Search Results (6)

At least three tephra layers, with ages around 2 Ma, crop out in the Pleistocene marine sequence of the Crotone basin, in southern Italy. We present the petrography and the mineral and glass chemistry of these layers, in order to correlate them with other Pleistocene sequences and, possibly, to identify the volcanic source(s). The oldest layer (a1) contains glass shards with homogeneous rhyolitic composition, together with crystals of ortho- and clinopyroxene, plagioclase and amphibole. The age, petrography and major elements’ glass composition allow for correlation with coeval tephra layers cropping out in the southern Apennines, near the town of Craco, in Valle Ricca, near Rome, and in the Periadriatic basin, in central Italy. Two other younger tephras (a3 and a4) can be distinguished by the absence of hydrous phases in a3 and the occurrence of biotite in a4. They show a higher variability in glass composition, which may be related to multiple volcanic sources. A fourth tephra of unknown position, but probably intermediate between a1 and a3, was also recognized. The volcanic source of the tephra layers was identified in a submerged paleo-arc in the central Tyrrhenian Sea, possibly corresponding to the Ventotene ridge. The paper also provides a dataset of glass trace elements’ composition for future correlations. Full article

The exact spatial and temporal behaviour of rapid climate shifts during the Last Glacial–Interglacial Transition are still not entirely understood. In order to investigate these events, it is necessary to have detailed palaeoenvironmental reconstructions at geographically spread study sites combined with reliable correlations between them. Tephrochronology, i.e., using volcanic ash deposits in geological archives as a dating and correlation tool, offers opportunities to examine the timing of events across wider regional scales. This study aims to review the posited asynchrony of the Younger Dryas stadial in comparison with Greenland Stadial-1 by correlating new proxy data from southernmost Sweden to previous palaeoclimate reconstructions in Europe based on the presence of the Hässeldalen Tephra, the Vedde Ash, and the Laacher See Tephra. μ-XRF core-scanning data were projected using a recently published age–depth model based on these tephras and several radiocarbon dates, and compared to previous findings, including by adapting previous chronologies to the recently proposed earlier date of the Laacher See Tephra (13,006 ± 9 cal. a BP). Although the results to some extent support the idea of a more synchronous Younger Dryas event than previously assumed, this issue requires further high-resolution proxy studies to overcome limitations of temporal precision. Full article

Altered tephras (K-bentonites) are of great importance for calibration of the geologic time scale, for local, regional, and global correlations, and paleoenvironmental reconstructions. Thus, definitive identification of individual tephras is critical. Single crystal geochemistry has been used to differentiate tephra layers, and apatite is one of the phenocrysts commonly occurring in tephras that has been widely used. Here, we use existing and newly acquired analytical datasets (electron probe micro-analyzer [EPMA] data and laser ablation ICP-MS [LA-ICP-MS] data, respectively) of apatite in several Ordovician K-bentonites that were collected from localities about 1200 km apart (Minnesota/Iowa/Wisconsin and Alabama, United States) to test the use of machine-learning (ML) techniques to identify with confidence individual tephra layers. Our results show that the decision tree based on EPMA data uses the elemental concentration patterns of Mg, Mn, and Cl, consistent with previous studies that emphasizes the utility of these elements for distinguishing Ordovician K-bentonites. Differences in the experimental setups of the analyses, however, can lead to offsets in absolute elemental concentrations that can have a significant impact on the correct identification and correlation of individual K-bentonite beds. The ML model using LA-ICP-MS data was able to identify several K-bentonites in the southern Appalachians and establish links to K-bentonites samples from the Upper Mississippi Valley. Furthermore, the ML model identified individual layers of multiphase eruptions, thus illustrating very well the great potential of applying ML techniques to tephrochronology. Full article

The 56 ka Monte Epomeo Green Tuff (MEGT) resulted from the largest volume explosive eruption from Ischia island (south Italy). Its tephra is one of the main stratigraphic markers of the central Mediterranean area. Despite its importance, a detailed characterisation of the petrography and mineral chemistry of MEGT is lacking. To fill this gap, we present detailed petrographic description and electron microprobe mineral chemistry data on samples collected on-land from the MEGT. Juvenile clasts include pumice, scoria, and obsidian fragments with porphyritic/glomeroporphyritic, vitrophyric, and fragmental textures. The porphyritic index is 13–40 vol.%, and phenocryst phases include alkali-feldspar, plagioclase, clinopyroxene, ferrian phlogopite, and titano-magnetite, in order of decreasing abundance; accessory phases include sphene, hydroxy-fluor-apatite, and rare edenite. Plagioclase varies from predominant andesine to subordinate oligoclase, whereas alkali-feldspar is more variable from sanidine to anorthoclase; quasi-pure sanidine commonly occurs as either rim or recrystallisation overgrowth of large phenocrysts due to hydrothermal alteration. Secondary minerals include veins and patches of carbonate minerals, Fe-Mn oxyhydroxides, clay minerals, and zeolites. Clinopyroxene is ferroan diopside (En_45–29Fs_7–27) and never reaches Na-rich compositions. This feature allows the discrimination of MEGT from aegirine-bearing, distal tephra layers erroneously attributed to MEGT, with implications for the areal distribution of Ischia explosive deposits. Full article

The Eemian was the last interglacial period (~130 to 115 ka BP) to precede the current interglacial. In Eastern Mediterranean marine sediments, it is marked by a well-developed and organic-rich “sapropel” layer (S5), which is thought to reflect an intensification and northward migration of the African monsoon rain belt over orbital timescales. However, despite the importance of these sediments, very little proxy-independent stratigraphic information is available to enable rigorous correlation of these sediments across the region. This paper presents the first detailed study of visible and non-visible (cryptotephra) layers found within these sediments at three marine coring sites: ODP Site 967B (Levantine Basin), KL51 (South East of Crete) and LC21 (Southern Aegean Sea). Major element analyses of the glass component were used to distinguish four distinct tephra events of Santorini (e.g., Vourvoulos eruption) and possible Anatolian provenance occurring during the formation of S5. Interpolation of core chronologies provides provisional eruption ages for the uppermost tephra (unknown Santorini, 121.8 ± 2.9 ka) and lowermost tephra (Anatolia or Kos/Yali/Nisyros, 126.4 ± 2.9 ka). These newly characterised tephra deposits have also been set into the regional tephrostratigraphy to illustrate the potential to precisely synchronise marine proxy records with their terrestrial counterparts, and also contribute to the establishment of a more detailed volcanic history of the Eastern Mediterranean. Full article

In this article, I show how an Ultisol, representative of a globally-important group of soils with clay-rich subsoils, low base saturation, and low fertility, in the central Waikato region in northern North Island, can be evaluated using soil stratigraphy and tephrochronology to answer challenging questions about its genesis, age and classification. The Kainui soil, a Typic Kandiudult (Soil Taxonomy) and Buried-granular Yellow Ultic Soil (New Zealand Soil Classification), occurs on low rolling hills of Mid-Quaternary age mainly in the Hamilton lowlands in, and north and northeast of, Hamilton city. It is a composite, multi-layered tephra-derived soil consisting of two distinct parts, upper and lower. The upper part is a coverbed typically c. 0.4–0.7 m in thickness (c. 0.6 m on average) comprising numerous late Quaternary rhyolitic and andesitic tephras that have been accumulating incrementally since c. 50 ka (the age of Rotoehu Ash at the coverbed’s base) whilst simultaneously being pedogenically altered (i.e., forming soil horizons) via developmental upbuilding pedogenesis during Marine Oxygen Isotope Stages (MOIS) 3-1. Any original depositional (fall) bedding has been almost entirely masked by pedogenic alteration. Sediments in lakes aged c. 20 ka adjacent to the low hills have preserved around 40 separate, thin, macroscopic tephra-fall beds mainly rhyolitic in composition, and equivalent subaerial deposits together form the upper c. 30 cm of the coverbed. Okareka (c. 21.8 ka), Okaia (c. 28.6 ka), Tāhuna (c. 39.3 ka) and (especially) Rotoehu tephras make up the bulk of the lower c. 30 cm of the coverbed. Tephra admixing has occurred throughout the coverbed because of soil upbuilding processes. Moderately well drained, this upper profile is dominated by halloysite (not allophane) in the clay fraction because of limited desilication. In contrast, Otorohanga soils, on rolling hills to the south of Hamilton, are formed in equivalent but thicker (>c. 0.8 m) late Quaternary tephras ≤c. 50 ka that are somewhat more andesitic although predominantly rhyolitic overall. These deeper soils are well drained with strong desilication and thus are allophanic, generating Typic Hapludands. Ubiquitous redox features, together with short-lived contemporary reduction observed in the lower coverbed of a Kainui soil profile, indicate that the Kainui soil in general is likely to be saturated by perching for several days, or near saturation for several months, each year. The perching occurs because the coverbed overlies a slowly-permeable, buried, clay-rich paleosol on upper Hamilton Ash beds, >c. 50 ka in age, which makes up the lower part of the two-storeyed Kainui soil. The coverbed-paleosol boundary is a lithologic discontinuity (unconformity). Irregular in shape, it represents a tree-overturn paleosurface that may be c. 74 ka in age (MOIS 5/4 boundary). The buried paleosol is markedly altered and halloysitic with relict clay skins (forming paleo-argillic and/or paleo-kandic horizons) and redoximorphic features. It is inferred to have formed via developmental upbuilding pedogenesis during the Last Interglacial (MOIS 5e). The entire Hamilton Ash sequence, c. 3 m in thickness and overlain unconformably by Rotoehu Ash and underlain by c. 340-ka Rangitawa Tephra at the base, represents a thick composite (accretionary) set of clayey, welded paleosols developed by upbuilding pedogenesis from MOIS 10 to 5. Full article