins and other bioactives with antioxidant and antidiabetic potential, and is increasingly explored as a functional ingredient in nutraceuticals. However, cultivar-dependent variability can strongly influence chemical composition and bioactivity, underscoring the need for careful selection of plant material prior to formulation. In the present study, twelve genotypes of elderberry were compared in terms of total polyphenols, antioxidant activity, and antiglycation potential. Based on the overall profile, ‘Samyl 1’ was advanced to formulation trials. Spray-dried carrier systems were produced using galactooligosaccharides (GOS) or chitooligosaccharides (COS), with or without colloidal silica. GOS-based powders retained anthocyanins at levels approaching theoretical values and exhibited superior thermal stability, as evidenced by differential scanning calorimetry, thermogravimetric analysis, and degradation-kinetic modeling, whereas COS matrices provided less effective stabilization. Incorporation of silica significantly enhanced technological properties, improving recovery, reducing agglomeration, and increasing flowability, without compromising anthocyanin content. All powders displayed low moisture (2.5–7.1%), favorable morphology, and preserved functional activity, aligning with stability requirements for shelf-stable plant extracts. Overall, the study demonstrates that strategic cultivar selection combined with GOS–silica carrier systems enables the production of stable elderberry powders that maintain high anthocyanin content and bioactivity. Such multifunctional ingredients couple prebiotic functionality with efficient delivery of polyphenols, highlighting their potential in nutraceutical and pharmaceutical formulations. Full article
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21 pages, 1777 KB  
Review
Cannabinoids in Chronic Pain: Clinical Outcomes, Adverse Effects and Legal Challenges
by Aleksandar Sic, Conor George, Daniela Ferrer Gonzalez, Vasilis-Spyridon Tseriotis and Nebojsa Nick Knezevic
Neurol. Int. 2025, 17(9), 141; https://doi.org/10.3390/neurolint17090141 (registering DOI) - 5 Sep 2025
Viewed by 1271
Abstract
Cannabinoids have gained increasing attention as potential therapeutic agents in chronic pain management. Their mechanisms of action, mediated through CB1 and CB2 receptors, provide a pharmacological alternative to conventional analgesics. The evidence is strongest for neuropathic pain and multiple sclerosis-related spasticity, while the [...] Read more.
Cannabinoids have gained increasing attention as potential therapeutic agents in chronic pain management. Their mechanisms of action, mediated through CB1 and CB2 receptors, provide a pharmacological alternative to conventional analgesics. The evidence is strongest for neuropathic pain and multiple sclerosis-related spasticity, while the results for fibromyalgia, osteoarthritis, and musculoskeletal pain remain inconsistent. The average pain reduction is modest, often not exceeding 0.5–1.0 points on a 10-point scale, and therapeutic gains are offset by safety concerns. Quantitative data show that discontinuation rates range from 4.3% at low-dose CBD to 12.9% at high-dose CBD, compared with 3.5% on placebo, while nabiximols (THC + CBD spray) are associated with dizziness in 25% of patients, somnolence in 8%, and treatment discontinuation in 12%. High-dose CBD also carries a measurable risk of hepatotoxicity. Regulatory heterogeneity further constrains trial feasibility, scalability, and patient access, with disparities evident across the United States, Europe, Canada, and Australia. Overall, cannabinoids provide modest, condition-specific analgesia and should be considered adjunctive rather than first-line options, reserved for patients unresponsive to conventional therapy. Future progress requires standardized formulations, harmonized international regulations, long-term safety data, and large-scale randomized controlled trials to clarify their role in evidence-based pain management. Full article
(This article belongs to the Section Pain Research)
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13 pages, 3206 KB  
Article
Preliminary Assessment of Bespoke (‘X-tec’) Silica Particles for IRS Applications
by Stephania Herodotou, Natalie Lissenden, Kevin Skinley, Derric Nimmo, Janneke Snetselaar, Amy Guy, Peter Myers and Svetlana Ryazanskaya
Insects 2025, 16(9), 937; https://doi.org/10.3390/insects16090937 - 5 Sep 2025
Viewed by 221
Abstract
The efficacy of indoor residual spray (IRS) products is affected by various factors, such as the substrate on which they are sprayed and the surface concentration and bioavailability of the insecticide. This study investigated the potential of bespoke silica particles (hereafter referred to [...] Read more.
The efficacy of indoor residual spray (IRS) products is affected by various factors, such as the substrate on which they are sprayed and the surface concentration and bioavailability of the insecticide. This study investigated the potential of bespoke silica particles (hereafter referred to as ‘X-tec silica’) as a unique carrier for insecticides to reduce the insecticide content in an IRS formulation by improving pickup by mosquitoes and optimising the physical state of the insecticide while maintaining its residual biological activity on a surface. Molecular computer modelling was used to define the critical crystallisation size of clothianidin, and silica particles were manufactured with pore diameters smaller than this length to maintain the insecticide in an amorphous state. Silica carriers were then formulated to incorporate clothianidin inside their pores, and a full material characterisation was conducted to assess the clothianidin coating position on/in the silica particles, their concentration, and their physical form. The clothianidin-formulated silica (10%) was sprayed at three different application rates (30, 60, and 90 mg active ingredient (a.i.)/m2) onto two surfaces: glazed and unglazed tiles. The tiles were tested for bioefficacy against the insecticide-susceptible Anopheles gambiae s.s. Kisumu mosquito strain at 1 week and 8 months post-spray application. At 1 week post-spray application, at 60 and 90 mg a.i./m2 application rates, 100% mortality was observed on both surfaces within 48 h. For the lowest concentration (30 mg a.i./m2), 100% mortality was reached within 72 h on glazed tiles; however, for unglazed tiles, due to the surface irregularity and porosity, it remained below 60%. At 8 months post-spray application, on glazed tiles, 100% mortality was reached within 24 h at 60 and 90 mg a.i./m2 application rates and within 48 h at 30 mg a.i./m2. On unglazed tiles, 96 h mortality was not measured; however, 100% mortality was reached within 72 h (90 mg a.i./m2) and 120 h (60 mg a.i./m2) at higher concentrations. At the lowest concentration (30 mg a.i./m2) at 120 h, mortality only reached 25%. The lowest application rate tested (30 mg a.i./m2) is ten times lower than that of current products on the market and demonstrates the potential of this approach. Preliminary findings from this study suggest that X-tec silica particles may enhance the effectiveness of IRS using clothianidin. However, further extensive research is needed to confirm this. Full article
(This article belongs to the Special Issue Insecticide Resistance in Mosquitoes)
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16 pages, 2240 KB  
Article
Foliar Transpiration Inhibitor Reduces Cd Accumulation in Rice Grain: The Potential Effect of the Endophytic Bacterial Community
by Ge Lei, Huijuan Song, Ziwen Gan, Yunchou Yang and Anwei Chen
Toxics 2025, 13(9), 755; https://doi.org/10.3390/toxics13090755 (registering DOI) - 5 Sep 2025
Viewed by 193
Abstract
Excess Cd in soils can be accumulated in rice, presenting a serious human health risk. The effect of foliar transpiration inhibitors (TIs) on the Cd content and the endophytic bacterial community in rice plants was unclear. We evaluated the key part of the [...] Read more.
Excess Cd in soils can be accumulated in rice, presenting a serious human health risk. The effect of foliar transpiration inhibitors (TIs) on the Cd content and the endophytic bacterial community in rice plants was unclear. We evaluated the key part of the rice plant to control the Cd translocation and the profile of the endophytic bacterium structure after spraying with foliar reagents; some possible typical endophytes were induced by the TIs to inhibit the Cd translocation in the rice plant. The rice plants in three sites with different available Cd content were sprayed with foliar TIs. We assessed the Cd, N, P, K and water-soluble saccharide (WSS) in different parts of the rice plant and the endophytic bacteria community in the stem. Foliar application of TIs reduced Cd translocation factor (TFCd) by ~20% from the root to the grain compared with that of CK. The TI can increase the adsorptive site concentration of stem nodes from 5.10 to 6.83 mmol/g. The diversity of the endophytic bacteria community was enhanced after application of TI, and the Shannon index increased from 3.29 to 3.92. The endophytic bacterial community induced by TI showed higher potentiality on the biofilm and stress-tolerant and metal-transport functions than that of CK, respectively. The relative abundances of Burkholderiaceae and Bacterium_g_Anaeromyxobacter were significantly negatively correlated (p < 0.05), with TFCd and positively correlated (p < 0.05), with water-solution saccharide content, simultaneously. The TI enhanced the endophytic diversity and amount. A high abundance of special endophytic bacteria induced by TI might decrease the TFCd. Full article
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22 pages, 457 KB  
Article
The Effects of Biostimulants on the Physiological Processes of Yield Formation and Resistance of Apples to Spring Frosts
by Zoya Evgen’evna Ozherelieva, Pavel Sergeevich Prudnikov, Anna Yur’evna Stupina and Anzhelika Olegovna Bolgova
Horticulturae 2025, 11(9), 1075; https://doi.org/10.3390/horticulturae11091075 - 5 Sep 2025
Viewed by 273
Abstract
The present research aimed to evaluate the effectiveness of new organo-mineral biostimulants in an apple orchard, including their relevance to spring frosts and to enhancing yield. The study evaluated the effects of foliar sprays with organo-mineral fertilizers on apple yield, comparing three treatments: [...] Read more.
The present research aimed to evaluate the effectiveness of new organo-mineral biostimulants in an apple orchard, including their relevance to spring frosts and to enhancing yield. The study evaluated the effects of foliar sprays with organo-mineral fertilizers on apple yield, comparing three treatments: 1—control (no treatment); 2—foliar spray with a 1% blend of “WPU” Antifreeze and 1% “WP Drip Ca + Mg”; 3—foliar application using a 3% solution of both “WPU” Antifreeze and “WP Drip Ca + Mg”. The NPC “White Pearl” foliar sprays exhibited cryoprotective properties to spring frosts through multiple mechanisms, i.e., prevention of cellular dehydration via elevated bound water content and accumulation of osmoprotective compounds including proline and soluble sugars. This research shows that the applied treatments improved carbohydrate metabolism by enhancing the biosynthesis of glucose and starch, as well as changing the donor–acceptor relationships between the leaf apparatus and the fruit toward the forming apple, promoting a better outflow of assimilates into ripening fruits. The 1% solution treatment enhanced apple yield by 70% (1.7-fold) relative to the untreated control. These findings indicate that the “White Pearl” organo-mineral fertilizer NPC (especially at 1% concentration) could serve as an effective supplement to conventional apple farming practices, boosting overall productivity. Full article
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22 pages, 1741 KB  
Review
Nanofluids for Sustainable Heat Transfer Enhancement: Beyond Thermal Conductivity
by Yunus Tansu Aksoy
Sustainability 2025, 17(17), 8006; https://doi.org/10.3390/su17178006 - 5 Sep 2025
Viewed by 392
Abstract
Nanofluids have long been explored for enhancing heat transfer, with early studies focusing primarily on improved thermal conductivity. However, in spray and droplet cooling applications, recent research indicates that conductivity alone cannot fully account for the observed performance gains. Additional mechanisms, such as [...] Read more.
Nanofluids have long been explored for enhancing heat transfer, with early studies focusing primarily on improved thermal conductivity. However, in spray and droplet cooling applications, recent research indicates that conductivity alone cannot fully account for the observed performance gains. Additional mechanisms, such as Brownian-motion-induced convection, dynamic wetting, and nanoparticle-driven surface modification, significantly affect droplet impact dynamics, spreading behavior, boiling transitions, and transient heat transfer during impact and evaporation. This review critically synthesizes these effects, emphasizing how nanofluids interact with complex flow fields, steep thermal gradients, and heated substrates. It also examines emerging strategies for optimizing nanofluid design, including hybrid suspensions and phase-change-enhanced formulations. These developments open new avenues for high-efficiency cooling in electronics, renewable energy systems, and industrial spray processes. By moving beyond thermal conductivity as the sole performance metric, this review promotes a multi-scale, interdisciplinary framework for advancing nanofluid-based thermal technologies that align with sustainability, energy efficiency, and cost effectiveness. Full article
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