Ionic Conductivity of the Li6PS5Cl0.5Br0.5 Argyrodite Electrolyte at Different Operating and Pelletizing Pressures and Temperatures
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Effect of Pelletizing Pressure on Electrolyte Pellet Thickness
3.2. Effect of Pelletizing and Operating Pressure on Ionic Conductivity
3.3. Effect of Operating Temperature on Ionic Conductivity
3.4. Effect of Pelletizing Temperature on Ionic Conductivity
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Conductivity | Pelletizing Pressure | Operating Pressure | Reference | Notes |
---|---|---|---|---|
(mS/cm) | (MPa) | (MPa) | ||
0.22–3.02 | 50–370 | 5–70 | Doux [15] | Li6PS5Cl |
4.96 | 1000 | - | Yu [21] | Li6PS5Cl |
1.33 | 333 | - | Boulineau [22] | Li6PS5Cl |
1.40 | 360 | - | Yubuchi [23] | Li6PS5Cl |
3.15 | 150 | - | Wang [24] | Li6PS5Cl |
1.10 | 750 | - | Sakuda [25] | Li6PS5Cl |
1.60 | 330 | - | Hwang [26] | Li6PS5Cl |
1.40 | 140 | - | Choi [27] | Li6PS5Cl |
1.29 | 350 | - | Zhang [28] | Li6PS5Cl |
1.79 | 380 | 50 | Ohno [29] | Li6PS5Cl |
1.53 | 375 | - | Ohno [29] | Li6PS5Cl |
2.6 | 370 | 75 | Ohno [29] | Li6PS5Cl |
1.9 | 720 | 0 | Ohno [29] | Li6PS5Cl |
2.14 | 325 | 0 | Ohno [29] | Li6PS5Cl, isostatic pelletizing |
0.443 | 275 | - | Ohno [29] | Li6PS5Cl |
2.98 | 441 | 315 | Ohno [29] | Li6PS5Cl |
0.79 | - | - | Wang [12] | Li6PS5Cl |
0.63 | 1000 | 10 | Ohno [29] | Li6PS5Cl |
1.00 | 300 | - | Zhang [30] | Li6PS5Cl without modified synthesizing process |
1.80 | 300 | - | Zhang [30] | Li6PS5Cl with modified synthesizing process |
0.50 | 300 | - | Zhang [30] | Li6PS5Br without modified synthesizing process |
1.30 | 300 | - | Zhang [30] | Li6PS5Br with modified synthesizing process |
0.36 | - | - | Wang [12] | Li6PS5Br |
0.30–2.45 | 100–500 | 5–500 | Cronau [31] | Li6PS5Br, with and without annealing at 550 °C (similar results reported whether using high operating pressure with no annealing or low operating pressure with annealing) |
3.63 | - | - | Wang [12] | Li6PS5Cl0.5Br0.5 |
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Dunham, J.; Carfang, J.; Yu, C.-Y.; Ghahremani, R.; Farahati, R.; Farhad, S. Ionic Conductivity of the Li6PS5Cl0.5Br0.5 Argyrodite Electrolyte at Different Operating and Pelletizing Pressures and Temperatures. Energies 2023, 16, 5100. https://doi.org/10.3390/en16135100
Dunham J, Carfang J, Yu C-Y, Ghahremani R, Farahati R, Farhad S. Ionic Conductivity of the Li6PS5Cl0.5Br0.5 Argyrodite Electrolyte at Different Operating and Pelletizing Pressures and Temperatures. Energies. 2023; 16(13):5100. https://doi.org/10.3390/en16135100
Chicago/Turabian StyleDunham, Joshua, Joshua Carfang, Chan-Yeop Yu, Raziyeh Ghahremani, Rashid Farahati, and Siamak Farhad. 2023. "Ionic Conductivity of the Li6PS5Cl0.5Br0.5 Argyrodite Electrolyte at Different Operating and Pelletizing Pressures and Temperatures" Energies 16, no. 13: 5100. https://doi.org/10.3390/en16135100