Search Results (364)

This study re-examines the ongoing debate over corporate disclosure frequency amid renewed calls to replace quarterly with semiannual reporting in U.S. markets. While traditional theories hold that frequent disclosure enhances informational efficiency by reducing asymmetry, emerging evidence highlights trade-offs involving managerial myopia, earnings management, and heightened short-term volatility. Using data from 2007 to 2024, the study compares Dow Jones Industrial Average firms, which report quarterly, with STOXX 50 firms, which report semiannually, to assess how disclosure cadence affects market reactions to earnings news The methodology involves identifying volatility regimes using Self-Exciting Threshold Autoregressive (SETAR) models, estimating dynamic betas with the GARCH(1,1) model, and analyzing shock transmission through vector autoregressions with cumulative impulse response functions (CIRFs). The results show that quarterly reporters exhibit larger immediate price reactions but faster normalization, implying that more frequent reporting accelerates information assimilation while amplifying contemporaneous volatility. Sectoral heterogeneity is pronounced: cyclical industries display higher beta volatility and steeper, but shorter-lived responses, whereas defensive stocks exhibit smoother convergence. These findings suggest that disclosure frequency influences both the intensity and duration of information shocks, providing insights for regulators who aim to balance transparency, market efficiency, and reporting costs across varying volatility and sectoral environments. Full article

Background/Objectives: The Commission d’examen des troubles mentaux (CETM), under Quebec’s Tribunal Administratif du Québec, reviews individuals found not criminally responsible on account of mental disorder (NCRMD). These hearings seek to balance public safety with reintegration, guided largely by treatment team recommendations. Despite the CETM’s central role in forensic psychiatry, limited empirical data exist on how its decisions align with clinical advice and which dynamic risk factors influence outcomes. This study aimed to (1) profile the CETM’s 2023 caseload, (2) evaluate concordance between CETM dispositions and treatment team recommendations, and (3) examine clinical, social, and legal factors associated with decision-making. Methods: We conducted a retrospective review of 1721 judgments issued by the CETM in 2023, retrieved from the publicly accessible Société Québécoise d’information juridique (SOQUIJ) database. Eligible cases included annual NCRMD review hearings, excluding trial fitness assessments and repeated hearings within the same year. A structured coding grid documented sociodemographic, administrative, legal, and clinical information, with emphasis on dynamic risk factors such as treatment adherence, substance use, and recent aggression. Descriptive analyses summarized population characteristics and concordance between clinical recommendations and CETM decisions. Results: The cohort was predominantly male (85%) with a mean age of 41 years. Psychotic disorders were the most frequent primary diagnoses (76%), frequently accompanied by substance use and antisocial traits. Most patients (79.6%) had prior psychiatric hospitalizations, while 25.5% had prior incarcerations. Nearly half displayed recent aggression or non-compliance. Treatment teams most often recommended conditional discharge (55%), followed by detention with conditions (21%) and unconditional release (19%). CETM decisions aligned with recommendations in 83.6% of cases; when divergent, rulings were more restrictive (8.6%) than permissive (4.6%). Conclusions: This study provides the first large-scale profile of Quebec’s CETM. High concordance with clinical teams was observed, but restrictive decisions were more frequent in cases of disagreement. The findings underscore the importance of incorporating standardized risk assessment tools to enhance transparency, consistency, and balance in forensic decision-making. Full article

In this study, zinc phthalocyanine (ZnPc) and copper phthalocyanine (CuPc) thin films fabricated by drop casting (DC) and close space sublimation (CSS) have been investigated and compared with ZnPc and CuPc solutions in formic acid (29 µmol/L). The results show that the CSS method produces films with improved molecular ordering, enhanced surface uniformity, superior optical and morphological properties compared to those obtained by drop casting. Moreover, CSS allows a precise and reproducible deposition, resulting in thinner, homogeneous layers with strong substrate adhesion and fewer defects. Optical characterization confirms that CSS films display high transparency (~90%), a sharp Q-band around 680 nm, and a fluorescence maximum at ~825 nm with the strongest emission intensity.In contrast, DC films show lower transparency (<70%), a slightly shifted Q-band (~675 nm), and similar emission around 825 nm. The fluorescence is strongly thickness-dependent: at ~100 nm, the emission band appears at 795 nm, while films thicker than 300 nm exhibit a red-shifted maximum at ~825 nm. AFM analysis further demonstrates the influence of deposition method: CSS yields smoother films with tunable morphology, while DC produces rougher, less controllable surfaces. Overall, CSS is shown to be the more effective approach for fabricating high-quality phthalocyanine films for optoelectronic applications such as photovoltaics and sensors. Full article

This study examines the potential use of rejected and discarded grains from the common bean industry as a starch source for producing plasticized films with glycerol. The observed morphological characteristics of starch granules from discarded grains were diverse, with round, oval, and kidney-like shapes and sizes ranging from 7 to 34 µm. We determined the pasting profile: the pasting temperature (GT) fell between 72 °C and 74 °C, while the peak viscosity (P_v) demonstrated a significant rise at 10% and 15% starch concentrations. To better understand pasting behavior, mathematical modeling was employed to predict P_v behavior, with an R² value of 0.98. All film formulations were successful, yielding transparent, homogeneous, odorless, flexible films with smooth surfaces. Scanning electron microscopy analysis of the films revealed a flawless surface devoid of fissures, cracks, and pores, displaying a rough texture with a consistent structure and some starch granules resembling empty sacks due to amylose and amylopectin leaching. The highest tensile strength was observed with 6% starch and 1.5 mL of glycerol and the lowest with 4.5% starch and 3.9 mL of glycerol. The findings suggest that starch derived from discarded grains from the bean industry has unique characteristics and properties, making it a promising alternative source for intelligent packaging development. Full article

This study examines how large-scale school infrastructure reforms shape teaching practice, using Australia’s Building the Education Revolution (BER) initiative as a case example. Guided by Cultural-Historical Activity Theory (CHAT), the research explores how redesigned learning environments act as mediating tools that influence pedagogy, collaboration, and teacher wellbeing. An explanatory sequential mixed-methods design was employed, combining survey data from 34 teachers with focus group interviews involving 13 participants in a redeveloped Victorian Primary School, Australia. Quantitative results showed that 70.5% of teachers reported changes in their teaching practices directly linked to the new infrastructure, with 100% affirming that they had enhanced collaboration opportunities. Qualitative findings revealed that features such as breakout rooms, shared learning zones, and transparent sightlines enabled differentiated instruction, co-teaching, and improved supervision, while also fostering professional pride and collegial support. Contradictions emerged around automated lighting systems, limited display space, and partial teacher consultation during the design process. CHAT analysis demonstrated how physical spaces interact with rules, community, and division of labour within the school activity system, producing both enabling conditions and systemic tensions. The study underscores the need for infrastructure planning to be pedagogically informed, inclusive of teacher voice, and designed to support adaptive, collaborative, and inclusive teaching practices. Full article

A significant number of digital marketers use unethical marketing methods that violate Search Engine Optimization guidelines, with the objective of deceiving engines into displaying a specific website as the top result. The practice of fake comments constitutes a violation of Search Engine Optimization policies and is directly impeding market transparency. In addition, the absence of established standards between search engines, evaluation platforms and other trusted agencies makes exploitation easy. Therefore, in order to ensure fair competition among digital businesses, we propose a decentralized system for detecting fake comments, leveraging Blockchain technology for verification. The implementation of smart contracts as self-executing agreements will be achieved by utilizing the Ethereum network and the Truffle Suite. The Ethereum smart contracts will immutably record every comment as a transaction, eliminating any central authority. When a comment is flagged as suspicious, a digital business can trigger a verification request. Stakeholders or reviewers then vote on authenticity. Smart contracts collect these votes and issue a definitive verdict on whether the comment is fake. Full article

Background: Digital transformation is reshaping public organizations worldwide, yet in low-resource contexts, its success is constrained by weak infrastructure and governance. In India, programs such as the Ayushman Bharat Digital Mission and the Aspirational Districts Programme rely on meso-level officers who act as key managerial intermediaries, but their organizational challenges remain understudied. Aim: This study examines sub-district health and nutrition officers’ experiences, organizational barriers, and adaptive strategies in implementing digital reforms. Methods: Eight in-depth interviews were conducted with Medical Officers in Charge (MOICs) and Child Development Project Officers (CDPOs) across urban, semi-urban, rural, and flood-prone blocks of Muzaffarpur, Bihar. Data were transcribed, translated, and thematically analyzed using Braun and Clarke’s approach, informed by organizational and technology adoption theories. Results: Officers valued digital tools for transparency and real-time monitoring but faced systemic barriers, including hardware decay, poor connectivity, fragmented platforms, and limited fiscal autonomy. Despite these, they displayed managerial agency through informal infrastructures such as WhatsApp, peer mentoring, and parallel records. COVID-19 accelerated digital use while widening inequities. Conclusions: Meso-level officers are critical enablers of organizational resilience. Their experiences highlight how leadership, governance, and adaptive management shape digital transformation in resource-constrained settings. Full article

Adipocyte cell models are essential for investigating adipogenesis, yet methodological inconsistencies pose challenges to obtaining reproducible and physiologically relevant results. Murine cell lines, such as 3T3-L1 and OP9, are commonly utilized due to their established adipogenic capabilities. However, differences in its metabolic, genetic regulation, and receptor signaling raise concerns about their applicability to human adipose biology. Human-derived models, including mesenchymal stem cells (hMSCs) and preadipocyte cell lines, offer a closer approximation to in vivo adipogenesis but display significant variability in differentiation efficiency. This variability is often compounded by heterogeneous differentiation protocols, variations in cell confluence, and unstandardized pharmacological induction strategies. A pivotal factor influencing adipogenic potential is the receptor toolkit, which dictates cellular responses to differentiation stimuli. This study systematically evaluates key receptors—PPARγ, glucocorticoid receptors (GR), insulin receptor (IR), thyroid hormone receptors (TR), estrogen receptors (ER), and adenosine receptors (AR)—across commonly used adipocyte models to assess their roles in adipogenic regulation. Additionally, we examine the impact of pharmacological agents capable of inducing adipogenesis (adipogens) and the methodological inconsistencies that contribute to variations in adipocyte differentiation. By addressing these factors, we aim to elucidate the extent to which receptor variability influences experimental outcomes and propose a more structured approach to interpreting adipogenesis research. This critical assessment underscores the need for greater methodological transparency and receptor profiling to enhance the reliability of adipocyte models in metabolic research. Standardizing differentiation methodologies while accounting for receptor diversity will be essential for refining in vitro models and improving their translational potential in the study of obesity, diabetes, and other metabolic disorders. Full article

In this work, hydrogel nanocomposites, as films, were prepared by embedding cerium oxide nanoparticles (CeO₂NPs) within xanthan gum (Xn)/poly(vinylalcohol) (PVA) matrices. Their physicochemical properties were tuned by adjusting the ratio between components and thermal treatment conditions. The cross-linking of the polymer network was confirmed by attenuated total reflectance–Fourier transform infrared (ATR-FTIR), thermal analysis, and swelling behavior. Morphological features were evaluated by atomic force microscopy (AFM), scanning electron microscopy (SEM), while optical properties were investigated by UV–Vis spectroscopy. Undoped films displayed high transparency (~80% transmittance at 400 nm), with thermal cross-linking determined only slight yellowing and negligible changes in absorption edge (300 ± 2 nm). In contrast, CeO₂NPs incorporation increased reflectance and introduced a new absorption threshold around 400 ± 2 nm, indicating nanoparticle–matrix interactions that modify optical behavior. Sorption studies with Methylene Blue (MB) and Crystal Violet (CV) dyes highlighted the influence of nanoparticle content and cross-linking on functional performance, with thermally treated samples showing the highest efficiency (~97–98% MB and 71–83% CV removal). Overall, the results demonstrate how structural tailoring and cross-linking control the characteristics of Xn/PVA/CeO₂ nanocomposites, providing insight into their design as multifunctional hydrogel materials for environmental applications. Full article

The development of high-speed computers and electronic memories, high-frequency communication networks, electroluminescent and photovoltaic devices, flexible displays, and more requires new materials with unique properties, such as a low dielectric constant, an adjustable refractive index, high hardness, thermal resistance, and processability. SiOC coatings possess a number of desirable properties required by modern technologies, including good heat and UV resistance, transparency, high electrical insulation, flexibility, and solubility in commonly used organic solvents. Chemical vapor deposition (CVD) is a very useful and convenient method to produce this type of layer. In this article we present the results of studies on SiOC coatings obtained from tetramethylcyclotetrasiloxane in a remote hydrogen plasma CVD process. The elemental composition (XPS, EDS) and chemical structure (FTIR and NMR spectroscopy-¹³C, ²⁹Si) of the obtained coatings were investigated. Photoluminescence analyses and ellipsometric and thermogravimetric measurements were also performed. The surface morphology was characterized using AFM and SEM. The obtained results allowed us to propose a mechanism for the initiation and growth of the SiOC layer. Full article

Sectoral vulnerability to distinct crisis types in small, open, and geopolitically exposed markets—such as Jordan—remains insufficiently quantified, constraining targeted policy design and portfolio allocation. This study’s primary purpose is to establish a transparent, comparable metric of sector-level market resilience that reveals how crisis typology reorders vulnerabilities and shapes recovery speed. Applying this framework, we assess Jordan’s equity market across three archetypal episodes—the Global Financial Crisis, the Arab Spring, and COVID-19—to clarify how shock channels reconfigure sectoral risk. Using daily Amman Stock Exchange sector indices (2001–2025), we estimate $GARCH\left(\mathrm{1,1}\right)$ models for each sector–crisis window and summarize volatility dynamics by persistence $(\alpha +\beta )$, interpreted as an inverse proxy for resilience; complementary diagnostics include maximum drawdown and days-to-recovery, with nonparametric (Kruskal–Wallis) and rank-based (Spearman, Friedman) tests to evaluate within-crisis differences and cross-crisis reordering. Results show pronounced heterogeneity in every crisis and shifting sectoral rankings: financials—especially banking—display the highest persistence during the GFC; tourism and transportation dominate during COVID-19; and tourism/electric-related industries are most persistent around the Arab Spring. Meanwhile, food & beverages, pharmaceuticals/medical, and education recurrently exhibit lower persistence. Higher persistence aligns with slower post-shock normalization. We conclude that resilience is sector-specific and contingent on crisis characteristics, implying targeted policy and portfolio responses; regulators should prioritize liquidity backstops, timely disclosure, and contingency planning for fragile sectors, while investors can mitigate crisis risk via dynamic sector allocation and volatility-aware risk management in emerging markets. Full article

Hydrogels comprise three-dimensional networks of hydrophilic polymers and have attracted considerable interest in various sectors, including the biomedical, pharmaceutical, agricultural, and food industries. These materials offer significant benefits for food packaging applications, such as high mechanical strength and excellent water absorption capacity, thereby contributing to the extension of product shelf life. Therefore, the aim of this study is to compare the performance of citric acid and glutaraldehyde as crosslinking agents in gelatine-based hydrogels reinforced with cellulose nanocrystals (CNC), contributing to the development of safe and environmentally responsible materials. The hydrogels were prepared using the casting method and characterised in terms of their physical, mechanical, and structural properties. The results indicated that hydrogels crosslinked with glutaraldehyde exhibited higher opacity, lower transparency, and greater mechanical strength, whereas those crosslinked with citric acid demonstrated improved clarity, reduced water permeability, and enhanced swelling capacity. The incorporation of CNC further improved mechanical strength, reduced weight loss, and altered both surface homogeneity and optical properties. Microstructural results obtained by SEM were consistent with the mechanical properties evaluated (TS, %E, and EM). The Gel-ca hydrogel displayed the highest elongation value (98%), reflecting better cohesion within the polymeric matrix. In contrast, films incorporating CNC exhibited greater roughness and cracking, which correlated with increased rigidity and mechanical strength, as evidenced by the high Young’s modulus (420 MPa in Gel-ga-CNC2). These findings suggest that the heterogeneity and porosity induced by CNC limit the mobility of polymer chains, resulting in less flexible and more rigid structures. Additionally, the DSC analysis revealed that gelatine hydrogels did not exhibit a well-defined Tg, due to the predominance of crystalline domains. Systems crosslinked with citric acid showed greater thermal stability (higher Tm and ΔH_m values), while those crosslinked with glutaraldehyde, although mechanically stronger, exhibited lower thermal stability. These results confirm the decisive effect of the crosslinking agent and CNC incorporation on the structural and thermal behaviour of hydrogels. In this context, the application of hydrogels in packaged products represents an eco-friendly alternative that enhances product presentation. This research supports the reduction in plastic consumption whilst promoting the principles of a circular economy and facilitating the development of materials with lower environmental impact. Full article

Quantitative proteomics relies on robust statistical methods for differential expression, critically impacting downstream functional enrichment. This meta-analysis systematically investigated how statistical hypothesis testing approaches and criteria for defining biological relevance influence functional enrichment concordance. We reanalyzed five independent label-free quantitative proteomics datasets using diverse frequentist (t-test, Limma, DEqMS, MSstats) and Bayesian (rstanarm) approaches. Concordance of Gene Ontology (GO) and KEGG pathways was assessed using Jaccard indices and correlation metrics, grouping comparisons by statistical test and biological relevance consistency. The results demonstrated highly significant differences in similarity distributions among the comparison groups. Comparisons varying only hypothesis testing methods (with constant relevance criteria, FC or Bayesian) showed the highest consistency. Conversely, comparisons with differing biological relevance criteria (or varied methodological choices) yielded significantly lower consistency, highlighting this definition’s critical impact on GO term overlaps. KEGG pathways displayed more uniform, method-insensitive concordance. Sensitivity analysis confirmed the findings’ robustness, underscoring that methodological choices profoundly influence functional enrichment outcomes. This work emphasizes the critical need for transparency and careful consideration of analytical decisions in proteomics research to ensure reproducible and biologically sound interpretations. Full article

This study examines transparent concrete (TC) utilizing bibliometric analysis of articles from the Scopus database to identify its performance, knowledge gaps, limitations, and applications. TC is a new type of sustainable building material that combines optical fibers with concrete and is lighter in weight than traditional concrete. Incorporating optical fibers in concrete enables light transmission, thereby reducing the need for artificial lighting in TC structures. TC is also referred to as light-transmitting concrete due to its unique properties. By utilizing natural light resources instead of electric lighting, buildings can better harness sunlight, providing both architectural beauty and energy savings. This approach decreases reliance on non-renewable resources and ultimately conserves energy. Scholars have focused a lot of attention on the superb light transmission and decorative appeal of TC. However, its applications in the construction sector have yet to gain traction due to the time-consuming production process, high labor costs, and limited studies on its durability and mechanical properties. This article reviews the applications, production processes, types of TC, bibliometric analysis, cost analysis, and the research findings related to mechanical, thermal, energy-saving, light-transmitting, and durability properties. TC showed a substantial decrease in the building’s total energy use and maintained strength comparable to conventional concrete. It also displayed minimal water resistance, porosity, and density, making it suitable for constructing buildings and lightweight road surfaces. Additionally, it offers notable aesthetic value. The study identifies gaps in durability and standardization while highlighting significant developments in TC’s mechanical behavior, thermal and energy performance, and applications. Furthermore, it summarizes the future research paths for TC, which are likely to enhance its implementation as a promising sustainable construction material. Full article

This study investigates the financial and operational feasibility of deploying electric vehicle (EV) charging infrastructure within high-density residential buildings, utilizing empirical operational data combined with comprehensive financial modeling. A 14-day monitoring period conducted at a residential complex comprising 958 units revealed distinct charging behaviors, with demand peaking during weekday evenings between 19:00 and 22:00 and displaying more dispersed yet lower overall utilization during weekends. Energy efficiency emerged as a significant operational constraint, as standby power consumption contributed substantially to total energy losses. Specifically, while total energy consumption reached 248.342 kW, only 138.24 kW were directly delivered to users, underscoring the necessity for energy-efficient hardware and intelligent load management systems to minimize idle consumption. The financial analysis identified pricing as the most critical determinant of project viability. Under current cost structures, financial break-even was attainable only at a profit margin of 0.2286 USD (8 THB) per kWh, while lower margins resulted in persistent financial deficits. Sensitivity analysis further demonstrated the considerable vulnerability of the project’s financial performance to small fluctuations in profit share and utilization rate. A 10% reduction in either parameter entirely eliminated the project’s ability to reach payback, while variations in energy costs, capital expenditures (CAPEX), and operational expenditures (OPEX) exerted comparatively limited influence. These findings emphasize the importance of precise demand forecasting, adaptive pricing strategies, and proactive government intervention to mitigate financial risks associated with residential EV charging deployment. Policy measures such as capital subsidies, technical regulations, and transparent pricing frameworks are essential to incentivize private sector investment and support sustainable expansion of EV infrastructure in residential sectors. Full article