Tourmalines as a Tool in Provenance Studies of Terrigenous Material in Extra-Carpathian Albian (Uppermost Lower Cretaceous) Sands of Miechów Synclinorium, Southern Poland
Abstract
:1. Introduction
2. Regional Geological Setting
3. Materials and Methods
4. Results
5. Discussion
6. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Locality | Lelów (LEL) | Przychody (PRZ) | Chełmo Mount Lower Part (GCHD) | Chełmo Mount Upper Part (GCHG) | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Sample | LEx14 | LEx20 | LEx47 | LEx64 | PRx1 | PRx10 | PRx24 | PRx29 | GCDx11 | GCDx29 | GCDx36 | GCDx55 | GCGx5 | GCGx25 | GCGx26 | GCGx55 |
SiO2 | 36.39 | 36.35 | 35.39 | 37.08 | 36.34 | 37.14 | 35.99 | 37.51 | 35.25 | 34.55 | 37.28 | 37.12 | 35.77 | 36.45 | 36.73 | 36.53 |
TiO2 | 0.95 | 0.15 | 0.28 | 0.51 | 0.13 | 0.41 | 0.95 | 0.71 | 1.32 | 0.82 | 0.97 | 0.64 | 0.97 | 0.27 | 0.7 | 0.74 |
B2O3* | 10.74 | 10.65 | 10.3 | 10.64 | 10.59 | 10.71 | 10.69 | 10.81 | 10.45 | 11.42 | 10.78 | 10.81 | 10.64 | 10.5 | 10.92 | 10.63 |
Al2O3 | 32.03 | 35.69 | 32.74 | 31.42 | 35.27 | 31.99 | 34.13 | 31.7 | 29.15 | 33.12 | 32 | 33.88 | 34.41 | 31.14 | 35.66 | 31.77 |
V2O3 | 0.11 | 0 | 0 | 0 | 0.03 | 0.07 | 0 | 0.07 | 0.07 | 0.13 | 0 | 0.15 | 0.11 | 0.04 | 0.03 | 0.03 |
Cr2O3 | 0.09 | 0 | 0 | 0 | 0 | 0 | 0.04 | 0.05 | 0 | 0.04 | 0 | 0.12 | 0.05 | 0.06 | 0.04 | 0.05 |
FeO | 3.93 | 10.43 | 12.86 | 5.99 | 10.75 | 5.33 | 6.84 | 4.66 | 8.75 | 11.1 | 4.94 | 4.18 | 8.24 | 10.82 | 2.5 | 6.09 |
MgO | 9.04 | 2.5 | 1.81 | 7.82 | 2.25 | 8.19 | 5.7 | 8.81 | 7.75 | 3.91 | 8.25 | 7.37 | 4.5 | 5.49 | 7.82 | 7.62 |
MnO | 0 | 0.12 | 0.12 | 0 | 0.14 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0.15 |
CaO | 1.7 | 0.06 | 0.07 | 0.2 | 0.04 | 0 | 0.71 | 0.59 | 2.88 | 0.99 | 0.65 | 0.35 | 0.67 | 0.06 | 0.63 | 0.84 |
Na2O | 1.73 | 1.37 | 2.46 | 2.7 | 1.42 | 2.78 | 1.93 | 2.52 | 1.23 | 1.6 | 2.33 | 2.19 | 1.67 | 2.3 | 1.87 | 2.02 |
K2O | 0.3 | 0.03 | 0.03 | 0 | 0.03 | 0.04 | 0.06 | 0.03 | 0.06 | 0.06 | 0.05 | 0 | 0.04 | 0 | 0.04 | 0 |
F | 0 | 0 | 0.15 | 0.53 | 0 | 0.33 | 0 | 0.3 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0.39 |
H2O * | 3.71 | 3.67 | 3.48 | 3.42 | 3.65 | 3.54 | 3.69 | 3.59 | 3.6 | 3.59 | 3.69 | 3.73 | 3.67 | 3.62 | 3.74 | 3.48 |
O = F | 0 | 0 | 0.06 | 0.22 | 0 | 0.14 | 0 | 0.13 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0.17 |
Total | 100.72 | 101.02 | 99.69 | 100.31 | 100.64 | 100.53 | 100.73 | 101.35 | 100.51 | 101.33 | 100.94 | 100.54 | 100.74 | 100.75 | 100.68 | 100.34 |
T-site | ||||||||||||||||
Si4+ | 5.888 | 5.932 | 5.975 | 6.056 | 5.966 | 6.028 | 5.852 | 6.028 | 5.863 | 5.763 | 6.009 | 5.967 | 5.841 | 6.033 | 5.845 | 5.971 |
Al3+ | 0.112 | 0.068 | 0.025 | 0 | 0.034 | 0 | 0.148 | 0 | 0.137 | 0.237 | 0 | 0.033 | 0.159 | 0 | 0.155 | 0.029 |
Y-, Z-site | ||||||||||||||||
Al3+ | 5.996 | 6.796 | 6.489 | 6.048 | 6.79 | 6.12 | 6.394 | 6.004 | 5.578 | 6.276 | 6.078 | 6.385 | 6.462 | 6.074 | 6.533 | 6.090 |
Ti4+ | 0.115 | 0.019 | 0.036 | 0.063 | 0.016 | 0.049 | 0.116 | 0.086 | 0.165 | 0.102 | 0.117 | 0.078 | 0.119 | 0.033 | 0.084 | 0.091 |
Cr3+ | 0.011 | 0 | 0 | 0 | 0 | 0 | 0.005 | 0.006 | 0 | 0.005 | 0 | 0.015 | 0.006 | 0.008 | 0.005 | 0.006 |
V3+ | 0.015 | 0 | 0 | 0 | 0.003 | 0.009 | 0 | 0.01 | 0.01 | 0.017 | 0 | 0.020 | 0.015 | 0.005 | 0.003 | 0.004 |
Fe2+ | 0.531 | 1.423 | 1.815 | 0.818 | 1.476 | 0.723 | 0.93 | 0.627 | 1.217 | 1.549 | 0.665 | 0.562 | 1.125 | 1.498 | 0.332 | 0.832 |
Mn2+ | 0 | 0.017 | 0.017 | 0 | 0.019 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0.020 |
Mg2+ | 2.181 | 0.609 | 0.455 | 1.904 | 0.550 | 1.981 | 1.381 | 2.112 | 1.921 | 0.972 | 1.981 | 1.766 | 1.095 | 1.355 | 1.855 | 1.858 |
Subtotal | 8.849 | 8.864 | 8.812 | 8.833 | 8.854 | 8.882 | 8.826 | 8.845 | 8.891 | 8.921 | 8.841 | 8.826 | 8.822 | 8.973 | 8.812 | 8.901 |
X-site | ||||||||||||||||
Ca2+ | 0.295 | 0.010 | 0.012 | 0.035 | 0.008 | 0 | 0.124 | 0.101 | 0.513 | 0.176 | 0.111 | 0.060 | 0.117 | 0.011 | 0.108 | 0.147 |
Na+ | 0.544 | 0.433 | 0.805 | 0.855 | 0.452 | 0.874 | 0.608 | 0.785 | 0.396 | 0.517 | 0.729 | 0.683 | 0.529 | 0.737 | 0.577 | 0.641 |
K+ | 0.006 | 0.006 | 0.007 | 0 | 0.006 | 0.009 | 0.011 | 0.006 | 0.012 | 0.013 | 0.009 | 0 | 0.009 | 0 | 0.007 | 0 |
vacancy | 0.155 | 0.55 | 0.176 | 0.110 | 0.535 | 0.117 | 0.257 | 0.108 | 0.079 | 0.294 | 0.151 | 0.257 | 0.345 | 0.252 | 0.308 | 0.212 |
OH− | 4 | 4 | 3.923 | 3.727 | 4 | 3.830 | 4 | 3.845 | 4 | 4 | 4 | 4 | 4 | 4 | 4 | 3.797 |
F- | 0 | 0 | 0.077 | 0.273 | 0 | 0.170 | 0 | 0.155 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0.203 |
SiO2 | 37.23 | 36.84 | 35.58 | 34.81 | 35.16 | 36.0 | 36.48 | 37.27 | 34.32 | 35.54 | 36.32 | 36.15 | 36.02 | 38.1 | 36.68 | 37.89 |
TiO2 | 0.66 | 0.66 | 0.62 | 0.79 | 0.39 | 0.28 | 0.65 | 0.35 | 0.7 | 0.87 | 0.77 | 0.76 | 0.51 | 0.13 | 1.21 | 0.03 |
B2O3 * | 10.83 | 10.65 | 10.46 | 10.5 | 10.49 | 10.59 | 10.83 | 10.74 | 10.08 | 10.71 | 10.7 | 10.68 | 10.62 | 10.93 | 10.62 | 10.96 |
Al2O3 | 33.14 | 32.33 | 33.19 | 26.07 | 34.36 | 34.47 | 34.82 | 32.1 | 30.01 | 34.85 | 34.11 | 34.07 | 34.52 | 32.43 | 30.76 | 36.07 |
V2O3 | 0 | 0 | 0 | 9.4 | 0 | 0.03 | 0 | 0.06 | 0 | 0.14 | 0.03 | 0.08 | 0 | 0 | 0 | 0 |
Cr2O3 | 0.05 | 0.08 | 0 | 3.67 | 0 | 0 | 0.06 | 0.06 | 0 | 0.04 | 0.09 | 0.08 | 0 | 0 | 0.06 | 0 |
FeO | 5.61 | 7.43 | 11.77 | 0.27 | 9.74 | 9.54 | 3.62 | 4.56 | 16.07 | 5.53 | 6.46 | 6.65 | 10 | 1.61 | 6.28 | 5.78 |
MgO | 7.58 | 6.26 | 3.02 | 8.11 | 3.85 | 3.85 | 7.39 | 8.6 | 1.91 | 6.2 | 5.9 | 5.88 | 3.63 | 10.63 | 7.8 | 5.63 |
MnO | 0 | 0 | 0.13 | 0 | 0 | 0.15 | 0 | 0 | 0 | 0.11 | 0.13 | 0 | 0 | 0 | 0 | 0 |
CaO | 0.21 | 0.29 | 0.23 | 1.3 | 0.28 | 0.24 | 1.18 | 0.11 | 0.76 | 0.92 | 0.35 | 0.34 | 0.15 | 0.23 | 0.66 | 0.11 |
Na2O | 2.34 | 2.36 | 2.03 | 1.75 | 1.97 | 1.82 | 1.59 | 2.73 | 2.16 | 1.68 | 1.89 | 1.95 | 1.87 | 2.94 | 2.5 | 1.493 |
K2O | 0.02 | 0 | 0.03 | 0.1 | 0.05 | 0.04 | 0.06 | 0.04 | 0.09 | 0.07 | 0.04 | 0.04 | 0.04 | 0.02 | 0.04 | 0.02 |
F | 0 | 0 | 0.33 | 0.1 | 0 | 0.12 | 0.12 | 0.83 | 0.45 | 0 | 0.32 | 0.35 | 0 | 1.41 | 0 | 0 |
H2O * | 3.72 | 3.68 | 3.45 | 3.57 | 3.62 | 3.59 | 3.68 | 3.31 | 3.26 | 3.69 | 3.54 | 3.52 | 3.66 | 3.11 | 3.66 | 3.78 |
O = F | 0 | 0 | 0.14 | 0.04 | 0 | 0.05 | 0.05 | 0.35 | 0.19 | 0 | 0.13 | 0.15 | 0 | 0.59 | 0 | 0 |
Total | 101.39 | 100.58 | 100.84 | 100.44 | 99.91 | 100.72 | 100.48 | 100.76 | 99.81 | 100.35 | 100.65 | 100.55 | 101.02 | 101.54 | 100.27 | 101.76 |
T-site | ||||||||||||||||
Si4+ | 5.977 | 6.010 | 5.911 | 5.761 | 5.827 | 5.910 | 5.855 | 6.032 | 5.920 | 5.770 | 5.901 | 5.884 | 5.897 | 6.058 | 6.004 | 6.007 |
Al3+ | 0.023 | 0 | 0.089 | 0.239 | 0.173 | 0.090 | 0.145 | 0 | 0.080 | 0.230 | 0.099 | 0.116 | 0.103 | 0 | 0 | 0 |
Y-, Z-site | ||||||||||||||||
Al3+ | 6.248 | 6.217 | 6.411 | 4.845 | 6.538 | 6.578 | 6.441 | 6.122 | 6.021 | 6.437 | 6.432 | 6.420 | 6.558 | 6.077 | 5.934 | 6.740 |
Ti4+ | 0.08 | 0.084 | 0.078 | 0.099 | 0.049 | 0.032 | 0.079 | 0.043 | 0.091 | 0.106 | 0.094 | 0.093 | 0.062 | 0.015 | 0.148 | 0.003 |
Cr3+ | 0.006 | 0.010 | 0 | 0.480 | 0 | 0 | 0.008 | 0.008 | 0 | 0.004 | 0.011 | 0.01 | 0 | 0 | 0.007 | 0 |
V3+ | 0 | 0 | 0 | 1.248 | 0 | 0.004 | 0 | 0.008 | 0 | 0.018 | 0.004 | 0.01 | 0 | 0 | 0 | 0 |
Fe2+ | 0.753 | 1.014 | 1.635 | 0.037 | 1.350 | 1.310 | 0.486 | 0.617 | 2.318 | 0.750 | 0.878 | 0.905 | 1.369 | 0.214 | 0.860 | 0.767 |
Mn2+ | 0 | 0 | 0.018 | 0 | 0 | 0.021 | 0 | 0 | 0 | 0.015 | 0.018 | 0 | 0 | 0 | 0 | 0 |
Mg2+ | 1.815 | 1.523 | 0.749 | 2.001 | 0.951 | 0.941 | 1.767 | 2.075 | 0.491 | 1.50 | 1.429 | 1.426 | 0.887 | 2.519 | 1.903 | 1.330 |
Subtotal | 8.902 | 8.848 | 8.891 | 8.710 | 8.888 | 8.886 | 8.781 | 8.873 | 8.921 | 8.83 | 8.866 | 8.864 | 8.876 | 8.825 | 8.852 | 8.840 |
X-site | ||||||||||||||||
Ca2+ | 0.036 | 0.051 | 0.041 | 0.231 | 0.049 | 0.041 | 0.202 | 0.020 | 0.140 | 0.161 | 0.061 | 0.060 | 0.025 | 0.039 | 0.115 | 0.019 |
Na+ | 0.728 | 0.748 | 0.655 | 0.560 | 0.634 | 0.579 | 0.496 | 0.856 | 0.721 | 0.530 | 0.596 | 0.614 | 0.592 | 0.905 | 0.794 | 0.459 |
K+ | 0.005 | 0.002 | 0.006 | 0.020 | 0.010 | 0.009 | 0.012 | 0.008 | 0.019 | 0.015 | 0.008 | 0.008 | 0.009 | 0.005 | 0.008 | 0.004 |
Vacancy | 0.231 | 0.199 | 0.298 | 0.188 | 0.308 | 0.371 | 0.290 | 0.116 | 0.121 | 0.294 | 0.335 | 0.318 | 0.374 | 0.051 | 0.083 | 0.519 |
OH− | 4 | 4 | 3.829 | 3.946 | 4 | 3.937 | 3.938 | 3.576 | 3.753 | 4 | 3.837 | 3.822 | 4 | 3.294 | 4 | 4 |
F− | 0 | 0 | 0.171 | 0.054 | 0 | 0.063 | 0.062 | 0.424 | 0.247 | 0 | 0.163 | 0.178 | 0 | 0.706 | 0 | 0 |
Locality | Zone I | Zone II | Zone III | Zone IV | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Point | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 |
SiO2 | 36.69 | 36.40 | 36.44 | 36.26 | 36.64 | 37.91 | 37.05 | 36.97 | 36.94 | 36.39 | 37.19 | 37.19 | 37.20 | 36.63 |
TiO2 | 1.12 | 0.93 | 1.35 | 0.58 | 1.032 | 0.31 | 0.61 | 0.64 | 0.66 | 0.74 | 0.76 | 0.72 | 0.65 | 0.69 |
B2O3 * | 10.71 | 10.68 | 10.67 | 10.76 | 10.67 | 10.74 | 10.68 | 10.83 | 10.75 | 10.73 | 10.79 | 10.85 | 10.93 | 10.7 |
Al2O3 | 32.35 | 33.01 | 31.67 | 32.73 | 32.28 | 31.98 | 32..13 | 32.80 | 32..51 | 32..42 | 31.98 | 32..51 | 32..40 | 32..19 |
Cr2O3 | 0.09 | 0.10 | 0.14 | 0 | 0.08 | 0 | 0 | 0.05 | 0 | 0.08 | 0 | 0 | 0.04 | 0 |
FeO | 6.55 | 7.39 | 6.77 | 5.05 | 6.73 | 7.51 | 6.93 | 4.81 | 4.29 | 4.74 | 5.23 | 4.69 | 4.65 | 4.46 |
MgO | 6.98 | 6.23 | 7.18 | 8.80 | 6.76 | 6.61 | 6.98 | 8.46 | 8.36 | 8.50 | 8.38 | 8.64 | 8.75 | 8.57 |
MnO | 0 | 0 | 0.16 | 0 | 0 | 0.07 | 0.06 | 0 | 0.04 | 0 | 0 | 0.01 | 0 | 0 |
CaO | 0.57 | 0.45 | 0.78 | 1.19 | 0.55 | 0.17 | 0.32 | 1.21 | 1.16 | 1.37 | 1.37 | 0.89 | 0.75 | 0.99 |
Na2O | 2.15 | 2.01 | 2.13 | 1.86 | 2.18 | 2.28 | 2.24 | 1.81 | 1.95 | 1.86 | 1.75 | 2.26 | 2.33 | 2.11 |
K2O | 0.05 | 0.04 | 0 | 0 | 0.03 | 0 | 0.05 | 0 | 0.05 | 0 | 0 | 0 | 0.04 | 0.04 |
F | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0.19 | 0 | 0.17 | 0 |
H2O * | 3.7 | 3.69 | 3.68 | 3.71 | 3.68 | 3.71 | 3.69 | 3.74 | 3.71 | 3.7 | 3.63 | 3.74 | 3.66 | 3.69 |
O = F | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0.08 | 0 | 0.07 | 0 |
Total | 100.96 | 100.93 | 100,97 | 100.94 | 100.63 | 101.29 | 100.74 | 101.32 | 100.42 | 100.53 | 101.35 | 101.5 | 101.64 | 100.07 |
T-site | ||||||||||||||
Si4+ | 5.954 | 5.922 | 5.933 | 5.857 | 5.966 | 6.135 | 6.027 | 5.934 | 5.970 | 5.896 | 5.991 | 5.958 | 5.968 | 5.948 |
Al3+ | 0.046 | 0.078 | 0.067 | 0.143 | 0.034 | 0 | 0 | 0.066 | 0.030 | 0.104 | 0.009 | 0.042 | 0.032 | 0.052 |
Y-, Z-site | ||||||||||||||
Al3+ | 6.142 | 6.251 | 6.010 | 6.087 | 6.162 | 6.099 | 6.161 | 6.141 | 6.163 | 6.086 | 6.063 | 6.094 | 6.094 | 6.110 |
Ti4+ | 0.137 | 0.114 | 0.166 | 0.071 | 0.126 | 0.037 | 0.074 | 0.078 | 0.081 | 0.091 | 0.092 | 0.0887 | 0.079 | 0.084 |
Cr3+ | 0.011 | 0.013 | 0.018 | 0 | 0.011 | 0 | 0 | 0.006 | 0 | 0.010 | 0 | 0 | 0.006 | 0 |
Fe2+ | 0.889 | 1.005 | 0.922 | 0.683 | 0.917 | 1.016 | 0.943 | 0.645 | 0.580 | 0.643 | 0.704 | 0.628 | 0.624 | 0.606 |
Mn2+ | 0 | 0 | 0.004 | 0.001 | 0.004 | 0.002 | 0 | 0.001 | 0.002 | 0 | 0 | 0.010 | 0 | 0.004 |
Mg2+ | 1.688 | 1.512 | 1.743 | 2.119 | 1.641 | 1.593 | 1.692 | 2.024 | 2.013 | 2.054 | 2.012 | 2.064 | 2.091 | 2.075 |
Subtotal | 8.867 | 8.895 | 8.863 | 8.961 | 8.861 | 8.747 | 8.870 | 8.895 | 8.839 | 8.884 | 8.871 | 8.8847 | 8.894 | 8.879 |
X-site | ||||||||||||||
Ca2+ | 0.100 | 0.078 | 0.135 | 0.205 | 0.095 | 0.029 | 0.056 | 0.207 | 0.201 | 0.238 | 0.236 | 0.153 | 0.129 | 0.172 |
Na+ | 0.677 | 0.632 | 0.672 | 0.583 | 0.688 | 0.715 | 0.706 | 0.563 | 0.61 | 0.585 | 0.547 | 0.701 | 0.723 | 0.664 |
K+ | 0.011 | 0.008 | 0 | 0 | 0.007 | 0 | 0.010 | 0 | 0.010 | 0 | 0 | 0 | 0.008 | 0.008 |
vacancy | 0.212 | 0.281 | 0.193 | 0.212 | 0.210 | 0.256 | 0.228 | 0.230 | 0.180 | 0.177 | 0.217 | 0.146 | 0.141 | 0.156 |
OH− | 4 | 4 | 4 | 4 | 4 | 4 | 4 | 4 | 4 | 4 | 3.902 | 4 | 3.914 | 4 |
F- | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0.098 | 0 | 0.086 | 0 |
Locality | Poland | Bohemian Massif | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
This Paper | Carpathian Exotics [124] | Jegłowa Schists [35] | Gneisses, Góry Sowie [35] | Wołowa Góra [35] | Pegmatite, Tatry Mnt. [35] | Granite, Tatry Mnt. [125] | Dolomitic Marble [60] | Pegmatites, Moldanubicum [126] | Tourmalinite, Svratka Unit [34] | Schists, Svratka Unit [34] | Gneisses, Velke Vrbno [57] | |
Number of Analysis | (512) | (1) | (1) | (1) | (1) | (1) | (8) | (6) | (10) | (23) | (4) | (6) |
SiO2 | 36.46 | 35.64 | 35.61 | 36.21 | 36.5 | 35.1 | 36.14 | 37.83 | 35.67 | 36.12 | 36.79 | 37.85 |
TiO2 | 0.64 | 0.26 | 0.56 | 0.77 | 0.27 | 0.53 | 0.26 | 0.07 | 0.64 | 0.87 | 0.68 | 0.47 |
B2O3 | 10.67 * | 7.8 | 10.37 | 10.61 | 10.58 | 10.4 | 10.49 * | 10.82 * | 10.44 | 10.56 * | 10.66 * | 10.81 * |
Al2O3 | 33.12 | 35.42 | 29.14 | 33.69 | 33.38 | 31.55 | 31.91 | 33.9 | 34.16 | 32.52 | 32.29 | 31.46 |
V2O3 | 0.03 | na | 0.02 | 0.03 | 0.01 | 0.02 | Na | na | na | 0.04 | 0.06 | 0.14 |
Cr2O3 | 0.03 | na | 0 | 0 | 0 | 0 | Na | na | na | 0 | 0 | 0.08 |
Fe2O3 | na | 2.22 | 6.47 | 0.45 | 0.11 | 2.81 | Na | na | 0.69 | na | na | na |
FeO | 6.78 | 11.2 | 6.7 | 6.96 | 6.62 | 7.56 | 10.64 | 1.68 | 9.43 | 10.6 | 8.2 | 0.39 |
MnO | 0.03 | 0.12 | 0.13 | 0.06 | 0.02 | 0.07 | 0.06 | na | 0.1 | 0.03 | 0 | 0.03 |
ZnO | 0.02 | na | 0.07 | 0.06 | 0.04 | 0.04 | Na | na | na | na | na | 0.01 |
MgO | 6.34 | 2.1 | 5.52 | 5.5 | 6.3 | 5.67 | 5.12 | 9.49 | 3.41 | 4.31 | 6.08 | 11.02 |
CaO | 0.42 | 0.84 | 0.72 | 0.61 | 0.54 | 0.76 | 0.3 | 0.83 | 0.3 | 0.3 | 0.31 | 1.07 |
Na2O | 1.97 | 1.89 | 1.63 | 1.42 | 1.77 | 1.73 | 2.09 | 1.89 | 1.69 | 2.13 | 2.26 | 2.23 |
K2O | 0.03 | 0.46 | 0.14 | 0.24 | 0.1 | 0.07 | 0.02 | 0.02 | 0.08 | 0.05 | 0.09 | 0.02 |
F | 0 | 0.22 | 0.25 | 0.27 | 0.7 | 0.36 | 0.05 | na | 0.23 | 0.49 | 0.46 | 0.29 |
H2O | 3.66 * | 2.02 | 3.14 | 3.37 | 3.18 | 3.41 | 3.59 * | 3.31 * | 2.98 | 3.28 * | 3.23 * | 3.58 * |
Total | 100.2 | 100.19 | 100.47 | 100.25 | 100.12 | 100.08 | 100.67 | 99.84 | 99.82 | 101.3 | 101.11 | 99.45 |
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Kotowski, J.; Nejbert, K.; Olszewska-Nejbert, D. Tourmalines as a Tool in Provenance Studies of Terrigenous Material in Extra-Carpathian Albian (Uppermost Lower Cretaceous) Sands of Miechów Synclinorium, Southern Poland. Minerals 2020, 10, 917. https://doi.org/10.3390/min10100917
Kotowski J, Nejbert K, Olszewska-Nejbert D. Tourmalines as a Tool in Provenance Studies of Terrigenous Material in Extra-Carpathian Albian (Uppermost Lower Cretaceous) Sands of Miechów Synclinorium, Southern Poland. Minerals. 2020; 10(10):917. https://doi.org/10.3390/min10100917
Chicago/Turabian StyleKotowski, Jakub, Krzysztof Nejbert, and Danuta Olszewska-Nejbert. 2020. "Tourmalines as a Tool in Provenance Studies of Terrigenous Material in Extra-Carpathian Albian (Uppermost Lower Cretaceous) Sands of Miechów Synclinorium, Southern Poland" Minerals 10, no. 10: 917. https://doi.org/10.3390/min10100917