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18 pages, 5808 KB  
Article
Numerical Investigation of the Reinforcement Effect of Fully Grouted Bolts on Layered Rock Masses Under Triaxial Loading with One Free Surface
by Shiming Jia, Yiming Zhao, Zhengzheng Xie, Zhe Xiang and Yanpei An
Appl. Sci. 2025, 15(17), 9689; https://doi.org/10.3390/app15179689 - 3 Sep 2025
Abstract
The layered composite roof of a coal mine roadway exhibits heterogeneity, with pronounced variations in layer thickness and strength. Fully grouted rock bolts installed in such layered roofs usually penetrate two or more strata and bond with them to form an integrated anchorage [...] Read more.
The layered composite roof of a coal mine roadway exhibits heterogeneity, with pronounced variations in layer thickness and strength. Fully grouted rock bolts installed in such layered roofs usually penetrate two or more strata and bond with them to form an integrated anchorage system. Roof failure typically initiates in the shallow strata and progressively propagates to deeper layers; thus, the mechanical properties of the rock at the free surface critically influence the overall stability of the layered roof and the load-transfer behavior of the bolts. In this study, a layered rock mass model was developed using three-dimensional particle flow code (PFC3D), and a triaxial loading scheme with a single free surface was applied to investigate the effects of free-surface rock properties, support parameters, and confining pressure on the load-bearing performance of the layered rock mass. The main findings are as follows: (1) Without support, the ultimate bearing capacity of a hard-rock-free-surface specimen is about 1.2 times that of a soft-rock-free-surface specimen. Applying support strengths of 0.2 MPa and 0.4 MPa enhanced the bearing capacity by 29–38% and 46–75%, respectively. (2) The evolution of axial stress in the bolts reflects the migration of the load-bearing core of the anchored body. Enhancing support strength improves the stress state of bolts and effectively mitigates the effects of high-stress conditions. (3) Under loading, soft rock layers exhibit greater deformation than hard layers. A hard-rock free surface effectively resists extrusion deformation from deeper soft rocks and provides higher bearing capacity. Shallow free-surface failure is significantly suppressed in anchored bodies, and “compression arch” zones are formed within multiple layers due to bolt support. Full article
(This article belongs to the Special Issue Innovations in Rock Mechanics and Mining Engineering)
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25 pages, 3974 KB  
Article
Modular Deep-Learning Pipelines for Dental Caries Data Streams: A Twin-Cohort Proof-of-Concept
by Ștefan Lucian Burlea, Călin Gheorghe Buzea, Florin Nedeff, Diana Mirilă, Valentin Nedeff, Maricel Agop, Dragoș Ioan Rusu and Laura Elisabeta Checheriță
Dent. J. 2025, 13(9), 402; https://doi.org/10.3390/dj13090402 - 2 Sep 2025
Abstract
Background: Dental caries arise from a multifactorial interplay between microbial dysbiosis, host immune responses, and enamel degradation visible on radiographs. Deep learning excels in image-based caries detection; however, integrative analyses that combine radiographic, microbiome, and transcriptomic data remain rare because public cohorts are [...] Read more.
Background: Dental caries arise from a multifactorial interplay between microbial dysbiosis, host immune responses, and enamel degradation visible on radiographs. Deep learning excels in image-based caries detection; however, integrative analyses that combine radiographic, microbiome, and transcriptomic data remain rare because public cohorts are seldom aligned. Objective: To determine whether three independent deep-learning pipelines—radiographic segmentation, microbiome regression, and transcriptome regression—can be reproducible implemented on non-aligned datasets, and to demonstrate the feasibility of estimating microbiome heritability in a matched twin cohort. Methods: (i) A U-Net with ResNet-18 encoder was trained on 100 annotated panoramic radiographs to generate a continuous caries-severity score from a predicted lesion area. (ii) Feed-forward neural networks (FNNs) were trained on supragingival 16S rRNA profiles (81 samples, 750 taxa) and gingival transcriptomes (247 samples, 54,675 probes) using randomly permuted severity scores as synthetic targets to stress-test preprocessing, training, and SHAP-based interpretability. (iii) In 49 monozygotic and 50 dizygotic twin pairs (n = 198), Bray–Curtis dissimilarity quantified microbial heritability, and an FNN was trained to predict recorded TotalCaries counts. Results: The U-Net achieved IoU = 0.564 (95% CI 0.535–0.594), precision = 0.624 (95% CI 0.583–0.667), recall = 0.877 (95% CI 0.827–0.918), and correlated with manual severity scores (r = 0.62, p < 0.01). The synthetic-target FNNs converged consistently but—as intended—showed no predictive power (R2 ≈ −0.15 microbiome; −0.18 transcriptome). Twin analysis revealed greater microbiome similarity in monozygotic versus dizygotic pairs (0.475 ± 0.107 vs. 0.557 ± 0.117; p = 0.0005) and a modest correlation between salivary features and caries burden (r = 0.25). Conclusions: Modular deep-learning pipelines remain computationally robust and interpretable on non-aligned datasets; radiographic severity provides a transferable quantitative anchor. Twin-cohort findings confirm heritable patterns in the oral microbiome and outline a pathway toward future clinical translation once patient-matched multi-omics are available. This framework establishes a scalable, reproducible foundation for integrative caries research. Full article
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18 pages, 2030 KB  
Article
Evaluation of Photosynthetic Performance and Adaptability of Grape Varieties in Arid Regions
by Runze Wang, Haixia Zhong, Fuchun Zhang, Xiaoming Zhou, Meijuan Cheng, Hengde Liu, Shuping Lin, Liping Wang, Xinyu Wu and Liqiang Liu
Horticulturae 2025, 11(9), 1041; https://doi.org/10.3390/horticulturae11091041 - 2 Sep 2025
Viewed by 34
Abstract
Photosynthetic characteristics are critical for grape growth and development. Drought conditions in arid regions significantly affect these characteristics. To identify grape varieties better suited for cultivation in arid environments, this study evaluated the leaf phenotypes and photosynthetic characteristics of 27 table grape varieties [...] Read more.
Photosynthetic characteristics are critical for grape growth and development. Drought conditions in arid regions significantly affect these characteristics. To identify grape varieties better suited for cultivation in arid environments, this study evaluated the leaf phenotypes and photosynthetic characteristics of 27 table grape varieties in Hotan Prefecture, China. Results revealed significant variations in leaf phenotypes and chlorophyll content (SPAD) among varieties under Hotan’s drought conditions. ‘Kyoho’ exhibited the largest leaf area (254.34 cm2), while ‘Munage’ had the smallest (112.43 cm2), and ‘Manaizi’ showed the highest chlorophyll content (SPAD = 44.21). ‘Munage’ and ‘Flame Seedless’ recorded the highest net photosynthetic rates (PNmax = 16.24 and 16.23 μmol·m−2·s−1, respectively), while ‘Thompson Seedless’ had the lowest respiratory loss (RD = 1.15 μmol·m−2·s−1) and light compensation point (Ic = 22.41 μmol·m−2·s−1), with a highly significant positive correlation between RD and Ic. ‘Crimson Seedless’ exhibited the highest light saturation point (Isat = 2745.15 μmol·m−2·s−1). Chlorophyll fluorescence analysis indicated that ‘Autumn Black’ had the highest PSII photochemical yield (Fv/Fm = 0.84), while ‘Zicuiwuhe’ showed high energy transfer indices (PIabs = 1.78, PItotal = 1.66) and electron transfer efficiency (φEo = 0.39). PIabs was significantly correlated with Fv/Fm, Fv/Fo, and energy flux parameters. ‘Molixiang’ demonstrated superior energy utilization, with the highest light absorption (ABS/CSm = 2440.8) and electron transfer flux (ETo/CSm = 874) and the lowest energy dissipation (DIo/CSm = 455.8), supported by a negative correlation between energy dissipation (DIo/CSm) and photochemical efficiency (φEo). Principal component analysis revealed that ‘Molixiang’ had the highest comprehensive photosynthetic adaptability score (0.97), followed by ‘Zicuiwuhe’ (0.79) and ‘Hetianhong’ (0.73), under Hotan’s drought stress conditions. These findings provide valuable insights for selecting and breeding grape varieties adapted to arid environments and climate change. Full article
(This article belongs to the Special Issue Advances in Tree Crop Cultivation and Fruit Quality Assessment)
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20 pages, 12575 KB  
Article
Seismic Fragility of Large-Span Elevated U-Shaped Aqueduct Based on Incremental Dynamic Analysis
by Jing Wei and Xinjun Yan
Appl. Sci. 2025, 15(17), 9623; https://doi.org/10.3390/app15179623 - 1 Sep 2025
Viewed by 150
Abstract
This study uses a U-shaped aqueduct structure in a specific irrigation area as the research object to examine the damage patterns of large-span elevated U-shaped aqueduct structures under seismic action. A single-span aqueduct model that integrates fluid–structure interaction is created with the finite [...] Read more.
This study uses a U-shaped aqueduct structure in a specific irrigation area as the research object to examine the damage patterns of large-span elevated U-shaped aqueduct structures under seismic action. A single-span aqueduct model that integrates fluid–structure interaction is created with the finite element program ANSYS. The incremental dynamic analysis approach is utilized to perform nonlinear dynamic time–history assessments for three types of bearings—plate rubber bearings, pot rubber bearings and lead-core rubber bearings—under conditions of an empty condition, a half-full condition and a design water level. Seismic fragility curves for the bearings and piers subjected to transverse seismic stress are developed using capacity–demand ratio models and specified damage limit states. The findings demonstrate that the likelihood of aqueduct components being damaged increases substantially as seismic intensity increases, with bearings failing before piers. Under the conditions of empty, half-full and design water levels, the structural mass increases as a result of higher water levels. This alters the dynamic response characteristics and increases the likelihood of failure in a variety of damage states. The probability of plate rubber bearings experiencing minor damage exceedance increases from 11.75% to 61.6% as the water level rises from vacant to design conditions. Lead-core rubber bearings provide better seismic isolation than plate rubber bearings and pot rubber bearings. This greatly lowers the aqueduct structure’s displacement response and damage likelihood. Under design water level circumstances, the chance of mild damage to lead rubber bearings is 8.64%, at a peak ground acceleration of 0.4 g. The damage probabilities for the pot rubber bearings and the plate rubber bearings are 80.68% and 97.45%, respectively. The research findings establish a theoretical foundation for the seismic design and damage evaluation of aqueduct structures in places with high seismic activity, ensuring the stable operation of water transfer projects and sustainable water resource utilization, presenting considerable technical applicability. Full article
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25 pages, 4353 KB  
Article
Adaptive Gradient Loading Mechanism of Ball–Column Composite Bearings Considering Collar Deformation
by Guanjie Li, Yongcun Cui, Hedong Wei, Zhiwen Yang and Yanguang Ni
Machines 2025, 13(9), 785; https://doi.org/10.3390/machines13090785 - 1 Sep 2025
Viewed by 138
Abstract
To address the issue of uneven load and premature failure in ball–column composite bearings caused by ring deformation, this study develops a mechanical analysis model, considering ring deformation based on flexible ring theory and rolling bearing design. It systematically examines radial deflection of [...] Read more.
To address the issue of uneven load and premature failure in ball–column composite bearings caused by ring deformation, this study develops a mechanical analysis model, considering ring deformation based on flexible ring theory and rolling bearing design. It systematically examines radial deflection of the ring and how key parameters affect load distribution and stress. The results demonstrate that the elastic deformation of the collar redistributes the load, reduces the roller column’s load-carrying efficiency, and disrupts the optimal load distribution mode. Increasing the number of loaded rolling elements significantly improves the load uniformity, reduces the peak contact stress, and enhances the overall load-carrying performance. By optimizing the clearance matching across three bearings rows, a load-adaptive gradient bearing mechanism is realized by dynamically transferring, 70–90% of the heavy-load optimal distribution. These findings address the domestic research gaps and offer theoretical support for the performance prediction and optimal design of integrated ball–column composite bearings. Full article
(This article belongs to the Section Machine Design and Theory)
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17 pages, 991 KB  
Article
Post-Traumatic Stress in Adolescence: The Mediating Role of Time Perspective Between Trauma Exposure, PTSD Symptoms, and Cannabis Use
by Alexander Pütz, Gerhard Hapfelmeier, Alexandra Martin, Stephan Bender and Marco Walg
Eur. J. Investig. Health Psychol. Educ. 2025, 15(9), 177; https://doi.org/10.3390/ejihpe15090177 - 1 Sep 2025
Viewed by 217
Abstract
Post-traumatic stress symptoms (PTSSs) are associated with an imbalanced time perspective (TP) as well as with unhealthy substance use. Although neurodevelopmental processes during adolescence may impact PTSS, most etiological models of post-traumatic stress disorder (PTSD) are derived from studies with adults and neglect [...] Read more.
Post-traumatic stress symptoms (PTSSs) are associated with an imbalanced time perspective (TP) as well as with unhealthy substance use. Although neurodevelopmental processes during adolescence may impact PTSS, most etiological models of post-traumatic stress disorder (PTSD) are derived from studies with adults and neglect possible distinctive characteristics in adolescent PTSD. This study examined possible direct and mediated relations between exposure to potentially traumatic experiences (EPTEs) and PTSS with TP as a potential mediator. In addition, the study investigated the direct and indirect effects of EPTE, TP, and PTSS on cannabis use. The aim of this study was to investigate whether findings from adult studies can be transferred to adolescent PTSD. One hundred and five patients between 14 and 20 years of age were recruited from child and adolescent psychiatric units. They answered questionnaires to assess EPTE, PTSS, TP, and cannabis use. Participants with clinically relevant PTSS showed imbalanced TP with a high orientation to negative past and a low orientation to positive past and future. Higher EPTE was associated with higher level of PTSS, but TP mediated the level of PTSS in this relation. PTSS predicted the frequency of cannabis use. It may therefore be beneficial to consider TP in PTSD therapy with the aim of reducing deviation from balanced TP and PTSS and preventing comorbid substance use. Full article
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22 pages, 8273 KB  
Article
The Influence of Thermal Stresses on the Load Distribution and Stress–Strain State of Cycloidal Reducers
by Milan Vasić, Mirko Blagojević, Samir Dizdar and Smajo Tuka
Appl. Sci. 2025, 15(17), 9607; https://doi.org/10.3390/app15179607 - 31 Aug 2025
Viewed by 172
Abstract
The design of cycloidal reducers requires a detailed knowledge of the intensity and character of load, as well as the maximum von Mises stresses on critical components. In the available literature, the load distribution and the stress–strain state of the cycloidal reducer elements [...] Read more.
The design of cycloidal reducers requires a detailed knowledge of the intensity and character of load, as well as the maximum von Mises stresses on critical components. In the available literature, the load distribution and the stress–strain state of the cycloidal reducer elements are typically determined based on factors such as cycloidal disc tooth profile modifications, contact deformations, and internal clearances, whereas the influence of thermal stresses is most often neglected. To address this research gap, an innovative numerical–analytical methodology has been developed, which, for the first time, enables the prediction of the distribution of temperature fields and the quantification of the influence of temperature on the contact forces and the stress–strain state of key elements of the cycloidal reducer. Furthermore, the proposed methodology can be adapted for application within a broader context of mechanical engineering. From a practical perspective, it is expected to be beneficial to companies engaged in the design of power transmission gearboxes, as valuable practical guidelines for engineering applications are provided. This study also provides new insights into the dominant sources of heat generation and offers a clearer understanding of how thermal energy is transferred from internal heat sources to the outer surface of the housing. Full article
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25 pages, 11849 KB  
Article
A Numerical Investigation on the Influence of Film-Cooling Hole Inclination Angle on the Stress Field of Surrounding Thermal Barrier Coating
by Zhengyu Shi, Yuhao Jia, Xing He, Zegang Tian and Yongbao Liu
Materials 2025, 18(17), 4079; https://doi.org/10.3390/ma18174079 - 31 Aug 2025
Viewed by 174
Abstract
Thermal barrier coating (TBC) around film-cooling holes is a key failure location for turbine blade TBC. This study built a numerical model. The model used conjugate heat transfer (CHT) and sequential thermal-stress calculation methods. It analyzed the temperature and stress fields in the [...] Read more.
Thermal barrier coating (TBC) around film-cooling holes is a key failure location for turbine blade TBC. This study built a numerical model. The model used conjugate heat transfer (CHT) and sequential thermal-stress calculation methods. It analyzed the temperature and stress fields in the TBC around film-cooling holes. The holes had different inclination angles (30°, 45°, and 60°). It also explored the balance between cooling effectiveness and stress at these angles. Results show that increasing the film-cooling hole angle reduces the cooling film coverage area significantly. Cooling effectiveness becomes worse. The temperature field near the holes is complex. Sharp temperature gradients exist there. An inverse temperature gradient appeared in the top coat (TC) layer at the hole exit. Stress in the TBC was analyzed next. Analysis was conducted under rated operating conditions. Analysis was also completed after 500 h of creep under these conditions. Stress concentration around the holes is obvious. At room temperature, Mode I cracks easily form upstream of the holes. Mode II cracks easily form downstream. Under rated conditions, mixed-mode cracks (I + II) easily form downstream. The coating experiences larger stress at room temperature. This means that the coating is more likely to spall during cooling. Increasing the hole angle can reduce stress concentration. It can also lower the chance of crack formation. However, a larger angle increases the normal momentum of the cooling jet. This reduces film coverage. Therefore, after considering both cooling effectiveness and TBC failure, the 45° film-cooling hole is optimal. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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26 pages, 2313 KB  
Article
First Tests on the Performance and Reliability of an Experimental Bio-Based UTTO Lubricant Used in an Agricultural Tractor
by Roberto Fanigliulo, Renato Grilli, Laura Fornaciari, Stefano Benigni and Daniele Pochi
Energies 2025, 18(17), 4612; https://doi.org/10.3390/en18174612 - 30 Aug 2025
Viewed by 234
Abstract
Inside the transmission group of an agricultural tractor, the efficiency of power transfer to moving parts, their lubrication, and protection from wear are guaranteed by UTTO (Universal Tractor Transmission Oil) fluids, which are also used to operate the hydraulic system. These fluids, with [...] Read more.
Inside the transmission group of an agricultural tractor, the efficiency of power transfer to moving parts, their lubrication, and protection from wear are guaranteed by UTTO (Universal Tractor Transmission Oil) fluids, which are also used to operate the hydraulic system. These fluids, with mineral or synthetic origin, are characterized by excellent lubricating properties, high toxicity, and low biodegradability, which makes it important to replace them with more eco-sustainable fluids, such as those based on vegetable oils that are highly biodegradable and have low toxicity. It is also important to consider EU policies on the use of such fluids in sensitive environmental applications. To this end, several experimental bio-UTTO formulations were tested at CREA to evaluate—compared to conventional fluids—their suitability for use as lubricants for transmissions and hydraulic systems through endurance tests carried out in a Fluid Test Rig (FTR) specifically developed by CREA to apply controlled and repeatable work cycles to small volumes of oil, which are characterized by high thermal and mechanical stresses. The technical performance and the main physical–chemical parameters of the fluids were continuously monitored during the work cycles. Based on these experiences, this study describes the first application of a methodological approach aimed at testing an experimental biobased UTTO on a tractor used in normal farm activity. The method was based on a former test at the FTR in which the performance of the bio-UTTO was compared to that of the conventional UTTO recommended by the tractor manufacturer. Given the good results of the FTR test, bio-UTTO was introduced in a 20-year-old medium-power tractor, replacing the mineral fluid originally supplied, for the first reliability tests during its normal use on the CREA farm. After almost 600 h of work, the technical performance and the trend of chemical–physical parameters of bio-UTTO did not undergo significant changes. No damage to the tractor materials or oil leaks was observed. The test is still ongoing, but according to the results, in line with the indications provided by the FTR test, the experimental bio-UTTO seems suitable for replacing the conventional fluid in the tractor used in this study. Full article
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10 pages, 9156 KB  
Article
Generalized Spin–Curl Force Beyond the Stress Tensor
by Tongtong Zhu, Guodong Zhu, Chuang Li, Bojian Shi, Rui Feng, Yongyin Cao, Yurui Fang and Weiqiang Ding
Sensors 2025, 25(17), 5367; https://doi.org/10.3390/s25175367 - 30 Aug 2025
Viewed by 352
Abstract
The optical force exerted on a dipole particle can be divided into gradient force, scattering force, and spin–curl force, all of which can be derived from Maxwell’s stress tensor with the dipole approximation. Here, we identify an additional spin–curl force for arbitrary objects [...] Read more.
The optical force exerted on a dipole particle can be divided into gradient force, scattering force, and spin–curl force, all of which can be derived from Maxwell’s stress tensor with the dipole approximation. Here, we identify an additional spin–curl force for arbitrary objects beyond the dipole approximation, which is named the generalized spin–curl force in this paper. The generalized spin–curl force originates from the Minkowski force density and depends on the imaginary parts of the permittivity, permeability, and chirality of the object. However, it remains imperceptible in conventional optical force calculations due to its exact cancellation by a compensatory surface force during MST surface integration. The study of the generalized spin–curl force provides critical insights into elucidating the mechanisms underlying optical momentum transfer and internal force distribution within complex media. Furthermore, the generalized spin–curl force offers a novel mechanism for enhancing optical sensors, enabling highly sensitive detection of absorptive or chiral perturbations in systems such as microcavities and metasurfaces. Its ability to manipulate internal force distributions also provides new pathways for advancing optical force probes and chirality-selective sensing at the nanoscale. Full article
(This article belongs to the Section Optical Sensors)
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19 pages, 23351 KB  
Article
Integrated Geomechanical Modeling of Multiscale Fracture Networks in the Longmaxi Shale Reservoir, Northern Luzhou Region, Sichuan Basin
by Guoyou Fu, Qun Zhao, Guiwen Wang, Caineng Zou and Qiqiang Ren
Appl. Sci. 2025, 15(17), 9528; https://doi.org/10.3390/app15179528 - 29 Aug 2025
Viewed by 196
Abstract
This study presents an integrated geomechanical modeling framework for predicting multi-scale fracture networks and their activity in the Longmaxi Formation shale reservoir, northern Luzhou region, southeastern Sichuan Basin—an area shaped by complex, multi-phase tectonic deformation that poses significant challenges for resource prospecting. The [...] Read more.
This study presents an integrated geomechanical modeling framework for predicting multi-scale fracture networks and their activity in the Longmaxi Formation shale reservoir, northern Luzhou region, southeastern Sichuan Basin—an area shaped by complex, multi-phase tectonic deformation that poses significant challenges for resource prospecting. The workflow begins with quantitative characterization of key mechanical parameters, including uniaxial compressive strength, Young’s modulus, Poisson’s ratio, and tensile strength, obtained from core experiments and log-based inversion. These parameters form the foundation for multi-phase finite element simulations that reconstruct paleo- and present-day stress fields associated with the Indosinian (NW–SE compression), Yanshanian (NWW–SEE compression), and Himalayan (near W–E compression) deformation phases. Optimized Mohr–Coulomb and tensile failure criteria, coupled with a multi-phase stress superposition algorithm, enable quantitative prediction of fracture density, aperture, and orientation through successive tectonic cycles. The results reveal that the Longmaxi Formation’s high brittleness and lithological heterogeneity interact with evolving stress regimes to produce fracture systems that are strongly anisotropic and phase-dependent: initial NE–SW-oriented domains established during the Indosinian phase were intensified during Yanshanian reactivation, while Himalayan uplift induced regional stress attenuation with limited new fracture formation. The cumulative stress effects yield fracture networks concentrated along NE–SW fold axes, fault zones, and intersection zones. By integrating geomechanical predictions with seismic attributes and borehole observations, the study constructs a discrete fracture network that captures both large-scale tectonic fractures and small-scale features beyond seismic resolution. Fracture activity is further assessed using friction coefficient analysis, delineating zones of high activity along fold–fault intersections and stress concentration areas. This principle-driven approach demonstrates how mechanical characterization, stress field evolution, and fracture mechanics can be combined into a unified predictive tool, offering a transferable methodology for structurally complex, multi-deformation reservoirs. Beyond its relevance to shale gas development, the framework exemplifies how advanced geomechanical modeling can enhance resource prospecting efficiency and accuracy in diverse geological settings. Full article
(This article belongs to the Special Issue Recent Advances in Prospecting Geology)
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14 pages, 3325 KB  
Article
Dual-Strategy Design Based on Polymer–Matrix Composite Cathode and Coated Separator for High-Performance Lithium–Iron Disulfide Batteries
by Fan Zhang, Qiang Lu, Jiachen Li, Qiongyue Zhang, Haotian Yu, Yahao Wang, Jinrui Li, Haodong Ren, Huirong Liang, Fei Shen and Xiaogang Han
Materials 2025, 18(17), 4058; https://doi.org/10.3390/ma18174058 - 29 Aug 2025
Viewed by 379
Abstract
Lithium–iron disulfide (Li-FeS2) batteries are plagued by the polysulfide shuttle effect and cathode structural degradation, which significantly hinder their practical application. This study proposes a dual-strategy design that combines a polyacrylonitrile–carbon nanotube (PAN-CNT) composite cathode and a polyvinylidene fluoride (PVDF)-conductive carbon-coated [...] Read more.
Lithium–iron disulfide (Li-FeS2) batteries are plagued by the polysulfide shuttle effect and cathode structural degradation, which significantly hinder their practical application. This study proposes a dual-strategy design that combines a polyacrylonitrile–carbon nanotube (PAN-CNT) composite cathode and a polyvinylidene fluoride (PVDF)-conductive carbon-coated separator to synergistically address these bottlenecks. The PAN-CNT binder establishes chemical anchoring between polyacrylonitrile and FeS2, enhancing electronic conductivity and mitigating volume expansion. Specifically, the binder boosts the initial discharge capacity by 35% while alleviating the stress-induced pulverization associated with volume changes. Meanwhile, the PVDF-conductive carbon-coated separator enables effective polysulfide trapping via dipole–dipole interactions between PVDF’s polar C-F groups and Li2Sx species while maintaining unobstructed ion transport with an ionic conductivity of 1.23 × 103 S cm1, achieving a Coulombic efficiency of 99.2%. The electrochemical results demonstrate that the dual-modified battery delivers a high initial discharge capacity of 650 mAh g−1 at 0.5 C, with a capacity retention rate of 61.5% after 120 cycles, significantly outperforming the control group’s 47.5% retention rate. Scanning electron microscopy and electrochemical impedance spectroscopy confirm that this synergistic design suppresses polysulfide migration and enhances interfacial stability, reducing the charge transfer resistance from 26 Ω to 11 Ω. By integrating polymer-based functional materials, this work presents a scalable and cost-effective approach for developing high-energy-density Li-FeS2 batteries, providing a practical pathway to overcome key challenges in their commercialization. Full article
(This article belongs to the Section Energy Materials)
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18 pages, 3388 KB  
Article
Analysis of Interfacial Properties in Flax Yarn-Reinforced Epoxy Resin Composites
by Xinlong Wang, Hongjun Li, Duncan Camilleri, B. Y. R. Surnam, Zhenyu Wu, Xiaoying Cheng, Lin Shi and Wenqi Lu
Fibers 2025, 13(9), 118; https://doi.org/10.3390/fib13090118 - 29 Aug 2025
Viewed by 278
Abstract
With the increasing demand for green materials, natural fiber-reinforced composites have garnered significant attention due to their environmental benefits and cost-effectiveness. However, the weak interfacial bonding between flax fibers and resin matrices limits their broader application. This study systematically investigates the interfacial properties [...] Read more.
With the increasing demand for green materials, natural fiber-reinforced composites have garnered significant attention due to their environmental benefits and cost-effectiveness. However, the weak interfacial bonding between flax fibers and resin matrices limits their broader application. This study systematically investigates the interfacial properties of single-ply and double-ply flax yarn-reinforced epoxy resin composites, focusing on interfacial shear strength (IFSS) and its influencing factors. Pull-out tests were conducted to evaluate the mechanical behavior of yarns under varying embedded lengths, while scanning electron microscopy (SEM) was employed to characterize interfacial failure modes. Critical embedded lengths were determined as 1.49 mm for single-ply and 2.71 mm for double-ply configurations. Results demonstrate that the tensile strength and elastic modulus of flax yarns decrease significantly with increasing gauge length. Single-ply yarns exhibit higher IFSS (30.90–32.03 MPa) compared to double-ply yarns (20.61–25.21 MPa), attributed to their tightly aligned fibers and larger interfacial contact area. Single-ply composites predominantly fail through interfacial debonding, whereas double-ply composites exhibit a hybrid failure mechanism involving interfacial separation, fiber slippage, and matrix fracture, caused by stress inhomogeneity from their multi-strand twisted structure. The study reveals that interfacial failure originates from the incompatibility between hydrophilic fibers and hydrophobic resin, coupled with stress concentration effects induced by the yarn’s multi-level hierarchical structure. These findings provide theoretical guidance for optimizing interfacial design in flax fiber composites to enhance load-transfer efficiency, advancing their application in lightweight, eco-friendly materials. Full article
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16 pages, 398 KB  
Article
Exact Solutions for the Non-Isothermal Poiseuille Flow of a FENE-P Fluid
by Evgenii S. Baranovskii
Polymers 2025, 17(17), 2343; https://doi.org/10.3390/polym17172343 - 29 Aug 2025
Viewed by 224
Abstract
In the present article, we study a nonlinear mathematical model for the steady-state non-isothermal flow of a dilute solution of flexible polymer chains between two infinite horizontal plates. Both plates are assumed to be at rest and impermeable, while the flow is driven [...] Read more.
In the present article, we study a nonlinear mathematical model for the steady-state non-isothermal flow of a dilute solution of flexible polymer chains between two infinite horizontal plates. Both plates are assumed to be at rest and impermeable, while the flow is driven by a constant pressure gradient. The fluid rheology model used is FENE-P type. The flow energy dissipation (mechanical-to-thermal energy conversion) is taken into account by using the Rayleigh function in the heat transfer equation. On the channel walls, we use one-parameter Navier’s conditions, which include a wide class of flow regimes at solid boundaries: from no-slip to perfect slip. Moreover, we consider the case of threshold-type slip boundary conditions, which state the slipping occurs only when the magnitude of the shear stresses overcomes a certain threshold value. Closed-form exact solutions to the corresponding boundary value problems are obtained. These solutions represent explicit formulas for the calculation of the velocity field, the temperature distribution, the pressure, the extra stresses, and the configuration tensor. The results of the work favor better understanding and more accurate description of complex dynamics and energy transfer processes in FENE-P fluid flows. Full article
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22 pages, 3603 KB  
Article
Computer Simulation of the Mechanical Behavior of the ‘Zygomatic Bones–Implants–Splinting Bar–Removable Overdenture’ Dental Structure Under Operational Loads
by Magomed Magomedov, Alexander Kozulin, Sergey Arutyunov, Alexey Drobyshev, Timur Dibirov, Eduard Kharazyan, Magomet Mustafaev, Artem Drobyshev and Sergey Panin
Dent. J. 2025, 13(9), 393; https://doi.org/10.3390/dj13090393 - 28 Aug 2025
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Abstract
Background/Objectives: When solving the problems of installing zygomatic implants after partial or full maxillectomy with subsequent attachment of a removable overdenture (ROD), computer simulation based on the finite element method (FEM) is an effective tool for treatment planning. In this study, stress-strain states [...] Read more.
Background/Objectives: When solving the problems of installing zygomatic implants after partial or full maxillectomy with subsequent attachment of a removable overdenture (ROD), computer simulation based on the finite element method (FEM) is an effective tool for treatment planning. In this study, stress-strain states of the ‘zygomatic bones–implants–splinting bar–ROD’ dental structure were evaluated under various loading conditions. Methods: A 3D FEM computer simulation was carried out to estimate stress-strain states of the elements of the dental structure and to study the effect of redistribution of the loads transferred from the ROD to the zygomatic bones through four implants. Results: That successive insertion and removal of the ROD caused identical stresses in the elements of the dental structure. Given the accepted level of critical stress of about 13 MPa, their values may be exceeded in the zygomatic bones during both processes. In the ROD, the equivalent stresses did not exceed the critical levels upon alternate loading of 50 N on the posterior teeth (both molars and premolars) under all biting and mastication. Taking into account the linear dependence of the applied load and the stresses in the ROD, it can be stated that its integrity is maintained until 118 N (or the generally accepted typical value of 100 N). Under the 90° biting angle, the equivalent stresses are below the critical level in all the studied cases; thus, the acceptable value increases to 213 N, but it is only 63 N at a biting angle of 45°. Conclusions: It has been established that the equivalent stresses in the zygomatic bones can exceed the critical stress level of 13 MPa. In addition, some practical recommendations and prospects of the study have been formulated. Full article
(This article belongs to the Special Issue Digital Implantology in Dentistry)
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