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Molecules, Volume 5, Issue 9 (September 2000), Pages 1055-1079

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Research

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Open AccessArticle Synthesis and Fungicidal Activity of 2-Imino-3-(4-arylthiazol-2-yl)-thiazolidin-4-ones and Their 5-Arylidene Derivatives
Molecules 2000, 5(9), 1055-1061; doi:10.3390/50901055
Received: 15 August 2000 / Accepted: 29 August 2000 / Published: 5 September 2000
Cited by 57 | PDF Full-text (32 KB)
Abstract Five derivatives of 2-imino-3-(4-arylthiazol-2-yl)-thiazolidin-4-ones and a series of their 5-arylidene derivatives have been synthesized and tested for antifungal activity against seven agricultural fungi. 2-Imino-3-(2,4-dichloro-5-fluorophenylthiazol-2-yl)-4-thiazolidi-none and 2-imino-3-(2,4-dichlorophenylthiazol-2-yl)-4-thiazolidione, both of them new compounds, exhibited higher fungicidal effects than the other compounds prepared. Full article
Open AccessArticle Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction
Molecules 2000, 5(9), 1062-1067; doi:10.3390/50901062
Received: 14 August 2000 / Accepted: 6 September 2000 / Published: 9 September 2000
Cited by 6 | PDF Full-text (35 KB)
Abstract An improved synthesis of bicyclo[2.2.1]hept-5-ene-2,3-dione by Swern oxidation of bicyclo[2.2.1]hept-5-ene-2,3-diol, and an unexpected ring-opening reaction by the Swern oxidation of pyrazine-fused congeners are described. Full article

Review

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Open AccessReview Recent Advances in the Substitution Reactions of Triorganylstannyl Ions with Aromatic Compounds by the SRN1 Mechanism. Synthetic Applications
Molecules 2000, 5(9), 1068-1079; doi:10.3390/50901068
Received: 30 May 2000 / Revised: 18 August 2000 / Accepted: 5 September 2000 / Published: 11 September 2000
Cited by 2 | PDF Full-text (65 KB)
Abstract
A review on the reactions of triorganyl stannyl ions with haloarenes is presented. Emphasis on the synthetic applications of the resulting triorganyl stannyl aryl compounds is made, with their inherent potential to build large molecules through the SRN1 sequence, i.e. ArX→ArSnR
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A review on the reactions of triorganyl stannyl ions with haloarenes is presented. Emphasis on the synthetic applications of the resulting triorganyl stannyl aryl compounds is made, with their inherent potential to build large molecules through the SRN1 sequence, i.e. ArX→ArSnR3→ArAr, which can be iteratively repeated when appropriately substituted substrates are chosen. Full article

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