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Search Results (2,028)

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Keywords = surface wear processes

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22 pages, 5453 KB  
Article
Real-Time Adaptive Nanofluid-Based Lubrication in Stainless Steel Turning Using an Intelligent Auto-Tuned MQL System
by Mahip Singh, Amit Rai Dixit, Anuj Kumar Sharma, Akash Nag and Sergej Hloch
Materials 2025, 18(20), 4714; https://doi.org/10.3390/ma18204714 (registering DOI) - 14 Oct 2025
Abstract
Achieving optimal lubrication during machining processes, particularly turning of stainless steel, remains a significant challenge due to dynamic variations in cutting conditions that affect tool life, surface quality, and environmental impact. Conventional Minimum Quantity Lubrication (MQL) systems provide fixed flow rates and often [...] Read more.
Achieving optimal lubrication during machining processes, particularly turning of stainless steel, remains a significant challenge due to dynamic variations in cutting conditions that affect tool life, surface quality, and environmental impact. Conventional Minimum Quantity Lubrication (MQL) systems provide fixed flow rates and often fail to adapt to changing process parameters, limiting their effectiveness under fluctuating thermal and mechanical loads. To address these limitations, this study proposes an ambient-aware adaptive Auto-Tuned MQL (ATM) system that intelligently controls both nanofluid concentration and lubricant flow rate in real time. The system employs embedded sensors to monitor cutting zone temperature, surface roughness, and ambient conditions, linked through a feedback-driven control algorithm designed to optimize lubrication delivery dynamically. A Taguchi L9 design was used for experimental validation on AISI 304 stainless steel turning, investigating feed rate, cutting speed, and nanofluid concentration. Results demonstrate that the ATM system substantially improves machining outcomes, reducing surface roughness by more than 50% and cutting force by approximately 20% compared to conventional MQL. Regression models achieved high predictive accuracy, with R-squared values exceeding 99%, and surface analyses confirmed reduced adhesion and wear under adaptive lubrication. The proposed system offers a robust approach to enhancing machining performance and sustainability through intelligent, real-time lubrication control. Full article
29 pages, 30122 KB  
Article
Micro-Structured Multifunctional Greener Coatings Obtained by Plasma Spray
by Spyridoula G. Farmaki, Dimitrios A. Exarchos, Panagiota T. Dalla, Elias A. Ananiadis, Vasileios Kechagias, Alexandros E. Karantzalis and Theodore E. Matikas
Appl. Mech. 2025, 6(4), 76; https://doi.org/10.3390/applmech6040076 (registering DOI) - 13 Oct 2025
Abstract
The increasing reliance on conventional coatings such as WC-Co raises serious environmental and health concerns due to the toxicity of cobalt and the ecological footprint of these materials. To address this challenge, the present study explores the development of eco-friendly multifunctional coatings via [...] Read more.
The increasing reliance on conventional coatings such as WC-Co raises serious environmental and health concerns due to the toxicity of cobalt and the ecological footprint of these materials. To address this challenge, the present study explores the development of eco-friendly multifunctional coatings via the Plasma Spray (PS) process, using titanium (Ti), silicon carbide (SiC), and tungsten carbide-cobalt (WC-Co) mixtures as alternative feedstocks. Steel substrates were coated under different deposition strategies (powder mixing, layer-by-layer) and current settings (800-900 A). The coatings were characterized by scanning electron microscopy (SEM/EDX), 3D profilometry, sliding wear testing, and potentiodynamic corrosion measurements. Results showed that Ti-WC (mix, 900 A) and Ti-SiC (layer, 900 A) coatings achieved the most favorable performance, combining excellent adhesion, uniform coverage, reduced porosity, and improved resistance to wear and corrosion compared to conventional Cr2O3 coatings. Notably, Ti-WC coatings provided surface roughness values comparable to Cr2O3, while significantly lowering the environmental impact. These findings demonstrate that PS-based Ti-WC and Ti-SiC systems can serve as sustainable and high-performance alternatives for protective applications in harsh environments, particularly in marine industries, supporting the transition toward coatings with reduced ecological footprint. Full article
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24 pages, 3803 KB  
Review
Review of Preparation and Key Functional Properties of Micro-Arc Oxidation Coatings on Various Metal Substrates
by Ningning Li, Huiyi Wang, Qiuzhen Liu, Zhenjie Hao, Da Xu, Xi Chen, Datian Cui, Lei Xu and Yaya Feng
Coatings 2025, 15(10), 1201; https://doi.org/10.3390/coatings15101201 - 12 Oct 2025
Viewed by 61
Abstract
Micro-arc oxidation (MAO) technology demonstrates remarkable advantages in fabricating ceramic coatings on lightweight alloys. For aluminum alloys, MAO rapidly forms dense, pore-free ceramic layers within minutes, significantly enhancing corrosion and wear resistance at low processing costs. In magnesium alloys, optimized electrolyte compositions and [...] Read more.
Micro-arc oxidation (MAO) technology demonstrates remarkable advantages in fabricating ceramic coatings on lightweight alloys. For aluminum alloys, MAO rapidly forms dense, pore-free ceramic layers within minutes, significantly enhancing corrosion and wear resistance at low processing costs. In magnesium alloys, optimized electrolyte compositions and process parameters enable composite coatings with a combination of high hardness and self-lubrication properties, while post-treatments like laser melting or corrosion inhibitors extend salt spray corrosion resistance. Titanium alloys benefit from MAO coatings with exceptional interfacial bonding strength and mechanical performance, making them ideal for biomedical implants and aerospace components. Notably, dense ceramic oxide films grown in situ via MAO on high-entropy alloys (HEAs) triple surface hardness and enhance wear/corrosion resistance. However, MAO applications on steel require pretreatments like aluminizing, thermal spraying, or ion plating. Current challenges include coating uniformity control, efficiency for complex geometries, and long-term stability. Future research focuses on multifunctional coatings (self-healing, antibacterial) and eco-friendly electrolyte systems to expand engineering applications. Full article
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28 pages, 8557 KB  
Article
Surface Optimization of Additively Manufactured (AM) Stainless Steel Components Using Combined Chemical and Electrochemical Post-Processing
by Pablo Edilberto Sanchez Guerrero, Andrew Grizzle, Daniel Fulford, Juan Estevez Hernandez, Lucas Rice and Pawan Tyagi
Coatings 2025, 15(10), 1197; https://doi.org/10.3390/coatings15101197 - 11 Oct 2025
Viewed by 182
Abstract
The design and production of goods have been completely transformed by additive manufacturing (AM), which makes it possible to create components with intricate and complex geometries that were previously impossible or impractical to produce. However, current technologies continue to produce coarse-surfaced metal components [...] Read more.
The design and production of goods have been completely transformed by additive manufacturing (AM), which makes it possible to create components with intricate and complex geometries that were previously impossible or impractical to produce. However, current technologies continue to produce coarse-surfaced metal components that typically exhibit fatigue properties, resulting in component failure and unfavorable friction coefficients on the printed part. Therefore, to improve the surface quality of the fabricated parts, post-processing of AM-created components is required. With emphasis on electroless nickel plating, ChemPolishing (CP), and ElectroPolishing (EP), this study investigates post-processing methods for stainless steel that is additively manufactured (AM). The rough surfaces created by additive manufacturing (AM) restrict direct use. While ElectroPolishing (EP) achieves high material removal rates but may not be consistent, ChemPolishing (CP) offers uniform smoothening. Nickel plating enhances additive manufacturing (AM) products’ resistance to wear and scratches and corrosion protection. To optimize nickel deposition, medium (6%–9%) and high (10%–13%) phosphorus nickel was tested using the L9 Taguchi design of experiments (DOE). Mechanical properties, including scratch resistance and adhesion, were evaluated using the TABER 5900 reciprocating (Taber Industries, North Tonawanda, NY, USA) abraser apparatus, a 5 N scratch test, and ASTM B-733 thermal shock method. Surface analysis was performed with the KEYENCE VHX-7000 microscope (Keyence Corporation, Itasca, IL, USA), and chemical composition before and after nickel deposition was assessed via the ThermoFisher Phenom XL scanning electron microscope (SEM, Thermo Fisher Scientific, Waltham, MA, USA) Optimal processing conditions, determined using Qualitek-4 software, Version 20.1.0 revealed improvements in both surface finish and mechanical robustness. This comprehensive analysis underscores the potential of nickel-coated additive manufacturing (AM) parts for enhanced performance, offering a pathway to more durable and efficient additive manufacturing (AM) applications. Full article
(This article belongs to the Special Issue Recent Advances in Surface Functionalisation, 2nd Edition)
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22 pages, 3981 KB  
Article
Experimental Investigation and Modelling of High-Speed Turn-Milling of H13 Tool Steel: Surface Roughness and Tool Wear
by Hamid Ghorbani, Bin Shi and Helmi Attia
Lubricants 2025, 13(10), 444; https://doi.org/10.3390/lubricants13100444 - 10 Oct 2025
Viewed by 90
Abstract
Turn-milling is a relatively new process which combines turning and milling operations, offering a number of advantages such as chip breaking and interrupted cutting, which improves tool life. In addition to providing the capability of producing eccentric forms or shapes, it increases productivity [...] Read more.
Turn-milling is a relatively new process which combines turning and milling operations, offering a number of advantages such as chip breaking and interrupted cutting, which improves tool life. In addition to providing the capability of producing eccentric forms or shapes, it increases productivity for difficult-to-machine material at lower cost. This study investigates the influence of cutting speed and feed on surface roughness and tool wear in conventional turning and turn-milling of H13 tool steel. The tests were conducted for longitudinal and face machining strategies. It was found that the range of surface roughness in turning is lower than in turn-milling. In longitudinal turning, face-turning, and face turn-milling operations, surface roughness is elevated in the higher feeds. However, the surface roughness in longitudinal turn-milling operations can be reduced by increasing the feed. Although the simultaneous rotation of the tool and workpiece in turn-milling could negatively affect the surface quality, this operation provides the advantage of an interrupted cutting mechanism that produces discontinuous chips. Also, the wear of the endmill in longitudinal and face turn-milling operations is lower than the wear of the inserts used in conventional longitudinal and face turning. Using Response Surface Methodology (RSM), mathematical models were developed for surface roughness and tool wear in each operation. The RSM models developed in this study achieved coefficients of determination (R2) above 90%, with prediction errors below 7% for surface roughness and below 3% for tool wear. The analysis of variance (ANOVA) revealed that the feed and cutting speed are the most influential parameters on the surface roughness and tool wear, respectively, with p-value < 0.05. The experimental results demonstrated that tool wear in turn-milling was reduced by up to 50% compared to conventional turning. Full article
(This article belongs to the Special Issue Recent Advances in Materials Forming, Machining and Tribology)
12 pages, 3323 KB  
Article
Effects of Laser Shock Processing on the Mechanical Properties of 6061-T6 Aluminium Alloy Using Nanosecond and Picosecond Laser Pulses
by Martha Guadalupe Arredondo Bravo, Gilberto Gomez-Rosas, Miguel Morales, David Munoz-Martin, Juan Jose Moreno-Labella, Jose Manuel Lopez Lopez, Jose Guadalupe Quiñones Galvan, Carlos Rubio-Gonzalez, Francisco Javier Casillas Rodriguez and Carlos Molpeceres
Materials 2025, 18(20), 4649; https://doi.org/10.3390/ma18204649 - 10 Oct 2025
Viewed by 255
Abstract
Laser shock processing (LSP) is a surface treatment technique used to enhance mechanical properties such as hardness, corrosion resistance, and wear resistance. This study investigates the effects of LSP on a 6061-T6 aluminium alloy using four treatment conditions: nanosecond (ns-LSP), picosecond (ps-LSP), and [...] Read more.
Laser shock processing (LSP) is a surface treatment technique used to enhance mechanical properties such as hardness, corrosion resistance, and wear resistance. This study investigates the effects of LSP on a 6061-T6 aluminium alloy using four treatment conditions: nanosecond (ns-LSP), picosecond (ps-LSP), and a combination of nanosecond–picosecond (nsps-LSP) and picosecond–nanosecond (psns-LSP) pulses. Two laser systems were employed: a Q-switched Nd:YAG laser (850 mJ/pulse, 6 ns, 1064 nm, 10 Hz), and an Ekspla Atlantic 355-60 laser (0.110 mJ/pulse, 13 ps, 1064 nm, 1 kHz). All treatments induced compressive residual stresses up to 1 mm in depth. Additionally, improvements in microhardness were observed, particularly at deeper layers in the combined nsps-LSP treatment. Surface roughness was measured and compared. Among all configurations, the nsps-LSP treatment produced the highest compressive residual stresses (−428 MPa) and greater microhardness at depth. These results suggest that the combined nsps-LSP treatment represents a promising approach to enhance the mechanical performance of metallic components. Full article
(This article belongs to the Special Issue Advances in Laser Processing Technology of Materials—Second Edition)
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28 pages, 2726 KB  
Proceeding Paper
Recent Advances in Tool Coatings and Materials for Superior Performance in Machining Nickel-Based Alloys
by Kerolina Sonowal and Partha Protim Borthakur
Eng. Proc. 2025, 105(1), 8; https://doi.org/10.3390/engproc2025105008 - 9 Oct 2025
Viewed by 308
Abstract
Nickel-based alloys, including Inconel 718 and alloy 625, are indispensable in industries such as aerospace, marine, and nuclear energy due to their exceptional mechanical strength, high-temperature performance, and corrosion resistance. However, these very properties pose severe machining challenges, such as accelerated tool wear, [...] Read more.
Nickel-based alloys, including Inconel 718 and alloy 625, are indispensable in industries such as aerospace, marine, and nuclear energy due to their exceptional mechanical strength, high-temperature performance, and corrosion resistance. However, these very properties pose severe machining challenges, such as accelerated tool wear, poor surface finish, and high cutting forces. Although several studies have investigated coatings, lubrication strategies, and process optimization, a comprehensive and up-to-date integration of these advancements is still lacking. To address this gap, a systematic review was conducted using Web of Science and Scopus databases. The inclusion criteria focused on peer-reviewed journal and conference articles published in the last eleven years (2014–2025), written in English, and directly addressing machining of nickel-based alloys, with particular emphasis on tool coatings, lubrication/cooling technologies, and machinability optimization. Exclusion criteria included duplicate records, non-English documents, papers lacking experimental or modeling results, and studies unrelated to tool life or coating performance. Following this screening process, 101 high-quality articles were selected for detailed analysis. The novelty of this work lies in synthesizing comparative insights across TiAlN, TiSiN, and CrAlSiN coatings, alongside advanced lubrication methods such as HPC, MQL, nano-MQL, and cryogenic cooling. Results highlight that CrAlSiN coatings retain hardness up to 36 ± 2 GPa after exposure to 700 °C and extend tool life by 4.2× compared to TiAlN, while optimized cooling strategies reduce flank wear by over 30% and improve tool longevity by up to 133%. The integration of coating performance, thermal stability, and lubrication effects into a unified framework provides actionable guidelines for machining optimization. The study concludes by proposing future research directions, including hybrid coatings, real-time process monitoring, and sustainable lubrication technologies, to bridge the remaining gaps in machinability and promote industrial adoption. This integrative approach establishes a robust foundation for advancing machining strategies of nickel-based superalloys, ensuring improved productivity, reduced costs, and enhanced component reliability. Full article
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15 pages, 4956 KB  
Article
Numerical Simulation and Microstructure Examination of a Low-Alloy Structural Steel for Laser Transformation Hardening Treatment
by Peiyu He, Liming Qian, Junnan Ren and Yun Wang
Photonics 2025, 12(10), 992; https://doi.org/10.3390/photonics12100992 - 8 Oct 2025
Viewed by 187
Abstract
The surface treated by laser phase transformation hardening exhibits superior hardness, enhanced wear resistance, and refined grain structure. In this study, both single-track and two-track laser phase transformation hardening processes were numerically simulated, with the simulation accuracy being verified experimentally. Furthermore, the optimal [...] Read more.
The surface treated by laser phase transformation hardening exhibits superior hardness, enhanced wear resistance, and refined grain structure. In this study, both single-track and two-track laser phase transformation hardening processes were numerically simulated, with the simulation accuracy being verified experimentally. Furthermore, the optimal overlap rate for laser two-track overlay was predicted based on the simulation results. An S355J2G3 metal block specimen was used as a case, numerical simulations of the phase transformation coupled with the temperature field on the specimen’s surface under laser irradiation were carried out using SYSWELD2019 software. The surface temperature distribution and the evolution of phase volume fractions were analyzed. Additionally, the changes in the temperature field within the softening zone and the distribution of tempering structures resulting from two-track laser overlay were examined. The discrepancy between experimental and simulated results for the hardening layer width was approximately 10%, while the error rates for the hardening layer depth and the tempering softening zone were below 5% and 10%, respectively. Based on simulations conducted with varying overlap rates, the flatness metric produces the best results at 50% overlap under these laser processing parameters. Full article
(This article belongs to the Section Lasers, Light Sources and Sensors)
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18 pages, 2078 KB  
Review
The Role of Tribocatalysis in Friction and Wear: A Review
by Diana Berman and Ali Erdemir
Lubricants 2025, 13(10), 442; https://doi.org/10.3390/lubricants13100442 - 8 Oct 2025
Viewed by 374
Abstract
When exposed to high contact pressure and shear conditions, the sliding and/or rolling contact interfaces of moving mechanical systems can experience significant friction and wear losses, thereby impairing their efficiency, reliability, and environmental sustainability. Traditionally, these losses have been minimized using high-performance solid [...] Read more.
When exposed to high contact pressure and shear conditions, the sliding and/or rolling contact interfaces of moving mechanical systems can experience significant friction and wear losses, thereby impairing their efficiency, reliability, and environmental sustainability. Traditionally, these losses have been minimized using high-performance solid and liquid lubricants or surface engineering techniques like physical and chemical vapor deposition. However, increasingly harsh operating conditions of more advanced mechanical systems (including wind turbines, space mechanisms, electric vehicle drivetrains, etc.) render such traditional methods less effective or impractical over the long term. Looking ahead, an emerging and complementary solution could be tribocatalysis, a process that spontaneously triggers the formation of nanocarbon-based tribofilms in situ and on demand at lubricated interfaces, significantly reducing friction and wear even without the use of high-performance additives. These films often comprise a wide range of amorphous or disordered carbons, crystalline graphite, graphene, nano-onions, nanotubes, and other carbon nanostructures known for their outstanding friction and wear properties under the most demanding tribological conditions. This review highlights recent advances in understanding the underlying mechanisms involved in forming these carbon-based tribofilms, along with their potential applications in real-world mechanical systems. These examples underscore the scientific significance and industrial potential of tribocatalysis in further enhancing the efficiency, reliability, and environmental sustainability of future mechanical systems. Full article
(This article belongs to the Special Issue Tribo-Catalysis)
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13 pages, 4227 KB  
Article
Wear Measurements in Cylindrical Telescopic Crowns Using an Active Piezoresistive Cantilever with an Integrated Gold Microsphere Probe
by Tomasz Dąbrowa, Dominik Badura, Bartosz Pruchnik, Władysław Kopczyński, Ivo W. Rangelow, Edward Kijak and Teodor Gotszalk
Materials 2025, 18(19), 4624; https://doi.org/10.3390/ma18194624 - 7 Oct 2025
Viewed by 305
Abstract
In this paper, we report a novel application of atomic force microscopy (AFM) for measurement of wear of prosthetic materials. In contrast to previously employed methods, we introduce AFM-based wear induction. In this way, we utilize AFM as both measurement technique and the [...] Read more.
In this paper, we report a novel application of atomic force microscopy (AFM) for measurement of wear of prosthetic materials. In contrast to previously employed methods, we introduce AFM-based wear induction. In this way, we utilize AFM as both measurement technique and the mean for surface wear. We describe the methodology along with the metrological advantages of the approach regarding the supreme resolution of volume measurement (down to 1 μm3). We investigate wear between prosthetic gold alloy (Degulor M) and FGP polymeric material from Bredent in nanoscale. For that purpose, we modify active piezoresistive cantilever, replacing the original tip with Degulor M microsphere. We elaborate on the process of modification and present how the mass volume and topology of the tip is controlled throughout the process. Wear process was performed in reciprocal motion over the length of 5 μm in 35,000 repetitions to mimic the actual conditions occurring in human mouth cavity. We present how this method, by focusing on a small area of investigated materials, leads to shortening the overall time of wear measurements from tong term observations down to several minutes. AFM-measured data present consistent relation between wear energy and wear volume. Exemplary results seem to confirm durability of the FGP-Degulor M mechanical contact and occurring strengthening of the mechanical contact with roughening of the polymeric surface. Full article
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22 pages, 4598 KB  
Article
Machinability of Vitrified Semi-Finished Products: Chip Formation and Heat Development at the Cutting Edge
by Jannick Fuchs, Yehor Kozlovets, Jonathan Alms, Markus Meurer, Christian Hopmann, Thomas Bergs and Mustapha Abouridouane
Polymers 2025, 17(19), 2681; https://doi.org/10.3390/polym17192681 - 3 Oct 2025
Viewed by 304
Abstract
Fibre-reinforced composites are facing new challenges in the context particular in sustainability and recyclability. Vitrimers could be useful as new matrices to support the increase in sustainability. Due to their high strength, which is comparable to that of thermosets often used in composites, [...] Read more.
Fibre-reinforced composites are facing new challenges in the context particular in sustainability and recyclability. Vitrimers could be useful as new matrices to support the increase in sustainability. Due to their high strength, which is comparable to that of thermosets often used in composites, and their covalent adaptive networks, which make them reshapeable for scaled-up manufacturing and recycling purposes, they are very useful. Orthogonal cutting is used for precise reshaping and functional integration into carbon fibre reinforced plastics. Vitrimers could improve processing results at the cutting edge as well as surface quality thanks to their self-healing properties compared to brittle matrices, as well as enabling the recycling of formed chips and scrap. This study showcases the manufacturing of a carbon fibre-reinforced vitrimer using 4-aminophenyl disulfide as a hardener, with vacuum-assisted resin infusion. The temperature of chip formation and the cutting parameters are then shown for different fibre orientations, cutting widths and speeds. The observed cutting forces are lower (less than 140 N) and more irregular for fibre orientations 45°/135°, increasing with cutting depth, and fluctuating periodically during machining. Despite varying cutting speeds, the forces remain relatively constant in range between 85 N and 175 N for 0°/90° fibre orientation and 50 N and 120 N for 45°/135° fibre orientation, with no significant tool wear observed and lower-damage depth and overhanging fibres observed for 0°/90° fibre orientation. Damage observation of the cutting tool shows promising results, with lower abrasion observed compared to thermoset matrices. Microscopic images of the broached surface also show good quality, which could be improved by self-healing of the matrix at higher temperatures. Temperature measurements of chip formation using a high-speed camera show a high temperature gradient as cutting speeds increase, but the temperature only ever exceeds 180 °C at cutting speeds of 150 m/min, ensuring reprocessability since this is below the degradation temperature. Therefore, orthogonal cutting of vitrimers can impact sustainable composite processing. Full article
(This article belongs to the Section Polymer Networks and Gels)
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19 pages, 20112 KB  
Article
A Comparison of High-Impulse and Direct-Current Magnetron Sputtering Processes for the Formation of Effective Bactericidal Oxide Coatings on Polymer Substrates
by Joanna Kacprzyńska-Gołacka, Piotr Wieciński, Bogusława Adamczyk-Cieślak, Sylwia Sowa, Wioletta Barszcz, Monika Łożyńska, Marek Kalbarczyk, Andrzej Krasiński, Halina Garbacz and Jerzy Smolik
Materials 2025, 18(19), 4591; https://doi.org/10.3390/ma18194591 (registering DOI) - 3 Oct 2025
Viewed by 373
Abstract
In this paper, silver oxide (AgO) and copper oxide (CuO) coatings are placed on a single sputtering target with the direct-current magnetron sputtering (DCMS) and high-power impulse magnetron sputtering (HIPIMS) methods. All the tested coatings are obtained in a reactive process using a [...] Read more.
In this paper, silver oxide (AgO) and copper oxide (CuO) coatings are placed on a single sputtering target with the direct-current magnetron sputtering (DCMS) and high-power impulse magnetron sputtering (HIPIMS) methods. All the tested coatings are obtained in a reactive process using a metallic target made by the Kurt Lesker company. The investigated coatings are deposited at room temperature on substrates made of pure iron (ARMCO) and polypropylene (PP) without substrate polarization. The deposition time for all the coatings is the same. The results of SEM and TEM investigations clearly show that using the HIPIMS method for the deposition of AgO and CuO coatings reduces their thickness and increases their structure density. Coatings produced with the HIPIMS method are characterized by a higher hardness and Young’s modulus. The value of hardness for AgO and CuO coatings deposited by the HIPIMS method is around 50% higher for AgO coatings and around 24% higher for CuO coatings compared to the coatings obtained by the DC method. This is also true of Young’s modulus values, which are around 30% higher for AgO coatings and 15% higher for CuO coatings produced by the HIPIMS method compared to those of coatings obtained with the DC method. AgO and CuO coatings deposited with both the methods (HIPIMS and DCMS) showed 100% reduction in the viability of two reference laboratory bacteria strains—Escherichia coli (Gram−) and Staphylococcus aureus (Gram+)—on both types of substrates. Additionally, these coatings are characterized by their hydrophobic properties, which means that they can create a protective barrier, making it difficult for bacteria to stick to the surface, limiting their development and preventing the phenomenon of biofouling. The HIPIMS technology allows for the deposition of coatings with better mechanical properties than those produced with the DCMS method, which means that they are more resistant to brittle fractures and wear and have very good antimicrobial properties. Full article
(This article belongs to the Special Issue Surface Modification of Materials for Multifunctional Applications)
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18 pages, 5613 KB  
Article
The Impact of Selected ESD Parameters on the Properties of Tungsten Layers
by Piotr Młynarczyk, Damian Bańkowski and Wojciech Depczyński
Materials 2025, 18(19), 4581; https://doi.org/10.3390/ma18194581 - 2 Oct 2025
Viewed by 355
Abstract
This article presents studies of surface layers produced by electro-spark deposition (ESD) on cast iron using a W-Ni-Co sintered electrode. To minimize the number of required experiments, a two-factor, five-level Hartley experimental design was chosen. The assessment involved observing the effect of voltage [...] Read more.
This article presents studies of surface layers produced by electro-spark deposition (ESD) on cast iron using a W-Ni-Co sintered electrode. To minimize the number of required experiments, a two-factor, five-level Hartley experimental design was chosen. The assessment involved observing the effect of voltage and capacitor capacity during the ESD process (on layer thickness and wear of the sample and counter-sample under technically dry friction conditions). Microscopic and tomographic observations were performed to analyze the thickness and structure of the layers. Image analysis methods were employed to examine the cross-section of the layers. ESD diffusion analyses were performed on the produced layer. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) were performed to characterize the microstructure and composition of the coating. In addition, in order to evaluate the performance properties of tungsten coatings, the tribological tests were also conducted on a TRB3 Ball-on-Disc testing device. Hardness tests confirm an increase in the hardness of cast iron with a tungsten layer by over 400 µHV. The tests showed that higher voltages during the ESD process result in thicker layers and reduced wear of the sample with a tungsten layer at the expense of increased wear of the counter-sample (ball). Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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22 pages, 16895 KB  
Article
Surface Characterization of Hot-Rolled AISI 440C Round Wire at the Different Steps of the Typical Production Process
by Alessio Malandruccolo, Stefano Rossi and Cinzia Menapace
Metals 2025, 15(10), 1102; https://doi.org/10.3390/met15101102 - 2 Oct 2025
Viewed by 252
Abstract
This study investigates the surface characteristics and corrosion behavior of a high-C martensitic stainless steel (AISI 440C) at different stages of its manufacturing process. As a class, these steels prioritize high mechanical properties and wear resistance over superior corrosion resistance. Hot working operations, [...] Read more.
This study investigates the surface characteristics and corrosion behavior of a high-C martensitic stainless steel (AISI 440C) at different stages of its manufacturing process. As a class, these steels prioritize high mechanical properties and wear resistance over superior corrosion resistance. Hot working operations, such as rolling, create a surface oxide scale that must be removed via pickling to restore the material’s inherent corrosion resistance. This process also eliminates the underlying Cr-depleted layer, allowing for the re-establishment of a protective passive film. Using potentiodynamic polarization curves and micrographic analysis, the material’s behavior in different conditions, as-rolled, with a post-heat treatment oxide scale, and in a bare, oxide-free state, has been assessed. The results showed that the material lacks stable passive behavior under all conditions. The as-rolled and heat-treated conditions both exhibited active behavior and formed thick, non-adherent corrosion products. The oxide layer formed after heat treatment performed the worst, showing a significant increase in corrosion current density. These findings confirm the material’s susceptibility to corrosion in Cl ion-rich environments, highlighting the need for limited storage in such conditions and rapid pickling after thermal processing to mitigate surface damage. Full article
(This article belongs to the Section Corrosion and Protection)
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17 pages, 5021 KB  
Article
Research on Surface Wear Characteristics and Adsorption Mechanism of Biodiesel Engine
by Lilin Li, Yazhou Mao, Dan Chen, Jingjing Chang, Xianfeng Qin, Xiang Qu, Zhenghan Wei and Runyi Ma
Lubricants 2025, 13(10), 434; https://doi.org/10.3390/lubricants13100434 - 30 Sep 2025
Viewed by 290
Abstract
As a renewable fuel for diesel engines, biodiesel plays a significant role in improving the lubricating performance of low-sulfur diesel. The decline in lubricity of low-sulfur diesel can lead to increased friction and exacerbated wear on the surfaces of diesel engine friction pairs, [...] Read more.
As a renewable fuel for diesel engines, biodiesel plays a significant role in improving the lubricating performance of low-sulfur diesel. The decline in lubricity of low-sulfur diesel can lead to increased friction and exacerbated wear on the surfaces of diesel engine friction pairs, whereas the addition of biodiesel can effectively mitigate such tribological issues. In this study, tribological performance tests of biodiesel-fueled engines were conducted, combined with molecular simulation methods. Using Materials Studio software, the adsorption behavior and dynamic processes of three typical fuel components: C7H16, C11H22O2, and C19H36O2, on the α-Fe (110) crystal surface were simulated. This systematically revealed the mechanism by which biodiesel improves friction and wear performance. The results indicate that biodiesel significantly enhances the lubricating properties of low-sulfur diesel. The carbonyl groups in biodiesel molecules exhibit high reactivity, demonstrating larger absolute values of adsorption energy and cohesive energy compared to alkane components, which indicates stronger surface adsorption capacity. This facilitates the formation of a stable and continuous lubricating film on metal surfaces, thereby providing anti-wear and friction-reducing effects, ultimately improving the wear resistance of key components in diesel engines. Full article
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