Search Results (9,332)

The solidification process is crucial for preparing high-performance superconductors and is strongly dependent on the characteristics of the starting powder, including particle size, morphology, and phase purity. This review concisely examines the study on four key superconductors: REBCO, Bi-2212, FeSeTe, and MgB₂. In REBCO, additives such as CeO₂, Pt, or BaO₂ powder can refine the RE-211 phase. In Bi-2212, Pb doping stabilizes the high-T_c phase. For FeSeTe, doping with F or Co modifies phase separation and introduces Δκ pinning. Meanwhile, in MgB₂, the incorporation of SiC nanoparticles powder generates effective pinning centers. Concurrently, processing conditions exert a decisive influence on the final microstructure, as demonstrated by the TSMG/TSIG route in REBCO, partial melting parameters for Bi-2212, specific cooling protocols and thermal treatments for FeSeTe, and optimized sintering and post-annealing processes for MgB₂. Future research directions should prioritize fundamental understanding of phase separation mechanisms during powder processing, development of multi-component doping strategies for powder modification, and advancement of scalable powder processing routes for practical conductor architectures. Full article

The modern world is confronting critical environmental and biomedical challenges, underscoring the urgent need for the development of multifunctional materials—an inherently interdisciplinary field, bridging materials science and engineering, environmental science and biomedicine. Titanium dioxide (TiO₂) is widely recognized for its photocatalytic and antiviral properties, enabling the degradation of pollutants and mitigation of viral contamination under solar irradiation. Nevertheless, it exhibits certain limitations, such as wide band gap and high recombination rate of photogenerated electron–hole pairs. To address these limitations, TiO₂ prepared by a co-precipitation method was modified with N-Doped Carbon Dots (N-CDs) via a hydrothermal treatment, which extend light absorption into the visible region and enhance charge separation. Further functionalization with silver nanoparticles (Ag NPs)—well known for their antimicrobial properties—via a simple thermal process under ambient conditions, introduced additional reactive oxygen species generation, creating a synergistic effect. The as-prepared TiO₂, TiO₂/N-CDs and TiO₂/N-CDs/Ag samples were characterized via several techniques, such as XRD, micro-Raman, FT-IR, TEM and UV-Vis. In addition, their photocatalytic and antiviral activity against methylene blue (MB) and nitrogen oxide (NO_x) pollutants, as well as SARS-CoV-2, was evaluated. Based on the results of liquid-phase photocatalysis, TiO₂, TiO₂/N-CDs and TiO₂/N-CDs/Ag presented a degradation efficiency of 78%, 85% and 95%, respectively, whereas different trends were observed under gaseous-phase conditions. The TiO₂/N-CDs/Ag hybrid material demonstrated superior antiviral activity against SARS-CoV-2 (IC₅₀: 1.24 ± 0.34 g/L), compared to both TiO₂ (IC₅₀: 1.78 ± 0.30 g/L) and TiO₂/N-CDs (IC₅₀: >2.5 g/L), highlighting its potential as an effective multifunctional material. Finally, TiO₂/N-CDs/Ag was incorporated onto a paper substrate, demonstrating antiviral activity, showing promising scalability for application across a wide range of future substrates. To the best of our knowledge, this is the first study presenting TiO₂/N-CDs/Ag with dual photocatalytic and antiviral activity. Full article

Beyond gas transport, red blood cells (RBCs) have emerging roles regarding innate immunity, regulating blood flow, and participating in nutrient transport, which can be engineered as drug delivery systems since they contribute to maintaining water homeostasis. Following extensive thermoanalytical studies of human blood plasma, our working group investigated the properties of RBCs, examining their role in healthy and in different disease states by using differential scanning calorimetry (DSC) and the deconvolution of the resulting thermal curve. In the first study, guinea pigs were treated with intraperitoneal chemotherapy. Cyclophosphamide treatment showed a dose-dependent difference between the thermal parameters of control and treated samples, indicating that DSC can be used in this area. Following deconvolution of the DSC studies, the changes can be attributed to the damaged compounds. In the second part of our study, a method for the thermal analysis and deconvolution of RBCs in patients with lower limb ischemia during a three-month cilostazol treatment was developed. The control DSC curve showed 5-6 distinct thermal domains, and in contrast to other drug treatments, this remained stable throughout the entire study period. No effects of stiffness or compact were caused by the anticancer drug cyclophosphamide were observed in the structure of RBCs. These preliminary results highlight the uniqueness of thermodynamic studies of RBCs and provide a fingerprint-like identification of a given individual or disease state. Full article

Given the depletion of conventional oil and gas resources, oil shale represents a promising alternative source of hydrocarbons that can be recovered through pyrolysis. This study examines the thermal decomposition of raw oil shale from the Tarfaya deposit and its decarbonized concentrate, studied by thermogravimetric analysis at different heating rates (5, 10, 20 and 40 °C/min). Pretreatment with acetic acid enabled the selective removal of calcite, confirmed by elemental, XRF, and XRD analyses, which revealed a relative enrichment in silica and dolomite in the oil shale concentrate. Pyrolysis of the raw shale occurs primarily between 300 and 500 °C, with a conversion rate of approximately 30%. In contrast, for the oil shale concentrate, the pyrolysis process begins at a relatively low temperature, within a wider temperature range (260–520 °C). Kinetic analysis based on Flynn–Wall–Ozawa (FWO) and Kissinger–Akahira–Sunose (KAS) methods shows that at a conversion rate of 60%, the activation energy achieves 14.09 kJ/mol and 10.78 kJ/mol, respectively. The results indicate that the selective removal of calcite by acetic acid treatment facilitates kerogen pyrolysis by reducing mineral–organic interactions. Indeed, calcite dilutes the reactive organic fraction and can act as a physical barrier limiting heat and mass transfer within the oil shale. Its removal improves, on the one hand, the accessibility of kerogen to thermal cracking and promotes its decomposition, and on the other hand, reduces the amount of residue after pyrolysis. In addition, the kinetic analysis based on Criado master curves reveals changes in the reaction mechanism after decarbonation treatment depending on the heating rate (β). A shift from a two-dimensional Avrami–Erofeev model (A2) to a three-dimensional model (A3) was observed at a low heating rate (β = 5 °C/min), suggesting a change in nucleation and growth dynamics during kerogen decomposition. At high heating rates (10, 20 and 40 °C/min), the thermal decomposition of kerogen combines several reaction mechanisms depending on the temperature range considered. Full article

Recycled aggregates (RAs) from construction and demolition waste (CDW) provide substantial circular-economy benefits, yet their elevated porosity, adhered mortar, and heterogeneity typically impair the mechanical performance and durability of recycled aggregate concrete (RAC). This PRISMA 2020-compliant systematic review synthesises 2180 records (2015–2026) to evaluate advanced strategies for enhancing RA quality prior to structural use. This paper critically compares removal-based treatments (mechanical, thermal, acid cleaning) with strengthening and densification approaches, including accelerated carbonation, pozzolanic and nano-silica coatings, polymer impregnation, microbial-induced calcium carbonate precipitation (MICP), and modified mixing methods such as triple-stage mixing (TSMA). Evidence shows that while all RA types (including recycled fine aggregate (RFA), recycled coarse aggregate (RCA), and their combination (RFCA)) can slightly reduce compressive strength and 30% replacement serves as a critical threshold, beyond this, strength loss accelerates, particularly in RCA and RFCA mixes. However, accelerated carbonation and TSMA consistently refine the interfacial transition zone, reduce water absorption by 17–30%, and recover 85–94% of natural aggregate concrete strength. Bio-deposition reduces water absorption by 13–21%, while acid/silica fume treatments improve late-age strength but carry environmental trade-offs. This review formulates a practice-oriented implementation framework for structural-grade RAC. Sustainability analyses indicate that carbonated RA can achieve net-positive CO₂ abatement when under low-carbon energy supply. A mechanistic schematic is presented to synthesise treatment-to-pore-structure/durability pathways across the four principal treatment routes, and a quantitative synthesis plot compares water absorption reductions across all treatment types using 13 data points drawn from included studies. A structured treatment comparison evaluates the energy intensity, industrial scalability, CO₂ footprint, and technology readiness level for each strategy. The remaining challenges include a lack of hybrid treatment studies, limited real-scale durability data, and insufficient mechanistic models linking treatment to pore structure evolution. This review recommends harmonised durability-based criteria and updates to standards (e.g., BS 8500, EN 12620) to support the scalable deployment of treated RA. Full article

This study investigates the hydrothermal modification of commercial titanium dioxide (TiO₂) in the presence of a natural licorice root extract (Glycyrrhiza glabra L.), serving as a stabilizing and growth-modulating agent. The experimental framework combines hydrothermal treatment in a Teflon-lined autoclave with subsequent thermal calcination to elucidate the structural, morphological, and chemical evolution of the material. The plant-based extract significantly influences particle assembly during synthesis, fostering the formation of an initial organic–inorganic hybrid system that results in enhanced morphological homogeneity compared to pristine TiO₂. Thermal analyses (TGA and DSC) demonstrated the progressive decomposition of the organic components with increasing temperature, yielding a thermally stable, predominantly inorganic material at 600 °C. Scanning Electron Microscopy (SEM) observations confirmed a more uniform particle distribution in the modified samples. X-ray diffraction (XRD) patterns corroborated that the primary crystalline phase of TiO₂ remains intact across all conditions, with structural variations limited to peak definition and long-range organization. Furthermore, FTIR spectroscopy supported the preservation of characteristic TiO₂ vibrational features while indicating a gradual depletion of weakly bound surface species following thermal treatment. In conclusion, these findings demonstrate that natural extracts can effectively function as growth-modulating agents, steering material organization without altering its intrinsic chemical properties. This approach aligns with the principles of Green Chemistry and the circular economy, highlighting the potential of renewable plant-based resources as functional additives for the sustainable processing of inorganic materials. Rather than seeking to outperform commercial benchmarks, this work establishes a viable and low-environmental-impact strategy for morphological and structural modulation. Full article

Urban water scarcity and climate change pose significant challenges for sustainable development, particularly in rapidly expanding metropolitan areas. In cities like Casablanca, these pressures also threaten the preservation of cultural heritage sites such as traditional public bathhouses (Hammams). This study investigates how Hammams can integrate sustainable water management solutions in alignment with Sustainable Development Goal 11 (SDG 11), focusing on the treatment and reuse of graywater. This study compares three graywater treatment systems, a Membrane Bioreactor (MBR), a Sequencing Batch Reactor (SBR), and a Moving Bed Biofilm Reactor (MBBR), evaluated through literature review and dimensioning calculations, and also integrates an existing treatment plant in Berlin that functions as a real-scale laboratory. The comparison is based on a set of technical, economic, and environmental criteria used for comparative engineering design assessment and evaluation for the selected Hammam water reuse applications. All systems are technically feasible but show distinct trade-offs. The SBR has the lowest energy demand and highest cost savings, the MBBR offers a compact and simple design, and the MBR provides the highest effluent quality at a higher energy cost. Heat recovery provides a significant thermal energy recovery potential but is reported separately from the electrical energy demand of the treatment systems. Full article

The high-rate recycling of scrap steel introduces persistent residual copper (Cu), which accumulates at prior austenite grain boundaries at the surface, during high-temperature reheating, leading to Cu-induced sensitization and deleterious “hot shortness”. To address this, a predictive analytical framework was derived using Fick’s Second Law and the Sekerka, Jeanfils, and Heckel (SJH) approach to model the dissolution of Cu-rich films as a 1D planar moving boundary problem. The validity of this analytical framework was first established through experimentation on controlled Cu-coated steel wire rods, where theoretical concentration profiles showed strong agreement with empirical depth profiles. When applied to a 0.21 wt.% Cu steel at 1000 °C, the model predicted a critical extinction time (t*) of approximately 8.57 min for the complete dissolution of a 20 nm sensitized film. Experimental trials on sensitized wire rods confirmed this prediction, demonstrating an 89% reduction in the frequency of detectable sensitized zones and a significant decrease in zone width following a 10 min thermal dwell. The approach provides a standardized, scalable, and composition-adaptable methodology, grounded in a 1D planar approximation, for optimizing desensitization heat treatments across a range of Cu contents, offering a practical strategy to increase scrap steel utilization while mitigating hot shortness. Full article

With the rapid expansion of wind energy infrastructure, there is an increasing accumulation of wind turbine blade waste (WTBW), which is mainly composed of glass fiber-reinforced thermosetting composites. Due to the irreversible nature of polymer crosslinking, conventional recycling methods remain limited. In this study, plasma vitrification was employed to convert WTBW into a reactive calcium-aluminum-silicate slag suitable for use in geopolymer materials. Plasma treatment at a temperature of approximately 2750 K resulted in the formation of predominantly amorphous vitrified slag (VS). Structural characterization using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS) revealed the spatial heterogeneity of the VS. This heterogeneity was influenced by thermal gradients and varied between samples collected from different slag discharge zones, both vertically and horizontally from the reactor. All VS samples contained between 30 and 89% amorphous phase and 10–55% anorthite, with the proportions varying by sampling location. Chemical stability tests showed the dissolution of calcium and aluminum in acidic media, resulting in a silica-enriched residual structure in which the Ca and Al content decreased to less than 0.5 at.% after 100 days. In contrast, exposure to alkaline media caused only minimal surface reorganization—the addition of 5 wt.% VS to acid-based geopolymers made with two metakaolin precursors resulted in a 35% decrease in the mechanical strength of pure metakaolin-based systems. In contrast, when metakaolin containing illite impurities was used, strength values were similar to those of the reference geopolymer. The results quantitatively demonstrate that plasma-derived slag exhibits composition-dependent reactivity, directly linked to its amorphous content and dissolution behavior. Full article

Improving the water-holding capacity (WHC) during the processing of rabbit meat can effectively enhance the texture of the final product, but it remains a practical challenge. This study aims to develop an ultrasound-assisted curdlan curing strategy to reduce the water loss of rabbit meat during the processing. Herein, the water retention performance, myofibrillar protein (MP) structure, and processing adaptability of rabbit meat as affected by the ultrasound-assisted curdlan curing treatment were investigated. Compared with the control group, ultrasound-assisted curdlan treatment increased WHC by 14.0% and reduced cooking loss by 15.4%. Moreover, this combined treatment showed significantly higher WHC and lower cooking loss than curdlan or ultrasound treatment alone (p < 0.05). Moreover, the ultrasound-assisted curdlan curing resulted in higher ultraviolet absorption and fluorescence intensity of myofibrillar proteins (MPs) in rabbit meat, but the intensity of the main protein band observed in SDS-PAGE was lower. Furthermore, the rabbit meat treated with the ultrasound-assisted curdlan curing maintains the highest water content (75.2% for steaming, 74.7% for boiling, 74.4% for microwaving, 70.1% for roasting, and 71.8% for air-frying) under various thermal processing methods. Therefore, the ultrasound-assisted curdlan curing offers a feasible route to improve water retention in rabbit meat, providing an applicable basis for reducing water loss in meat production. Full article

Proton exchange membranes (PEMs) are essential for PEM fuel cells, with proton conductivity arising from the hydration-induced ionic channel network. PEM performance can be enhanced through pretreatments, such as annealing, which reconstruct the ionic channels. This study investigates the ionic channel network variation in Nafion 212 under continuous annealing at 90 °C using current-sensing atomic force microscopy (CSAFM). A nanoscale PEM fuel cell was formed with a Pt-coated CSAFM tip and Pt-coated Nafion surface. Topography and surface roughness analyses revealed geometrical changes from annealing. Current-sensing images and histograms qualitatively assessed local conductance and ionic channel distribution. The ionic channel network density was quantitatively evaluated using the number of protons moving through the ionic channel network (NPMI), derived from CSAFM and electrodynamics principles. NPMI directly reflects ionic channel density. From the unannealed state to 60 h, NPMI increased linearly at 1 × 10⁴ h⁻¹, indicating enhanced channel formation. Beyond 60 h, NPMI decreased linearly at 1.9 × 10⁵ h⁻¹, reflecting progressive network degradation. As the ionic channel network increases, the number of protons reaching the membrane surface also increases, whereas in the opposite case it decreases. Thus, NPMI becomes evaluation criterion for ionic channel network density. These findings systematically link nanoscale structural changes to ionic channel reconstruction and proton transport in Nafion 212, providing insight into PEM performance evolution under thermal treatment. Full article

Hot extrusion tools operate under severe thermal and mechanical conditions, which significantly limit their service life. During operation, the punch and die absorb large amounts of heat from the hot billet while being subjected to high pressures and intense friction, leading to severe abrasive wear and progressive hardness reduction. In practice, the punch generally exhibits a shorter service life than the die. The present study proposes a technological solution for reconditioning worn extrusion punches using vibration-assisted welding (VAW). A wear-resistant layer was deposited by MIG welding using DUR 600 filler material, while mechanical vibrations were introduced through a vibrating welding table. The applied vibration regime consisted of a frequency of 50 Hz–108 Hz and acceleration components of a_x = 30–60 m/s² and a_z = 35–70 m/s². The experimental investigations included macroscopic analysis, hardness and microhardness measurements, microstructural observations, and SEM-EDS line scanning analysis of the dilution zone between the cladding material and the base metal. The results suggest that vibration-assisted welding may influence the microstructural characteristics, hardness distribution, and dilution behavior of the cladded layer. The vibrated specimens exhibited higher hardness values in the range of 702 to 908 HV5–10. Under the investigated conditions, the process did not require additional hardening treatment, and only a stress-relief annealing stage was applied. The proposed VAW approach appears to be a promising option for the reconditioning of hot extrusion tools; however, further investigations are required to validate its performance under industrial conditions. Full article

This paper presents the results of research conducted on the influence of thermoplastic extrusion parameters (layer height per pass—L_h and the percentage fill density—I_d) and heat treatment (annealing) on the compressive strength of specimens manufactured by thermoplastic extrusion of virgin and recycled polyethylene terephthalate glycol (PETG and rPETG) filaments. To support the study, using the parameters L_h = (0.10–0.20) mm and I_d = (50–100)%, 90 compression test specimens were manufactured from PETG and rPETG (45 specimens for each material), which were subsequently subjected to heat treatment by annealing at a temperature of 75 °C for a period of 180 min. The results obtained highlight a significant correlation between the variable manufacturing parameters (L_h and I_d) and the compressive strengths (C_s). The average compressive strengths of the 45 specimens made from PETG are 44.15% lower than the average compressive strengths of the specimens made from rPETG. The annealing heat treatment resulted in a 31.40% decrease in the average compressive strengths of the specimens made from PETG and a 0.63% increase in the average compressive strengths of the specimens made from rPETG. The specimens made from PETG exhibited increased thermal sensitivity, which led to molecular relaxation, while rPETG exhibited superior thermal stability acquired through recycling. Full article

The progressive deployment of renewable energy systems has engendered a considerable increase in the generation of glycol-based coolant waste, specifically ethylene glycol (EG) and propylene glycol (PG), thereby raising significant environmental apprehensions. This review analyses the critical environmental challenge and examines the feasibility of microbial degradation as a viable and sustainable alternative to glycol waste treatment, while highlighting significant gaps in current hazardous glycol waste management practices. Present waste management practices are largely founded on incineration or membrane filtration approaches, both of which exhibit significant energy demands and inefficiencies in large-scale waste handling. Reported performance ranges from >99% EG recovery at 10–16 kWh/m³ by electrodialysis and 80–95% recovery at 2–4 MJ/kg by vacuum distillation, to ~17 MJ/kg combustion heat from incineration; biological methods, though promising, currently operate below 10% glycol concentration, an order of magnitude below the 10–100% range in real coolants. We analyze the current understanding of metabolic pathways involved in glycol biodegradation, drawing on the peer-reviewed literature, bioinformatics, and patent databases. Special attention is given to the challenges of high glycol concentrations in industrial coolants and the formation of toxic oxidation products during thermal aging. The review also explores recent advances in genetic engineering approaches to enhance microbial degradation efficiency. Finally, we discuss the potential integration of biological recycling methods into existing waste management systems and future prospects for converting glycol waste into value-added products through microbial biotransformation. Full article

The rapid electrification of road transport has increased interest in distributed energy strategies that reduce grid demand and support decarbonization. Vehicle-integrated photovoltaics (VIPV), including vehicle-applied photovoltaic configurations (VAPV), can generate electricity directly on the vehicle. This systematic review examines peer-reviewed VIPV literature published between 2015 and 2026, focusing on the distinction between theoretical photovoltaic generation and practically usable energy. A Scopus search conducted on 2 May 2026 identified 196 records, of which 88 studies were included after screening against predefined criteria. Due to heterogeneity in vehicle types, climates, technologies, modeling assumptions, and reported metrics, no meta-analysis was performed. Instead, the review applies a multi-layered framework covering climate, geometry, thermal effects, electrical mismatch, battery state-of-charge interactions, fleet-scale modeling, economics, and life-cycle implications. The evidence shows that VIPV is technically feasible and can deliver measurable energy yields, especially in high-irradiance regions and vehicles with favorable daytime parking exposure. However, useful contribution depends strongly on curvature losses, dynamic shading, electrical configuration, SOC limits, charging behavior, seasonality, and vehicle energy demand. Therefore, VIPV is best understood as a context-dependent supplementary energy strategy rather than a transformative standalone solution. Its strongest value lies in specific vehicle classes, climates, and usage patterns where on-board generation can reduce charging demand, support operational resilience, or improve distributed self-consumption. The review also proposes minimum reporting requirements for future studies, including annual energy yield, Wh/km contribution, PV area or capacity, mileage assumptions, SOC modeling, and curtailment treatment. The review was not formally registered, and no formal risk-of-bias or certainty assessment was applied. Full article