Next Article in Journal
Preparation and Characterization of Novel Gellan Gum Hydrogels Suitable for Modified Drug Release
Next Article in Special Issue
Mouse Models Targeting Selenocysteine tRNA Expression for Elucidating the Role of Selenoproteins in Health and Development
Previous Article in Journal
A New 4α-Methylated Sterol from a Nephthea sp. (Nephtheidae) Bornean Soft Coral
Previous Article in Special Issue
Synthesis and Pharmacological Screening of Several Aroyl and Heteroaroyl Selenylacetic Acid Derivatives as Cytotoxic and Antiproliferative Agents
Article Menu

Article Versions

Export Article

Open AccessCommunication
Molecules 2009, 14(9), 3367-3375; doi:10.3390/molecules14093367

Cesium Carbonate-Catalyzed α-Phenylchalcogenation of Carbonyl Compounds with Diphenyl Dichalcogenide

Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan
*
Author to whom correspondence should be addressed.
Received: 31 July 2009 / Revised: 26 August 2009 / Accepted: 2 September 2009 / Published: 2 September 2009
(This article belongs to the Special Issue Selenium and Tellurium Chemistry)
Download PDF [247 KB, uploaded 18 June 2014]   |  

Abstract

It was found that cesium carbonate has a unique catalytic ability on the reaction of carbonyl compounds with diphenyl diselenide to give the corresponding α-phenylseleno carbonyl compounds in moderate to good yields. Similarly, the α-phenylthiolation of carbonyl compounds with diphenyl disulfide was promoted by the cesium carbonate catalyst.
Keywords: cesium carbonate; α-phenylchalcogenation; carbonyl compounds; diphenyl dichalcogenide cesium carbonate; α-phenylchalcogenation; carbonyl compounds; diphenyl dichalcogenide
Figures

This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Nishiyama, Y.; Koguma, Y.; Tanaka, T.; Umeda, R. Cesium Carbonate-Catalyzed α-Phenylchalcogenation of Carbonyl Compounds with Diphenyl Dichalcogenide. Molecules 2009, 14, 3367-3375.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top