Modeling of Proton-Conducting Solid Oxide Fuel Cells Fueled with Syngas
Abstract
:1. Introduction
2. Model Development
- (1)
- The model is 2D, neglecting the 3D effect;
- (2)
- Heat radiation is assumed to be negligible;
- (3)
- The flow in the gas channels is laminar due to low velocity and small dimension;
- (4)
- Electrochemical reactions are assumed to take place at the electrode-electrolyte interface only.
2.1. Electrochemical Model
2.2. Chemical Model
2.3. Computational Fluid Dynamic (CFD) Model
CO | CO2 | H2 | O2 | N2 | H2O | |
---|---|---|---|---|---|---|
σi (A) | 3.69 | 3.941 | 2.827 | 3.467 | 3.798 | 2.641 |
εi/k (K2·J−1) | 91.7 | 195.2 | 59.7 | 106.7 | 71.4 | 809.1 |
3. Numerical Methodologies
4. Results and Analysis
Parameter | Value |
---|---|
Operating temperature, T (K) | 1073 |
Operating pressure, P (bar) | 1.0 |
Electrode porosity, ε | 0.4 |
Electrode tortuosity, ξ | 3.0 |
Average pore radius, rp (μm) | 0.5 |
Anode-supported electrolyte: | - |
Anode thickness da (μm) | 500 |
Electrolyte thickness, L (μm) | 100 |
Cathode thickness, dc (μm) | 100 |
Height of gas flow channel (mm) | 1.0 |
Length of the planar SOFC (mm) | 40 |
Thickness of interconnector (mm) | 0.5 |
Inlet velocity at anode: U0 (m·s−1) | 1.0 |
Cathode inlet gas molar ratio: O2/N2/ | 0.18/0.79/0.03 |
Anode inlet gas molar ratio: H2/CO (Syngas) | 3/1 |
SOFC operating potential (V) | 0.7 |
Thermal conductivity of SOFC component (W·m−1·K−1) | - |
Anode | 11.0 |
Electrolyte | 2.7 |
Cathode | 6.0 |
Interconnect | 1.1 |
4.1. Effect of Syngas Composition
4.2. Effect of Operating Temperature
4.3. Effect of Steam Addition
5. Conclusions
Acknowledgments
Author Contributions
Nomenclature
Bg | Permeability of the porous electrode (m2) |
cp | Heat capactity (J·kg−1·K−1) |
da | Thickness of anode (µm) |
dc | Thickness of cathode (µm) |
Effective diffusion coefficient of species i in gas mixture (cm2·s−1) | |
Di,k | Knudsen diffusion coefficient of i (cm2·s−1) |
Di,j | Binary diffusion coefficient of i and j (cm2·s−1) |
E | Equilibrium potential (V) |
E0 | Reversible potential at standard condition (V) |
F | Faraday constant (9.6485 × 104 C·mol−1) |
HWGS | Heat generation from water gas shift reaction (J·mol−1) |
J | Current density (A·m−2) |
k | Thermal conductivity (W·m−1·K−1) |
L | Thickness of the electrolyte (m) |
Mi | Molecular weight of species i (kg·mol-1) |
n | Number of electrons transferred |
P | Operating pressure (bar) |
Partial pressure (bar) of species i at electrode-electrolyte interface | |
RWGSR | Rate of water gas shift reaction (mol·m−3·s−1) |
rp | Mean pore radius of electrode (µm) |
R | Universal gas constant (8.3145 J·mol−1·K−1) |
∆S | Entropy change of electrochitalicical reactions (kJ·kg−1·K−1) |
Sm | Source term in continuity equation (kg·m−3·s−1) |
Sx, Sy | Source terms in momentum equations (kg·m−2·s−2) |
ST | Source terms in energy equations (W·m−3) |
Ssp | Source terms in species equations (kg·m−3·s−1) |
T | Operating titalicperature (K) |
U | Velocity in x direction (m·s−1) |
U0 | Gas velocity at the SOFC inlet (m·s−1) |
V | SOFC operating potential (V); Velocity in y direction (m·s−1) |
X | Molar fraction of species i |
Y | Mass fraction of species i |
ε | Electrode porosity |
ξ | Electrode tortuosity |
σi,j | Mean characteristic length of species i and j (Å) |
σionic | Ionic conductivity of the electrolyte (Ω−1·m−1) |
ΩD | Dimensionless diffusion collision integral |
ρ | Density of the gas mixture (kg·m−3) |
µ | Viscosity of gas mixture (kg·m−1·s−1) |
ηact,a | Activation overpotential at anode (V) |
ηact,c | Activation overpotential at cathode (V) |
ηohmic | Ohmic overpotential of the electrolyte (V) |
Conflicts of Interest
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Ni, M.; Shao, Z.; Chan, K.Y. Modeling of Proton-Conducting Solid Oxide Fuel Cells Fueled with Syngas. Energies 2014, 7, 4381-4396. https://doi.org/10.3390/en7074381
Ni M, Shao Z, Chan KY. Modeling of Proton-Conducting Solid Oxide Fuel Cells Fueled with Syngas. Energies. 2014; 7(7):4381-4396. https://doi.org/10.3390/en7074381
Chicago/Turabian StyleNi, Meng, Zongping Shao, and Kwong Yu Chan. 2014. "Modeling of Proton-Conducting Solid Oxide Fuel Cells Fueled with Syngas" Energies 7, no. 7: 4381-4396. https://doi.org/10.3390/en7074381