Search Results (2,531)

Since tires from end-of-life vehicles are not entirely biodegradable and pose a serious environmental problem, their disposal has become a significant global environmental concern. One technique to decrease these environmental issues is incorporating waste rubber to make sustainable green concrete. This study examined the usage of waste supplementary cementitious materials (SCMs) such as fly ash (FA), metakaolin (MK), marble powder (MP), slag (SL), and silica fume (SF) for surface precoating of crumb rubber (CR) to improve the mechanical properties of the produced crumb rubber concrete (CRC) by strengthening the bond between CR and cement paste in the interfacial transition zone (ITZ). The CR replaced (0, 15%, and 25%) of sand by weight in the preparation of CRC mixtures. A total of eleven CRC mixes were cast to investigate the fresh properties, compressive strength, and splitting tensile strength. In addition, the compressive stress-strain curve was investigated, and peak stress, peak strain, energy absorption, toughness, and modulus of elasticity have been evaluated. The outcomes showed that precoating CR using FA, followed by MK, has the strongest effect on increasing CRC compressive performance. The 25% substitution of sand with FA-treated CR increased compressive strength after 28 days, splitting tensile strength, peak stress, toughness, and modulus of elasticity by 34.7%, 23.7%, 34.8%, 26.1%, and 25.2%, respectively, in comparison to the same percentage of untreated CR. The proposed approach demonstrates a viable pathway for integrating waste materials and SCM-based technologies to develop high-performance, sustainable cementitious composites. Full article

Carbon fiber textile-reinforced engineered cementitious composite (CTR-ECC) is widely utilized in structural strengthening applications due to its advantages of low weight and high strength. A comprehensive understanding of its mechanical behavior under off-axis tension is crucial for addressing the prevalent off-axis stress states in engineering practice. This paper presents an experimental investigation on the off-axis tensile properties of CTR-ECC. Specimens were fabricated with four off-axis angles: 0°, 15°, 30°, and 45°. The study revealed three main findings: (1) Under axial (0°) loading, failure is characterized by yarn fracture and interface slip, whereas off-axis tension induces a stable progressive delamination failure in textile-reinforced ECC systems. (2) While CTR-ECC exhibits higher tensile strength than plain ECC at all angles, its strength decreases significantly as the off-axis angle increases (e.g., a 27.1% reduction at 15°). Off-axis layouts, however, substantially improve energy absorption, with strain energy density increasing by up to 368.4% at 30°. (3) A phenomenological constitutive model was developed, which can adequately capture the stress–strain response of CTR-ECC under various off-axis angles, with coefficients of determination (R²) exceeding 0.9 in all cases. These results provide important insights into the failure mechanisms and performance design of CTR-ECC under off-axis tension conditions. Full article

Basalt fiber-reinforced polymer (BFRP) composites are increasingly considered as a sustainable alternative to traditional FRP systems for the strengthening of reinforced concrete (RC) structures, owing to their favorable mechanical properties, durability, and lower environmental impact. This study investigates the effectiveness of externally bonded BFRP strips for the strengthening of RC beam–column joints, with particular attention to the influence of strengthening layout on the structural response. An experimental program was carried out on full-scale RC beam–column joint specimens subjected to monotonic loading with load–unload cycles of increasing amplitude. Each specimen was first tested in its original configuration to induce controlled damage and subsequently strengthened using BFRP strips arranged according to two different layouts. This approach enabled a direct comparison between the behaviour of pre-damaged and retrofitted specimens and allowed the contribution of the BFRP reinforcement to be clearly identified. BFRP strengthening markedly improves joint performance, enhancing strength, ductility, and energy dissipation while limiting stiffness degradation. The results underline the critical role of the strengthening layout in governing the effectiveness of the composite system, as well as the influence of substrate cracking in the activation of the BFRP reinforcement. Full article

A comprehensive first-principles investigation of bulk and surface Cu defects in Zn-based chalcogenides (ZnO, ZnS, and ZnSe) is presented, aimed at assessing the effect of Cu doping on the optoelectronic properties of these materials and at addressing the photocatalytic activity towards the hydrogen evolution reaction (HER). Defect formation energies, adiabatic and optical charge-transition levels of the bulk materials are determined, and their dependence on growth conditions and Fermi-level position is analysed. The results indicate that, whereas ZnO supports both donor- and acceptor-like Cu defects with pronounced Jahn-Teller distortions, ZnS and ZnSe predominantly stabilise substitutional Cu as a mid-gap acceptor with weaker electron-lattice coupling and similar absolute transition levels. Calculated vertical transition energies rationalise the characteristic emission of Cu-doped samples in terms of defect-mediated optical cycles. The focus is then placed on surface energetics, which differ markedly from bulk behaviour and critically influence photocatalytic performance. Explicit modelling of HER demonstrates that Cu substitution dramatically reduces the overpotential on ZnS and ZnSe by tuning hydrogen adsorption toward the Sabatier optimum, while in ZnO the beneficial effect of Cu doping is diminished by the excessive strengthening of the adsorbate-surface interactions. Finally, the measured HER activities are rationalised by proposing a defect-mediated mechanism involving electron trapping at the surface Cu site, cooperative proton adsorption, and hydride formation. These findings establish defect thermodynamics and surface charge localisation as key design parameters for optimising materials engineering strategies in photocatalytic applications. Full article

In this paper, the supersaturated solid solution of Al-Cu3-Si-Mg alloy prepared by molten metal die forging (MMDF) was used as the research object. The formation and evolution of precipitates during aging treatment were investigated through experiments at different temperatures and times, and the precipitation mechanisms and sequences of various precipitates were analyzed. The main precipitated phases formed in the supersaturated solid solution of the Al-Cu3-Si-Mg alloy after aging treatment are θ(Al₂Cu), θ′(Al_3.6Cu₂), γ′(Al_0.63Mg_0.37), and η′(Cu, Si). Based on XRD and TEM analysis under different aging treatment conditions, the precipitation sequence is determined as follows: SSS → GP₀ → GP₀ + γ′ → GP₀ + (γ′ + γ) + θ″ + η′ → (γ′ + γ) + (θ″ + θ′) + (η′ + η) → (γ′ + γ) + (θ + θ′) + (η′ + η) → (γ′ + γ) + (θ + θ′) + η → γ + θ + η. After aging treatment at 165–185 °C for 4 h, chain-like θ(Al₂Cu) precipitates are discontinuously distributed at the α-Al grain boundaries, and disc-shaped θ′(Al_3.6Cu₂) and θ″(Al₂Cu) phases mainly precipitate within the grains. When the temperature exceeds 185 °C, the chain-like θ(Al₂Cu) precipitates at the grain boundaries gradually become continuous, and the fraction increase from 1.5% to 15.2%. The amount of the θ(Al₂Cu) phase in the grains increases from 2 to 6, and the size of θ′(Al_3.6Cu₂) decreases obviously. After aging treatment at 185 °C for 5–6 h, the chain-like θ(Al₂Cu) precipitates become more continuous, and the fraction continues to increase from 32.1% to 52.6%. The effect of chain-like precipitates at grain boundaries on the mechanical properties of the matrix is opposite to the strengthening contribution of dispersed intragranular precipitates. When the aging condition exceeds 185 °C × 5 h, the excessive formation of chain-like grain boundary precipitates causes both the strength and hardness of the alloy to show a decreasing trend. Full article

This research developed a ZrSi₂-TiB₂-modified alumina fiber/boron phenolic resin ceramizable composite intended to fulfill the criteria for high-temperature resistance, oxidation resistance, and structural load-bearing capacity in reusable thermal protection systems. The composite exhibits a low thermal conductivity of 0.405 W·m⁻¹·K⁻¹, a reduced density of 2.11 g·cm⁻³, and a high mass retention rate of 89.45% after heat treatment at 1200 °C in air. During thermal cycling at 1200 °C with a 30 min dwell time, it consistently demonstrates excellent stability, mass retention, and mechanical properties, indicating its potential for applications in reusable thermal protection systems. Following 20 cycles, the variation in length and width remains below 0.6%, the mass retention surpasses 80%, and the flexural strength remains above 20 MPa after 15 cycles. Microstructural evolution and thermodynamic analysis disclose that the in situ ceramization reaction of ZrSi₂ and TiB₂ consumes oxygen, inhibits oxygen diffusion, and fills pores and microcracks with oxidation products (SiO₂ and B₂O₃), thereby forming self-healing and densifying phases. This synergistic mechanism of self-healing and densification ensures the reusability of the composite. The research illustrates the performance evolution patterns and strengthening mechanisms of the composite under extreme thermal conditions, confirming its outstanding performance in repeated usage evaluations. Full article

To address the insufficient strength of friction-stir-welded (FSW) ultra-high-strength Al–Cu–Li alloy joints, the effects of post-weld heat treatment (PWHT) on microstructural evolution and mechanical properties were systematically investigated. The as-welded joint showed a “W”-shaped microhardness profile, with the minimum value located in the thermo-mechanically affected zone (TMAZ), mainly caused by the dissolution of T₁ phases and precipitation of coarse AlCu, AlCuMg, and AlCuMn phases during welding. Direct artificial aging at 155 °C for 24 h failed to improve joint strength due to solute depletion induced by pre-existing coarse secondary phases. Solution treatment re-dissolved coarse precipitates into the matrix, and subsequent aging led to uniform precipitation dominated by T₁ and θ′ phases, with a consistent microhardness of ~155 HV across all zones. By introducing pre-stretching deformation after solution treatment, T₁ became the dominant strengthening phase in all regions, accompanied by a remarkable increase in both microhardness and tensile strength. With 3% pre-stretching, the microhardness reached 185 HV, and the ultimate tensile strength of the joint reached 600 MPa, corresponding to a joint efficiency as high as 95%, which is superior to most reported values for Al–Li alloy FSW joints. This study clarifies the precipitation evolution mechanism under tailored PWHT and provides an effective strategy for property regulation of high-performance Al–Cu–Li alloy FSW structures in aerospace applications. Full article

In this study, 310S austenitic stainless-steel was welded using a laser with varying amounts of Nb to systematically investigate the effect of Nb on solidification cracking susceptibility, mechanical properties, and corrosion resistance of the weld. Under the present experimental conditions, the critical restraint width was higher for the 0.58 wt.% Nb and 1.45 wt.% Nb welds than for the Nb-free and 2.3 wt.% Nb welds, indicating that Nb addition affected the solidification cracking response of the weld. At low-to-moderate Nb contents, Nb can aggravate compositional segregation and increase the presence of low-melting-point liquid films, thereby increasing cracking susceptibility. At higher Nb contents, the reduced cracking susceptibility was accompanied by microstructural refinement and changes in the distribution of Nb-rich constituents during solidification. With increasing Nb content, the number of precipitated phases in the weld increases, mainly distributed at the austenite grain boundaries in granular, elongated, and chain-like forms. The introduction of Nb generally increases the microhardness and tensile strength of the welded joint, attributed to grain refinement strengthening and solid-solution strengthening. The reduction in area first increased and then decreased, suggesting that excessive Nb addition may reduce ductility because of the increased amount of grain-boundary precipitates and local strengthening heterogeneity. With increasing Nb content, the Ir/Ia ratio decreased from 67.6% to 52.2%, suggesting improved intergranular corrosion resistance. This improvement is likely related to the preferential reaction of Nb with carbon, which may suppress the formation of Cr-depleted zones at grain boundaries. Overall, Nb addition improved the corrosion resistance and increased the hardness and tensile strength of the weld; however, its effect on solidification cracking susceptibility was non-monotonic, indicating that careful control of Nb content is required to balance cracking susceptibility, mechanical properties, and corrosion resistance. Full article

In recent years, the rapid rise of antimicrobial resistance has intensified the search for alternative agents to treat drug-resistant infections. Antimicrobial peptides (AMPs) are promising therapeutic candidates due to their broad-spectrum activity, diverse mechanisms of action, relatively low risk of resistance development, and potential for use in combination therapies. This review outlines current knowledge on the properties and mechanisms of action of AMPs compared to conventional antibiotics. Furthermore, it discusses synergistic interactions between antimicrobial peptides and antibiotics, focusing on the underlying mechanisms, therapeutic implications, and translational challenges. It also summarizes key in vitro and in vivo studies, demonstrating enhanced antimicrobial efficacy of AMP–antibiotic combinations, including mechanisms such as increased membrane permeability, disruption of intracellular pathways, inhibition of biofilm formation, and efflux pump inhibition. The immunomodulatory and wound-healing properties of AMPs are also highlighted as factors that further strengthen their therapeutic potential in vivo. The review concludes with an overview of the main limitations hindering clinical translation and highlights ongoing research efforts aimed at optimizing AMP-based combination therapies against multidrug-resistant pathogens. Full article

Operational shutdowns following hazardous liquid pipeline incidents are critical but poorly understood events that impact the U.S. energy supply. Although prior research has investigated the causes and outcomes of pipeline failures, limited work has explained what drives both the likelihood of a shutdown and the duration once it begins. The goal of this study is to address this gap by developing a hurdle regression model to examine the two-stage shutdown mechanism in pipeline incidents, using the Pipeline and Hazardous Materials Safety Administration (PHMSA) incident dataset from 2010 to 2025. The hurdle model consists of a logistic regression restricted to pre-decision predictors to model the probability of shutdown, and a lognormal regression to model the duration of those leading to shutdown. The results revealed that distinct factors are associated with each outcome. Shutdown probability is associated with pre-decision operational and contextual indicators, including operating pressure at the time of incident, accident type, location, monitoring presence, and response delay. In contrast, shutdown duration is associated with logistical complexity and post-incident severity, including incidents at pipeline crossings, pressures exceeding 110% of the maximum operating pressure, and reported property damage. These findings, while exploratory in nature given the use of public incident data, offer practical reference points for operators and regulators who aim to shorten recovery time and strengthen the resilience of energy infrastructure. Full article

Aiming to address the problems of shield chamber blockage and poor muck discharge faced by earth pressure balance shields during tunneling in sandy strata, bentonite slurry is used for muck improvement. Using a multi-scale approach combining macro-scale experiments, micro-scale analysis, and molecular dynamics simulations, this study systematically investigates the interface interactions between particles of sandy soil in shield tunneling and the improvement mechanism of sodium-based bentonite slurry additives. Through the macroscopic experiment, the sodium bentonite slurry soil–water ratio of 1:7 and injection ratio of 25% showed the best improvement effect. After improvement, the permeability coefficient decreased by 99.72%; the cohesion of the excavated soil increased from 3.055 kPa to 11.458 kPa, representing a 275.06% increase; and the angle of internal friction decreased from 42.318° to 36.985°, a decrease of 12.60%. The improvement was significant. Through SEM, XRD, and FTIR microanalysis, it is found that bentonite slurry forms a flexible film on the surface of sandy soil. By coating sand particles, filling voids in the soil, and enhancing interparticle cohesion, it improves the properties of the soil. On the nanoscale, a Na-MMT/SiO₂ system model is established based on molecular dynamics simulations to elucidate the interactions between bentonite slurry and sand particle interfaces. The results indicate the presence of van der Waals forces and hydrogen bonds between Na-MMT and SiO₂. Interlayer water molecules form a hydrogen bond network that strengthens interfacial bonding, enabling bentonite slurry to tightly adhere to soil particle surfaces. This improves the microstructure of the soil, thereby enhancing its macroscopic properties. Full article

This study presents a hierarchical conductive-network strategy to overcome the performance trade-off in cement structural supercapacitors (CSSCs). By incorporating one-dimensional carbon nanotubes (CNTs) and two-dimensional graphene oxide (GO) into Portland cement, we simultaneously enhance its electrochemical and mechanical properties. The approach exploits the complementary roles of the two nanomaterials: CNTs establish a three-dimensional percolation network that facilitates electron transport, while GO promotes formation of a denser calcium silicate hydrate (C-S-H) gel and refines the pore structure by complexing with calcium ions, thereby improving ionic pathways. The k12gc sample attains a specific capacitance of 66.8 F g⁻¹ at 0.1 mA cm⁻², a 58.4% rise in conductivity and a 63% reduction in charge-transfer resistance. At the same time, the composite reduces harmful macropores by 27.9% and strengthens the material, with compressive and flexural strengths increasing by 4.8% and 8.3%, respectively. This work establishes a rational design principle based on functional division between CNTs and GO for developing high-performance, multifunctional CSSCs. Full article

The pursuit of lightweight, high-performance sports equipment drives the development of Al-Li-Mg alloys, yet systematic studies linking a complete processing route, from as-cast to peak-aged condition, to microstructural evolution and mechanical properties remain limited. This work provides the first comprehensive investigation of how a sequential processing route (homogenization, hot rolling, solution treatment, and peak aging) transforms the coarse as-cast structure of an Al-Li-Mg alloy into a refined, recrystallized grain architecture with a uniform dispersion of nanoscale δ′-Al₃Li precipitates. This microstructural transformation leads to a dramatic enhancement in mechanical properties: the peak-aged alloy exhibits increases of approximately 92%, 139%, and 925% in yield strength, ultimate tensile strength, and elongation, respectively, relative to the as-cast condition. The dominant strengthening mechanism is identified as dislocation shearing of coherent δ′-Al₃Li precipitates (average radius ~5 nm, well below the ~25 nm transition threshold for Orowan looping), which enhances strength without compromising ductility, demonstrating the critical role of the processing route in tailoring microstructures and mechanical properties for lightweight sports equipment. Full article

Point cloud registration in environments lacking rich textures or containing repetitive structures remains highly susceptible to misalignments. The core challenge lies in balancing the demand for extracting highly distinctive local features with the computational cost of global context modeling. In this paper, we propose a robust registration framework that efficiently combines rotation-equivariant geometric representations with state space models of linear complexity to mitigate feature ambiguity and mismatch. First, a multivariate geometric encoding mechanism is embedded within convolutional layers, enhancing local feature distinctiveness under strict rotation equivariance by explicitly leveraging surface properties. Second, to efficiently establish long-range spatial dependencies, we replace standard dense attention with a hybrid geometry-state aggregation module. This module integrates local geometric self-attention with the Mamba architecture, strengthening focus on overlapping regions without the quadratic computational burden. Finally, we optimize the generated correspondences through a physically consistent hypothesis generator to compute reliable rigid transformation results. On standard benchmarks, our framework demonstrates exceptional robustness to ambiguous matches, achieving a 96.3% registration recall on the 3DMatch dataset and outstanding accuracy on the KITTI dataset. Full article

Fungal infections represent an escalating global health challenge due to their increasing incidence, the emergence of multidrug-resistant pathogens, and the limited development of new antifungal agents. Therapeutic efficacy is compromised by mutations in drug targets, overexpression of efflux pumps, alterations in the ergosterol biosynthetic pathway, biofilm-associated tolerance, and extensive genomic plasticity. The growing prevalence of antifungal resistance and the limited availability of effective therapeutic options highlight the urgent need to strengthen epidemiological surveillance and accelerate research into innovative therapeutic strategies. In this review, we discuss the potential of lipid-based drug delivery systems (LDDSs) as a versatile strategy to optimize antifungal administration and overcome resistance mechanisms. Liposomes (LPs), solid lipid nanoparticles (SLNs), nanostructured lipid carriers (NLCs), and lipid nanoparticles (LNPs) offer high biocompatibility, efficient encapsulation of hydrophobic compounds, structural stability, and controlled drug release. Their nanoscale properties facilitate penetration into biofilms, promote intracellular uptake, and reduce the impact of efflux-mediated drug extrusion, thereby improving cellular penetration and circumventing resistance pathways. In addition, LDDSs increase bioavailability, reduce toxicity, and promote drug accumulation within poorly accessible tissue compartments. Overall, LDDSs represent a promising approach to expand the therapeutic arsenal against both superficial and invasive fungal infections, particularly those caused by multidrug-resistant pathogens. Full article