Search Results (248)

The functional performance and structural integrity of natural rock materials under fluctuating environmental stressors are pivotal for their advanced applications. As a non-ionizing and radiation-free technology, terahertz (THz) spectroscopy offers a safe and promising alternative for non-destructive testing (NDT), uniquely capable of being deployed in open and unshielded environments. However, limited penetration depth, exacerbated by both the dense geological matrix and the extreme sensitivity of THz waves to moisture states, has long hindered its widespread application in rock characterization. This study establishes a quantitative Terahertz Time-Domain Spectroscopy (THz-TDS) framework to characterize four lithologies under drying–wetting cycles. Exponential signal attenuation across thicknesses was quantified based on the Beer–Lambert law, with attenuation coefficients ranging from 0.15 to 0.74 per millimeter. Planar transmission imaging successfully visualizes lithologic and moisture-dependent heterogeneity: limestone exhibits a dense, homogeneous structure with stable amplitude distribution; sandstone and purple sandstone show parallel statistical trends, reflecting uniform pore networks; and granite demonstrates the most pronounced imaging contrast under varying moisture states, driven by complex grain-boundary scattering. The findings reveal that THz transmission is dictated by the synergistic effects of mineral compositions and pore structures: scattering at grain boundaries and fractures leads to significant energy dissipation, whereas clay-rich lithologies exhibit the highest sensitivity to moisture variations due to water adsorption and interfacial polarization effects. As an exploration of THz technology in the non-destructive evaluation of rock materials, these findings establish an analytical framework for the quantitative assessment of microstructure evolution. Full article

Modern turbine engines, when operating at high temperatures, can inhale calcium–magnesium–alumina–silicate particles (CaO-MgO-Al₂O₃-SiO₂, CMAS) from the air, which can erode the thermal barrier coatings on the blade surface, affecting the service life of the thermal barrier coatings and, in severe cases, leading to premature blade failure. Therefore, it is of great significance to effectively detect the thickness of CMAS deposited on the surface of the thermal barrier coatings at an early stage of CMAS erosion to ensure the high-temperature structural integrity of the hot-end components of aeroengines. Based on this, this study proposes a method combining terahertz time-domain spectroscopy technology and a hybrid machine learning algorithm for the quantitative detection of the thickness of CMAS on the surface of thermal barrier coatings. Firstly, the terahertz time-domain spectroscopy experimental data of CMAS were obtained using a terahertz experimental system, and the refractive index and absorption coefficient of CMAS in the terahertz frequency band were calculated. The FDTD method, Gaussian noise addition, and wavelet denoising processing were combined to further simulate the terahertz detection process of thermal barrier coatings with different thicknesses of CMAS attached to the surface under high-temperature conditions, and the terahertz simulation detection data were obtained. Principal component analysis (PCA) was used to reduce the dimensionality of the original experimental and simulation data, and a support vector machine (SVM) model integrating PCA and bacterial foraging optimization (BFO) algorithm was constructed. The research results show that the integrated model exhibits excellent performance in predicting the thickness of CMAS, with a correlation coefficient of 0.95, and the mean absolute error (MAE) and root mean square error (RMSE) are 0.13 μm and 0.46 μm, respectively. This study provides a new high-precision method for non-destructive detection of the thickness of CMAS on the surface of thermal barrier coatings, which has certain engineering application value for ensuring the service performance of thermal barrier coatings under harsh service conditions. Although the current method is based on simulated and experimental data under controlled conditions, it has the potential to be developed into an in situ monitoring strategy in the future, enabling real-time assessment of CMAS thickness on the coating surface during engine operation. Full article

Accurate measurements of light–matter interactions at subwavelength scales are critical for advancing nanophotonic and quantum optical technologies. In this paper, we present the far-field terahertz (THz) spectroscopy of a single planar meta-atom of subwavelength dimensions embedded within a square or circular aperture on a thin free-standing metal film. The meta-atom, composed of concentric disk and ring structures interconnected by narrow bridges, was fabricated by a mask-less direct laser ablation (DLA) technique to exhibit a pronounced transmission peak near a resonance frequency of 0.35 THz. We propose a novel spectral analysis framework that accounts for aperture-to-beam area mismatch suppressing non-resonant background contributions originating from edge diffraction and aperture discontinuities which are commonly encountered in subwavelength geometries. This technical analysis yields transmission spectra with improved accuracy providing good agreement with finite-difference time-domain (FDTD) simulations. A foundation for precise optical characterization of a single subwavelength size resonator is demonstrated paving the way for applications in quantum sensing, meta-surface design, and low-dimensional optoelectronic systems. Full article

Porphyry-type deposits are characterized by well-developed alteration zoning, among which potassic alteration is closely associated with mineralization and represents a key target for prospecting and exploration. The Dengshang molybdenum deposit is a porphyry-type deposit within the Yanliao molybdenum metallogenic belt. Characterized by deep burial and unclear alteration zoning, it presents challenges for prospecting and exploration. This study integrates field surveys, petrographic analysis, and terahertz time-domain spectroscopy (THz-TDS) to characterize the altered wall rocks and molybdenite ores, aiming to support deep prospecting. The main findings reveal a clear spatial gradient from potassic to propylitic alteration zones within and around the rhyolite porphyry intrusion. THz-TDS reveals that the THz spectral characteristics of potassic-altered wall rocks are closely related to the structure of minerals and the intensity of hydrothermal alteration. Propylitically altered wall rocks exhibit distinctive spectral signatures in the terahertz band. For molybdenite ores, the molybdenite content shows a negative correlation with THz amplitude and a positive correlation with both the absorption coefficient and refractive index. This study proposes that the lower refractive index and absorption coefficient of potassic wall rocks, coupled with the higher values in ores, reflect the spatial position of the ore body. Additionally, the characteristic THz spectral curve of propylitically altered rocks can aid in delineating ore body boundaries. These findings hold practical guiding significance for prospecting and exploration. Full article

Chalcogenide glasses are known as optical materials for the infrared spectral range. These compounds may also be of interest as materials for the low-frequency part of the terahertz range of electromagnetic waves, which is currently being intensively studied in connection with the numerous possible applications of terahertz radiation. However, the terahertz optical characteristics of chalcogenide glasses remain poorly studied. In this work, eight different compositions of GeAsSeSbSnTe chalcogenide glasses were investigated using terahertz time-domain spectroscopy. A number of compositions, in particular GeSeTe and AsSeSbSn, were studied in the terahertz spectral range for the first time. Spectra of the refractive index and extinction coefficient were obtained for studied materials in the spectral range of 0.1–2.2 THz. The experimental frequency dependence of the product of the terahertz power absorption coefficient and the refractive index for the entire set of studied glasses is approximated by a power function. It was established that the exponent of the approximating power functions varies from 1.68 to 2.34 depending on the composition of the chalcogenide glass. For the studied glasses, a correlation was found between the values of the average coordination number characterizing the chalcogenide glass structure, and the values of the exponent of the functions approximating the THz absorption spectra. Full article

Aiming to address the problems of low accuracy in coal–rock identification during coal mining, which lead to energy waste and safety hazards, a high-precision coal–rock medium identification method combining terahertz time-domain spectroscopy technology and multiple machine learning algorithms is proposed. By preparing coal–rock samples with a gradient change in coal content, terahertz time-domain spectroscopy data of coal–rock mixed media are collected, and optical parameters such as the refractive index and absorption coefficient are extracted. Principal component analysis is used to reduce the dimensionality of the terahertz data, and machine learning algorithms such as support vector machine, least squares support vector machine, artificial neural networks, and random forests are adopted for classification and identification. The study found that terahertz waves are more sensitive to coal–rock media in the 0.7–1.3 THz frequency band, and that the refractive index and absorption coefficient of coal–rock mixed media are significantly positively correlated with coal content within the range of 0–30%. After feature extraction and K-fold cross-validation, the random forest model achieved a coal–rock classification accuracy of over 96% on the test set, significantly outperforming other comparison algorithms. The research verifies the efficiency and practicality of terahertz technology combined with multiple machine learning algorithms in coal–rock identification, providing a new method for fields such as mineral separation. This method has, to a certain extent, broken through the accuracy bottleneck of traditional coal–rock identification technologies within its applicable range, providing a new solution for real-time detection of coal–rock interfaces and is expected to further reduce the risks of ineffective mining and roof accidents in the future. Full article

To elucidate the influence of water on terahertz (THz) spectral responses, terahertz time-domain spectroscopy (THz-TDS) was employed to monitor the thermal decomposition of copper(II) sulfate pentahydrate in this study. Continuous dehydration of the hydrate induces pronounced variations in the THz signal. At the initial stage of thermal decomposition, these changes primarily originate from the evolving state and amount of water confined within the CuSO₄·5H₂O lattice. After detaching from the crystalline framework, the released water molecules do not evaporate immediately; instead, they transiently reside near the copper sulfate as free water. When the temperature reaches approximately 60 °C, a dynamic equilibrium is established between crystalline water and free water. The THz spectral data reveal that the sample exhibits its strongest THz absorption at this temperature. Consequently, the THz signal during decomposition displays a characteristic trend: an initial decrease followed by an enhancement. These findings demonstrate that THz-TDS represents a promising approach for probing the state and content of water, thereby contributing to the development of a powerful analytical tool for fundamental studies in mineralogy. Full article

Biochemical detection is fundamental to various scientific disciplines, yet conventional methods still face inherent bottlenecks in achieving rapid, ultrasensitive, and simultaneous multi-target analysis. Terahertz (THz) waves, characterized by their unique spectral fingerprinting capabilities and non-destructive properties, have emerged as a compelling platform for advanced biochemical sensing. This review outlines the evolution of THz biochemical sensing over the past two decades, tracing its progression from passive identification toward intelligent perception. We structure this technological trajectory around four core themes: sensitivity enhancement, specific recognition, multi-target visualization, and system intelligence. We first evaluate the fundamental limitations of direct detection techniques, such as THz time-domain spectroscopy (THz-TDS). Building on this, we examine how metamaterial-assisted architectures utilize high-quality-factor resonances to achieve trace-level detection, pushing the limits of detection (LOD) down to the ng/mL or even pg/mL scale, and how surface chemical functionalization provides a molecular lock mechanism for selective targeting in complex samples. Furthermore, we highlight the paradigm shift from single-point spectral measurements to spatially resolved multi-target imaging using pixelated metasurfaces. Finally, the review addresses emerging directions, including dynamically tunable intelligent metasurfaces, multimodal on-chip integration platforms, and the growing integration of artificial intelligence (AI) in inverse design and data interpretation, which achieves classification accuracies exceeding 95% even in complex matrices. By synthesizing these developments, this review provides a comprehensive perspective on the future trajectory of THz sensing technologies. Full article

Terahertz time-domain spectroscopy (THz-TDS) has emerged as a powerful tool for probing hydrated materials and biological tissues, where water dynamics dominate the dielectric response. This study focuses on improving the methodology of THz-TDS by replacing conventional cuvettes, which introduce unwanted absorption, reflections, and liquid bubbles that must be accounted for during measurement interpretation, with nitrocellulose membranes of various pore sizes. The membranes were hydrated with deionized water and sealed with food-grade cling film, and their transmission properties were measured using THz-TDS. To interpret the measurements, transfer matrix method simulations were performed using the optical constants of water reported by some experimentalists, allowing verification of our data. The findings for deionized water highlight the reliability of the methodology. Our results demonstrate that nitrocellulose membranes provide stable and reproducible transmission measurements in good agreement with theoretical reference models, supported by weight retention studies and reproducibility tests conducted in spatial, temporal, and random measurement conditions. These improvements contribute to the development of more robust THz-TDS approaches for hydrated biological materials and suggest future applications in non-invasive tissue hydration monitoring and biomedical diagnostics. Full article

A water-rich muscle-equivalent tissue-mimicking phantom within a polymeric matrix was experimentally evaluated through a multimodal characterization methodology to determine whether it reproduces the coupled dielectric–thermal behavior of hydrated biological tissue under exposure to electromagnetic waves. The material was analyzed using thermogravimetric analysis, microwave dielectric spectroscopy from 1.5 to 4.0 GHz, VIS–NIR spectroscopy between 350 and 1200 nm, and terahertz time-domain reflection. The thermogravimetric results confirmed dominant water content, with primary mass loss below 200 °C, establishing hydration as the governing factor of its thermal response. Next, the microwave dielectric measurements show that the phantom exhibits a relative permittivity of 37.4 and an electrical conductivity of 2.4 S/m. On the other hand, the VIS–NIR spectra show smooth broadband absorption with limited spatial variability, and principal component analysis reveals macroscopic optical homogeneity without structural spectral distortion. In the THz regime, strong broadband attenuation characteristic of water-rich matrices is observed, and reflection-mode measurements enable robust assessment of temporal stability through time- and frequency-domain signatures. Finally, a microwave thermal validation demonstrates stable behavior under low-power excitation, whereas under hyperthermia-level irradiation, a significant thermal drift of −3.985 °C/h was reached under non-adiabatic conditions, identifying hydration-mediated moisture redistribution as the principal limitation during prolonged high-power exposure. Collectively, these results demonstrate cross-regime dielectric–thermal consistency while explicitly defining the hydration-driven constraints governing long-term stability, providing a validated reference material for broadband electromagnetic and thermal biomedical experimentation. Full article

Clathrates have gained considerable attention due to their potential impact on various industries, including oil and gas production, and more recently in the fields ranging from energy storage and transportation to environmental protection and gas separation processes, opening up new technological possibilities. Overall, the attention is focused on their spontaneous and uncontrolled formation/nucleation in offshore oil and gas pipelines, which can lead to numerous and serious operational problems. Accordingly, significant research efforts have focused on understanding the mechanisms of clathrate formation and inhibition or dissociation. Different approaches are being explored; some are ambitious and innovative, whereas others seek further validation. Among these, particular interest has emerged in the coupling of Terahertz (THz) radiation with the collective low-energy and/or vibrational modes of water, and/or other molecules, as well as their clusters. In this review, we summarize recent advances and findings in this promising research field, highlighting the potential applications of THz radiation and spectroscopy, future applications in the field of clathrates, and the technological progress toward the implementation of THz-based solutions in transportation and industrial processes. Full article

Adhesive fracture in layered structures is governed by subsurface crack evolution that cannot be accessed using surface-based diagnostics. Methods such as digital image correlation and optical spectroscopy measure surface deformation but implicitly assume a straight and uniform crack front, an assumption that becomes invalid for interfacial fracture with wide crack openings and asymmetric propagation. In this work, terahertz time-domain spectroscopy (THz-TDS) is combined with double-cantilever beam testing to directly map subsurface crack-front geometry in opaque adhesive joints. A strontium titanate-doped epoxy is used to enhance dielectric contrast. Multilayer refractive index extraction, pulse deconvolution, and diffusion-based image enhancement are employed to separate overlapping terahertz echoes and reconstruct two-dimensional delay maps of interfacial separation. The measured crack geometry is coupled with load–displacement data and augmented beam theory to compute spatially averaged stresses and energy release rates. The measurements resolve crack openings down to approximately 100 μm and reveal pronounced width-wise non-uniform crack advance and crack-front curvature during stable growth. These observations demonstrate that surface-based crack-length measurements can either underpredict or overpredict fracture toughness depending on the measurement location. Fracture toughness values derived from width-averaged subsurface crack fronts agree with J-integral estimates obtained from surface digital image correlation. Signal-to-noise limitations near the crack tip define the primary resolution limit. The results establish THz-TDS as a quantitative tool for subsurface fracture mechanics and provide a framework for physically representative toughness measurements in layered and bonded structures. Full article

Over the past two decades, terahertz (THz) spectroscopy has demonstrated remarkable potential for the investigation of liquids, including studies of living organisms and biological components in their natural, aqueous environments. The main advantages of THz radiation lie in its ability to interact with collective and low-energy vibrational modes of macromolecules and microorganisms, while being non-harmful due to the low photon energy involved. These characteristics make THz spectroscopy particularly valuable for research in liquids compared to other well-established techniques such as Raman and infrared spectroscopy. In this study, we offer a concise overview and comparison of two case studies from our earlier publications, highlighting how Ultrabroadband THz spectroscopy and Intense THz Spectroscopy serve as complementary methods for advancing research in liquids. Ultrabroadband THz spectroscopy enables simultaneous probing of both intermolecular and intramolecular interactions in a single experiment. On the other hand, intense THz spectroscopy greatly simplifies the determination of the optical constants of liquid solutions, eliminating the need for additional assumptions or prior knowledge. Moreover, it offers high sensitivity, allowing the detection of dilute solutions and subtle spectral variations. Currently, these two techniques typically rely on different THz sources, as achieving both broadband coverage and high intensity in a single setup remains challenging. In fact, the experimental results reviewed here were obtained at two different times and within two distinct scientific collaborations. In particular, the intense source was accessed through a collaboration with Prof. Novelli at Ruhr University in Bochum. Integrating both capabilities into a single apparatus would be highly desirable. Therefore, we also present a theoretical investigation of a novel experimental approach that could enable combined ultrabroadband and intense THz spectroscopy, merging the strengths of both methods. Full article

We present systematic experimental studies of the impact of subwavelength structural geometries and electromagnetic field polarization on the resonance behavior of metallic metasurfaces at D-band frequencies. The measured influence of the photoconductive receiver antenna design in terahertz time-domain spectroscopy on the frequency-domain spectral features was analyzed. Numerical simulations reveal distinct resonance characteristics in the D-band regime, where extraordinary amplitude transmission is highly dependent on the array dimensions and field polarization orientation. The metasurface enables significant enhancements in surface electric fields and resonance response, attributed to the effective excitation of strong dipolar modes. These results demonstrate the extraordinary transmission capabilities of subwavelength metallic arrays and provide valuable insights for designing compact, low-loss, and tunable terahertz functional components needed in next-generation communications. Full article

Terahertz (THz) waves, situated between the infrared and microwave regions, possess distinctive properties such as non-contact, high penetration, and high resolution. These properties render them highly advantageous for non-destructive thickness measurement of multilayer structural materials. In comparison with conventional ultrasound or X-ray techniques, THz thickness measurement has the capacity to acquire thickness data for multilayer structures without compromising the integrity of the specimen and is characterized by its environmental sustainability. The extant THz thickness measurement techniques principally encompass time-domain spectroscopy, frequency-domain spectroscopy, and model-based inversion and deep learning methods. A variety of methodologies have been demonstrated to possess complementary advantages in addressing subwavelength-scale thin layers, overlapping multilayer interfaces, and complex environmental interferences. These methodologies render them suitable for a range of measurement scenarios and precision requirements. A wide range of technologies related to this field have been applied in various disciplines, including aerospace thermal barrier coating inspection, semiconductor process monitoring, automotive coating quality assessment, and oil film thickness monitoring. The ongoing enhancement in system integration and continuous algorithm optimization has led to significant advancements in THz thickness measurement, propelling it towards high resolution, real-time performance, and intelligence. This development offers a wide range of engineering applications with considerable potential for future growth and innovation. Full article