Search Results (567)

This paper discusses the efficiency of ultrasonic-assisted bitumen extraction from bituminous sands of the Beke deposit (Mangistau region, Kazakhstan) using alkaline aqueous solutions. The process parameters, including ultrasonic frequency (22 kHz), power (up to 1500 W), solution pH (>12), and optimal NaOH concentration (1 wt.%) were optimized to achieve a maximum bitumen recovery of 98 wt.% within 8 min. The most effective sand-to-solution mass ratio was determined as 1:2, while the optimal process temperature was 75 °C. The application of ultrasound significantly enhances cavitation and reagent penetration, enabling efficient separation of bitumen with minimal chemical usage. Fourier-transform infrared (FTIR) spectroscopy and GC–MS analyses revealed the presence of aromatic hydrocarbons, paraffinic and naphthenic structures, as well as sulfur- and oxygen-containing functional groups (e.g., sulfoxides, carboxylic acids). These characteristics suggest moderate maturity and a high degree of aromaticity of the organic matter. Despite suitable thermal and compositional properties, the extracted bitumen exhibits a relatively low stiffness and softening point, indicating the need for additional upgrading (e.g., oxidation) prior to use in road construction. Although standard rheological tests (e.g., dynamic shear rhinometry) were not conducted in this study, the penetration and softening point values suggest a relatively soft binder, possibly unsuitable for high-temperature paving applications without modification. Future research will focus on rheological evaluation and oxidative upgrading to meet the ST RK 1373-2013 specification requirements. Full article

Heat stress induces metabolic adaptations in fish, including the regulation of triglyceride (TG) synthesis/degradation to preserve cellular lipid balance and energy homeostasis. Diacylglycerol acyltransferase (DGAT) catalyzes the final step in TG synthesis. However, the molecular mechanisms by which DGAT regulates TG metabolism in heat-stressed fish remain unexplored. Our previous study suggested that miR-10c regulates dgat2 expression in genetically improved farmed tilapia (GIFT, Oreochromis niloticus) under heat stress. Here, we characterized the GIFT miR-10c precursor as a 65-nucleotide transcript yielding a 22 nt mature miRNA (oni-miR-10c). A phylogenetic analysis revealed a high level of miR-10c sequence conservation across species. A dual-luciferase reporter assay confirmed dgat2 as a direct target of miR-10c. Overexpression of miR-10c in vivo down-regulated dgat2 transcripts and DGAT2 protein. SiRNA-knockdown of dgat2 resulted in upregulation of cpt1α, fas, and lpl and downregulation of hsl, thereby reprogramming lipid metabolism in GIFT hepatocytes. Thus, the miR-10c-dgat2 regulatory axis facilitates TG hydrolysis and promotes fatty acid metabolism under heat stress. Our findings highlight miR-10c’s potential as a dgat2 inhibitor and its function in regulating lipid metabolism in heat-stressed GIFT. Our study reveals a key molecular pathway mediating thermal adaptation of energy metabolism in fish, providing novel targets for preventing heat-induced metabolic disorders. Full article

The study presents the results of investigations into various types of anhydrous pyrolysis aimed at determining the kinetic parameters of hydrocarbon generation processes from source rocks. Surface outcrop samples from the Silesian, Dukla, and Skole units, characterized by a low level of thermal maturity, were used as experimental material. The samples predominantly represented the Menilite Beds from the aforementioned three units, but also included Istebna, Lgota, Verovice, and Spas beds, which exhibit significantly lower parameters that describe generation properties. The anhydrous pyrolysis experiments provided information on the rate of organic matter decomposition (TG/DSC), the degree of conversion (Rock-Eval), the quality of the obtained products (Py/GC), and the isotopic composition of the gaseous products (Py/GC/IRMS). Chromatographic analyses confirmed the oil-prone nature of kerogen contained in the Menilites from the Dukla Unit (Tylawa area), the Silesian Unit (Iwonicz fold), and the Skole Unit, revealing an equal share of all hydrocarbon fractions: C₁–C₉, C₁₀–C₁₅, and C₁₅₊. Through the integration of pyrolytic studies conducted on potential source rocks in the polish Outer Carpathians, a new type of information was obtained regarding the rate of organic matter decomposition, as well as the fractional and isotopic composition of the pyrolysis products. The set of obtained results was used to estimate the activation energy and characterize the potential source levels. The innovative aspect of this approach involved the isotopic characterization of gaseous products generated during thermal degradation of the source rocks. These data were subsequently used to establish genetic correlations with natural gases accumulated in hydrocarbon reservoirs of the Carpathian region. It has been demonstrated that pyrolysis using PY-GC-IRMS can yield results comparable to those obtained through generation in natural geological conditions. Full article

The Qiongdongnan Basin constitutes a sedimentary basin characterized by elevated temperatures, significant overpressures, and abundant hydrocarbons. Investigations within this basin have identified hydrothermal fluid movements linked to overpressure conditions, comprising two vertically separated overpressured intervals. The shallow overpressure compartment is principally caused by a combination of undercompaction and clay diagenesis. In contrast, the deeper high-pressure compartment results from hydrocarbon gas generation. Numerical pressure modeling indicates late-stage (post-5 Ma) development of significant overpressure within the deep compartment. It is proposed that accelerated subsidence in the Pliocene-Quaternary initiated substantial gas generation, thereby promoting the formation of the deep overpressured system. Multiple organic maturation parameters, combined with fluid inclusion microthermometry, reveal a thermal anomaly adjacent to the upper boundary of the deep overpressured zone. This anomaly indicates vertical transport of hydrothermal fluids ascending from the underlying high-pressure zone. Laser Raman spectroscopy confirms the presence of both hydrocarbons and carbon dioxide within these migrating fluids. Integration of fluid inclusion thermometry with burial history modeling constrains the timing of hydrocarbon-carrying fluid charge to the interval from 4.2 Ma onward, synchronous with modeled peak gas generation and a phase of pronounced overpressure buildup. We propose that upon exceeding the fracture gradient threshold, fluid pressure triggered upward migration of deeply sourced, hydrocarbon-enriched fluids through hydrofracturing pathways. This process led to localized dissolution and fracturing near the top of the deep overpressured system, while simultaneously facilitating significant hydrocarbon accumulation and forming preferential accumulation zones. These findings provide critical insights into petroleum exploration in overpressured sedimentary basins. Full article

Wind power is integral to the transformation of energy systems towards sustainability. However, the increasing number of wind turbines approaching the end of their service life presents significant challenges in terms of waste management and environmental sustainability. Rotor blades, typically composed of thermoset polymer composites reinforced with glass or carbon fibres, are particularly problematic due to their low recyclability and complex material structure. The aim of this article is to provide a system-level review of current end-of-life strategies for wind turbine components, with particular emphasis on blade recycling and decision-oriented comparison, and its integration into circular economy frameworks. The paper explores three main pathways: operational life extension through predictive maintenance and design optimisation; upcycling and second-life applications; and advanced recycling techniques, including mechanical, thermal, and chemical methods, and reports qualitative/quantitative indicators together with an indicative Technology Readiness Level (TRL). Recent innovations, such as solvolysis, microwave-assisted pyrolysis, and supercritical fluid treatment, offer promising recovery rates but face technological and economic as well as environmental compliance limitations. In parallel, the review considers deployment maturity and economics, including an indicative mapping of cost and deployment status to support decision-making. Simultaneously, reuse applications in the construction and infrastructure sectors—such as concrete additives or repurposed structural elements—demonstrate viable low-energy alternatives to full material recovery, although regulatory barriers remain. The study also highlights the importance of systemic approaches, including Extended Producer Responsibility (EPR), Digital Product Passports and EU-aligned policy/finance instruments, and cross-sectoral collaboration. These instruments are essential for enhancing material traceability and fostering industrial symbiosis. In conclusion, there is no universal solution for wind turbine blade recycling. Effective integration of circular principles will require tailored strategies, interdisciplinary research, and bankable policy support. Addressing these challenges is crucial for minimising the environmental footprint of the wind energy sector. Full article

Accurate prediction of crop phenological stages is essential for effective crop management. Such a prediction provides the timing of phenological stages, thus aiding in scheduling management practices, understanding the potential risks of adverse weather at critical phenological stages, and adjusting sowing dates. Temperature is the dominant climatic factor affecting maize (Zea mays L.) development, with photoperiod serving as a secondary influence. This study used maize field data with recorded flowering and maturity dates to evaluate the stability of phenological stage predictions obtained using the calendar days method, thermal functions, and photothermal functions. These methods were used to calculate the number of days, accumulated temperature, and accumulated photothermal units from sowing to flowering and from flowering to maturity. Results showed that thermal functions produced the most stable predictions, with the lowest average coefficient of variation (CV) being 8.37%. The thermal functions were further categorized as empirical linear, empirical nonlinear, and process-based. Within each category, the functions with the lowest average CVs were growing degree days (GDD_8,34; 9.12%), thermal leaf unit (GTI; 7.74%), and agricultural production system simulator (APSIM; 8.26%), respectively. Among them, GTI had the lowest CV, indicating its superior stability in predicting maize phenological stages. These results provide a basis for selecting thermal models in maize phenology research and can support improved decision-making in crop scheduling and management. Full article

The Permian Kupferschiefer shale, a key stratigraphic unit within the Zechstein sequence of the Fore-Sudetic Monocline, represents both a metal-rich lithofacies and a potential source rock for hydrocarbon generation. This study presents a comprehensive geochemical characterization of selected Kupferschiefer samples obtained from the Legnica–Głogów Copper District (LGOM) and exploratory boreholes. Analytical methods included Rock-Eval pyrolysis, Py-GC/FID, elemental analysis, TG-FTIR, biomarker profiling, and stable carbon isotope measurements. Results indicate that the shales contain significant amounts of Type II and mixed Type II/III kerogen, derived primarily from marine organic matter with minor terrestrial input. The organic matter maturity, expressed by T_max, places most samples within the oil window. Rock-Eval S2 values exceed 60 mg HC/g rock in some samples, confirming excellent generative potential. Py-GC/FID data further support high hydrocarbon yields, particularly in samples from the CG-4 borehole and LGOM mines. The thermal decomposition of kerogen reveals multiple degradation phases, with evolved gas analysis identifying sulfur-containing compounds and hydrocarbons indicative of sapropelic origin. Isotopic compositions of bitumen and kerogen suggest syngenetic relationships and marine depositional settings, with samples from a North Poland borehole showing isotopic enrichment consistent with post-depositional oxidation. Kinetic parameters calculated using the Kissinger–Akahira–Sunose method demonstrate variable activation energies (107–341 kJ/mol), correlating with differences in organic matter composition and mineral matrix. The observed variability in geochemical properties highlights both regional and facies-dependent influences on the shale’s generative capacity. The study concludes that the Kupferschiefer in southwestern and northern Poland exhibits substantial hydrocarbon generation potential. This potential has been previously underestimated due to the unit’s thinness, but localized zones with high TOC, favorable kerogen type, and low activation energy could be viable exploration targets for natural gas. Full article

Ice cream is a frozen aerated dessert composed of milk solids, sugars, stabilizers, and fat—with the latter being a key component in defining its structural and sensory properties. This study evaluated the influence of four fat sources—low-trans vegetable fat (T1), butter (T2), UHT cream (T3), and fresh cream (T4)—on the physical and structural characteristics of ice cream, including overrun, melting resistance, texture, color, and rheology, at different stages of processing (before and after maturation). Oscillatory rheological analysis revealed predominantly elastic behavior (G′ > G″) after maturation in all samples, indicating a stable viscoelastic solid structure. Formulations containing T3 and T1 showed the highest overrun values, indicating greater air incorporation, whereas the butter-based formulation (T2) showed the lowest overrun values. Melting resistance followed the following order: T3 > T4 > T2 > T1; therein, the UHT cream formulation exhibited the greatest thermal stability, which was likely due to protein denaturation and aggregation induced by high-temperature processing. Texture analysis showed that the T1 formulation required the lowest maximum extrusion force, while T2 required the highest, reflecting an inverse correlation with overrun values. T1 also displayed the most distinct rheological profile, which was likely due to its specific crystallization behavior and reduced destabilization of the fat globule membrane—which favored the development of a more structured internal network. These findings demonstrate that both the source and processing of fat have a significant impact on the formation of the structural matrix and the final functional properties of ice cream. The results offer technical insights for the development of formulations tailored to specific physical characteristics, optimizing texture, stability, and performance throughout the production process. Full article

The Baorao Trough of the Jiergalangtu Sag, located in the central Erlian Basin, is rich in petroleum resources. However, due to a lack of systematic geochemical characterization and comparative studies with other source rocks, the hydrocarbon generation potential of its Jurassic strata remains unclear. In this study, 125 samples from the Baorao Trough were analyzed to evaluate their hydrocarbon generation potential, identify organic matter sources and depositional environments, and characterize hydrocarbon generation and expulsion. Results show that source rocks from the first member of the Tengge’er (K₁bt₁) Formation and the Aershan (K₁ba) Formation have high organic matter content, favorable kerogen types, and have reached low to medium maturity. In contrast, Jurassic source rocks are predominantly Type III kerogen and highly mature. K₁bt₁ was deposited in a weakly oxidizing to reducing, brackish environment, while K₁ba formed under weakly reducing, saline conditions. Jurassic source rocks also developed in weakly reducing, brackish to saline settings. Notably, saline and reducing environments promote the development of high-quality source rocks. The lower total organic carbon (TOC) threshold for effective source rocks in the study area is 0.8%, and the hydrocarbon expulsion threshold for vitrinite reflectance ratio (R_o) is approximately 0.8%. Accordingly, K₁bt₁ and K₁ba have undergone partial hydrocarbon expulsion but remain within the oil-generating window, indicating strong oil-generating potential. Jurassic source rocks likely experienced early thermal cracking of Type III kerogen, with generated oil migrating or escaping during early geological activity. However, some gas-generating potential remains. These findings provide significant evidence for assessing resource potential, predicting the distribution of high-quality source rocks and favorable exploration areas. Full article

Non-thermal technologies (NTTs) such as ultrasound (US), pulsed electric fields (PEF), high-pressure processing (HPP), cold plasma (CP), and pulsed light (PL) are emerging as versatile tools in food fermentation, offering microbial control and process enhancement without the detrimental heat effects of conventional methods. Operating at ambient low temperatures, these techniques preserve heat-sensitive compounds, modulate microbial activity, and improve mass transfer, enabling both quality retention and functional enrichment. Recent studies highlight their potential to stimulate metabolic pathways and enhance the release of bioactive compounds, opening new opportunities for fermented food production. The bibliometric analysis of the recent literature further reveals a growing interest in NTT applications in fermentation, with HPP and PEF showing the highest industrial maturity. Each technology exhibits distinct mechanisms and optimal niches across upstream, midstream, and downstream stages: HPP for uniform volumetric treatment, US for fermentation intensification, CP for surface-selective oxidative chemistry, PEF for membrane permeability control, and PL for rapid, residue-free decontamination. While the degree of industrial readiness varies, critical barriers such as scale-up limitations, high capital costs, energy distribution uniformity, process standardization, and techno-economic feasibility remain to be overcome. Beyond technical aspects, the successful commercialization of NTTs will also depend on addressing regulatory approval pathways, ensuring consumer trust and acceptance, and demonstrating their contribution to sustainability goals through lower energy use, reduced food waste, and environmentally responsible processing. Strategic, stand-alone, or hybrid applications of NTTs can therefore act not only as technological alternatives but also as enablers of a more sustainable, consumer-centered, and innovation-driven food system. Full article

The rapid development of the space economy is posing big challenges, a major one being space debris mitigation. In this respect, the Horizon Europe EARS project aims to introduce the disruptive concept of reusability in the SmallSat market, taking a step towards a more sustainable exploitation of space. The main objective of EARS has been to outline the concept of operations (CONOPS) of a small reusable satellite and the maturation of the relevant key enabling technologies needed to guarantee safe re-entry of the satellite and its payload. In this paper, we present the preliminary design of the EARS spacecraft and its CONOPS and mission engineering with an overview of the simulations conducted to assess the aerodynamic load during spacecraft re-entry and the Plasmatron tests executed for the selection and characterization of the materials suitable for the construction of an inflatable thermal protection system to guarantee a safe atmospheric re-entry. Full article

The objective of this study was to evaluate the technical properties and assess the durability of a novel high-performance concrete with aggregates composed entirely of reactive powders derived from chalcedonite—a mineral previously not utilized in HPC technology. Since there is insufficient information on chalcedonite-based concretes in the scientific literature, the presented research aims to address these knowledge gaps. The characterization of the chalcedonite powder involved the determination of specific gravity, particle size distribution, specific surface area, and particle morphology through microscopic analysis. The hardened chalcedonite-based and reference quartz-based high-performance concretes were subjected to a comprehensive suite of tests to determine their physical properties (bulk density, water absorption, and capillary absorption) and mechanical properties (flexural and compressive strength). Durability was further assessed based on compressive strength criteria, including frost resistance and carbonation resistance. To simulate long-term performance and better evaluate the durability of the high-performance concretes, specimens were tested following standard water curing and after additional maturation processes, including thermal treatment, which in the extreme case resulted in a seven-day compressive strength of 176.9 MPa, a value higher by 56.7 MPa (corresponding to an increase of 47.1%) compared to the strength of the identical concrete not subjected to thermal treatment. To explore the potential for architectural applications, particularly in outdoor environments, capillary absorption testing was of particular importance, as it provided insight into the material’s resistance to eventual pigment leaching from the mineral matrix. Full article

Cyanobacteria are a natural source of bioactive compounds increasingly recognized for their anti-inflammatory properties. In the Euganean Thermal District (Italy), thermal muds, used to cure arthro-rheumatic diseases, are prepared using natural clay and thermal water, resulting in a mature mud characterized by a complex microbial biofilm dominated by Cyanobacteria. Among these, Phormidium sp. ETS-05 has been shown to contribute to the therapeutic properties of the mud, mainly through the production of bioactive compounds such as exopolysaccharides (EPSs) and glycoglycerolipids (GLs). In contrast, the role of biomolecules from Thermospirulina andreolii ETS-09 and Kovacikia euganea ETS-13, also abundant in mature muds but at higher maturation temperatures, has not been investigated. This study focuses on the lipid profiles of these cyanobacteria, cultivated under temperature conditions that mimic their natural environment and that are different for the three species. Lipid extracts were analyzed for GLs classes and fatty acid composition, and their anti-inflammatory potential was assessed in vivo using a zebrafish inflammation model. All extracts showed anti-inflammatory activity with Phormidium sp. ETS-05 displaying the highest lipid content and the most rapid and potent beneficial effect, likely due to the specific composition of its GLs, presenting the greatest abundance of polyunsaturated fatty acids. These findings provide new insights into the biological basis of the therapeutic effects of Euganean muds and emphasize the importance of maturation conditions for cyanobacterial growth and bioactive lipid production. Full article

Immature soybean seeds, after steaming or boiling, are widely consumed in Northeast Asia. However, changes in isoflavones and antioxidant activities during processing at different seed stages remain underexplored. In this study, soybean seeds at four maturity stages (R5–R8) were analyzed for 12 isoflavones and evaluated after steaming. Total isoflavone content increased from R6 to R7 and remained stable to R8, presenting a 10-fold increase in R7 than in R6. Levels of malonyl derivatives, such as malonylgenistin, malonyldaidzin, and malonylglycitin, consistently decreased with longer steam treatment at all seed stages. In contrast, β-glycoside forms, such as genistin and daidzin, increased after steaming, with notably high content at R7. Additionally, ABTS radical scavenging activity and total phenolic content showed strong positive correlations with total and major isoflavones, whereas DPPH radical scavenging activity showed no correlation with maturity stage or steam treatment. These findings indicate that isoflavone stability and conversion are strongly affected by seed maturation and that the R7 stage offers a favorable balance for high isoflavone and antioxidant intake in soybean seeds. Full article

With the escalation of global warming and environmental pollution, electric products characterized by zero emissions, low vibration, and minimal pollution are increasingly favored by consumers. As a pivotal loading and transportation tool, the electrification of forklifts progressed earlier and is relatively mature. However, the prevalent low-voltage systems (72 V or 80 V) in current electric forklifts exhibit issues such as elevated heat loss, restricted motor instantaneous power due to voltage constraints, susceptibility to electrical erosion, and challenges in achieving rapid charging. To address these challenges, a powertrain solution employing high-voltage lithium batteries (320 V) as energy storage units for electric forklifts is proposed. The key parameters of the high-voltage lithium battery were meticulously calculated and selected. The powertrain architecture of the high-voltage lithium battery electric forklift was analyzed, and operational conditions were thoroughly examined. To verify the superior energy efficiency performance of the proposed high-voltage electric forklift in comparison to its low-voltage counterparts, a test prototype was constructed, and comprehensive tests, including average energy consumption and thermal equilibrium assessments, were conducted. The test results demonstrated that under average energy consumption conditions, the operational duration ranged from 8.89 to 13.34 h, surpassing the 7.5 h achieved by low-voltage electric forklifts. The thermal equilibrium temperatures of all electrical control units remained below 43 °C, significantly lower than the 80 °C shutdown protection threshold allowed for low-voltage forklifts. These findings indicate that the proposed high-voltage lithium battery electric forklift exhibits relatively low energy consumption, significantly enhances overall operational efficiency, and ensures stable operation, providing a viable solution and reference for the electrification of forklifts and other construction machinery. Full article